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Title: Evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperature

Abstract

This work studies the evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperatures (up to 800 °C). A multiscale investigation is carried out to study the thermal degradation of cementitious composite materials at multiple scale levels: at cement past level, the dehydration kinetics of cement hydrates (i.e., C–S–H, CH and aluminate hydrates) and development of microcracks are studied as functions of exposure temperatures. The damage mechanism of the inclusion phases and damages within the interfacial transition zone (ITZ) under elevated temperature are also investigated. In addition, the change of mechanical (i.e., elastic moduli, compressive strengths) and thermal (thermal conductivities) properties are measured as functions of the exposure temperature. Based on the experimental studies, a multiscale thermal degradation model is developed where the thermal degradations of cement paste (including water composition, porosity, and solid phase changes), inclusion phases, and the interfaces are captured through a multiscale sub-stepping homogenization scheme. The thermal degradation model is validated through multiple sets of experimental data. Finally, the influence of key parameters including the particle size distribution of the inclusions, the chemical composition, as well as the effects of ITZ damage are studied.

Authors:
 [1];  [1];  [1];  [2]
  1. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Civil and Environmental Engineering
  2. Moffatt & Nichol Inc., Raleigh, NC (United States)
Publication Date:
Research Org.:
Univ. of Alabama, Tuscaloosa, AL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Building Technologies Office; National Science Foundation (NSF)
OSTI Identifier:
1848857
Alternate Identifier(s):
OSTI ID: 1778479
Grant/Contract Number:  
EE0008677; CMMI-1663302; CMMI-1954517
Resource Type:
Accepted Manuscript
Journal Name:
Cement and Concrete Composites
Additional Journal Information:
Journal Volume: 118; Journal Issue: C; Journal ID: ISSN 0958-9465
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Construction & building technology; Materials Science; Cementitious composites; Thermal damage; Lightweight fillers; Micro-mechanics model

Citation Formats

Shen, Zhenglai, Zhou, Hongyu, Brooks, Adam, and Hanna, Dominic. Evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperature. United States: N. p., 2021. Web. doi:10.1016/j.cemconcomp.2021.103931.
Shen, Zhenglai, Zhou, Hongyu, Brooks, Adam, & Hanna, Dominic. Evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperature. United States. https://doi.org/10.1016/j.cemconcomp.2021.103931
Shen, Zhenglai, Zhou, Hongyu, Brooks, Adam, and Hanna, Dominic. Thu . "Evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperature". United States. https://doi.org/10.1016/j.cemconcomp.2021.103931. https://www.osti.gov/servlets/purl/1848857.
@article{osti_1848857,
title = {Evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperature},
author = {Shen, Zhenglai and Zhou, Hongyu and Brooks, Adam and Hanna, Dominic},
abstractNote = {This work studies the evolution of elastic and thermal properties of cementitious composites containing micro-size lightweight fillers after exposure to elevated temperatures (up to 800 °C). A multiscale investigation is carried out to study the thermal degradation of cementitious composite materials at multiple scale levels: at cement past level, the dehydration kinetics of cement hydrates (i.e., C–S–H, CH and aluminate hydrates) and development of microcracks are studied as functions of exposure temperatures. The damage mechanism of the inclusion phases and damages within the interfacial transition zone (ITZ) under elevated temperature are also investigated. In addition, the change of mechanical (i.e., elastic moduli, compressive strengths) and thermal (thermal conductivities) properties are measured as functions of the exposure temperature. Based on the experimental studies, a multiscale thermal degradation model is developed where the thermal degradations of cement paste (including water composition, porosity, and solid phase changes), inclusion phases, and the interfaces are captured through a multiscale sub-stepping homogenization scheme. The thermal degradation model is validated through multiple sets of experimental data. Finally, the influence of key parameters including the particle size distribution of the inclusions, the chemical composition, as well as the effects of ITZ damage are studied.},
doi = {10.1016/j.cemconcomp.2021.103931},
journal = {Cement and Concrete Composites},
number = C,
volume = 118,
place = {United States},
year = {Thu Apr 01 00:00:00 EDT 2021},
month = {Thu Apr 01 00:00:00 EDT 2021}
}

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