Two-Step Patterning of Scalable All-Inorganic Halide Perovskite Arrays
Abstract
Halide perovskites have many important optoelectronic properties, including high emission efficiency, high absorption coefficients, color purity, and tunable emission wavelength, which makes these materials promising for optoelectronic applications. However, the inability to precisely control large-scale patterned growth of halide perovskites limits their potential toward various device applications. Here, we report a patterning method for the growth of a cesium lead halide perovskite single crystal array. Our approach consists of two steps: (1) cesium halide salt arrays patterning and (2) chemical vapor transport process to convert salt arrays into single crystal perovskite arrays. Characterizations including energy-dispersive X-ray spectroscopy and photoluminescence have been employed to confirm the chemical compositions and the optical properties of the as-synthesized perovskite arrays. This patterning method enables the patterning of single crystal cesium lead halide perovskite arrays with tunable spacing (from 2 to 20 μm) and crystal size (from 200 nm to 1.2 μm) in high production yield (almost every pixel in the array is successfully grown with converted perovskite crystals). Furthermore, our large-scale patterning method renders a platform for the study of fundamental properties and opportunities for perovskite-based optoelectronic applications.
- Authors:
-
[1];
[3];
[4]
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Kavli Energy NanoScience Inst., Berkeley, CA (United States); Yonsei Univ., Seoul (Korea); Sungkyunkwan Univ. (SKKU), Suwon (Korea)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoScience Inst., Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1841153
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 14; Journal Issue: 3; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; halide perovskite; patterning; crystal growth; large-scale array; chemical vapor transport; perovskite optoelectronics; crystals; crystallization; wetting; crystal structure; perovskites
Citation Formats
Lin, Chung-Kuan, Zhao, Qiuchen, Zhang, Ye, Cestellos-Blanco, Stefano, Kong, Qiao, Lai, Minliang, Kang, Joohoon, and Yang, Peidong. Two-Step Patterning of Scalable All-Inorganic Halide Perovskite Arrays. United States: N. p., 2020.
Web. doi:10.1021/acsnano.9b09685.
Lin, Chung-Kuan, Zhao, Qiuchen, Zhang, Ye, Cestellos-Blanco, Stefano, Kong, Qiao, Lai, Minliang, Kang, Joohoon, & Yang, Peidong. Two-Step Patterning of Scalable All-Inorganic Halide Perovskite Arrays. United States. https://doi.org/10.1021/acsnano.9b09685
Lin, Chung-Kuan, Zhao, Qiuchen, Zhang, Ye, Cestellos-Blanco, Stefano, Kong, Qiao, Lai, Minliang, Kang, Joohoon, and Yang, Peidong. Fri .
"Two-Step Patterning of Scalable All-Inorganic Halide Perovskite Arrays". United States. https://doi.org/10.1021/acsnano.9b09685. https://www.osti.gov/servlets/purl/1841153.
@article{osti_1841153,
title = {Two-Step Patterning of Scalable All-Inorganic Halide Perovskite Arrays},
author = {Lin, Chung-Kuan and Zhao, Qiuchen and Zhang, Ye and Cestellos-Blanco, Stefano and Kong, Qiao and Lai, Minliang and Kang, Joohoon and Yang, Peidong},
abstractNote = {Halide perovskites have many important optoelectronic properties, including high emission efficiency, high absorption coefficients, color purity, and tunable emission wavelength, which makes these materials promising for optoelectronic applications. However, the inability to precisely control large-scale patterned growth of halide perovskites limits their potential toward various device applications. Here, we report a patterning method for the growth of a cesium lead halide perovskite single crystal array. Our approach consists of two steps: (1) cesium halide salt arrays patterning and (2) chemical vapor transport process to convert salt arrays into single crystal perovskite arrays. Characterizations including energy-dispersive X-ray spectroscopy and photoluminescence have been employed to confirm the chemical compositions and the optical properties of the as-synthesized perovskite arrays. This patterning method enables the patterning of single crystal cesium lead halide perovskite arrays with tunable spacing (from 2 to 20 μm) and crystal size (from 200 nm to 1.2 μm) in high production yield (almost every pixel in the array is successfully grown with converted perovskite crystals). Furthermore, our large-scale patterning method renders a platform for the study of fundamental properties and opportunities for perovskite-based optoelectronic applications.},
doi = {10.1021/acsnano.9b09685},
journal = {ACS Nano},
number = 3,
volume = 14,
place = {United States},
year = {Fri Feb 14 00:00:00 EST 2020},
month = {Fri Feb 14 00:00:00 EST 2020}
}
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