Co-infiltration of Nickel and Mixed Conducting Gd0.1Ce0.9O2-δ and La0.6Sr0.3Ni0.15Cr0.85O3-δ Phases in Ni-YSZ Anodes for Improved Stability and Performance
Abstract
Liquid-phase infiltration of nickel (Ni) nanoparticles in Ni/yttria-stabilized-zirconia (YSZ) cermet anodes for solid oxide fuel cells can improve anode performance provided that the infiltrated nanoparticles on YSZ connect to form conducting pathways and the Ni nanoparticles do not coarsen significantly. This study explores liquid phase co-infiltration of Ni with mixed conducting oxides, the latter providing microstructural stability and conductive pathways between Ni nanoparticles. Two mixed conducting oxides have been studied: Gd0.1Ce0.9O2-δ (GDC), a predominantly ionic conductor, and La0.6Sr0.3Ni0.15Cr0.85O3-δ (LSNC), a predominantly electronic conductor. Experimental results show that both oxides improve the nickel nanoparticle stability and charge transfer kinetics. However, the electrochemical performance of the Ni-GDC-infiltrated electrode is much better than that of the Ni-LSNC-infiltrated electrode. This is attributed to the citrate–nitrate combustion reaction required to form LSNC, which fills the pores of the anode and inhibits gas diffusion, reducing the performance of the Ni-LSNC-infiltrated electrode.
- Authors:
-
- Boston Univ., MA (United States)
- Publication Date:
- Research Org.:
- Boston Univ., MA (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1833228
- Grant/Contract Number:
- FE0026096
- Resource Type:
- Accepted Manuscript
- Journal Name:
- JOM. Journal of the Minerals, Metals & Materials Society
- Additional Journal Information:
- Journal Volume: 71; Journal Issue: 11; Journal ID: ISSN 1047-4838
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Lu, Yanchen, Gasper, Paul, Nikiforov, Alexey Y., Pal, Uday B., Gopalan, Srikanth, and Basu, Soumendra N. Co-infiltration of Nickel and Mixed Conducting Gd0.1Ce0.9O2-δ and La0.6Sr0.3Ni0.15Cr0.85O3-δ Phases in Ni-YSZ Anodes for Improved Stability and Performance. United States: N. p., 2019.
Web. doi:10.1007/s11837-019-03723-1.
Lu, Yanchen, Gasper, Paul, Nikiforov, Alexey Y., Pal, Uday B., Gopalan, Srikanth, & Basu, Soumendra N. Co-infiltration of Nickel and Mixed Conducting Gd0.1Ce0.9O2-δ and La0.6Sr0.3Ni0.15Cr0.85O3-δ Phases in Ni-YSZ Anodes for Improved Stability and Performance. United States. https://doi.org/10.1007/s11837-019-03723-1
Lu, Yanchen, Gasper, Paul, Nikiforov, Alexey Y., Pal, Uday B., Gopalan, Srikanth, and Basu, Soumendra N. Tue .
"Co-infiltration of Nickel and Mixed Conducting Gd0.1Ce0.9O2-δ and La0.6Sr0.3Ni0.15Cr0.85O3-δ Phases in Ni-YSZ Anodes for Improved Stability and Performance". United States. https://doi.org/10.1007/s11837-019-03723-1. https://www.osti.gov/servlets/purl/1833228.
@article{osti_1833228,
title = {Co-infiltration of Nickel and Mixed Conducting Gd0.1Ce0.9O2-δ and La0.6Sr0.3Ni0.15Cr0.85O3-δ Phases in Ni-YSZ Anodes for Improved Stability and Performance},
author = {Lu, Yanchen and Gasper, Paul and Nikiforov, Alexey Y. and Pal, Uday B. and Gopalan, Srikanth and Basu, Soumendra N.},
abstractNote = {Liquid-phase infiltration of nickel (Ni) nanoparticles in Ni/yttria-stabilized-zirconia (YSZ) cermet anodes for solid oxide fuel cells can improve anode performance provided that the infiltrated nanoparticles on YSZ connect to form conducting pathways and the Ni nanoparticles do not coarsen significantly. This study explores liquid phase co-infiltration of Ni with mixed conducting oxides, the latter providing microstructural stability and conductive pathways between Ni nanoparticles. Two mixed conducting oxides have been studied: Gd0.1Ce0.9O2-δ (GDC), a predominantly ionic conductor, and La0.6Sr0.3Ni0.15Cr0.85O3-δ (LSNC), a predominantly electronic conductor. Experimental results show that both oxides improve the nickel nanoparticle stability and charge transfer kinetics. However, the electrochemical performance of the Ni-GDC-infiltrated electrode is much better than that of the Ni-LSNC-infiltrated electrode. This is attributed to the citrate–nitrate combustion reaction required to form LSNC, which fills the pores of the anode and inhibits gas diffusion, reducing the performance of the Ni-LSNC-infiltrated electrode.},
doi = {10.1007/s11837-019-03723-1},
journal = {JOM. Journal of the Minerals, Metals & Materials Society},
number = 11,
volume = 71,
place = {United States},
year = {Tue Aug 13 00:00:00 EDT 2019},
month = {Tue Aug 13 00:00:00 EDT 2019}
}
Works referenced in this record:
An Effective Property Model for Infiltrated Electrodes in Solid Oxide Fuel Cells
journal, October 2013
- Hardjo, Eric F.; Monder, Dayadeep S.; Karan, Kunal
- Journal of The Electrochemical Society, Vol. 161, Issue 1
Degradation and Relaxation Effects of Ni Patterned Anodes in H[sub 2]–H[sub 2]O Atmosphere
journal, January 2010
- Utz, A.; Störmer, H.; Leonide, A.
- Journal of The Electrochemical Society, Vol. 157, Issue 6
Lowering the Temperature of Solid Oxide Fuel Cells
journal, November 2011
- Wachsman, E. D.; Lee, K. T.
- Science, Vol. 334, Issue 6058
Optimization of Infiltration Techniques Used to Construct Ni/YSZ Anodes
journal, October 2013
- Keyvanfar, P.; Birss, V.
- ECS Transactions, Vol. 57, Issue 1
Infiltration of SOFC Stacks: Evaluation of the Electrochemical Performance Enhancement and the Underlying Changes in the Microstructure
journal, December 2015
- Kiebach, R.; Zielke, P.; Høgh, J. V. T.
- Fuel Cells, Vol. 16, Issue 1
Infiltration of ionic-, electronic- and mixed-conducting nano particles into La0.75Sr0.25MnO3–Y0.16Zr0.84O2 cathodes – A comparative study of performance enhancement and stability at different temperatures
journal, April 2013
- Kiebach, Ragnar; Knöfel, Christina; Bozza, Francesco
- Journal of Power Sources, Vol. 228
Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers
journal, January 2016
- Irvine, John T. S.; Neagu, Dragos; Verbraeken, Maarten C.
- Nature Energy, Vol. 1, Issue 1
Improving intermediate temperature performance of Ni-YSZ cermet anodes for solid oxide fuel cells by liquid infiltration of nickel nanoparticles
journal, August 2018
- Lu, Yanchen; Gasper, Paul; Pal, Uday B.
- Journal of Power Sources, Vol. 396
The fractal nature of the three-phase boundary: A heuristic approach to the degradation of nanostructured solid oxide fuel cell anodes
journal, August 2017
- Bertei, A.; Ruiz-Trejo, E.; Kareh, K.
- Nano Energy, Vol. 38
Stability of Nickel-Infiltrated Anodes in Intermediate Temperature SOFCs
journal, June 2015
- Miller, E. C.; Sherman, Q.; Gao, Z.
- ECS Transactions, Vol. 68, Issue 1
Study on the effects of polarization on local morphological change of nickel at active three-phase-boundary using patterned nickel-film electrode in solid oxide fuel cell anode
journal, August 2017
- Jiao, Zhenjun; Shikazono, Naoki
- Acta Materialia, Vol. 135
Effect of anodic current density on the spreading of infiltrated nickel nanoparticles in nickel-yttria stabilized zirconia cermet anodes
journal, January 2019
- Gasper, Paul; Lu, Yanchen; Basu, Soumendra N.
- Journal of Power Sources, Vol. 410-411
Optimization of Infiltration Techniques Used to Construct Ni/YSZ Anodes
journal, January 2014
- Keyvanfar, Parastoo; Birss, Viola
- Journal of The Electrochemical Society, Vol. 161, Issue 5
Switching on electrocatalytic activity in solid oxide cells
journal, August 2016
- Myung, Jae-ha; Neagu, Dragos; Miller, David N.
- Nature, Vol. 537, Issue 7621
Progress in material selection for solid oxide fuel cell technology: A review
journal, July 2015
- Mahato, Neelima; Banerjee, Amitava; Gupta, Alka
- Progress in Materials Science, Vol. 72
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges
journal, January 2012
- Jiang, San Ping
- International Journal of Hydrogen Energy, Vol. 37, Issue 1
Polarization measurements on single-step co-fired solid oxide fuel cells (SOFCs)
journal, October 2007
- Yoon, Kyung Joong; Zink, Peter; Gopalan, Srikanth
- Journal of Power Sources, Vol. 172, Issue 1
A-site deficient perovskite: the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes
journal, January 2015
- Sun, Yifei; Li, Jianhui; Zeng, Yimin
- Journal of Materials Chemistry A, Vol. 3, Issue 20
Microstructural Modeling and Effective Properties of Infiltrated SOFC Electrodes
journal, October 2013
- Bertei, A.; Pharoah, J. G.; Gawel, D. A. W.
- ECS Transactions, Vol. 57, Issue 1
Fabrication and modification of solid oxide fuel cell anodes via wet impregnation/infiltration technique
journal, September 2013
- Liu, Zhangbo; Liu, Beibei; Ding, Dong
- Journal of Power Sources, Vol. 237
Combined Deconvolution and CNLS Fitting Approach Applied on the Impedance Response of Technical Ni∕8YSZ Cermet Electrodes
journal, January 2008
- Sonn, V.; Leonide, A.; Ivers-Tiffée, E.
- Journal of The Electrochemical Society, Vol. 155, Issue 7
Improved controllability of wet infiltration technique for fabrication of solid oxide fuel cell anodes
journal, November 2017
- Kishimoto, Masashi; Kawakami, Yuki; Otani, Yuki
- Scripta Materialia, Vol. 140
Quantitative relationships between composition, particle size, triple phase boundary length and surface area in nickel-cermet anodes for Solid Oxide Fuel Cells
journal, September 2011
- Holzer, L.; Münch, B.; Iwanschitz, B.
- Journal of Power Sources, Vol. 196, Issue 17
Fabrication of High-Performance Ni/Y[sub 2]O[sub 3]-ZrO[sub 2] Cermet Anodes of Solid Oxide Fuel Cells by Ion Impregnation
journal, January 2002
- Jiang, San Ping; Duan, Yvonne Y.; Love, Jonathan G.
- Journal of The Electrochemical Society, Vol. 149, Issue 9
In operando optical study of active three phase boundary of nickel-yttria stabilized zirconia solid-oxide fuel cell anode under polarization
journal, August 2018
- Jiao, Zhenjun; Shikazono, Naoki
- Journal of Power Sources, Vol. 396
Recent Progress in the Development of Anode Materials for Solid Oxide Fuel Cells
journal, April 2011
- Cowin, Peter I.; Petit, Christophe T. G.; Lan, Rong
- Advanced Energy Materials, Vol. 1, Issue 3
Reactivating the Ni-YSZ electrode in solid oxide cells and stacks by infiltration
journal, February 2018
- Skafte, Theis Løye; Hjelm, Johan; Blennow, Peter
- Journal of Power Sources, Vol. 378
High-Performance SOFC Cathodes Prepared by Infiltration
journal, March 2009
- Vohs, John M.; Gorte, Raymond J.
- Advanced Materials, Vol. 21, Issue 9
Stability of Ni–yttria stabilized zirconia anodes based on Ni-impregnation
journal, November 2010
- Klemensø, Trine; Thydén, Karl; Chen, Ming
- Journal of Power Sources, Vol. 195, Issue 21
Evaluation and Modeling of the Cell Resistance in Anode-Supported Solid Oxide Fuel Cells
journal, January 2008
- Leonide, A.; Sonn, V.; Weber, A.
- Journal of The Electrochemical Society, Vol. 155, Issue 1
Solid Oxide Fuel Cell Anode Materials for Direct Hydrocarbon Utilization
journal, August 2012
- Ge, Xiao-Ming; Chan, Siew-Hwa; Liu, Qing-Lin
- Advanced Energy Materials, Vol. 2, Issue 10