Investigating the CO2 pressure effect on underwater laser-induced plasma emission of Eu and Yb
Abstract
Laser-induced breakdown spectroscopy (LIBS) is an emerging analytical technique for in situ determination of elements in natural resources. The technique is employed for the study of two rare earth elements (Eu and Yb) in aqueous solutions at pressures ranging from ambient to 250 bar. Underwater plasma is created at ambient and elevated pressures to record LIBS spectra from their solutions using Nd:YAG laser operated at its fundamental wavelength of 1064 nm. The effect of CO2 pressure on the characteristic spectral signatures of these two rare earth elements is presented. Variation of intensity, integrated intensity, and width of selected emission lines with CO2 pressure is explained. Here, the technique could potentially be used for the detection of rare earth elements in oceanic, carbon sequestration, and geothermal fluids.
- Authors:
-
[1];
- National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Mississippi State Univ., Mississippi State, MS (United States)
- National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
- Mississippi State Univ., Mississippi State, MS (United States)
- Publication Date:
- Research Org.:
- National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1841256
- Alternate Identifier(s):
- OSTI ID: 1693631
- Grant/Contract Number:
- 89243318CFE000003
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Spectrochimica Acta. Part B, Atomic Spectroscopy
- Additional Journal Information:
- Journal Volume: 149; Journal Issue: November 2018; Journal ID: ISSN 0584-8547
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
Citation Formats
Bhatt, Chet R., Jain, Jinesh C., and McIntyre, Dustin L. Investigating the CO2 pressure effect on underwater laser-induced plasma emission of Eu and Yb. United States: N. p., 2018.
Web. doi:10.1016/j.sab.2018.07.002.
Bhatt, Chet R., Jain, Jinesh C., & McIntyre, Dustin L. Investigating the CO2 pressure effect on underwater laser-induced plasma emission of Eu and Yb. United States. https://doi.org/10.1016/j.sab.2018.07.002
Bhatt, Chet R., Jain, Jinesh C., and McIntyre, Dustin L. Fri .
"Investigating the CO2 pressure effect on underwater laser-induced plasma emission of Eu and Yb". United States. https://doi.org/10.1016/j.sab.2018.07.002. https://www.osti.gov/servlets/purl/1841256.
@article{osti_1841256,
title = {Investigating the CO2 pressure effect on underwater laser-induced plasma emission of Eu and Yb},
author = {Bhatt, Chet R. and Jain, Jinesh C. and McIntyre, Dustin L.},
abstractNote = {Laser-induced breakdown spectroscopy (LIBS) is an emerging analytical technique for in situ determination of elements in natural resources. The technique is employed for the study of two rare earth elements (Eu and Yb) in aqueous solutions at pressures ranging from ambient to 250 bar. Underwater plasma is created at ambient and elevated pressures to record LIBS spectra from their solutions using Nd:YAG laser operated at its fundamental wavelength of 1064 nm. The effect of CO2 pressure on the characteristic spectral signatures of these two rare earth elements is presented. Variation of intensity, integrated intensity, and width of selected emission lines with CO2 pressure is explained. Here, the technique could potentially be used for the detection of rare earth elements in oceanic, carbon sequestration, and geothermal fluids.},
doi = {10.1016/j.sab.2018.07.002},
journal = {Spectrochimica Acta. Part B, Atomic Spectroscopy},
number = November 2018,
volume = 149,
place = {United States},
year = {Fri Jul 06 00:00:00 EDT 2018},
month = {Fri Jul 06 00:00:00 EDT 2018}
}
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Works referencing / citing this record:
Laser focusing geometry effects on laser-induced plasma and laser-induced breakdown spectroscopy in bulk water
journal, January 2019
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