Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates

Abstract

Interest in Criegee intermediates (CIs), often termed carbonyl oxides, and their role in tropospheric chemistry has grown massively since the demonstration of laboratory-based routes to their formation and characterization in the gas phase. This article reviews current knowledge regarding the electronic spectroscopy of atmospherically relevant CIs like CH2OO, CH3CHOO, (CH3)2COO and larger CIs like methyl vinyl ketone oxide and methacrolein oxide that are formed in the ozonolysis of isoprene, and of selected conjugated carbene-derived CIs of interest in the synthetic chemistry community. Of the aforementioned atmospherically relevant CIs, all except CH2OO and (CH3)2COO exist in different conformers which, under tropospheric conditions, can display strikingly different thermal loss rates via unimolecular and bimolecular processes. Calculated photolysis rates based on their absorption properties suggest that solar photolysis will rarely be a significant contributor to the total loss rate for any CI under tropospheric conditions. Nonetheless, there is ever-growing interest in the absorption cross sections and primary photochemistry of CIs following excitation to the strongly absorbing 1ππ* state, and how this varies with CI, with conformer and with excitation wavelength. Furthermore, the later part of this review surveys the photochemical data reported to date, including a range of studies that demonstrate prompt photo-inducedmore » fission of the terminal O–O bond, and speculates about possible alternate decay processes that could occur following non-adiabatic coupling to, and dissociation from, highly internally excited levels of the electronic ground state of a CI.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
+ Show Author Affiliations
  1. Univ. of Louisiana, Lafayette, LA (United States)
  2. Univ. of Pennsylvania, Philadelphia, PA (United States)
  3. Univ. of Bristol (United Kingdom)
Publication Date:
Research Org.:
Univ. of Pennsylvania, Philadelphia, PA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1903758
Grant/Contract Number:  
FG02-87ER13792; 2003422
Resource Type:
Accepted Manuscript
Journal Name:
Photochemistry and Photobiology
Additional Journal Information:
Journal Volume: 99; Journal Issue: 1; Journal ID: ISSN 0031-8655
Publisher:
The American Society of Photobiology
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Karsili, Tolga N. V., Marchetti, Barbara, Lester, Marsha I., and Ashfold, Michael N. R. Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates. United States: N. p., 2022. Web. doi:10.1111/php.13665.
Copy to clipboard
Karsili, Tolga N. V., Marchetti, Barbara, Lester, Marsha I., & Ashfold, Michael N. R. Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates. United States. https://doi.org/10.1111/php.13665
Copy to clipboard
Karsili, Tolga N. V., Marchetti, Barbara, Lester, Marsha I., and Ashfold, Michael N. R. Fri . "Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates". United States. https://doi.org/10.1111/php.13665. https://www.osti.gov/servlets/purl/1903758.
Copy to clipboard
@article{osti_1903758,
title = {Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates},
author = {Karsili, Tolga N. V. and Marchetti, Barbara and Lester, Marsha I. and Ashfold, Michael N. R.},
abstractNote = {Interest in Criegee intermediates (CIs), often termed carbonyl oxides, and their role in tropospheric chemistry has grown massively since the demonstration of laboratory-based routes to their formation and characterization in the gas phase. This article reviews current knowledge regarding the electronic spectroscopy of atmospherically relevant CIs like CH2OO, CH3CHOO, (CH3)2COO and larger CIs like methyl vinyl ketone oxide and methacrolein oxide that are formed in the ozonolysis of isoprene, and of selected conjugated carbene-derived CIs of interest in the synthetic chemistry community. Of the aforementioned atmospherically relevant CIs, all except CH2OO and (CH3)2COO exist in different conformers which, under tropospheric conditions, can display strikingly different thermal loss rates via unimolecular and bimolecular processes. Calculated photolysis rates based on their absorption properties suggest that solar photolysis will rarely be a significant contributor to the total loss rate for any CI under tropospheric conditions. Nonetheless, there is ever-growing interest in the absorption cross sections and primary photochemistry of CIs following excitation to the strongly absorbing 1ππ* state, and how this varies with CI, with conformer and with excitation wavelength. Furthermore, the later part of this review surveys the photochemical data reported to date, including a range of studies that demonstrate prompt photo-induced fission of the terminal O–O bond, and speculates about possible alternate decay processes that could occur following non-adiabatic coupling to, and dissociation from, highly internally excited levels of the electronic ground state of a CI.},
doi = {10.1111/php.13665},
journal = {Photochemistry and Photobiology},
number = 1,
volume = 99,
place = {United States},
year = {Fri Jun 17 00:00:00 EDT 2022},
month = {Fri Jun 17 00:00:00 EDT 2022}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1111/php.13665
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Gas-Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO 2
journal, September 2012

  • Berndt, Torsten; Jokinen, Tuija; Mauldin, Roy L.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 19
  • DOI: 10.1021/jz301158u

Kinetics of Unimolecular Decay of Methyl Vinyl Ketone Oxide, an Isoprene-Derived Criegee Intermediate, under Atmospherically Relevant Conditions
journal, November 2020

  • Lin, Yen-Hsiu; Yang, Chung-Hsin; Takahashi, Kaito
  • The Journal of Physical Chemistry A, Vol. 124, Issue 45
  • DOI: 10.1021/acs.jpca.0c07928

Direct Probing of Criegee Intermediates from Gas-Phase Ozonolysis Using Chemical Ionization Mass Spectrometry
journal, September 2017

  • Berndt, Torsten; Herrmann, Hartmut; Kurtén, Theo
  • Journal of the American Chemical Society, Vol. 139, Issue 38
  • DOI: 10.1021/jacs.7b05849

Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene
journal, January 2016

  • Nguyen, Tran B.; Tyndall, Geoffrey S.; Crounse, John D.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 15
  • DOI: 10.1039/C6CP00053C

Oxygen-17 and carbon-13 identification of the dimethyldioxirane intermediate arising in the reaction of potassium caroate with acetone
journal, February 1987

  • Cassidei, Luigi; Fiorentino, Michele; Mello, Rosella
  • The Journal of Organic Chemistry, Vol. 52, Issue 4
  • DOI: 10.1021/jo00380a045

Novel pathway of SO 2 oxidation in the atmosphere: reactions with monoterpene ozonolysis intermediates and secondary organic aerosol
journal, January 2018

  • Ye, Jianhuai; Abbatt, Jonathan P. D.; Chan, Arthur W. H.
  • Atmospheric Chemistry and Physics, Vol. 18, Issue 8
  • DOI: 10.5194/acp-18-5549-2018

CH Stretch Activation of CH 3 CHOO: Deep Tunneling to Hydroxyl Radical Products
journal, March 2019

  • Barber, Victoria P.; Pandit, Shubhrangshu; Esposito, Vincent J.
  • The Journal of Physical Chemistry A, Vol. 123, Issue 13
  • DOI: 10.1021/acs.jpca.8b12324

Preparation, properties, and reactions of carbonyl oxides
journal, May 1991

Criegee intermediates and their impacts on the troposphere
journal, January 2018

  • Khan, M. A. H.; Percival, C. J.; Caravan, R. L.
  • Environmental Science: Processes & Impacts, Vol. 20, Issue 3
  • DOI: 10.1039/C7EM00585G

Synthesis, Electronic Spectroscopy, and Photochemistry of Methacrolein Oxide: A Four-Carbon Unsaturated Criegee Intermediate from Isoprene Ozonolysis
journal, August 2019

  • Vansco, Michael F.; Marchetti, Barbara; Trongsiriwat, Nisalak
  • Journal of the American Chemical Society, Vol. 141, Issue 38
  • DOI: 10.1021/jacs.9b05193

Criegee intermediates: production, detection and reactivity
journal, July 2020

  • Chhantyal-Pun, Rabi; Khan, M. Anwar H.; Taatjes, Craig A.
  • International Reviews in Physical Chemistry, Vol. 39, Issue 3
  • DOI: 10.1080/0144235X.2020.1792104

Absolute Ultraviolet Absorption Spectrum of a Criegee Intermediate CH 2 OO
journal, November 2013

  • Sheps, Leonid
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 24
  • DOI: 10.1021/jz402191w

UV Photodissociation Dynamics of the CH 3 CHOO Criegee Intermediate: Action Spectroscopy and Velocity Map Imaging of O-Atom Products
journal, July 2015

  • Li, Hongwei; Fang, Yi; Kidwell, Nathanael M.
  • The Journal of Physical Chemistry A, Vol. 119, Issue 30
  • DOI: 10.1021/acs.jpca.5b05352

Reactions of criegee intermediates in the gas phase
journal, January 1994

Temperature- and Pressure-Dependent Kinetics of CH 2 OO + CH 3 COCH 3 and CH 2 OO + CH 3 CHO: Direct Measurements and Theoretical Analysis : TEMPERATURE- AND PRESSURE-DEPENDENT KINETICS OF CH
journal, May 2016

  • Elsamra, Rehab M. I.; Jalan, Amrit; Buras, Zachary J.
  • International Journal of Chemical Kinetics, Vol. 48, Issue 8
  • DOI: 10.1002/kin.21007

A Simple and Efficient Method for Simulating the Electronic Absorption Spectra of Criegee Intermediates: Benchmarking on CH 2 OO and CH 3 CHOO
journal, May 2021

  • McCoy, Julia C.; Marchetti, Barbara; Thodika, Mushir
  • The Journal of Physical Chemistry A, Vol. 125, Issue 19
  • DOI: 10.1021/acs.jpca.1c01074

Unimolecular dissociation dynamics of vibrationally activated CH3CHOO Criegee intermediates to OH radical products
journal, April 2016

  • Kidwell, Nathanael M.; Li, Hongwei; Wang, Xiaohong
  • Nature Chemistry, Vol. 8, Issue 5
  • DOI: 10.1038/nchem.2488

Role of Conical Intersections in Molecular Spectroscopy and Photoinduced Chemical Dynamics
journal, May 2012

Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes: 1. Ethene, trans -2-butene, and 2,3-dimethyl-2-butene
journal, December 2001

  • Hasson, Alam S.; Orzechowska, Grazyna; Paulson, Suzanne E.
  • Journal of Geophysical Research: Atmospheres, Vol. 106, Issue D24
  • DOI: 10.1029/2001JD000597

Dynamics of the reaction CH2I + O2 probed via infrared emission of CO, CO2, OH and H2CO
journal, January 2020

  • Chen, Ting-Yu; Lee, Yuan-Pern
  • Physical Chemistry Chemical Physics, Vol. 22, Issue 31
  • DOI: 10.1039/D0CP01940B

Direct experimental probing and theoretical analysis of the reaction between the simplest Criegee intermediate CH 2 OO and isoprene
journal, January 2017

  • Decker, Z. C. J.; Au, K.; Vereecken, L.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 12
  • DOI: 10.1039/C6CP08602K

Ultraviolet Spectrum and Photochemistry of the Simplest Criegee Intermediate CH 2 OO
journal, December 2012

  • Beames, Joseph M.; Liu, Fang; Lu, Lu
  • Journal of the American Chemical Society, Vol. 134, Issue 49
  • DOI: 10.1021/ja310603j

Formation of secondary aerosols from the ozonolysis of styrene: Effect of SO2 and H2O
journal, December 2017

A Computational Re-examination of the Criegee Intermediate–Sulfur Dioxide Reaction
journal, October 2015

  • Kuwata, Keith T.; Guinn, Emily J.; Hermes, Matthew R.
  • The Journal of Physical Chemistry A, Vol. 119, Issue 41
  • DOI: 10.1021/acs.jpca.5b06565

Sulfur Dioxide Modifies Aerosol Particle Formation and Growth by Ozonolysis of Monoterpenes and Isoprene
journal, April 2019

  • Stangl, Christopher M.; Krasnomowitz, Justin M.; Apsokardu, Michael J.
  • Journal of Geophysical Research: Atmospheres, Vol. 124, Issue 8
  • DOI: 10.1029/2018JD030064

Oxidation of Atmospheric SO2 by Products of the Ozone–Olefin Reaction
journal, April 1971

Modeling the Conformer-Dependent Electronic Absorption Spectra and Photolysis Rates of Methyl Vinyl Ketone Oxide and Methacrolein Oxide
journal, January 2022

  • McCoy, Julia C.; Léger, Spencer J.; Frey, Conrad F.
  • The Journal of Physical Chemistry A, Vol. 126, Issue 4
  • DOI: 10.1021/acs.jpca.1c08381

Surprisingly long lifetime of methacrolein oxide, an isoprene derived Criegee intermediate, under humid conditions
journal, February 2021

Insights into the Ultrafast Dynamics of CH 2 OO and CH 3 CHOO Following Excitation to the Bright 1 ππ* State: The Role of Singlet and Triplet States
journal, November 2021

  • Esposito, Vincent J.; Werba, Olivia; Bush, Sarah A.
  • Photochemistry and Photobiology, Vol. 98, Issue 4
  • DOI: 10.1111/php.13560

Night-time radical chemistry during the TORCH campaign
journal, June 2009

A new atmospherically relevant oxidant of sulphur dioxide
journal, August 2012

  • Mauldin III, R. L.; Berndt, T.; Sipilä, M.
  • Nature, Vol. 488, Issue 7410
  • DOI: 10.1038/nature11278

Carbonyl Oxides: Zwitterions or Diradicals?
journal, April 1990

  • Sander, Wolfram
  • Angewandte Chemie International Edition in English, Vol. 29, Issue 4
  • DOI: 10.1002/anie.199003441

Competition between H 2 O and (H 2 O) 2 reactions with CH 2 OO/CH 3 CHOO
journal, January 2016

  • Lin, Liang-Chun; Chang, Hung-Tzu; Chang, Chien-Hsun
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 6
  • DOI: 10.1039/C5CP06446E

Tunneling effects in the unimolecular decay of (CH 3 ) 2 COO Criegee intermediates to OH radical products
journal, April 2017

  • Fang, Yi; Barber, Victoria P.; Klippenstein, Stephen J.
  • The Journal of Chemical Physics, Vol. 146, Issue 13
  • DOI: 10.1063/1.4979297

Elucidating the molecular mechanisms of Criegee-amine chemistry in the gas phase and aqueous surface environments
journal, January 2019

  • Kumar, Manoj; Francisco, Joseph S.
  • Chemical Science, Vol. 10, Issue 3
  • DOI: 10.1039/C8SC03514H

Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol
journal, January 2017

  • Ng, Nga Lee; Brown, Steven S.; Archibald, Alexander T.
  • Atmospheric Chemistry and Physics, Vol. 17, Issue 3
  • DOI: 10.5194/acp-17-2103-2017

Spectrum simulation and decomposition with nuclear ensemble: formal derivation and application to benzene, furan and 2-phenylfuran
journal, June 2012

Photodissociation Dynamics of CH 2 OO on Multiple Potential Energy Surfaces: Experiment and Theory
journal, July 2021

  • Esposito, Vincent J.; Liu, Tianlin; Wang, Guanghan
  • The Journal of Physical Chemistry A, Vol. 125, Issue 30
  • DOI: 10.1021/acs.jpca.1c03643

Structure-dependent reactivity of Criegee intermediates studied with spectroscopic methods
journal, January 2017

  • Jr-Min Lin, Jim; Chao, Wen
  • Chemical Society Reviews, Vol. 46, Issue 24
  • DOI: 10.1039/C7CS00336F

The reaction of Criegee intermediate CH 2 OO with water dimer: primary products and atmospheric impact
journal, January 2017

  • Sheps, Leonid; Rotavera, Brandon; Eskola, Arkke J.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 33
  • DOI: 10.1039/C7CP03265J

Impact of the water dimer on the atmospheric reactivity of carbonyl oxides
journal, January 2016

  • Anglada, Josep M.; Solé, Albert
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 26
  • DOI: 10.1039/C6CP02531E

Oxidation of SO 2 by stabilized Criegee intermediate (sCI) radicals as a crucial source for atmospheric sulfuric acid concentrations
journal, January 2013

  • Boy, M.; Mogensen, D.; Smolander, S.
  • Atmospheric Chemistry and Physics, Vol. 13, Issue 7
  • DOI: 10.5194/acp-13-3865-2013

Velocity map imaging of O-atom products from UV photodissociation of the CH2OO Criegee intermediate
journal, June 2015

  • Li, Hongwei; Fang, Yi; Beames, Joseph M.
  • The Journal of Chemical Physics, Vol. 142, Issue 21
  • DOI: 10.1063/1.4921990

2H-Imidazol-2-one O-Oxide: A Criegee Intermediate from a σ0π2 Singlet Ground-State Carbene
journal, March 2022

  • Wagner, J. Philipp
  • Journal of the American Chemical Society, Vol. 144, Issue 13
  • DOI: 10.1021/jacs.1c13705

Absolute photodissociation cross sections of thermalized methyl vinyl ketone oxide and methacrolein oxide
journal, January 2022

  • Lin, Yen-Hsiu; Takahashi, Kaito; Lin, Jim Jr-Min
  • Physical Chemistry Chemical Physics, Vol. 24, Issue 17
  • DOI: 10.1039/D2CP00476C

Quantum dynamical investigation of the simplest Criegee intermediate CH 2 OO and its O–O photodissociation channels
journal, October 2014

  • Samanta, Kousik; Beames, Joseph M.; Lester, Marsha I.
  • The Journal of Chemical Physics, Vol. 141, Issue 13
  • DOI: 10.1063/1.4894746

Ozone, chemical reactivity and biological functions
journal, October 2018

Nascent energy distribution of the Criegee intermediate CH 2 OO from direct dynamics calculations of primary ozonide dissociation
journal, May 2018

  • Pfeifle, Mark; Ma, Yong-Tao; Jasper, Ahren W.
  • The Journal of Chemical Physics, Vol. 148, Issue 17
  • DOI: 10.1063/1.5028117

Observation of the simplest Criegee intermediate CH 2 OO in the gas-phase ozonolysis of ethylene
journal, March 2015

  • Womack, Caroline C.; Martin-Drumel, Marie-Aline; Brown, Gordon G.
  • Science Advances, Vol. 1, Issue 2
  • DOI: 10.1126/sciadv.1400105

The states that hide in the shadows: the potential role of conical intersections in the ground state unimolecular decay of a Criegee intermediate
journal, January 2022

  • Marchetti, Barbara; Esposito, Vincent J.; Bush, Rachel E.
  • Physical Chemistry Chemical Physics, Vol. 24, Issue 1
  • DOI: 10.1039/D1CP02601A

Velocity map imaging of OH radical products from IR activated (CH3)2COO Criegee intermediates
journal, September 2016

  • Li, Hongwei; Kidwell, Nathanael M.; Wang, Xiaohong
  • The Journal of Chemical Physics, Vol. 145, Issue 10
  • DOI: 10.1063/1.4962361

Full-Dimensional Potential Energy Surface and Ro-vibrational Levels of Dioxirane
journal, October 2015

Experimental and computational studies of Criegee intermediate reactions with NH 3 and CH 3 NH 2
journal, January 2019

  • Chhantyal-Pun, Rabi; Shannon, Robin J.; Tew, David P.
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 26
  • DOI: 10.1039/C8CP06810K

Relatively Selective Production of the Simplest Criegee Intermediate in a CH 4 /O 2 Electric Discharge: Kinetic Analysis of a Plausible Mechanism
journal, November 2014

  • Nguyen, Thanh Lam; McCarthy, Michael C.; Stanton, John F.
  • The Journal of Physical Chemistry A, Vol. 119, Issue 28
  • DOI: 10.1021/jp510554g

Vector correlations in photodissociation dynamics
journal, October 1987

  • Houston, Paul L.
  • The Journal of Physical Chemistry, Vol. 91, Issue 21
  • DOI: 10.1021/j100305a003

Four-Carbon Criegee Intermediate from Isoprene Ozonolysis: Methyl Vinyl Ketone Oxide Synthesis, Infrared Spectrum, and OH Production
journal, July 2018

  • Barber, Victoria P.; Pandit, Shubhrangshu; Green, Amy M.
  • Journal of the American Chemical Society, Vol. 140, Issue 34
  • DOI: 10.1021/jacs.8b06010

Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications
journal, March 2014

  • Welz, Oliver; Eskola, Arkke J.; Sheps, Leonid
  • Angewandte Chemie International Edition, Vol. 53, Issue 18
  • DOI: 10.1002/anie.201400964

Products of Criegee intermediate reactions with NO 2 : experimental measurements and tropospheric implications
journal, January 2017

  • Caravan, Rebecca L.; Khan, M. Anwar H.; Rotavera, Brandon
  • Faraday Discussions, Vol. 200
  • DOI: 10.1039/C7FD00007C

UV spectroscopic characterization of an alkyl substituted Criegee intermediate CH 3 CHOO
journal, June 2013

  • Beames, Joseph M.; Liu, Fang; Lu, Lu
  • The Journal of Chemical Physics, Vol. 138, Issue 24
  • DOI: 10.1063/1.4810865

Adventures in ozoneland: down the rabbit-hole
journal, January 2011

  • Donahue, Neil M.; Drozd, Greg T.; Epstein, Scott A.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 23
  • DOI: 10.1039/c0cp02564j

The physical chemistry of Criegee intermediates in the gas phase
journal, July 2015

Infrared Detection of Criegee Intermediates Formed during the Ozonolysis of β-Pinene and Their Reactivity towards Sulfur Dioxide
journal, January 2014

  • Ahrens, Jennifer; Carlsson, Philip T. M.; Hertl, Nils
  • Angewandte Chemie International Edition, Vol. 53, Issue 3
  • DOI: 10.1002/anie.201307327

Spectroscopy of the Simplest Criegee Intermediate CH 2 OO: Simulation of the First Bands in Its Electronic and Photoelectron Spectra
journal, August 2012

  • Lee, Edmond P. F.; Mok, Daniel K. W.; Shallcross, Dudley E.
  • Chemistry - A European Journal, Vol. 18, Issue 39
  • DOI: 10.1002/chem.201200848

Temperature and isotope effects in the reaction of CH 3 CHOO with methanol
journal, January 2019

  • Chao, Wen; Lin, Yen-Hsiu; Yin, Cangtao
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 25
  • DOI: 10.1039/C9CP02534K

Temperature-Dependent Rate Coefficient for the Reaction of CH 3 SH with the Simplest Criegee Intermediate
journal, April 2019

  • Li, Yu-Lin; Lin, Yen-Hsiu; Yin, Cangtao
  • The Journal of Physical Chemistry A, Vol. 123, Issue 19
  • DOI: 10.1021/acs.jpca.8b12553

Effects of water vapor on the reaction of CH 2 OO with NH 3
journal, January 2019

  • Chao, Wen; Yin, Cangtao; Takahashi, Kaito
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 40
  • DOI: 10.1039/C9CP04682H

Kinetics of a Criegee intermediate that would survive high humidity and may oxidize atmospheric SO 2
journal, August 2015

  • Huang, Hao-Li; Chao, Wen; Lin, Jim Jr-Min
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 35
  • DOI: 10.1073/pnas.1513149112

A theoretical study of the reactions of parent and substituted Criegee intermediates with water and the water dimer
journal, January 2004

  • Ryzhkov, Andrew B.; Ariya, Parisa A.
  • Physical Chemistry Chemical Physics, Vol. 6, Issue 21
  • DOI: 10.1039/b408414d

Dynamics Insight into Isomerization and Dissociation of Hot Criegee Intermediate CH3CHOO
journal, January 2019

  • Wang, Zhiping; Dyakov, Yuri A.; Bu, Yuxiang
  • The Journal of Physical Chemistry A, Vol. 123, Issue 5
  • DOI: 10.1021/acs.jpca.8b11908

Temperature dependence of the reaction of anti-CH 3 CHOO with water vapor
journal, January 2016

  • Lin, Liang-Chun; Chao, Wen; Chang, Chun-Hung
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 40
  • DOI: 10.1039/C6CP05171E

Theoretical study of photochemical processes involving singlet excited states of formaldehyde carbonyl oxide in the atmosphere
journal, December 2002

Recent Advances and Perspectives on Nonadiabatic Mixed Quantum–Classical Dynamics
journal, April 2018

Direct Determination of the Simplest Criegee Intermediate (CH 2 OO) Self Reaction Rate
journal, June 2014

  • Buras, Zachary J.; Elsamra, Rehab M. I.; Green, William H.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
  • DOI: 10.1021/jz5008406

Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO
journal, April 2013

Photodissociation dynamics of methyl vinyl ketone oxide: A four-carbon unsaturated Criegee intermediate from isoprene ozonolysis
journal, November 2021

  • Wang, Guanghan; Liu, Tianlin; Caracciolo, Adriana
  • The Journal of Chemical Physics, Vol. 155, Issue 17
  • DOI: 10.1063/5.0068664

Reaction of diphenylmethylene and phenylmethylene with oxygen. A matrix isolation study
journal, January 1989

  • Sander, Wolfram W.
  • The Journal of Organic Chemistry, Vol. 54, Issue 2
  • DOI: 10.1021/jo00263a014

Theoretical studies of atmospheric reaction mechanisms in the troposphere
journal, January 2012

  • Vereecken, Luc; Francisco, Joseph S.
  • Chemical Society Reviews, Vol. 41, Issue 19
  • DOI: 10.1039/c2cs35070j

Efficiency of Anti-Stokes Fluorescence in Dyes
journal, June 1933

Direct Kinetic Measurements of Reactions between the Simplest Criegee Intermediate CH 2 OO and Alkenes
journal, March 2014

  • Buras, Zachary J.; Elsamra, Rehab M. I.; Jalan, Amrit
  • The Journal of Physical Chemistry A, Vol. 118, Issue 11
  • DOI: 10.1021/jp4118985

The Pressure Dependence of the OH Radical Yield from Ozone−Alkene Reactions
journal, August 2000

  • Fenske, Jill D.; Hasson, Alam S.; Paulson, Suzanne E.
  • The Journal of Physical Chemistry A, Vol. 104, Issue 33
  • DOI: 10.1021/jp001100u

Atmospheric Fate of Criegee Intermediate Formed During Ozonolysis of Styrene in the Presence of H 2 O and NH 3 : The Crucial Role of Stereochemistry
journal, September 2018

  • Banu, Tahamida; Sen, Kaushik; Das, Abhijit K.
  • The Journal of Physical Chemistry A, Vol. 122, Issue 42
  • DOI: 10.1021/acs.jpca.8b06835

Kinetics of the unimolecular reaction of CH 2 OO and the bimolecular reactions with the water monomer, acetaldehyde and acetone under atmospheric conditions
journal, January 2015

  • Berndt, Torsten; Kaethner, Ralf; Voigtländer, Jens
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 30
  • DOI: 10.1039/C5CP02224J

Atmospheric isoprene ozonolysis: impacts of stabilised Criegee intermediate reactions with SO 2 , H 2 O and dimethyl sulfide
journal, January 2015

  • Newland, M. J.; Rickard, A. R.; Vereecken, L.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 16
  • DOI: 10.5194/acp-15-9521-2015

A new approach to determine the absolute photodissociation cross section of molecules in a cell
journal, September 2021

  • Lin, Yen‐Hsiu; Lin, Jim Jr‐Min
  • Journal of the Chinese Chemical Society, Vol. 69, Issue 1
  • DOI: 10.1002/jccs.202100336

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates
journal, November 2020

  • Cox, R. Anthony; Ammann, Markus; Crowley, John N.
  • Atmospheric Chemistry and Physics, Vol. 20, Issue 21
  • DOI: 10.5194/acp-20-13497-2020

NO3 radical production from the reaction between the Criegee intermediate CH2OO and NO2
journal, January 2013

  • Ouyang, Bin; McLeod, Matthew W.; Jones, Roderic L.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 40
  • DOI: 10.1039/c3cp53024h

Hydrogen-Bonding Mediated Reactions of Criegee Intermediates in the Gas Phase: Competition between Bimolecular and Termolecular Reactions and the Catalytic Role of Water
journal, September 2019

  • Chao, Wen; Yin, Cangtao; Takahashi, Kaito
  • The Journal of Physical Chemistry A, Vol. 123, Issue 39
  • DOI: 10.1021/acs.jpca.9b07117

Effects of stabilized Criegee intermediates (sCIs) on sulfate formation: a sensitivity analysis during summertime in Beijing–Tianjin–Hebei (BTH), China
journal, October 2019

The reaction of Criegee intermediates with NO, RO2, and SO2, and their fate in the atmosphere
journal, January 2012

  • Vereecken, L.; Harder, H.; Novelli, A.
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 42
  • DOI: 10.1039/c2cp42300f

Detailed mechanism of the CH 2 I + O 2 reaction: Yield and self-reaction of the simplest Criegee intermediate CH 2 OO
journal, September 2014

  • Ting, Wei-Lun; Chang, Chun-Hung; Lee, Yu-Fang
  • The Journal of Chemical Physics, Vol. 141, Issue 10
  • DOI: 10.1063/1.4894405

The UV absorption spectrum of the simplest Criegee intermediate CH 2 OO
journal, January 2014

  • Ting, Wei-Lun; Chen, Ying-Hsuan; Chao, Wen
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 22
  • DOI: 10.1039/C4CP00877D

Dioxiranes: synthesis and reactions of methyldioxiranes
journal, August 1985

  • Murray, Robert W.; Jeyaraman, Ramasubbu
  • The Journal of Organic Chemistry, Vol. 50, Issue 16
  • DOI: 10.1021/jo00216a007

Limits of the Nuclear Ensemble Method for Electronic Spectra Simulations: Temperature Dependence of the ( E )-Azobenzene Spectrum
journal, August 2020

  • Sršeň, Štěpán; Sita, Jaroslav; Slavíček, Petr
  • Journal of Chemical Theory and Computation, Vol. 16, Issue 10
  • DOI: 10.1021/acs.jctc.0c00579

Computational Chemical Kinetics for the Reaction of Criegee Intermediate CH 2 OO with HNO 3 and Its Catalytic Conversion to OH and HCO
journal, May 2017

  • Raghunath, P.; Lee, Yuan-Pern; Lin, M. C.
  • The Journal of Physical Chemistry A, Vol. 121, Issue 20
  • DOI: 10.1021/acs.jpca.7b02196

UV Spectroscopic Characterization of Dimethyl- and Ethyl-Substituted Carbonyl Oxides
journal, March 2014

  • Liu, Fang; Beames, Joseph M.; Green, Amy M.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 12
  • DOI: 10.1021/jp412726z

UV absorption spectrum of the C2 Criegee intermediate CH 3 CHOO
journal, August 2014

  • Smith, Mica C.; Ting, Wei-Lun; Chang, Chun-Hung
  • The Journal of Chemical Physics, Vol. 141, Issue 7
  • DOI: 10.1063/1.4892582

CH2 + O2: reaction mechanism, biradical and zwitterionic character, and formation of CH2OO, the simplest Criegee intermediate
journal, January 2022

  • Mazarei, Elham; Barker, John R.
  • Physical Chemistry Chemical Physics, Vol. 24, Issue 2
  • DOI: 10.1039/D1CP04372B

The Role of   * Excited States in the Photodissociation of Heteroaromatic Molecules
journal, June 2006

Communication: Ultraviolet photodissociation dynamics of the simplest Criegee intermediate CH 2 OO
journal, October 2013

  • Lehman, Julia H.; Li, Hongwei; Beames, Joseph M.
  • The Journal of Chemical Physics, Vol. 139, Issue 14
  • DOI: 10.1063/1.4824655

Role of Criegee Intermediates in Secondary Sulfate Aerosol Formation in Nocturnal Power Plant Plumes in the Southeast US
journal, February 2019

Electronic spectroscopy of methyl vinyl ketone oxide: A four-carbon unsaturated Criegee intermediate from isoprene ozonolysis
journal, December 2018

  • Vansco, Michael F.; Marchetti, Barbara; Lester, Marsha I.
  • The Journal of Chemical Physics, Vol. 149, Issue 24
  • DOI: 10.1063/1.5064716

Criegee Intermediates Beyond Ozonolysis: Synthetic and Mechanistic Insights
journal, March 2021

  • Hassan, Zahid; Stahlberger, Mareen; Rosenbaum, Nicolai
  • Angewandte Chemie International Edition, Vol. 60, Issue 28
  • DOI: 10.1002/anie.202014974

Atmospheric Formation of OH Radicals and H2O2 from Alkene Ozonolysis under Humid Conditions
journal, February 2002

UV absorption spectrum and photodissociation dynamics of CH2OO following excitation to the B1 A′ state
journal, July 2021

Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years
journal, January 2014

  • Sindelarova, K.; Granier, C.; Bouarar, I.
  • Atmospheric Chemistry and Physics, Vol. 14, Issue 17
  • DOI: 10.5194/acp-14-9317-2014

Two Pathways for Dissociation of Highly Energized syn-CH3CHOO to OH Plus Vinoxy
journal, August 2016

Fourier-transform microwave spectroscopy of an alkyl substituted Criegee intermediate anti-CH3CHOO
journal, April 2015

How big is the substituent dependence of the solar photolysis rate of Criegee intermediates?
journal, January 2018

  • Yin, Cangtao; Takahashi, Kaito
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 23
  • DOI: 10.1039/C8CP02015A

Ozonolysis Fragment Quenching by Nitrate Formation:  The Pressure Dependence of Prompt OH Radical Formation
journal, October 2004

  • Presto, Albert A.; Donahue, Neil M.
  • The Journal of Physical Chemistry A, Vol. 108, Issue 42
  • DOI: 10.1021/jp047162s

Atmospheric Chemistry of CH2OO: The Hydrolysis of CH2OO in Small Clusters of Sulfuric Acid
journal, March 2021

  • Wang, Rui; Wen, Mingjie; Chen, Xu
  • The Journal of Physical Chemistry A, Vol. 125, Issue 12
  • DOI: 10.1021/acs.jpca.1c02006

Total radical yields from tropospheric ethene ozonolysis
journal, January 2011

  • Alam, Mohammed S.; Camredon, Marie; Rickard, Andrew R.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 23
  • DOI: 10.1039/c0cp02342f

Radical Product Yields from the Ozonolysis of Short Chain Alkenes under Atmospheric Boundary Layer Conditions
journal, November 2013

  • Alam, Mohammed S.; Rickard, Andrew R.; Camredon, Marie
  • The Journal of Physical Chemistry A, Vol. 117, Issue 47
  • DOI: 10.1021/jp408745h

Absolute UV absorption cross sections of dimethyl substituted Criegee intermediate (CH 3 ) 2 COO
journal, June 2016

Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate
journal, April 2020

  • Caravan, Rebecca L.; Vansco, Michael F.; Au, Kendrew
  • Proceedings of the National Academy of Sciences, Vol. 117, Issue 18
  • DOI: 10.1073/pnas.1916711117

High resolution absolute absorption cross sections of the B̃ 1 A′–X̃ 1 A′ transition of the CH 2 OO biradical
journal, January 2015

  • Foreman, Elizabeth S.; Kapnas, Kara M.; Jou, YiTien
  • Phys. Chem. Chem. Phys., Vol. 17, Issue 48
  • DOI: 10.1039/C5CP04977F

Effects of the substituents on the reactivity of carbonyl oxides. A theoretical study on the reaction of substituted carbonyl oxides with water
journal, January 2011

  • Anglada, J. M.; González, J.; Torrent-Sucarrat, M.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 28
  • DOI: 10.1039/c1cp20872a

Reaction of diphenylcarbene with oxygen: a laser flash photolysis study
journal, November 1984

  • Werstiuk, N. H.; Casal, H. L.; Scaiano, J. C.
  • Canadian Journal of Chemistry, Vol. 62, Issue 11
  • DOI: 10.1139/v84-410

Prompt release of O 1 D products upon UV excitation of CH 2 OO Criegee intermediates
journal, July 2017

  • Vansco, Michael F.; Li, Hongwei; Lester, Marsha I.
  • The Journal of Chemical Physics, Vol. 147, Issue 1
  • DOI: 10.1063/1.4977987

UV absorption of Criegee intermediates: quantitative cross sections from high-level ab initio theory
journal, January 2018

  • Sršeň, Š.; Hollas, D.; Slavíček, P.
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 9
  • DOI: 10.1039/C8CP00199E

Unimolecular Decomposition Rate of the Criegee Intermediate (CH 3 ) 2 COO Measured Directly with UV Absorption Spectroscopy
journal, February 2016

  • Smith, Mica C.; Chao, Wen; Takahashi, Kaito
  • The Journal of Physical Chemistry A, Vol. 120, Issue 27
  • DOI: 10.1021/acs.jpca.5b12124

Direct kinetic measurement of the reaction of the simplest Criegee intermediate with water vapor
journal, January 2015

Measuring Rate Constants for Reactions of the Simplest Criegee Intermediate (CH 2 OO) by Monitoring the OH Radical
journal, January 2014

  • Liu, Yingdi; Bayes, Kyle D.; Sander, Stanley P.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 4
  • DOI: 10.1021/jp407058b

Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH 3 ) 2 COO
journal, December 2016

  • Chhantyal-Pun, Rabi; Welz, Oliver; Savee, John D.
  • The Journal of Physical Chemistry A, Vol. 121, Issue 1
  • DOI: 10.1021/acs.jpca.6b07810

Unimolecular Decay of Criegee Intermediates to OH Radical Products: Prompt and Thermal Decay Processes
journal, March 2018

A kinetic study of the CH 2 OO Criegee intermediate self-reaction, reaction with SO 2 and unimolecular reaction using cavity ring-down spectroscopy
journal, January 2015

  • Chhantyal-Pun, Rabi; Davey, Anthony; Shallcross, Dudley E.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 5
  • DOI: 10.1039/C4CP04198D

The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere
journal, January 2008

  • Johnson, David; Marston, George
  • Chemical Society Reviews, Vol. 37, Issue 4
  • DOI: 10.1039/b704260b

Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2
journal, January 2012

TIME-RESOLVED ABSORPTION SPECTROSCOPIC DETECTION OF 10,10-DIMETHYL-10-SILAANTHRACEN-9(10H)-ONE OXIDE
journal, August 1983

  • Sugawara, Tadashi; Iwamura, Hiizu; Hayashi, Hisaharu
  • Chemistry Letters, Vol. 12, Issue 8
  • DOI: 10.1246/cl.1983.1261

Direct measurement of Criegee intermediate (CH2OO) reactions with acetone, acetaldehyde, and hexafluoroacetone
journal, January 2012

  • Taatjes, Craig A.; Welz, Oliver; Eskola, Arkke J.
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 30
  • DOI: 10.1039/c2cp40294g

Dynamics and spectroscopy of CH 2 OO excited electronic states
journal, January 2016

  • Kalinowski, Jaroslaw; Foreman, Elizabeth S.; Kapnas, Kara M.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 16
  • DOI: 10.1039/C6CP00807K

Reactions between Criegee Intermediates and the Inorganic Acids HCl and HNO 3 : Kinetics and Atmospheric Implications
journal, July 2016

  • Foreman, Elizabeth S.; Kapnas, Kara M.; Murray, Craig
  • Angewandte Chemie International Edition, Vol. 55, Issue 35
  • DOI: 10.1002/anie.201604662

Experimental Evidence of Dioxole Unimolecular Decay Pathway for Isoprene-Derived Criegee Intermediates
journal, April 2020

  • Vansco, Michael F.; Caravan, Rebecca L.; Zuraski, Kristen
  • The Journal of Physical Chemistry A, Vol. 124, Issue 18
  • DOI: 10.1021/acs.jpca.0c02138

Propinal O-oxide
journal, May 1994

Direct Kinetic and Atmospheric Modeling Studies of Criegee Intermediate Reactions with Acetone
journal, August 2019

Chemiluminescence from arylcarbene oxidation: Phenylchlorocarbene and (2-chlorophenyl)carbene
journal, January 1987

P-Benzoquinone O-oxide
journal, April 1988

  • Sander, Wolfram W.
  • The Journal of Organic Chemistry, Vol. 53, Issue 9
  • DOI: 10.1021/jo00244a045

Temperature-Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates
journal, June 2017

  • Chhantyal-Pun, Rabi; McGillen, Max R.; Beames, Joseph M.
  • Angewandte Chemie International Edition, Vol. 56, Issue 31
  • DOI: 10.1002/anie.201703700

UV Spectrum of the Simplest Deuterated Criegee Intermediate CD 2 OO : UV Spectrum of CD
journal, March 2017

  • Ting, Allen Wei-Lun; Lin, Jim Jr-Min
  • Journal of the Chinese Chemical Society, Vol. 64, Issue 4
  • DOI: 10.1002/jccs.201700049

Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact
journal, December 2019

Extremely rapid self-reaction of the simplest Criegee intermediate CH2OO and its implications in atmospheric chemistry
journal, March 2014

  • Su, Yu-Te; Lin, Hui-Yu; Putikam, Raghunath
  • Nature Chemistry, Vol. 6, Issue 6
  • DOI: 10.1038/nchem.1890

The importance of water clusters (H2O)n (n=2,…,4) in the reaction of Criegee intermediate with water in the atmosphere
journal, February 2006

UV Absorption Spectrum and Photodissociation Channels of the Simplest Criegee Intermediate (CH 2 OO)
journal, December 2014

  • Dawes, Richard; Jiang, Bin; Guo, Hua
  • Journal of the American Chemical Society, Vol. 137, Issue 1
  • DOI: 10.1021/ja510736d

Spectral and chemical properties of dimethyldioxirane as determined by experiment and ab initio calculations
journal, June 1987

  • Adam, Waldemar; Chan, Yuk Yee; Cremer, Dieter
  • The Journal of Organic Chemistry, Vol. 52, Issue 13
  • DOI: 10.1021/jo00389a029

Criegee Intermediate–Alcohol Reactions, A Potential Source of Functionalized Hydroperoxides in the Atmosphere
journal, December 2017

New theoretical investigations of the photodissociation of ozone in the Hartley, Huggins, Chappuis, and Wulf bands
journal, January 2007

  • Grebenshchikov, S. Yu.; Qu, Z. -W.; Zhu, H.
  • Physical Chemistry Chemical Physics, Vol. 9, Issue 17
  • DOI: 10.1039/b701020f

Kinetics of IO Production in the CH 2 I + O 2 Reaction Studied by Cavity Ring-Down Spectroscopy
journal, August 2015

  • Foreman, Elizabeth S.; Murray, Craig
  • The Journal of Physical Chemistry A, Vol. 119, Issue 34
  • DOI: 10.1021/acs.jpca.5b05058

Atmospheric Chemistry of Criegee Intermediates: Unimolecular Reactions and Reactions with Water
journal, October 2016

  • Long, Bo; Bao, Junwei Lucas; Truhlar, Donald G.
  • Journal of the American Chemical Society, Vol. 138, Issue 43
  • DOI: 10.1021/jacs.6b08655

An Extended Computational Study of Criegee Intermediate–Alcohol Reactions
journal, December 2018

  • Watson, Nathan A. I.; Black, Joshua A.; Stonelake, Thomas M.
  • The Journal of Physical Chemistry A, Vol. 123, Issue 1
  • DOI: 10.1021/acs.jpca.8b09349

Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates
journal, January 2017

  • Vereecken, L.; Novelli, A.; Taraborrelli, D.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 47
  • DOI: 10.1039/C7CP05541B

An experimental and theoretical study on rotational constants of vibrationally excited CH2OO
journal, February 2015

Reaction of bicyclo[6.3.0]undeca-2,4,6,8,11-pentaen-10-ylidene in oxygen-doped matrixes: characterization of the first carbonyl oxide with a .pi.-donating ring system
journal, July 1990

  • Murata, Shigeru; Tomioka, Hideo; Kawase, Takeshi
  • The Journal of Organic Chemistry, Vol. 55, Issue 15
  • DOI: 10.1021/jo00302a003

UV absorption probing of the conformer-dependent reactivity of a Criegee intermediate CH 3 CHOO
journal, January 2014

  • Sheps, Leonid; Scully, Ashley M.; Au, Kendrew
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 48
  • DOI: 10.1039/C4CP04408H

Open questions on the reactivity of Criegee intermediates
journal, March 2021

  • Caravan, Rebecca L.; Vansco, Michael F.; Lester, Marsha I.
  • Communications Chemistry, Vol. 4, Issue 1
  • DOI: 10.1038/s42004-021-00483-5

Investigation of the thermal and photochemical reactions of ozone with styrene in argon and krypton matrices
journal, September 2012

Mechanisms of gas-phase and liquid-phase ozonolysis
journal, November 1978

  • Harding, Lawrence B.; Goddard, William A.
  • Journal of the American Chemical Society, Vol. 100, Issue 23
  • DOI: 10.1021/ja00491a010

Kinetics of CH 2 OO reactions with SO 2 , NO 2 , NO, H 2 O and CH 3 CHO as a function of pressure
journal, January 2014

  • Stone, Daniel; Blitz, Mark; Daubney, Laura
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 3
  • DOI: 10.1039/C3CP54391A

Direct evidence for a substantive reaction between the Criegee intermediate, CH 2 OO, and the water vapour dimer
journal, January 2015

  • Lewis, Tom R.; Blitz, Mark A.; Heard, Dwayne E.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 7
  • DOI: 10.1039/C4CP04750H

Theoretical Study of the Reaction of Carbonyl Oxide with Nitrogen Dioxide: CH 2 OO + NO 2 : THEORETICAL STUDY OF THE REACTION OF CARBONYL OXIDE WITH NITROGEN DIOXIDE
journal, August 2017

  • Vereecken, L.; Nguyen, H. M. T.
  • International Journal of Chemical Kinetics, Vol. 49, Issue 10
  • DOI: 10.1002/kin.21112

Gas-Phase Ozonolysis of Alkenes:  Formation of OH from Anti Carbonyl Oxides
journal, July 2002

  • Kroll, Jesse H.; Donahue, Neil M.; Cee, Victor J.
  • Journal of the American Chemical Society, Vol. 124, Issue 29
  • DOI: 10.1021/ja0266060

Absolute Infrared Absorption Cross Section of the Simplest Criegee Intermediate Near 1285.7 cm –1
journal, October 2018

  • Chang, Yuan-Pin; Li, Yu-Lin; Liu, Meng-Ling
  • The Journal of Physical Chemistry A, Vol. 122, Issue 45
  • DOI: 10.1021/acs.jpca.8b06759

Free radical modelling studies during the UK TORCH Campaign in Summer 2003
journal, January 2007

  • Emmerson, K. M.; Carslaw, N.; Carslaw, D. C.
  • Atmospheric Chemistry and Physics, Vol. 7, Issue 1
  • DOI: 10.5194/acp-7-167-2007

Unimolecular reaction of acetone oxide and its reaction with water in the atmosphere
journal, May 2018

  • Long, Bo; Bao, Junwei Lucas; Truhlar, Donald G.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 24
  • DOI: 10.1073/pnas.1804453115

CH2OO Criegee intermediate UV absorption cross-sections and kinetics of CH2OO + CH2OO and CH2OO + I as a function of pressure
journal, January 2020

  • Mir, Zara S.; Lewis, Thomas R.; Onel, Lavinia
  • Physical Chemistry Chemical Physics, Vol. 22, Issue 17
  • DOI: 10.1039/D0CP00988A

Imaging the dynamics of gas phase reactions
journal, January 2006

  • Ashfold, Michael N. R.; Nahler, N. Hendrik; Orr-Ewing, Andrew J.
  • Phys. Chem. Chem. Phys., Vol. 8, Issue 1
  • DOI: 10.1039/B509304J

Substituent effects on the spectroscopic properties of Criegee intermediates
journal, October 2017

  • Trabelsi, Tarek; Kumar, Manoj; Francisco, Joseph S.
  • The Journal of Chemical Physics, Vol. 147, Issue 16
  • DOI: 10.1063/1.4998170

Criegee Intermediate Reactions with Carboxylic Acids: A Potential Source of Secondary Organic Aerosol in the Atmosphere
journal, June 2018

    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: