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Title: Simulated lightning strike investigation of CFRP comprising a novel Polyaniline/Phenol based electrically conductive resin matrix

Abstract

Traditional carbon fiber reinforced plastics (CFRPs) have been reported to exhibit lower electrical conductivity in the through-thickness direction, and have since paved the path for developing new resin systems to improve the through-thickness electrical conductivity and functionality of CFRP laminates. This work designs and investigates a novel Polyaniline (PANI)/Phenol resin, which possesses high electrical conductivity and mechanical strength. The CFRP manufactured by this PANI/Phenol resin with an addition of up to (~23.30%) phenol resulted in 0.6 S/cm through-thickness conductivity and demonstrated flexural strength and modulus values of 477 MPa and 59.2 GPa, respectively. We further evaluate the effectiveness of lightning strike protection of PANI/Phenol-based conductive CFRP laminates with a simulated lightning strike test. In essence, this research reports on PANI/Phenol-based CFRP's effectiveness as a material for lightning suppression without applying traditional metal-based lightning strike protection (LSP) systems.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [4]; ORCiD logo [1]
  1. Univ. of Tokyo (Japan)
  2. Univ. Siegen (Germany)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Japan Aerospace Exploration Agency (ISAS/JAXA), Sagamihara, Kanagawa (Japan)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; Japan Society for the Promotion of Science (JSPS)
OSTI Identifier:
1817448
Alternate Identifier(s):
OSTI ID: 1811926
Grant/Contract Number:  
AC05-00OR22725; 16H02424; AC05- 00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Composites Science and Technology
Additional Journal Information:
Journal Volume: 214; Journal Issue: NA; Journal ID: ISSN 0266-3538
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; polyaniline; electrically conductive CFRP; lightning strike protection

Citation Formats

Zhou, Yu, Raghu, Swathi N.V., Kumar, Vipin, Okada, Takao, and Yokozeki, Tomohiro. Simulated lightning strike investigation of CFRP comprising a novel Polyaniline/Phenol based electrically conductive resin matrix. United States: N. p., 2021. Web. doi:10.1016/j.compscitech.2021.108971.
Zhou, Yu, Raghu, Swathi N.V., Kumar, Vipin, Okada, Takao, & Yokozeki, Tomohiro. Simulated lightning strike investigation of CFRP comprising a novel Polyaniline/Phenol based electrically conductive resin matrix. United States. https://doi.org/10.1016/j.compscitech.2021.108971
Zhou, Yu, Raghu, Swathi N.V., Kumar, Vipin, Okada, Takao, and Yokozeki, Tomohiro. Sat . "Simulated lightning strike investigation of CFRP comprising a novel Polyaniline/Phenol based electrically conductive resin matrix". United States. https://doi.org/10.1016/j.compscitech.2021.108971. https://www.osti.gov/servlets/purl/1817448.
@article{osti_1817448,
title = {Simulated lightning strike investigation of CFRP comprising a novel Polyaniline/Phenol based electrically conductive resin matrix},
author = {Zhou, Yu and Raghu, Swathi N.V. and Kumar, Vipin and Okada, Takao and Yokozeki, Tomohiro},
abstractNote = {Traditional carbon fiber reinforced plastics (CFRPs) have been reported to exhibit lower electrical conductivity in the through-thickness direction, and have since paved the path for developing new resin systems to improve the through-thickness electrical conductivity and functionality of CFRP laminates. This work designs and investigates a novel Polyaniline (PANI)/Phenol resin, which possesses high electrical conductivity and mechanical strength. The CFRP manufactured by this PANI/Phenol resin with an addition of up to (~23.30%) phenol resulted in 0.6 S/cm through-thickness conductivity and demonstrated flexural strength and modulus values of 477 MPa and 59.2 GPa, respectively. We further evaluate the effectiveness of lightning strike protection of PANI/Phenol-based conductive CFRP laminates with a simulated lightning strike test. In essence, this research reports on PANI/Phenol-based CFRP's effectiveness as a material for lightning suppression without applying traditional metal-based lightning strike protection (LSP) systems.},
doi = {10.1016/j.compscitech.2021.108971},
journal = {Composites Science and Technology},
number = NA,
volume = 214,
place = {United States},
year = {Sat Jul 31 00:00:00 EDT 2021},
month = {Sat Jul 31 00:00:00 EDT 2021}
}

Works referenced in this record:

Cost optimization of composite aircraft structures including variable laminate qualities
journal, October 2008


The coupling mechanism and damage prediction of carbon fiber/epoxy composites exposed to lightning current
journal, November 2018


Enhanced thermomechanical and electrical properties of multiwalled carbon nanotube paper reinforced epoxy laminar composites
journal, January 2018


Lightning Discharge and Fundamentals of Lightning Protection
journal, June 2012


The decoupling electrical and thermal conductivity of fullerene/polyaniline hybrids reinforced polymer composites
journal, May 2017


Coupled thermal–electrical analysis for carbon fiber/epoxy composites exposed to simulated lightning current
journal, August 2010

  • Ogasawara, Toshio; Hirano, Yoshiyasu; Yoshimura, Akinori
  • Composites Part A: Applied Science and Manufacturing, Vol. 41, Issue 8
  • DOI: 10.1016/j.compositesa.2010.04.001

A review of the electrical and mechanical properties of carbon nanofiller-reinforced polymer composites
journal, October 2018


Lightning strike damage behavior of carbon fiber reinforced epoxy, bismaleimide, and polyetheretherketone composites
journal, June 2018


Lightning Damage of Carbon Fiber/Epoxy Laminates with Interlayers Modified by Nickel-Coated Multi-Walled Carbon Nanotubes
journal, February 2017


Highly conductive graphene oxide/polyaniline hybrid polymer nanocomposites with simultaneously improved mechanical properties
journal, March 2016


Strain sensing behavior of multifunctional polyaniline-based thermoset polymer under static loading conditions
journal, August 2019


Development of electrically conductive structural BMI based CFRPs for lightning strike protection
journal, October 2018


New Insight into Organic Metal Polyaniline Morphology and Structure
journal, December 2010


Cationic scavenging by polyaniline: Boon or bane from synthesis point of view of its nanocomposites
journal, August 2018


Artificial lightning testing on graphite/epoxy composite laminate
journal, October 2010

  • Hirano, Yoshiyasu; Katsumata, Shingo; Iwahori, Yutaka
  • Composites Part A: Applied Science and Manufacturing, Vol. 41, Issue 10
  • DOI: 10.1016/j.compositesa.2010.06.008

Mechanical and electrical properties of PANI-based conductive thermosetting composites
journal, May 2015

  • Kumar, V.; Yokozeki, T.; Goto, T.
  • Journal of Reinforced Plastics and Composites, Vol. 34, Issue 16
  • DOI: 10.1177/0731684415588551

Current status of carbon fibre and carbon fibre composites recycling
journal, July 2020


Lightning strike resistance of an electrically conductive CFRP with a CSA-doped PANI/epoxy matrix
journal, December 2017


Thermoelectric properties and intrinsic conduction processes in DBSA and NaSIPA doped polyanilines
journal, September 2018


Synthesis and characterization of the electrically conductive polymeric composite for lightning strike protection of aircraft structures
journal, January 2017


Factors affecting direct lightning strike damage to fiber reinforced composites: A review
journal, February 2020


Thermal doping of polyaniline by sulfonic acids
journal, January 2003

  • Poussin, Denis; Morgan, Huda; Foot, Peter J?S
  • Polymer International, Vol. 52, Issue 3
  • DOI: 10.1002/pi.1107

Electro-mechanical fatigue of CFRP laminates for aircraft applications
journal, September 2015


Two-dimensional reinforcement of epoxy composites: alignment of multi-walled carbon nanotubes in two directions
journal, January 2020


Light weight non-metallic lightning strike protection film for CFRP
journal, December 2020


Lightning strike damage on the composite laminates with carbon nanotube films: Protection effect and damage mechanism
journal, July 2019


Experimental and numerical study on residual strength of aircraft carbon/epoxy composite after lightning strike
journal, April 2018


Effect of through-thickness electrical conductivity of CFRPs on lightning strike damages
journal, November 2018


Study of nanoparticles aggregation/agglomeration in polymer particulate nanocomposites by mechanical properties
journal, May 2016


Lightning damage suppression in a carbon fiber-reinforced polymer with a polyaniline-based conductive thermoset matrix
journal, April 2016


Polyaniline thermoset blends and composites
journal, May 2017


Scavenging phenomenon and improved electrical and mechanical properties of polyaniline–divinylbenzene composite in presence of MWCNT
journal, November 2017

  • Kumar, Vipin; Yokozeki, Tomohiro; Goto, Teruya
  • International Journal of Mechanics and Materials in Design, Vol. 14, Issue 4
  • DOI: 10.1007/s10999-017-9397-y