Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes

Tsai, Hsinhan; Huang, Hsin‐Hsiang; Watt, John; Hou, Cheng‐Hung; Strzalka, Joseph; Shyue, Jing‐Jong; Wang, Leeyih; Nie, Wanyi

doi:10.1002/advs.202105850

Title: Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes

Authors:

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^[3];

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Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of California, Berkeley, CA (United States)
National Taiwan Univ., Taipei (Taiwan)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Academia Sinica, Taipei (Taiwan)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Tue Mar 15 00:00:00 EDT 2022

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Laboratory Directed Research and Development (LDRD) Program. Los Alamos National Laboratory (LANL); Ministry of Science and Technology (MOST), Taiwan; Academia Sinica, Taiwan; National Taiwan University; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program

OSTI Identifier:: 1869208

Alternate Identifier(s):: OSTI ID: 1874197

Report Number(s):: LA-UR-21-30401
Journal ID: ISSN 2198-3844; 173699

Grant/Contract Number:: AC02-06CH11357; 89233218CNA000001; 108-2113-M-002-015-MY3; 108-2911-I-002-561; AS-iMATE-109-31

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Science

Additional Journal Information:: Journal Volume: 9; Journal Issue: 14; Journal ID: ISSN 2198-3844

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY; metal-organic frameworks; blue light emitting diodes (LEDs); inorganic perovskite nanocrystals

Citation Formats


                    Tsai, Hsinhan, Huang, Hsin‐Hsiang, Watt, John, Hou, Cheng‐Hung, Strzalka, Joseph, Shyue, Jing‐Jong, Wang, Leeyih, and Nie, Wanyi. Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes.  United States: N. p., 2022. 
Web.  doi:10.1002/advs.202105850.

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                    Tsai, Hsinhan, Huang, Hsin‐Hsiang, Watt, John, Hou, Cheng‐Hung, Strzalka, Joseph, Shyue, Jing‐Jong, Wang, Leeyih, & Nie, Wanyi. Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes.  United States.  https://doi.org/10.1002/advs.202105850

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                    Tsai, Hsinhan, Huang, Hsin‐Hsiang, Watt, John, Hou, Cheng‐Hung, Strzalka, Joseph, Shyue, Jing‐Jong, Wang, Leeyih, and Nie, Wanyi. Tue .  
"Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes".  United States.  https://doi.org/10.1002/advs.202105850.  https://www.osti.gov/servlets/purl/1869208.

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@article{osti_1869208,

  title        = {Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes},

  author       = {Tsai, Hsinhan and Huang, Hsin‐Hsiang and Watt, John and Hou, Cheng‐Hung and Strzalka, Joseph and Shyue, Jing‐Jong and Wang, Leeyih and Nie, Wanyi},

  abstractNote = {},

  doi          = {10.1002/advs.202105850},

  journal      = {Advanced Science},

  number       = 14,

  volume       = 9,

  place        = {United States},

  year         = {Tue Mar 15 00:00:00 EDT 2022},

  month        = {Tue Mar 15 00:00:00 EDT 2022}

}

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https://doi.org/10.1002/adma.202106498
Highly stable cesium lead iodide perovskite quantum dot light-emitting diodes

Journal Article Zou, Chen ; Huang, Chun-Ying ; Sanehira, Erin M. ; ... - Nanotechnology

Recently, all-inorganic perovskites such as CsPbBr3 and CsPbI3, have emerged as promising materials for light-emitting applications. While encouraging performance has been demonstrated, the stability issue of the red-emitting CsPbI3 is still a major concern due to its small tolerance factor. Here we report a highly stable CsPbI3 quantum dot LED with red emission fabricated using an improved purification approach. The device achieved decent external quantum efficiency (EQE) of 0.21 % at a bias of 6 V and outstanding operational stability, with a L70 lifetime (EL intensity decreases to 70% of starting value) of 16 h and 1.5 h under amore »« less
Cited by 38
https://doi.org/10.1088/1361-6528/aa8b8b

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Title: Cesium Lead Halide Perovskite Nanocrystals Assembled in Metal–Organic Frameworks for Stable Blue Light Emitting Diodes

Citation Formats

Efficient Blue and White Perovskite Light-Emitting Diodes via Manganese Doping journal, November 2018

Ionic transport in hybrid lead iodide perovskite solar cells journal, June 2015

Perovskite-type superlattices from lead halide perovskite nanocubes journal, May 2021

Large cation ethylammonium incorporated perovskite for efficient and spectra stable blue light-emitting diodes journal, August 2020

Sonochemical synthesis and structural characterization of a nano-structure Pb(II) benzentricarboxylate coordination polymer: new precursor to pure phase nanoparticles of Pb(II) oxide journal, January 2010

Bipolar-shell resurfacing for blue LEDs based on strongly confined perovskite quantum dots journal, July 2020

Lattice anchoring stabilizes solution-processed semiconductors journal, May 2019

The birth of the blue LED journal, November 2014

Intermarriage of Halide Perovskites and Metal‐Organic Framework Crystals journal, September 2020

Utilization of Trapped Optical Modes for White Perovskite Light-Emitting Diodes with Efficiency over 12% journal, February 2021

CsPbBr3 perovskite detectors with 1.4% energy resolution for high-energy γ-rays journal, December 2020

Spectra stable blue perovskite light-emitting diodes journal, April 2019

Efficient light-emitting diodes from mixed-dimensional perovskites on a fluoride interface journal, October 2020

Luminescent Metal–Organic Frameworks for White LEDs journal, December 2020

Ion Migration-Induced Degradation and Efficiency Roll-off in Quasi-2D Perovskite Light-Emitting Diodes journal, June 2020

Employing Polar Solvent Controlled Ionization in Precursors for Synthesis of High-Quality Inorganic Perovskite Nanocrystals at Room Temperature journal, January 2018

Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent journal, October 2018

Blue perovskite light-emitting diodes: progress, challenges and future directions journal, January 2019

Ligand-engineered bandgap stability in mixed-halide perovskite LEDs journal, March 2021

Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes journal, January 2021

Metal Halide Perovskite Nanocrystals in Metal–Organic Framework Host: Not Merely Enhanced Stability journal, August 2020

Printable organometallic perovskite enables large-area, low-dose X-ray imaging journal, October 2017

A sensitive and robust thin-film x-ray detector using 2D layered perovskite diodes journal, April 2020

Critical Role of Vertical Phase Separation in Small-Molecule Organic Solar Cells journal, March 2018

Introduction to Metal–Organic Frameworks journal, September 2011

Highly Efficient Perovskite-Quantum-Dot Light-Emitting Diodes by Surface Engineering journal, August 2016

An Efficient and Reversible Battery Anode Electrode Derived from a Lead-Based Metal–Organic Framework journal, May 2021

Directed assembly of layered perovskite heterostructures as single crystals journal, September 2021

Highly Efficient Perovskite Nanocrystal Light-Emitting Diodes Enabled by a Universal Crosslinking Method journal, March 2016

Investigating the Effects of Chemical Gradients on Performance and Reliability within Perovskite Solar Cells with TOF-SIMS journal, February 2020

Imbedded Nanocrystals of CsPbBr 3 in Cs 4 PbBr 6 : Kinetics, Enhanced Oscillator Strength, and Application in Light-Emitting Diodes journal, October 2017

Lamellar and liquid crystal ordering in solvent-annealed all-conjugated block copolymers journal, January 2014

Secondary Ion Mass Spectrometry (SIMS) for Chemical Characterization of Metal Halide Perovskites journal, June 2020

Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal–organic frameworks journal, September 2021

High-efficiency perovskite–polymer bulk heterostructure light-emitting diodes journal, November 2018

All-inorganic perovskite nanocrystal scintillators journal, August 2018

P-Type Conduction in Mg-Doped GaN Treated with Low-Energy Electron Beam Irradiation (LEEBI) journal, December 1989

Efficient blue light-emitting diodes based on quantum-confined bromide perovskite nanostructures journal, August 2019

High‐Performance Perovskite‐Based Blue Light‐Emitting Diodes with Operational Stability by Using Organic Ammonium Cations as Passivating Agents journal, October 2020

Liquid-phase sintering of lead halide perovskites and metal-organic framework glasses journal, October 2021

Conversion of invisible metal-organic frameworks to luminescent perovskite nanocrystals for confidential information encryption and decryption journal, October 2017

2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications journal, June 2015

Stable blue perovskite light-emitting diodes achieved by optimization of crystal dimension through zinc bromide addition journal, June 2021

Rational molecular passivation for high-performance perovskite light-emitting diodes journal, March 2019

Rearranging Low-Dimensional Phase Distribution of Quasi-2D Perovskites for Efficient Sky-Blue Perovskite Light-Emitting Diodes journal, August 2020

Efficient and Spectrally Stable Blue Perovskite Light‐Emitting Diodes Employing a Cationic π‐Conjugated Polymer journal, September 2021

High-Brightness Blue and White LEDs based on Inorganic Perovskite Nanocrystals and their Composites journal, April 2017

Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors. Erratum journal, January 2013

Hollow metal halide perovskite nanocrystals with efficient blue emissions journal, April 2020

Ligand-Mediated Synthesis of Shape-Controlled Cesium Lead Halide Perovskite Nanocrystals via Reprecipitation Process at Room Temperature journal, February 2016

Distribution control enables efficient reduced-dimensional perovskite LEDs journal, November 2021

Validated Analysis of Component Distribution Inside Perovskite Solar Cells and Its Utility in Unveiling Factors of Device Performance and Degradation journal, May 2020

Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays journal, August 2020

Critical Role of Organic Spacers for Bright 2D Layered Perovskites Light‐Emitting Diodes journal, February 2020

A fabrication process for flexible single-crystal perovskite devices journal, July 2020

High‐Performance Blue Perovskite Light‐Emitting Diodes Enabled by Efficient Energy Transfer between Coupled Quasi‐2D Perovskite Layers journal, November 2020

Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX 3 ) journal, October 2015

Insight into the Ligand-Mediated Synthesis of Colloidal CsPbBr 3 Perovskite Nanocrystals: The Role of Organic Acid, Base, and Cesium Precursors journal, July 2016

Degradation Mechanism and Lifetime Improvement Strategy for Blue Phosphorescent Organic Light-Emitting Diodes journal, March 2017

Characterization of stability and challenges to improve lifetime in perovskite LEDs journal, August 2021

Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures journal, October 2018

The working principle of hybrid perovskite gamma-ray photon counter journal, July 2020

Blue‐green laser diodes journal, September 1991

Candela‐class high‐brightness InGaN/AlGaN double‐heterostructure blue‐light‐emitting diodes journal, March 1994

Comprehensive defect suppression in perovskite nanocrystals for high-efficiency light-emitting diodes journal, January 2021

Efficient CsPbBr 3 Perovskite Light-Emitting Diodes Enabled by Synergetic Morphology Control journal, December 2018

Detection of gamma photons using solution-grown single crystals of hybrid lead halide perovskites journal, July 2016

Thermal stability of CsPbBr 3 perovskite as revealed by in situ transmission electron microscopy journal, July 2019

THE PREPARATION AND PROPERTIES OF VAPOR‐DEPOSITED SINGLE‐CRYSTAL‐LINE GaN journal, November 1969

Study of degradation mechanism of blue light emitting diodes journal, July 2005

Introduction: Porous Framework Chemistry journal, August 2020

Chlorine distribution management for spectrally stable and efficient perovskite blue light-emitting diodes journal, January 2021

New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH 2 ) 3 )(CH 3 NH 3 ) n Pb n I 3 n +1 : Structure, Properties, and Photovoltaic Performance journal, November 2017

Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut journal, February 2015

Efficient Blue and White Perovskite Light-Emitting Diodes via Manganese Doping
journal, November 2018

Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015

Perovskite-type superlattices from lead halide perovskite nanocubes
journal, May 2021

Large cation ethylammonium incorporated perovskite for efficient and spectra stable blue light-emitting diodes
journal, August 2020

Sonochemical synthesis and structural characterization of a nano-structure Pb(II) benzentricarboxylate coordination polymer: new precursor to pure phase nanoparticles of Pb(II) oxide
journal, January 2010

Bipolar-shell resurfacing for blue LEDs based on strongly confined perovskite quantum dots
journal, July 2020

Lattice anchoring stabilizes solution-processed semiconductors
journal, May 2019

The birth of the blue LED
journal, November 2014

Intermarriage of Halide Perovskites and Metal‐Organic Framework Crystals
journal, September 2020

Utilization of Trapped Optical Modes for White Perovskite Light-Emitting Diodes with Efficiency over 12%
journal, February 2021

CsPbBr3 perovskite detectors with 1.4% energy resolution for high-energy γ-rays
journal, December 2020

Spectra stable blue perovskite light-emitting diodes
journal, April 2019

Efficient light-emitting diodes from mixed-dimensional perovskites on a fluoride interface
journal, October 2020

Luminescent Metal–Organic Frameworks for White LEDs
journal, December 2020

Ion Migration-Induced Degradation and Efficiency Roll-off in Quasi-2D Perovskite Light-Emitting Diodes
journal, June 2020

Employing Polar Solvent Controlled Ionization in Precursors for Synthesis of High-Quality Inorganic Perovskite Nanocrystals at Room Temperature
journal, January 2018

Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent
journal, October 2018

Blue perovskite light-emitting diodes: progress, challenges and future directions
journal, January 2019

Ligand-engineered bandgap stability in mixed-halide perovskite LEDs
journal, March 2021

Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes
journal, January 2021

Metal Halide Perovskite Nanocrystals in Metal–Organic Framework Host: Not Merely Enhanced Stability
journal, August 2020

Printable organometallic perovskite enables large-area, low-dose X-ray imaging
journal, October 2017

A sensitive and robust thin-film x-ray detector using 2D layered perovskite diodes
journal, April 2020

Critical Role of Vertical Phase Separation in Small-Molecule Organic Solar Cells
journal, March 2018

Introduction to Metal–Organic Frameworks
journal, September 2011

Highly Efficient Perovskite-Quantum-Dot Light-Emitting Diodes by Surface Engineering
journal, August 2016

An Efficient and Reversible Battery Anode Electrode Derived from a Lead-Based Metal–Organic Framework
journal, May 2021

Directed assembly of layered perovskite heterostructures as single crystals
journal, September 2021

Highly Efficient Perovskite Nanocrystal Light-Emitting Diodes Enabled by a Universal Crosslinking Method
journal, March 2016

Investigating the Effects of Chemical Gradients on Performance and Reliability within Perovskite Solar Cells with TOF-SIMS
journal, February 2020

Imbedded Nanocrystals of CsPbBr ₃ in Cs ₄ PbBr ₆ : Kinetics, Enhanced Oscillator Strength, and Application in Light-Emitting Diodes
journal, October 2017

Lamellar and liquid crystal ordering in solvent-annealed all-conjugated block copolymers
journal, January 2014

Secondary Ion Mass Spectrometry (SIMS) for Chemical Characterization of Metal Halide Perovskites
journal, June 2020

Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal–organic frameworks
journal, September 2021

High-efficiency perovskite–polymer bulk heterostructure light-emitting diodes
journal, November 2018

All-inorganic perovskite nanocrystal scintillators
journal, August 2018

P-Type Conduction in Mg-Doped GaN Treated with Low-Energy Electron Beam Irradiation (LEEBI)
journal, December 1989

Efficient blue light-emitting diodes based on quantum-confined bromide perovskite nanostructures
journal, August 2019

High‐Performance Perovskite‐Based Blue Light‐Emitting Diodes with Operational Stability by Using Organic Ammonium Cations as Passivating Agents
journal, October 2020

Liquid-phase sintering of lead halide perovskites and metal-organic framework glasses
journal, October 2021

Conversion of invisible metal-organic frameworks to luminescent perovskite nanocrystals for confidential information encryption and decryption
journal, October 2017

2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
journal, June 2015

Stable blue perovskite light-emitting diodes achieved by optimization of crystal dimension through zinc bromide addition
journal, June 2021

Rational molecular passivation for high-performance perovskite light-emitting diodes
journal, March 2019

Rearranging Low-Dimensional Phase Distribution of Quasi-2D Perovskites for Efficient Sky-Blue Perovskite Light-Emitting Diodes
journal, August 2020

Efficient and Spectrally Stable Blue Perovskite Light‐Emitting Diodes Employing a Cationic π‐Conjugated Polymer
journal, September 2021

High-Brightness Blue and White LEDs based on Inorganic Perovskite Nanocrystals and their Composites
journal, April 2017

Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors. Erratum
journal, January 2013

Hollow metal halide perovskite nanocrystals with efficient blue emissions
journal, April 2020

Ligand-Mediated Synthesis of Shape-Controlled Cesium Lead Halide Perovskite Nanocrystals via Reprecipitation Process at Room Temperature
journal, February 2016

Distribution control enables efficient reduced-dimensional perovskite LEDs
journal, November 2021

Validated Analysis of Component Distribution Inside Perovskite Solar Cells and Its Utility in Unveiling Factors of Device Performance and Degradation
journal, May 2020

Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays
journal, August 2020

Critical Role of Organic Spacers for Bright 2D Layered Perovskites Light‐Emitting Diodes
journal, February 2020

A fabrication process for flexible single-crystal perovskite devices
journal, July 2020

High‐Performance Blue Perovskite Light‐Emitting Diodes Enabled by Efficient Energy Transfer between Coupled Quasi‐2D Perovskite Layers
journal, November 2020

Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX ₃ )
journal, October 2015

Insight into the Ligand-Mediated Synthesis of Colloidal CsPbBr ₃ Perovskite Nanocrystals: The Role of Organic Acid, Base, and Cesium Precursors
journal, July 2016

Degradation Mechanism and Lifetime Improvement Strategy for Blue Phosphorescent Organic Light-Emitting Diodes
journal, March 2017

Characterization of stability and challenges to improve lifetime in perovskite LEDs
journal, August 2021

Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures
journal, October 2018

The working principle of hybrid perovskite gamma-ray photon counter
journal, July 2020

Blue‐green laser diodes
journal, September 1991

Candela‐class high‐brightness InGaN/AlGaN double‐heterostructure blue‐light‐emitting diodes
journal, March 1994

Comprehensive defect suppression in perovskite nanocrystals for high-efficiency light-emitting diodes
journal, January 2021

Efficient CsPbBr ₃ Perovskite Light-Emitting Diodes Enabled by Synergetic Morphology Control
journal, December 2018

Detection of gamma photons using solution-grown single crystals of hybrid lead halide perovskites
journal, July 2016

Thermal stability of CsPbBr 3 perovskite as revealed by in situ transmission electron microscopy
journal, July 2019

THE PREPARATION AND PROPERTIES OF VAPOR‐DEPOSITED SINGLE‐CRYSTAL‐LINE GaN
journal, November 1969

Study of degradation mechanism of blue light emitting diodes
journal, July 2005

Introduction: Porous Framework Chemistry
journal, August 2020

Chlorine distribution management for spectrally stable and efficient perovskite blue light-emitting diodes
journal, January 2021

New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH ₂ ) ₃ )(CH ₃ NH ₃ ) _n Pb _n I _{3 n +1} : Structure, Properties, and Photovoltaic Performance
journal, November 2017

Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015