Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization
Abstract
Molecular weight distribution imposes considerable influence on the properties of polymers, making it an important parameter, impacting morphology and structural behavior of polymeric materials. Atom transfer radical polymerization (ATRP) has established itself as a powerful tool to prepare polymers with predetermined molecular weight, preserved chain-end functionality, and low dispersity. More recently, ATRP has also been shown to provide a means to deliberately broaden molecular weight distributions, and, via retaining living chain-ends, to enable the formation of block copolymers with designed block dispersity, featuring new microstructures and potentially attractive properties. Here, similar methodologies have been developed to facilitate tuning of the dispersity of polymeric brushes grown from nanoparticles thus resulting in hybrid materials with enhanced fracture toughness and high inorganic content. Recent advances have given access to brush architectures comprised of uni- and bimodal block copolymers with unique morphologies along with interesting mechanical, thermal, and optical properties.
- Authors:
-
- Carnegie Mellon University, Pittsburgh, PA (United States)
- Publication Date:
- Research Org.:
- Carnegie Mellon Univ., Pittsburgh, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1978818
- Alternate Identifier(s):
- OSTI ID: 1825783
- Grant/Contract Number:
- SC0018784
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polymer Chemistry
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 42; Journal ID: ISSN 1759-9954
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Polymer Science
Citation Formats
Yin, Rongguan, Wang, Zongyu, Bockstaller, Michael R., and Matyjaszewski, Krzysztof. Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization. United States: N. p., 2021.
Web. doi:10.1039/d1py01178b.
Yin, Rongguan, Wang, Zongyu, Bockstaller, Michael R., & Matyjaszewski, Krzysztof. Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization. United States. https://doi.org/10.1039/d1py01178b
Yin, Rongguan, Wang, Zongyu, Bockstaller, Michael R., and Matyjaszewski, Krzysztof. Wed .
"Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization". United States. https://doi.org/10.1039/d1py01178b. https://www.osti.gov/servlets/purl/1978818.
@article{osti_1978818,
title = {Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization},
author = {Yin, Rongguan and Wang, Zongyu and Bockstaller, Michael R. and Matyjaszewski, Krzysztof},
abstractNote = {Molecular weight distribution imposes considerable influence on the properties of polymers, making it an important parameter, impacting morphology and structural behavior of polymeric materials. Atom transfer radical polymerization (ATRP) has established itself as a powerful tool to prepare polymers with predetermined molecular weight, preserved chain-end functionality, and low dispersity. More recently, ATRP has also been shown to provide a means to deliberately broaden molecular weight distributions, and, via retaining living chain-ends, to enable the formation of block copolymers with designed block dispersity, featuring new microstructures and potentially attractive properties. Here, similar methodologies have been developed to facilitate tuning of the dispersity of polymeric brushes grown from nanoparticles thus resulting in hybrid materials with enhanced fracture toughness and high inorganic content. Recent advances have given access to brush architectures comprised of uni- and bimodal block copolymers with unique morphologies along with interesting mechanical, thermal, and optical properties.},
doi = {10.1039/d1py01178b},
journal = {Polymer Chemistry},
number = 42,
volume = 12,
place = {United States},
year = {Wed Oct 13 00:00:00 EDT 2021},
month = {Wed Oct 13 00:00:00 EDT 2021}
}
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