Selected Area Deposition of High Purity Gold for Functional 3D Architectures
Abstract
Selected area deposition of high purity gold films onto nanoscale 3D architectures is highly desirable as gold is conductive, inert, plasmonically active, and can be functionalized with thiol chemistries, which are useful in many biological applications. Here, we show that high-purity gold coatings can be selectively grown with the Me2Au (acac) precursor onto nanoscale 3D architectures via a pulsed laser pyrolytic chemical vapor deposition process. The selected area of deposition is achieved due to the high thermal resistance of the nanoscale geometries. Focused electron beam induced deposits (FEBID) and carbon nanofibers are functionalized with gold coatings, and we demonstrate the effects that laser irradiance, pulse width, and precursor pressure have on the growth rate. Furthermore, we demonstrate selected area deposition with a feature-targeting resolutions of ~100 and 5 µm, using diode lasers coupled to a multimode (915 nm) and single mode (785 nm) fiber optic, respectively. The experimental results are rationalized via finite element thermal modeling.
- Authors:
-
[1];
[1];
[2]
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); USDOE Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1973341
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanomaterials
- Additional Journal Information:
- Journal Volume: 13; Journal Issue: 4; Journal ID: ISSN 2079-4991
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; selected area deposition; chemical vapor deposition; laser heating; 3-dimensional nanostructures
Citation Formats
Lasseter, John, Rack, Philip D., and Randolph, Steven J. Selected Area Deposition of High Purity Gold for Functional 3D Architectures. United States: N. p., 2023.
Web. doi:10.3390/nano13040757.
Lasseter, John, Rack, Philip D., & Randolph, Steven J. Selected Area Deposition of High Purity Gold for Functional 3D Architectures. United States. https://doi.org/10.3390/nano13040757
Lasseter, John, Rack, Philip D., and Randolph, Steven J. Fri .
"Selected Area Deposition of High Purity Gold for Functional 3D Architectures". United States. https://doi.org/10.3390/nano13040757. https://www.osti.gov/servlets/purl/1973341.
@article{osti_1973341,
title = {Selected Area Deposition of High Purity Gold for Functional 3D Architectures},
author = {Lasseter, John and Rack, Philip D. and Randolph, Steven J.},
abstractNote = {Selected area deposition of high purity gold films onto nanoscale 3D architectures is highly desirable as gold is conductive, inert, plasmonically active, and can be functionalized with thiol chemistries, which are useful in many biological applications. Here, we show that high-purity gold coatings can be selectively grown with the Me2Au (acac) precursor onto nanoscale 3D architectures via a pulsed laser pyrolytic chemical vapor deposition process. The selected area of deposition is achieved due to the high thermal resistance of the nanoscale geometries. Focused electron beam induced deposits (FEBID) and carbon nanofibers are functionalized with gold coatings, and we demonstrate the effects that laser irradiance, pulse width, and precursor pressure have on the growth rate. Furthermore, we demonstrate selected area deposition with a feature-targeting resolutions of ~100 and 5 µm, using diode lasers coupled to a multimode (915 nm) and single mode (785 nm) fiber optic, respectively. The experimental results are rationalized via finite element thermal modeling.},
doi = {10.3390/nano13040757},
journal = {Nanomaterials},
number = 4,
volume = 13,
place = {United States},
year = {Fri Feb 17 00:00:00 EST 2023},
month = {Fri Feb 17 00:00:00 EST 2023}
}
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