Sn0.24WO3 hexagonal tungsten bronze prepared via the metal chloride route

Jin, Lun; Guo, Shu; Cava, Robert J.

doi:10.1016/j.jssc.2020.121553

Title: Sn_0.24WO₃ hexagonal tungsten bronze prepared via the metal chloride route

Abstract

In this work, we report the synthesis of Sn_0.24WO₃ single crystals via an alternative, less well-known, solid-state synthetic approach that involves the use of tin chloride as a starting material. The compound adopts an unusual variant of the hexagonal tungsten bronze structure in space group P6/mmm (a = 7.4264(7) Å and c = 3.7843(4) Å) with a previously unreported distribution of Sn cations, disordered over two distinct sites in the tunnels. Sn_0.24WO₃ shows no signs of superconductivity down to 170 mK and exhibits weakly-metallic conducting behavior.

Authors:

Jin, Lun ^[1]; Guo, Shu ^[1]; Cava, Robert J. ^[1]

Princeton Univ., NJ (United States). Dept. of Chemistry

Publication Date:: Tue Jul 28 00:00:00 EDT 2020

Research Org.:: Princeton Univ., NJ (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1850194

Alternate Identifier(s):: OSTI ID: 1646537

Grant/Contract Number:: FG02-98ER45706

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Solid State Chemistry

Additional Journal Information:: Journal Volume: 291; Journal Issue: C; Journal ID: ISSN 0022-4596

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry; Bronzes; Hexagonal tungsten bronzes; Sn–W–O; Metal chloride route; Single crystal X-ray diffraction; Temperature-dependent resistivity

Citation Formats


                    Jin, Lun, Guo, Shu, and Cava, Robert J. Sn0.24WO3 hexagonal tungsten bronze prepared via the metal chloride route.  United States: N. p., 2020. 
Web.  doi:10.1016/j.jssc.2020.121553.

Copy to clipboard


                    Jin, Lun, Guo, Shu, & Cava, Robert J. Sn0.24WO3 hexagonal tungsten bronze prepared via the metal chloride route.  United States.  https://doi.org/10.1016/j.jssc.2020.121553

Copy to clipboard


                    Jin, Lun, Guo, Shu, and Cava, Robert J. Tue .  
"Sn0.24WO3 hexagonal tungsten bronze prepared via the metal chloride route".  United States.  https://doi.org/10.1016/j.jssc.2020.121553.  https://www.osti.gov/servlets/purl/1850194.

Copy to clipboard


                    
@article{osti_1850194,

  title        = {Sn0.24WO3 hexagonal tungsten bronze prepared via the metal chloride route},

  author       = {Jin, Lun and Guo, Shu and Cava, Robert J.},

  abstractNote = {In this work, we report the synthesis of Sn0.24WO3 single crystals via an alternative, less well-known, solid-state synthetic approach that involves the use of tin chloride as a starting material. The compound adopts an unusual variant of the hexagonal tungsten bronze structure in space group P6/mmm (a = 7.4264(7) Å and c = 3.7843(4) Å) with a previously unreported distribution of Sn cations, disordered over two distinct sites in the tunnels. Sn0.24WO3 shows no signs of superconductivity down to 170 mK and exhibits weakly-metallic conducting behavior.},

  doi          = {10.1016/j.jssc.2020.121553},

  journal      = {Journal of Solid State Chemistry},

  number       = C,

  volume       = 291,

  place        = {United States},

  year         = {Tue Jul 28 00:00:00 EDT 2020},

  month        = {Tue Jul 28 00:00:00 EDT 2020}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.jssc.2020.121553

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Chemical synthesis and electronic conduction properties of sodium and potassium tungsten bronzes
journal, December 2000

Fan, R.; Chen, X. H.; Gui, Z.
Journal of Physics and Chemistry of Solids, Vol. 61, Issue 12
DOI: 10.1016/S0022-3697(00)00202-X

Superconductivity in the tungsten bronzes
journal, November 1978

Ostenson, J. E.; Shanks, H. R.; Finnemore, D. K.
Journal of the Less Common Metals, Vol. 62
DOI: 10.1016/0022-5088(78)90024-3

Superconductivity in the tungsten bronze ${Rb}_{x} W O_{3}$ $(0.20 ⩽ x ⩽ 0.33)$ in connection with its structure, electronic density of states, and phonon density of states
journal, November 2007

Brusetti, R.; Bordet, P.; Bossy, J.
Physical Review B, Vol. 76, Issue 17
DOI: 10.1103/PhysRevB.76.174511

Low temperature magnetic susceptibility of uranium and rare earth tungsten oxide bronzes
journal, November 1974

Thomas, Jack F.; Sienko, M. J.
The Journal of Chemical Physics, Vol. 61, Issue 10
DOI: 10.1063/1.1681684

New lithium, ammonium, and tin hexagonal tungsten bronzes prepared hydrothermallly
journal, August 1968

Gier, T. E.; Pease, D. C.; Sleight, A. W.
Inorganic Chemistry, Vol. 7, Issue 8
DOI: 10.1021/ic50066a036

Normal and superconducting properties of $K_{x}$ W $O_{3}$
journal, March 1981

Cadwell, L. H.; Morris, R. C.; Moulton, W. G.
Physical Review B, Vol. 23, Issue 5
DOI: 10.1103/PhysRevB.23.2219

Preparation, structure, and Mössbauer spectra of tin tungsten bronzes
journal, December 1970

McColm, I. J.; Steadman, R.; Howe, A.
Journal of Solid State Chemistry, Vol. 2, Issue 4
DOI: 10.1016/0022-4596(70)90051-4

Electrical and Magnetic Properties of Potassium Tungsten Bronze and Rubidium Tungsten Bronze
journal, June 1963

Sienko, M. J.; Morehouse, Sheila MacEnness
Inorganic Chemistry, Vol. 2, Issue 3
DOI: 10.1021/ic50007a014

An X-Ray and Electron Diffraction Study of the Intergrowth Tungsten Bronze Sb0.16WO3
journal, December 1997

Triantafyllou, S. T.; Christidis, P. C.; Lioutas, Ch. B.
Journal of Solid State Chemistry, Vol. 134, Issue 2
DOI: 10.1006/jssc.1997.7577

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
Journal of Applied Crystallography, Vol. 48, Issue 1
DOI: 10.1107/S1600576714022985

Etude comparative des structures M _x WO ₃ de type bronze hexagonal. II. Evolution structurale dans la série des bronzes In _x WO ₃ (0,12 < x < 0,33)
journal, July 1979

Labbé, P.; Goreaud, M.; Raveau, B.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 35, Issue 7
DOI: 10.1107/S0567740879007123

Effect of Oxygen Concentration on Superconducting Properties of Rubidium Tungsten Bronzes Rb x WO y
journal, January 2007

Ting, L. C.; Hsieh, H. H.; Kang, H. H.
Journal of Superconductivity and Novel Magnetism, Vol. 20, Issue 3
DOI: 10.1007/s10948-006-0186-3

Structural Studies of Calcium Tungsten Bronzes, CaxWO3, Formed at High Pressure
journal, July 2000

Zakharov, N. D.; Werner, P.; Zibrov, I. P.
Crystal Research and Technology, Vol. 35, Issue 6-7
DOI: 10.1002/1521-4079(200007)35:6/7<713::AID-CRAT713>3.0.CO;2-Z

Superconducting phase diagram of In _x WO ₃ synthesized by indium deintercalation
journal, July 2013

Bocarsly, Joshua D.; Hirai, Daigorou; Ali, M. N.
EPL (Europhysics Letters), Vol. 103, Issue 1
DOI: 10.1209/0295-5075/103/17001

Investigation of the Rb–W–O system in connexion with the superconducting properties of the hexagonal tungsten bronzes
journal, April 2003

Brusetti, R.; Bordet, P.; Marcus, J.
Journal of Solid State Chemistry, Vol. 172, Issue 1
DOI: 10.1016/S0022-4596(03)00006-9

The Preparation and Properties of a Barium Tungsten Bronze
journal, July 1965

Conroy, Lawrence E.; Yokokawa, Toshio
Inorganic Chemistry, Vol. 4, Issue 7
DOI: 10.1021/ic50029a015

The sodium tungsten bronzes as plasmonic materials: fabrication, calculation and characterization
journal, June 2017

Tegg, Levi; Cuskelly, Dylan; Keast, Vicki J.
Materials Research Express, Vol. 4, Issue 6
DOI: 10.1088/2053-1591/aa6c40

Superconductivity in hexagonal tungsten bronzes
journal, May 1967

Remeika, J. P.; Geballe, T. H.; Matthias, B. T.
Physics Letters A, Vol. 24, Issue 11
DOI: 10.1016/0375-9601(67)90616-0

Conduction properties of the hexagonal tungsten bronze, ${Rb}_{x} W O_{3}$
journal, September 1979

Stanley, R. K.; Morris, R. C.; Moulton, W. G.
Physical Review B, Vol. 20, Issue 5
DOI: 10.1103/PhysRevB.20.1903

The h ‐Sb _x WO _{3+2 x} Oxygen Excess Antimony Tungsten Bronze
journal, January 2019

von Rohr, Fabian O.; Ryser, Alice; Ji, Huiwen
Chemistry – A European Journal, Vol. 25, Issue 8
DOI: 10.1002/chem.201805251

Superconductivity in WO $_{2.6}$ F $_{0.4}$ synthesized by reaction of WO $_{3}$ with teflon
journal, November 2011

Hirai, D.; Climent-Pascual, E.; Cava, R. J.
Physical Review B, Vol. 84, Issue 17
DOI: 10.1103/PhysRevB.84.174519

Thallium-Tungsten Bronze: A Solid State Defect Structure ¹
journal, November 1959

Sienko, M. J.
Journal of the American Chemical Society, Vol. 81, Issue 21
DOI: 10.1021/ja01530a012

Crystal structure and superconductivity of rubidium tungsten bronzes RbxWO3 prepared by a hybrid microwave method
journal, April 2008

Guo, Juan; Dong, Cheng; Yang, Lihong
Materials Research Bulletin, Vol. 43, Issue 4
DOI: 10.1016/j.materresbull.2008.01.005

On the structure of tetragonal tin-tungsten bronzes
journal, October 1972

Steadman, R.
Materials Research Bulletin, Vol. 7, Issue 10
DOI: 10.1016/0025-5408(72)90167-5

Opportunities and challenges in science and technology of WO3 for electrochromic and related applications
journal, February 2008

Deb, Satyen K.
Solar Energy Materials and Solar Cells, Vol. 92, Issue 2
DOI: 10.1016/j.solmat.2007.01.026

Tungsten-based oxide semiconductors for solar hydrogen generation
journal, January 2013

Janáky, C.; Rajeshwar, K.; de Tacconi, N. R.
Catalysis Today, Vol. 199
DOI: 10.1016/j.cattod.2012.07.020

Superconductivity of sodium tungsten bronze with cubic structure
journal, February 1996

Garif'yanov, N. N.; Khlebnikov, S. Ya.; Khlebnikov, I. S.
Czechoslovak Journal of Physics, Vol. 46, Issue S2
DOI: 10.1007/BF02583735

Single-crystal structure validation with the program PLATON
journal, January 2003

Spek, A. L.
Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13
DOI: 10.1107/S0021889802022112

Crystal structure of a hexagonal tin tungsten bronze prepared by a mild reaction
journal, March 1995

Xu, X.
Solid State Ionics, Vol. 76, Issue 3-4
DOI: 10.1016/0167-2738(94)00281-V

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J.
Journal of Applied Crystallography, Vol. 42, Issue 2
DOI: 10.1107/S0021889808042726

Le systeme SbWO3 et les bronzes de tungstene — Antimoine
journal, May 1975

Parmentier, M.; Gleitzer, C.; Courtois, A.
Materials Research Bulletin, Vol. 10, Issue 5
DOI: 10.1016/0025-5408(75)90003-3

Preparation of tungsten bronzes from metals halides
journal, March 1968

Conroy, Lawrence E.; Podolsky, George
Inorganic Chemistry, Vol. 7, Issue 3
DOI: 10.1021/ic50061a049

Superconducting properties of the $K_{x} {WO}_{3}$ tetragonal tungsten bronze and the superconducting phase diagram of the tungsten bronze family
journal, March 2014

Haldolaarachchige, Neel; Gibson, Quinn; Krizan, Jason
Physical Review B, Vol. 89, Issue 10
DOI: 10.1103/PhysRevB.89.104520

Enhancement of the superconducting transition temperature near a phase instability in NaxWO3
journal, August 1974

Shanks, Howard R.
Solid State Communications, Vol. 15, Issue 4
DOI: 10.1016/0038-1098(74)90254-3

The tungsten bronzes and related compounds
journal, January 1968

Dickens, P. G.; Whittingham, M. S.
Quarterly Reviews, Chemical Society, Vol. 22, Issue 1
DOI: 10.1039/qr9682200030

Magnetic susceptibility of cubic uranium tungsten bronzes between 4.2 and 560.deg.K
journal, June 1969

Ostertag, Werner
Inorganic Chemistry, Vol. 8, Issue 6
DOI: 10.1021/ic50076a034

Electronic Band Structure Study of the Anomalous Electrical and Superconducting Properties of Hexagonal Alkali Tungsten Bronzes A _x WO ₃ (A = K, Rb, Cs)
journal, April 1997

Lee, Kwang-Soon; Seo, Dong-Kyun; Whangbo, Myung-Hwan
Journal of the American Chemical Society, Vol. 119, Issue 17
DOI: 10.1021/ja964455t

Superconductivity of Sodium Tungsten Bronzes
journal, December 1964

Raub, Ch. J.; Sweedler, A. R.; Jensen, M. A.
Physical Review Letters, Vol. 13, Issue 25
DOI: 10.1103/PhysRevLett.13.746

Superconductivity and crystal structural origins of the metal-insulator transition in ${Ba}_{6 - x} {Sr}_{x} {Nb}_{10} O_{30}$ tetragonal tungsten bronzes
journal, December 2015

Kolodiaznyi, Taras; Sakurai, Hiroya; Isobe, Masaaki
Physical Review B, Vol. 92, Issue 21
DOI: 10.1103/PhysRevB.92.214508

Superconductivity of the alkali tungsten bronzes
journal, March 1965

Sweedler, A. R.; Raub, Ch. J.; Matthias, B. T.
Physics Letters, Vol. 15, Issue 2
DOI: 10.1016/0031-9163(65)91292-8

Similar Records in DOE PAGES and OSTI.GOV collections:

The h–Sb_xWO_3+2x Oxygen Excess Antimony Tungsten Bronze

Journal Article von Rohr, Fabian O. ; Ryser, Alice ; Ji, Huiwen ; ... - Chemistry - A European Journal

Here, we describe the previously unreported oxygen excess hexagonal antimony tungsten bronze with composition Sb_0.5W₃O₁₀, in the following denoted as h–Sb_xWO_3+2x with x = 0.167, to demonstrate its analogy to classical A_xWO₃ tungsten bronzes. This compound forms in a relatively narrow temperature range between 580 °C < T < 620 °C. It was obtained as a dark–blue polycrystalline powder, and as thin, needle–shaped, blue single crystals. h–Sb_xWO_3+2x crystallizes in the hexagonal space group P6/mmm with the cell parameters a=7.4369(4) Å and c=3.7800(2) Å. The antimony and excess oxygen occupy the hexagonal channels within the network of corner–sharing WO₆ octahedra. h–Sb_xWO_3+2xmore »« less
Cited by 6
https://doi.org/10.1002/chem.201805251

Full Text Available
Rietveld analysis of Na[sub x]WO[sub 3+x/2][center dot]yH[sub 2]O, which has the hexagonal tungsten bronze structure

Journal Article Reis, K P ; Whittingham, M S ; Prince, E

Powder neutron diffraction and Rietveld analysis were used to investigate the crystal structures of hydrated and deuterated samples of Na[sub x]WO[sub 3+x/2][center dot]yH[sub 2]O (x [approximately] 0.17, y [approximately] 0.23). The compound, which crystallizes with the symmetry of space group P6/mmm, is related to the hexagonal tungsten bronze structure but differs from it due to the presence of sodium and oxygen along the hexagonal tunnel. Some of the oxygens appear in the structure as water molecules. The oxygen is disordered along the z axis in the hexagonal cavity with sodium in the hexagonal window.
Preparation of hexagonal WO{sub 3} from hexagonal ammonium tungsten bronze for sensing NH{sub 3}

Journal Article Szilagyi, Imre Miklos ; Lisheng, Wang ; Gouma, Pelagia-Irene ; ... - Materials Research Bulletin

Hexagonal tungsten oxide (h-WO{sub 3}) was prepared by annealing hexagonal ammonium tungsten bronze, (NH{sub 4}){sub 0.07}(NH{sub 3}){sub 0.04}(H{sub 2}O){sub 0.09}WO{sub 2.95}. The structure, composition and morphology of h-WO{sub 3} were studied by XRD, XPS, Raman, {sup 1}H MAS (magic angle spinning) NMR, scanning electron microscopy (SEM), and BET-N{sub 2} specific surface area measurement, while its thermal stability was investigated by in situ XRD. The h-WO{sub 3} sample was built up by 50-100 nm particles, had an average specific surface area of 8.3 m{sup 2}/g and was thermally stable up to 450 deg. C. Gas sensing tests showed that h-WO{sub 3}more »« less
https://doi.org/10.1016/j.materresbull.2008.08.003
Conduction properties of the hexagonal tungsten bronze, Rb/sub x/WO/sub 3/

Journal Article Stanley, R K ; Morris, R C ; Moulton, W G - Phys. Rev., B: Condens. Matter; (United States)

Studies of the electrical transport properties: resistivity, Hall effect, and Seebeck coefficient: of the hexagonal tungsten bronze Rb/sub x/WO/sub 3/ for 0.16< or =x< or =0.33 are reported for the temperature range from 1.5 to 300 K. In the normal state, these properties show temperature-dependent anomalies which suggest a phase transition with temperature. The temperature at which this transition occurs is shown to depend on the Rb concentration, exhibiting a sharp maximum near x=0.25. As the Rb concentration is decreased below x = 0.33 the superconducting transition temperature first increases above the value of 1.94 K at x=0.33 and thenmore »« less
https://doi.org/10.1103/PhysRevB.20.1903
A green route for microwave synthesis of sodium tungsten bronzes Na{sub x}WO{sub 3} (0<x<1)

Journal Article Juan, Guo ; Cheng, Dong ; Lihong, Yang ; ... - Journal of Solid State Chemistry

A green route has been developed for microwave synthesis of sodium tungsten bronzes Na{sub x}WO{sub 3} (0<x<1) from Na{sub 2}WO{sub 4}, WO{sub 3} and tungsten powder. The hybrid microwave synthesis was carried out in argon atmosphere using CuO powder as the heating medium. Tungsten powder is used as the reducing agent instead of the alkali metal iodides previously used for the microwave synthesis of oxide bronzes. The prepared samples were characterized by powder X-ray diffraction, energy-dispersive X-ray analysis and scanning electron microscopy, and their phase constitutions, crystal structures and morphologies are in consistence with that in the literature. This synthesismore »« less
https://doi.org/10.1016/j.jssc.2004.10.017

Similar Records
Related Works
dataset (1)

Title: Sn0.24WO3 hexagonal tungsten bronze prepared via the metal chloride route

Abstract

Citation Formats

Chemical synthesis and electronic conduction properties of sodium and potassium tungsten bronzes journal, December 2000

Superconductivity in the tungsten bronzes journal, November 1978

Superconductivity in the tungsten bronze Rb x W O 3 ( 0.20 ⩽ x ⩽ 0.33 ) in connection with its structure, electronic density of states, and phonon density of states journal, November 2007

Low temperature magnetic susceptibility of uranium and rare earth tungsten oxide bronzes journal, November 1974

New lithium, ammonium, and tin hexagonal tungsten bronzes prepared hydrothermallly journal, August 1968

Normal and superconducting properties of K x W O 3 journal, March 1981

Preparation, structure, and Mössbauer spectra of tin tungsten bronzes journal, December 1970

Electrical and Magnetic Properties of Potassium Tungsten Bronze and Rubidium Tungsten Bronze journal, June 1963

An X-Ray and Electron Diffraction Study of the Intergrowth Tungsten Bronze Sb0.16WO3 journal, December 1997

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination journal, January 2015

Etude comparative des structures M x WO 3 de type bronze hexagonal. II. Evolution structurale dans la série des bronzes In x WO 3 (0,12 < x < 0,33) journal, July 1979

Effect of Oxygen Concentration on Superconducting Properties of Rubidium Tungsten Bronzes Rb x WO y journal, January 2007

Structural Studies of Calcium Tungsten Bronzes, CaxWO3, Formed at High Pressure journal, July 2000

Superconducting phase diagram of In x WO 3 synthesized by indium deintercalation journal, July 2013

Investigation of the Rb–W–O system in connexion with the superconducting properties of the hexagonal tungsten bronzes journal, April 2003

The Preparation and Properties of a Barium Tungsten Bronze journal, July 1965

The sodium tungsten bronzes as plasmonic materials: fabrication, calculation and characterization journal, June 2017

Superconductivity in hexagonal tungsten bronzes journal, May 1967

Conduction properties of the hexagonal tungsten bronze, Rb x W O 3 journal, September 1979

The h ‐Sb x WO 3+2 x Oxygen Excess Antimony Tungsten Bronze journal, January 2019

Superconductivity in WO 2.6 F 0.4 synthesized by reaction of WO 3 with teflon journal, November 2011

Thallium-Tungsten Bronze: A Solid State Defect Structure 1 journal, November 1959

Crystal structure and superconductivity of rubidium tungsten bronzes RbxWO3 prepared by a hybrid microwave method journal, April 2008

On the structure of tetragonal tin-tungsten bronzes journal, October 1972

Opportunities and challenges in science and technology of WO3 for electrochromic and related applications journal, February 2008

Tungsten-based oxide semiconductors for solar hydrogen generation journal, January 2013

Superconductivity of sodium tungsten bronze with cubic structure journal, February 1996

Single-crystal structure validation with the program PLATON journal, January 2003

Crystal structure of a hexagonal tin tungsten bronze prepared by a mild reaction journal, March 1995

OLEX2 : a complete structure solution, refinement and analysis program journal, January 2009

Le systeme SbWO3 et les bronzes de tungstene — Antimoine journal, May 1975

Preparation of tungsten bronzes from metals halides journal, March 1968

Superconducting properties of the K x WO 3 tetragonal tungsten bronze and the superconducting phase diagram of the tungsten bronze family journal, March 2014

Enhancement of the superconducting transition temperature near a phase instability in NaxWO3 journal, August 1974

The tungsten bronzes and related compounds journal, January 1968

Magnetic susceptibility of cubic uranium tungsten bronzes between 4.2 and 560.deg.K journal, June 1969

Electronic Band Structure Study of the Anomalous Electrical and Superconducting Properties of Hexagonal Alkali Tungsten Bronzes A x WO 3 (A = K, Rb, Cs) journal, April 1997

Superconductivity of Sodium Tungsten Bronzes journal, December 1964

Superconductivity and crystal structural origins of the metal-insulator transition in Ba 6 − x Sr x Nb 10 O 30 tetragonal tungsten bronzes journal, December 2015

Superconductivity of the alkali tungsten bronzes journal, March 1965

Title: Sn_0.24WO₃ hexagonal tungsten bronze prepared via the metal chloride route

Chemical synthesis and electronic conduction properties of sodium and potassium tungsten bronzes
journal, December 2000

Superconductivity in the tungsten bronzes
journal, November 1978

Superconductivity in the tungsten bronze ${Rb}_{x} W O_{3}$ $(0.20 ⩽ x ⩽ 0.33)$ in connection with its structure, electronic density of states, and phonon density of states
journal, November 2007

Low temperature magnetic susceptibility of uranium and rare earth tungsten oxide bronzes
journal, November 1974

New lithium, ammonium, and tin hexagonal tungsten bronzes prepared hydrothermallly
journal, August 1968

Normal and superconducting properties of $K_{x}$ W $O_{3}$
journal, March 1981

Preparation, structure, and Mössbauer spectra of tin tungsten bronzes
journal, December 1970

Electrical and Magnetic Properties of Potassium Tungsten Bronze and Rubidium Tungsten Bronze
journal, June 1963

An X-Ray and Electron Diffraction Study of the Intergrowth Tungsten Bronze Sb0.16WO3
journal, December 1997

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

Etude comparative des structures M _x WO ₃ de type bronze hexagonal. II. Evolution structurale dans la série des bronzes In _x WO ₃ (0,12 < x < 0,33)
journal, July 1979

Effect of Oxygen Concentration on Superconducting Properties of Rubidium Tungsten Bronzes Rb x WO y
journal, January 2007

Structural Studies of Calcium Tungsten Bronzes, CaxWO3, Formed at High Pressure
journal, July 2000

Superconducting phase diagram of In _x WO ₃ synthesized by indium deintercalation
journal, July 2013

Investigation of the Rb–W–O system in connexion with the superconducting properties of the hexagonal tungsten bronzes
journal, April 2003

The Preparation and Properties of a Barium Tungsten Bronze
journal, July 1965

The sodium tungsten bronzes as plasmonic materials: fabrication, calculation and characterization
journal, June 2017

Superconductivity in hexagonal tungsten bronzes
journal, May 1967

Conduction properties of the hexagonal tungsten bronze, ${Rb}_{x} W O_{3}$
journal, September 1979

The h ‐Sb _x WO _{3+2 x} Oxygen Excess Antimony Tungsten Bronze
journal, January 2019

Superconductivity in WO $_{2.6}$ F $_{0.4}$ synthesized by reaction of WO $_{3}$ with teflon
journal, November 2011

Thallium-Tungsten Bronze: A Solid State Defect Structure ¹
journal, November 1959

Crystal structure and superconductivity of rubidium tungsten bronzes RbxWO3 prepared by a hybrid microwave method
journal, April 2008

On the structure of tetragonal tin-tungsten bronzes
journal, October 1972

Opportunities and challenges in science and technology of WO3 for electrochromic and related applications
journal, February 2008

Tungsten-based oxide semiconductors for solar hydrogen generation
journal, January 2013

Superconductivity of sodium tungsten bronze with cubic structure
journal, February 1996

Single-crystal structure validation with the program PLATON
journal, January 2003

Crystal structure of a hexagonal tin tungsten bronze prepared by a mild reaction
journal, March 1995

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

Le systeme SbWO3 et les bronzes de tungstene — Antimoine
journal, May 1975

Preparation of tungsten bronzes from metals halides
journal, March 1968

Superconducting properties of the $K_{x} {WO}_{3}$ tetragonal tungsten bronze and the superconducting phase diagram of the tungsten bronze family
journal, March 2014

Enhancement of the superconducting transition temperature near a phase instability in NaxWO3
journal, August 1974

The tungsten bronzes and related compounds
journal, January 1968

Magnetic susceptibility of cubic uranium tungsten bronzes between 4.2 and 560.deg.K
journal, June 1969

Electronic Band Structure Study of the Anomalous Electrical and Superconducting Properties of Hexagonal Alkali Tungsten Bronzes A _x WO ₃ (A = K, Rb, Cs)
journal, April 1997

Superconductivity of Sodium Tungsten Bronzes
journal, December 1964

Superconductivity and crystal structural origins of the metal-insulator transition in ${Ba}_{6 - x} {Sr}_{x} {Nb}_{10} O_{30}$ tetragonal tungsten bronzes
journal, December 2015

Superconductivity of the alkali tungsten bronzes
journal, March 1965