Small molecule crystals with 1D water wires modulate electronic properties of surface water networks

Saraei, Nina; Gupta, Alexander J.; Hietsoi, Oleksandr; Frye, Brian C.; Hofsommer, Dillon T.; Sumanasekera, Gamini; Gupta, Gautam; Mashuta, Mark S.; Buchanan, Robert M.; Grapperhaus, Craig A.

doi:10.1016/j.apmt.2020.100895

Title: Small molecule crystals with 1D water wires modulate electronic properties of surface water networks

Abstract

This work evaluates the effect of water vapor pressure on the surface conductivity of a hydrated small molecule crystal under dry and wet conditions. The crystal contains a discrete metal complex with waters of hydration in structural positions and in 1D water wires. Under dry conditions, the surface of the hydrated crystal behaves as a near ideal capacitor. Under wet conditions, the waters of hydration serve as a template to assemble surface water networks by organization of water from the environment. The surface water provides pathways for charge transfer attributed to proton mobility that increases conductivity by > 3 orders in magnitude. Modulation between wet and dry conditions tunes the conductivity of the crystal surface via a two-step process, which has been evaluated kinetically as a function of the water vapor pressure.

Authors:

Saraei, Nina ^[1]; Gupta, Alexander J. ^[2]; Hietsoi, Oleksandr ^[3]; Frye, Brian C. ^[1]; Hofsommer, Dillon T. ^[1]; Sumanasekera, Gamini ^[4]; Gupta, Gautam ^[2]; Mashuta, Mark S. ^[1]; Buchanan, Robert M. ^[1]; Grapperhaus, Craig A. ^[1]

Univ. of Louisville, KY (United States). Dept. of Chemistry
Univ. of Louisville, KY (United States). Dept. of Chemical Engineering
Univ. of Louisville, KY (United States). Dept. of Chemistry; Middle Tennessee State Univ., Murfreesboro, TN (United States). Dept. of Chemistry
Univ. of Louisville, KY (United States). Dept. of Physics and Astronomy

Publication Date:: Sun Dec 06 00:00:00 EST 2020

Research Org.:: Univ. of Louisville, KY (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1849835

Alternate Identifier(s):: OSTI ID: 1781185

Grant/Contract Number:: FG02-08CH11538; CHE-1665136; CHE1800245

Resource Type:: Accepted Manuscript

Journal Name:: Applied Materials Today

Additional Journal Information:: Journal Volume: 22; Journal Issue: C; Journal ID: ISSN 2352-9407

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Materials Science; Surface conductivity; Electronic properties; Proton mobility; Water wires; Humidity sensor

Citation Formats


                    Saraei, Nina, Gupta, Alexander J., Hietsoi, Oleksandr, Frye, Brian C., Hofsommer, Dillon T., Sumanasekera, Gamini, Gupta, Gautam, Mashuta, Mark S., Buchanan, Robert M., and Grapperhaus, Craig A. Small molecule crystals with 1D water wires modulate electronic properties of surface water networks.  United States: N. p., 2020. 
Web.  doi:10.1016/j.apmt.2020.100895.

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                    Saraei, Nina, Gupta, Alexander J., Hietsoi, Oleksandr, Frye, Brian C., Hofsommer, Dillon T., Sumanasekera, Gamini, Gupta, Gautam, Mashuta, Mark S., Buchanan, Robert M., & Grapperhaus, Craig A. Small molecule crystals with 1D water wires modulate electronic properties of surface water networks.  United States.  https://doi.org/10.1016/j.apmt.2020.100895

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                    Saraei, Nina, Gupta, Alexander J., Hietsoi, Oleksandr, Frye, Brian C., Hofsommer, Dillon T., Sumanasekera, Gamini, Gupta, Gautam, Mashuta, Mark S., Buchanan, Robert M., and Grapperhaus, Craig A. Sun .  
"Small molecule crystals with 1D water wires modulate electronic properties of surface water networks".  United States.  https://doi.org/10.1016/j.apmt.2020.100895.  https://www.osti.gov/servlets/purl/1849835.

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@article{osti_1849835,

  title        = {Small molecule crystals with 1D water wires modulate electronic properties of surface water networks},

  author       = {Saraei, Nina and Gupta, Alexander J. and Hietsoi, Oleksandr and Frye, Brian C. and Hofsommer, Dillon T. and Sumanasekera, Gamini and Gupta, Gautam and Mashuta, Mark S. and Buchanan, Robert M. and Grapperhaus, Craig A.},

  abstractNote = {This work evaluates the effect of water vapor pressure on the surface conductivity of a hydrated small molecule crystal under dry and wet conditions. The crystal contains a discrete metal complex with waters of hydration in structural positions and in 1D water wires. Under dry conditions, the surface of the hydrated crystal behaves as a near ideal capacitor. Under wet conditions, the waters of hydration serve as a template to assemble surface water networks by organization of water from the environment. The surface water provides pathways for charge transfer attributed to proton mobility that increases conductivity by > 3 orders in magnitude. Modulation between wet and dry conditions tunes the conductivity of the crystal surface via a two-step process, which has been evaluated kinetically as a function of the water vapor pressure.},

  doi          = {10.1016/j.apmt.2020.100895},

  journal      = {Applied Materials Today},

  number       = C,

  volume       = 22,

  place        = {United States},

  year         = {Sun Dec 06 00:00:00 EST 2020},

  month        = {Sun Dec 06 00:00:00 EST 2020}

}

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Title: Small molecule crystals with 1D water wires modulate electronic properties of surface water networks

Abstract

Citation Formats

Co–Ca Phosphonate Showing Humidity-Sensitive Single Crystal to Single Crystal Structural Transformation and Tunable Proton Conduction Properties journal, November 2015

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Proton Conductivity: Materials and Applications journal, January 1996

Polarized Water Wires under Confinement in Chiral Channels journal, July 2015

Small Water Clusters in Crystalline Hydrates journal, September 2003

Structures and Solid-State Dynamics of One-Dimensional Water Chains Stabilized by Imidazole Channels journal, November 2003

Energiebänder der tunnelnden Überschuß-Protonen in flüssigen Säuren. Eine IR-spektroskopische Untersuchung der Natur der Gruppierungen H 5 O 2 + journal, April 1968

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Single Crystal to Single Crystal Structural Transformations in Molecular Framework Materials
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journal, June 2019

How Water’s Properties Are Encoded in Its Molecular Structure and Energies
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Proton Conductivity: Materials and Applications
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Polarized Water Wires under Confinement in Chiral Channels
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Structures and Solid-State Dynamics of One-Dimensional Water Chains Stabilized by Imidazole Channels
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Energiebänder der tunnelnden Überschuß-Protonen in flüssigen Säuren. Eine IR-spektroskopische Untersuchung der Natur der Gruppierungen H ₅ O ₂ ⁺
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