High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

Jin, Baitang; Li, Shiguang; Liang, Xinhua

doi:10.1021/acs.iecr.1c03705

Title: High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

Abstract

In this study, highly dispersed nickel (Ni) nanoparticles (NPs) with an average particle size of 4.3 nm were uniformly deposited on the outer surface, the inner channel surface, and inside the pores of 20-cm long 4-channel α-Al₂O₃ hollow fibers (HFs) by atomic layer deposition (ALD) for dry reforming of methane (DRM). Cerium oxide (CeO₂) was added to promote the catalytic performance of Ni/Al₂O₃-HF catalysts. Rationally designed filling methods, by tuning the reactor size and inert fillings, can reduce the catalyst bed voidage in a fixed bed reactor for better reactant gas distribution, effectively utilize the Ni reactive sites, and achieve excellent catalytic performance. It was found that the CeO₂-promoted Ni/Al₂O₃-HF catalyst was highly active and highly stable without deactivation during an overall 400-hr DRM test at 850 ºC. CeO₂ with reversible valence states could participate in surface reactions; especially, the formation of CeAlO₃ provided sufficient surface Ce³⁺ for CO₂ activation and enhanced the stability and reusability of the HF catalysts.

Authors:

Jin, Baitang ^[1]; Li, Shiguang ^[2];

^[1]

Missouri Univ. of Science and Technology, Rolla, MO (United States)
Gas Technology Institute, Des Plaines, IL (United States)

Publication Date:: Tue Dec 14 00:00:00 EST 2021

Research Org.:: Gas Technology Institute, Des Plaines, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1968722

Grant/Contract Number:: FE0029760

Resource Type:: Accepted Manuscript

Journal Name:: Industrial and Engineering Chemistry Research

Additional Journal Information:: Journal Volume: 61; Journal Issue: 29; Journal ID: ISSN 0888-5885

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Atomic layer deposition; Catalysts; Deposition; Hydrocarbons; Precursors

Citation Formats


                    Jin, Baitang, Li, Shiguang, and Liang, Xinhua. High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane.  United States: N. p., 2021. 
Web.  doi:10.1021/acs.iecr.1c03705.

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                    Jin, Baitang, Li, Shiguang, & Liang, Xinhua. High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane.  United States.  https://doi.org/10.1021/acs.iecr.1c03705

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                    Jin, Baitang, Li, Shiguang, and Liang, Xinhua. Tue .  
"High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane".  United States.  https://doi.org/10.1021/acs.iecr.1c03705.  https://www.osti.gov/servlets/purl/1968722.

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@article{osti_1968722,

  title        = {High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane},

  author       = {Jin, Baitang and Li, Shiguang and Liang, Xinhua},

  abstractNote = {In this study, highly dispersed nickel (Ni) nanoparticles (NPs) with an average particle size of 4.3 nm were uniformly deposited on the outer surface, the inner channel surface, and inside the pores of 20-cm long 4-channel α-Al2O3 hollow fibers (HFs) by atomic layer deposition (ALD) for dry reforming of methane (DRM). Cerium oxide (CeO2) was added to promote the catalytic performance of Ni/Al2O3-HF catalysts. Rationally designed filling methods, by tuning the reactor size and inert fillings, can reduce the catalyst bed voidage in a fixed bed reactor for better reactant gas distribution, effectively utilize the Ni reactive sites, and achieve excellent catalytic performance. It was found that the CeO2-promoted Ni/Al2O3-HF catalyst was highly active and highly stable without deactivation during an overall 400-hr DRM test at 850 ºC. CeO2 with reversible valence states could participate in surface reactions; especially, the formation of CeAlO3 provided sufficient surface Ce3+ for CO2 activation and enhanced the stability and reusability of the HF catalysts.},

  doi          = {10.1021/acs.iecr.1c03705},

  journal      = {Industrial and Engineering Chemistry Research},

  number       = 29,

  volume       = 61,

  place        = {United States},

  year         = {Tue Dec 14 00:00:00 EST 2021},

  month        = {Tue Dec 14 00:00:00 EST 2021}

}

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Title: High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

Abstract

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Effect of Gd Promoter on the Structure and Catalytic Performance of Mesoporous Ni/Al 2 O 3 –CeO 2 in Dry Reforming of Methane journal, November 2018

Ni/CeO2–Al2O3 catalysts for the dry reforming of methane: The effect of CeAlO3 content and nickel crystallite size on catalytic activity and coke resistance journal, July 2015

Ni/CeO2 catalysts for methane partial oxidation: Synthesis driven structural and catalytic effects journal, July 2016

High-performance of nanostructured Ni/CeO2 catalyst on CO2 methanation journal, July 2020

High carbon-resistance Ni/CeAlO3-Al2O3 catalyst for CH4/CO2 reforming journal, June 2013

Characterization of ceria-coated alumina carrier journal, August 2002

Remarkable activity and stability of Ni catalyst supported on CeO2-Al2O3 via CeAlO3 perovskite towards glycerol steam reforming for hydrogen production journal, December 2017

Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen journal, March 2019

Synergy of Single-Atom Ni 1 and Ru 1 Sites on CeO 2 for Dry Reforming of CH 4 journal, April 2019

Dry reforming of methane by stable Ni–Mo nanocatalysts on single-crystalline MgO
journal, February 2020

Ni-based bimetallic heterogeneous catalysts for energy and environmental applications
journal, January 2016

Rightsizing carbon dioxide removal
journal, May 2017

A roadmap for rapid decarbonization
journal, March 2017

A review of dry (CO ₂ ) reforming of methane over noble metal catalysts
journal, January 2014

Nickel on alumina catalysts for the production of hydrogen rich mixtures via the biogas dry reforming reaction: Influence of the synthesis method
journal, August 2015

Syngas production via the biogas dry reforming reaction over nickel supported on modified with CeO 2 and/or La 2 O 3 alumina catalysts
journal, April 2016

An in depth investigation of deactivation through carbon formation during the biogas dry reforming reaction for Ni supported on modified with CeO2 and La2O3 zirconia catalysts
journal, October 2018

Cobalt carbide nanoprisms for direct production of lower olefins from syngas
journal, October 2016

The effect of synthesis gas composition on the Fischer–Tropsch synthesis over Co/γ-Al2O3 and Co–Re/γ-Al2O3 catalysts
journal, July 2007

An Introduction of CO ₂ Conversion by Dry Reforming with Methane and New Route of Low-Temperature Methanol Synthesis
journal, March 2013

Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst
journal, June 2017

Reforming of methane with carbon dioxide over cerium oxide promoted nickel nanoparticles deposited on 4-channel hollow fibers by atomic layer deposition
journal, January 2020

The catalytic methanation of coke oven gas over Ni-Ce/Al2O3 catalysts prepared by microwave heating: Effect of amorphous NiO formation
journal, March 2015

Synthesis gas production over highly active and stable nanostructured Ni MgO Al 2 O 3 catalysts in dry reforming of methane: Effects of Ni contents
journal, April 2017

Enhanced activity and stability of MgO-promoted Ni/Al2O3 catalyst for dry reforming of methane: Role of MgO
journal, January 2021

Dry reforming of methane over La2O2CO3-modified Ni/Al2O3 catalysts with moderate metal support interaction
journal, May 2020

Isotopic and kinetic assessment of the mechanism of reactions of CH4 with CO2 or H2O to form synthesis gas and carbon on nickel catalysts
journal, June 2004

Design of packed bed reactors: guides to catalyst shape, size, and loading selection
journal, April 2001

Optimizing catalyst supports at single catalyst pellet and packed bed reactor levels: A comparison study
journal, March 2021

Alumina-Supported Spinel NiAl ₂ O ₄ as a Catalyst for Re-forming Pyrolysis Gas
journal, May 2019

Highly active and stable Ni dispersed on mesoporous CeO2-Al2O3 catalysts for production of syngas by dry reforming of methane
journal, February 2021

Preparation and characterization of α-Al2O3 hollow fiber membranes with four-channel configuration
journal, January 2015

Effect of metal particle size on coking during CO2 reforming of CH4 over Ni–alumina aerogel catalysts
journal, May 2000

Uniform coating of TiO ₂ on high aspect ratio substrates with complex morphology by vertical forced-flow atomic layer deposition
journal, January 2017

Modification of ceramic membranes for pore structure tailoring: The atomic layer deposition route
journal, April 2012

Atomic layer deposition of Al 2 O 3 on porous polypropylene hollow fibers for enhanced membrane performances
journal, April 2018

Atomic Layer Deposition as a General Method Turns any 3D‐Printed Electrode into a Desired Catalyst: Case Study in Photoelectrochemisty
journal, May 2019

Nano-engineered nickel catalysts supported on 4-channel α-Al ₂ O ₃ hollow fibers for dry reforming of methane
journal, March 2018

Atomic layer deposition of iron(III) oxide on zirconia nanoparticles in a fluidized bed reactor using ferrocene and oxygen
journal, January 2009

Surface reactions during atomic layer deposition of Pt derived from gas phase infrared spectroscopy
journal, July 2009

Highly active and stable alumina supported nickel nanoparticle catalysts for dry reforming of methane
journal, February 2017

Synthesis and physicochemical characterizations of Ni/Al2O3–ZrO2 nanocatalyst prepared via impregnation method and treated with non-thermal plasma for CO2 reforming of CH4
journal, September 2013

Syngas production with dry reforming of methane over Ni/ZSM-5 catalysts
journal, July 2016

Carbon dioxide reforming of methane over Ni incorporated into Ce–ZrO2 catalysts
journal, November 2004

Carbon dioxide reforming of methane over Ni/Mo/SBA-15-La2O3 catalyst: Its characterization and catalytic performance
journal, September 2011

Synthesis, characterization and catalytic performance of MgO-coated Ni/SBA-15 catalysts for methane dry reforming to syngas and hydrogen
journal, August 2013

Methane dry reforming over Ni/Mg-Al-O: On the significant promotional effects of rare earth Ce and Nd metal oxides
journal, May 2018

MCM-41 supported nickel-based bimetallic catalysts with superior stability during carbon dioxide reforming of methane: Effect of strong metal–support interaction
journal, September 2009

Temperature-dependent anti-coking behaviors of highly stable Ni-CaO-ZrO 2 nanocomposite catalysts for CO 2 reforming of methane
journal, July 2017

Improved Effect of Fe on the Stable NiFe/Al ₂ O ₃ Catalyst in Low-Temperature Dry Reforming of Methane
journal, July 2020

Effect of Gd Promoter on the Structure and Catalytic Performance of Mesoporous Ni/Al ₂ O ₃ –CeO ₂ in Dry Reforming of Methane
journal, November 2018

Ni/CeO2–Al2O3 catalysts for the dry reforming of methane: The effect of CeAlO3 content and nickel crystallite size on catalytic activity and coke resistance
journal, July 2015

Ni/CeO2 catalysts for methane partial oxidation: Synthesis driven structural and catalytic effects
journal, July 2016

High-performance of nanostructured Ni/CeO2 catalyst on CO2 methanation
journal, July 2020

High carbon-resistance Ni/CeAlO3-Al2O3 catalyst for CH4/CO2 reforming
journal, June 2013

Characterization of ceria-coated alumina carrier
journal, August 2002

Remarkable activity and stability of Ni catalyst supported on CeO2-Al2O3 via CeAlO3 perovskite towards glycerol steam reforming for hydrogen production
journal, December 2017

Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen
journal, March 2019

Synergy of Single-Atom Ni ₁ and Ru ₁ Sites on CeO ₂ for Dry Reforming of CH ₄
journal, April 2019