On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics
Abstract
Here, we discuss the Arrhenius behavior of electrical conductivity σ during flash sintering of 3 mol% yttria stabilized zirconia (3YSZ). In situ x-ray diffraction is used to determine sample temperature. Sintering contribution to σ is excluded by investigating the flash event on a dense ceramic. We show that total conductivity follows an Arrhenius-like equation in both dense and green samples, even during Stage II of flash. The non-linearity often verified during flash sintering of 3YSZ is therefore related to the furnace temperature instead of the sample temperature when building the ln(σ) vs. 1/T plots. Furthermore, we verified a change in the activation energy for conduction prior to the ignition of the flash event and discussed the possible mechanisms. For instance, the decrease in activation energy from Stage I to II in the dense sample is attributed to a contribution from electronic carriers.
- Authors:
-
[1];
[1];
[2];
- Univ. of Sao Paulo (Brazil); Univ. of Colorado, Boulder, CO (United States)
- Univ. of Colorado, Boulder, CO (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Univ. of Sao Paulo (Brazil)
- Univ. of Colorado, Boulder, CO (United States); Univ. Federal de Sao Carlos (UFSCAR) (Brazil)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Sao Paulo Research Foundation (FAPESP); National Council for Scientific and Technological Development (CNPq); US Army Research Office (ARO); US Department of the Navy, Office of Naval Research (ONR)
- OSTI Identifier:
- 1817201
- Alternate Identifier(s):
- OSTI ID: 1804581
- Report Number(s):
- BNL-222041-2021-JAAM
Journal ID: ISSN 1359-6462
- Grant/Contract Number:
- SC0012704; 2018/04331-5; 2018/19730-6; 2019/03786-1; 2019/14677-9; 200573/2018-7; W911NF-16-1-0200; N00014-18-1-2270
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scripta Materialia
- Additional Journal Information:
- Journal Volume: 203; Journal ID: ISSN 1359-6462
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; zirconia; electric field-assisted sintering; synchrotron; x-ray diffraction
Citation Formats
Campos, João V., Lavagnini, Isabela R., Avila, Viviana, Yoon, Bola, Ghose, Sanjit, Raj, Rishi, Pallone, Eliria M.J.A., and Jesus, Lilian M. On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics. United States: N. p., 2021.
Web. doi:10.1016/j.scriptamat.2021.114093.
Campos, João V., Lavagnini, Isabela R., Avila, Viviana, Yoon, Bola, Ghose, Sanjit, Raj, Rishi, Pallone, Eliria M.J.A., & Jesus, Lilian M. On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics. United States. https://doi.org/10.1016/j.scriptamat.2021.114093
Campos, João V., Lavagnini, Isabela R., Avila, Viviana, Yoon, Bola, Ghose, Sanjit, Raj, Rishi, Pallone, Eliria M.J.A., and Jesus, Lilian M. Wed .
"On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics". United States. https://doi.org/10.1016/j.scriptamat.2021.114093. https://www.osti.gov/servlets/purl/1817201.
@article{osti_1817201,
title = {On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics},
author = {Campos, João V. and Lavagnini, Isabela R. and Avila, Viviana and Yoon, Bola and Ghose, Sanjit and Raj, Rishi and Pallone, Eliria M.J.A. and Jesus, Lilian M.},
abstractNote = {Here, we discuss the Arrhenius behavior of electrical conductivity σ during flash sintering of 3 mol% yttria stabilized zirconia (3YSZ). In situ x-ray diffraction is used to determine sample temperature. Sintering contribution to σ is excluded by investigating the flash event on a dense ceramic. We show that total conductivity follows an Arrhenius-like equation in both dense and green samples, even during Stage II of flash. The non-linearity often verified during flash sintering of 3YSZ is therefore related to the furnace temperature instead of the sample temperature when building the ln(σ) vs. 1/T plots. Furthermore, we verified a change in the activation energy for conduction prior to the ignition of the flash event and discussed the possible mechanisms. For instance, the decrease in activation energy from Stage I to II in the dense sample is attributed to a contribution from electronic carriers.},
doi = {10.1016/j.scriptamat.2021.114093},
journal = {Scripta Materialia},
number = ,
volume = 203,
place = {United States},
year = {Wed Jun 30 00:00:00 EDT 2021},
month = {Wed Jun 30 00:00:00 EDT 2021}
}
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