Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte

Li, Yang; Arnold, William; Halacoglu, Selim; Jasinski, Jacek B.; Druffel, Thad; Wang, Hui

doi:10.1002/adfm.202101636

Title: Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte

Abstract

All-solid-state sodium (Na) batteries (ASSSBs) using sulfide-based solid electrolytes (SEs) have attracted intensive attention due to their superior safety, high energy density and low cost. However, interfacial issue is one of the biggest challenges to achieve high-performance sulfide-based ASSSBs due to the serious reactions between active Na metal and sulfide SEs at the interface. To address the interfacial challenges, we propose in this paper a simple and efficient approach by introducing a polymer electrolyte as an interlayer to stabilize the interface. Na₃SbS₄ as a model sulfide SE is used to demonstrate the interlayer strategy to stabilize the interface by preventing the detrimental reactions and inhibiting Na dendrites. As a result, stable Na plating/stripping was observed in Na symmetric cells under the current density of 0.1 mA cm^–2. Moreover, ASSSBs with Na metal and TiS₂ electrode delivered long-term stability over 300 cycles remaining a specific capacity above 100 mAh g^–1, and FeS₂||Na cells exhibited an impressive specific capacity of up to 200 mAh g^–1 after the 20th cycles. This work demonstrates an efficient strategy to address interfacial challenges between sulfide SEs and Na metal, which contributes to the development of ASSSBs in next-generation energy storage systems.

Authors:

^[1]; Arnold, William ^[1]; Halacoglu, Selim ^[1]; Jasinski, Jacek B. ^[1]; Druffel, Thad ^[1];

^[1]

Univ. of Louisville, KY (United States)

Publication Date:: Fri Apr 30 00:00:00 EDT 2021

Research Org.:: Univ. of Louisville, KY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

OSTI Identifier:: 1785686

Grant/Contract Number:: SC0021257

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Volume: 31; Journal Issue: 28; Journal ID: ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; sulfide electrolyte; Na3SbS4; interlayer; solid-state Na battery; interface stability

Citation Formats


                    Li, Yang, Arnold, William, Halacoglu, Selim, Jasinski, Jacek B., Druffel, Thad, and Wang, Hui. Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte.  United States: N. p., 2021. 
Web.  doi:10.1002/adfm.202101636.

Copy to clipboard


                    Li, Yang, Arnold, William, Halacoglu, Selim, Jasinski, Jacek B., Druffel, Thad, & Wang, Hui. Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte.  United States.  https://doi.org/10.1002/adfm.202101636

Copy to clipboard


                    Li, Yang, Arnold, William, Halacoglu, Selim, Jasinski, Jacek B., Druffel, Thad, and Wang, Hui. Fri .  
"Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte".  United States.  https://doi.org/10.1002/adfm.202101636.  https://www.osti.gov/servlets/purl/1785686.

Copy to clipboard


                    
@article{osti_1785686,

  title        = {Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte},

  author       = {Li, Yang and Arnold, William and Halacoglu, Selim and Jasinski, Jacek B. and Druffel, Thad and Wang, Hui},

  abstractNote = {All-solid-state sodium (Na) batteries (ASSSBs) using sulfide-based solid electrolytes (SEs) have attracted intensive attention due to their superior safety, high energy density and low cost. However, interfacial issue is one of the biggest challenges to achieve high-performance sulfide-based ASSSBs due to the serious reactions between active Na metal and sulfide SEs at the interface. To address the interfacial challenges, we propose in this paper a simple and efficient approach by introducing a polymer electrolyte as an interlayer to stabilize the interface. Na3SbS4 as a model sulfide SE is used to demonstrate the interlayer strategy to stabilize the interface by preventing the detrimental reactions and inhibiting Na dendrites. As a result, stable Na plating/stripping was observed in Na symmetric cells under the current density of 0.1 mA cm–2. Moreover, ASSSBs with Na metal and TiS2 electrode delivered long-term stability over 300 cycles remaining a specific capacity above 100 mAh g–1, and FeS2||Na cells exhibited an impressive specific capacity of up to 200 mAh g–1 after the 20th cycles. This work demonstrates an efficient strategy to address interfacial challenges between sulfide SEs and Na metal, which contributes to the development of ASSSBs in next-generation energy storage systems.},

  doi          = {10.1002/adfm.202101636},

  journal      = {Advanced Functional Materials},

  number       = 28,

  volume       = 31,

  place        = {United States},

  year         = {Fri Apr 30 00:00:00 EDT 2021},

  month        = {Fri Apr 30 00:00:00 EDT 2021}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1002/adfm.202101636

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Solid-State Sodium Batteries
journal, February 2018

Zhao, Chenglong; Liu, Lilu; Qi, Xingguo
Advanced Energy Materials, Vol. 8, Issue 17
DOI: 10.1002/aenm.201703012

Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application
journal, March 2019

Huang, Yongxin; Zhao, Luzi; Li, Li
Advanced Materials, Vol. 31, Issue 21
DOI: 10.1002/adma.201808393

Grain-boundary-resistance-less Na3SbS4-Se solid electrolytes for all-solid-state sodium batteries
journal, December 2019

Wan, Hongli; Mwizerwa, Jean Pierre; Han, Fudong
Nano Energy, Vol. 66
DOI: 10.1016/j.nanoen.2019.104109

Unveiling the Advances of 2D Materials for Li/Na-S Batteries Experimentally and Theoretically
journal, February 2020

Ye, Chao; Chao, Dongliang; Shan, Jieqiong
Matter, Vol. 2, Issue 2
DOI: 10.1016/j.matt.2019.12.020

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery
journal, December 2018

Fan, Xiulin; Ji, Xiao; Han, Fudong
Science Advances, Vol. 4, Issue 12
DOI: 10.1126/sciadv.aau9245

Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy–O2 batteries
journal, November 2018

Ma, Jin-ling; Meng, Fan-lu; Yu, Yue
Nature Chemistry, Vol. 11, Issue 1
DOI: 10.1038/s41557-018-0166-9

Na ₃ SbS ₄ : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries
journal, July 2016

Banerjee, Abhik; Park, Kern Ho; Heo, Jongwook W.
Angewandte Chemie, Vol. 128, Issue 33
DOI: 10.1002/ange.201604158

Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017

Tian, Yaosen; Shi, Tan; Richards, William D.
Energy & Environmental Science, Vol. 10, Issue 5
DOI: 10.1039/C7EE00534B

Aqueous-solution synthesis of Na ₃ SbS ₄ solid electrolytes for all-solid-state Na-ion batteries
journal, January 2018

Kim, Tae Won; Park, Kern Ho; Choi, Young Eun
Journal of Materials Chemistry A, Vol. 6, Issue 3
DOI: 10.1039/C7TA09242C

Hybrid electrolyte with robust garnet-ceramic electrolyte for lithium anode protection in lithium-oxygen batteries
journal, May 2018

Wang, Jin; Yin, Yanbin; Liu, Tong
Nano Research, Vol. 11, Issue 6
DOI: 10.1007/s12274-018-1972-5

Electrochemical Properties and Discharge Mechanism of Na/TiS ₂ Cells with Liquid Electrolyte at Room Temperature
journal, December 2012

Ryu, Ho-Suk; Kim, Jong-Seon; Park, Jin-Soo
Journal of The Electrochemical Society, Vol. 160, Issue 2
DOI: 10.1149/2.084302jes

A wide-ranging review on Nasicon type materials
journal, February 2011

Anantharamulu, N.; Koteswara Rao, K.; Rambabu, G.
Journal of Materials Science, Vol. 46, Issue 9
DOI: 10.1007/s10853-011-5302-5

Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage
journal, January 2019

Liu, Tiefeng; Zhang, Yaping; Jiang, Zhanguo
Energy & Environmental Science, Vol. 12, Issue 5
DOI: 10.1039/C8EE03727B

Progress of the Interface Design in All-Solid-State Li-S Batteries
journal, March 2018

Yue, Junpei; Yan, Min; Yin, Ya-Xia
Advanced Functional Materials, Vol. 28, Issue 38
DOI: 10.1002/adfm.201707533

Solid‐State Plastic Crystal Electrolytes: Effective Protection Interlayers for Sulfide‐Based All‐Solid‐State Lithium Metal Batteries
journal, March 2019

Wang, Changhong; Adair, Keegan R.; Liang, Jianwen
Advanced Functional Materials, Vol. 29, Issue 26
DOI: 10.1002/adfm.201900392

Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective
journal, October 2018

Hou, Wenru; Guo, Xianwei; Shen, Xuyang
Nano Energy, Vol. 52
DOI: 10.1016/j.nanoen.2018.07.036

Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries
journal, January 2018

Zhang, Dechao; Cao, Xiaoting; Xu, Di
Electrochimica Acta, Vol. 259
DOI: 10.1016/j.electacta.2017.10.173

Reactivity-Guided Interface Design in Na Metal Solid-State Batteries
journal, April 2019

Tian, Yaosen; Sun, Yingzhi; Hannah, Daniel C.
Joule, Vol. 3, Issue 4
DOI: 10.1016/j.joule.2018.12.019

Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries
journal, August 2020

Li, Yang; Arnold, William; Thapa, Arjun
ACS Applied Materials & Interfaces, Vol. 12, Issue 38
DOI: 10.1021/acsami.0c08261

TiS ₂ as an Advanced Conversion Electrode for Sodium-Ion Batteries with Ultra-High Capacity and Long-Cycle Life
journal, September 2018

Tao, Hongwei; Zhou, Min; Wang, Ruxing
Advanced Science, Vol. 5, Issue 11
DOI: 10.1002/advs.201801021

Computational and Experimental Investigations of Na-Ion Conduction in Cubic Na ₃ PSe ₄
journal, December 2015

Bo, Shou-Hang; Wang, Yan; Kim, Jae Chul
Chemistry of Materials, Vol. 28, Issue 1
DOI: 10.1021/acs.chemmater.5b04013

Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries
journal, January 2018

Zhao, Yang; Adair, Keegan R.; Sun, Xueliang
Energy & Environmental Science, Vol. 11, Issue 10
DOI: 10.1039/C8EE01373J

Main Challenges for High Performance NAS Battery: Materials and Interfaces
journal, May 2012

Wen, Zhaoyin; Hu, Yingying; Wu, Xiangwei
Advanced Functional Materials, Vol. 23, Issue 8
DOI: 10.1002/adfm.201200473

Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives
journal, May 2010

Lu, Xiaochuan; Xia, Guanguang; Lemmon, John P.
Journal of Power Sources, Vol. 195, Issue 9
DOI: 10.1016/j.jpowsour.2009.11.120

An Adjustable‐Porosity Plastic Crystal Electrolyte Enables High‐Performance All‐Solid‐State Lithium‐Oxygen Batteries
journal, April 2020

Wang, Jin; Huang, Gang; Chen, Kai
Angewandte Chemie International Edition, Vol. 59, Issue 24
DOI: 10.1002/anie.202002309

Multifunctional Sandwich-Structured Electrolyte for High-Performance Lithium-Sulfur Batteries
journal, January 2018

Qu, Hongtao; Zhang, Jianjun; Du, Aobing
Advanced Science, Vol. 5, Issue 3
DOI: 10.1002/advs.201700503

Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries
journal, August 2019

Zhang, Qing; Cao, Daxian; Ma, Yi
Advanced Materials, Vol. 31, Issue 44
DOI: 10.1002/adma.201901131

Vacancy-Contained Tetragonal Na ₃ SbS ₄ Superionic Conductor
journal, April 2016

Zhang, Long; Zhang, Dechao; Yang, Kun
Advanced Science, Vol. 3, Issue 10
DOI: 10.1002/advs.201600089

Na ₁₁ Sn ₂ PS ₁₂ : a new solid state sodium superionic conductor
journal, January 2018

Zhang, Z.; Ramos, E.; Lalère, F.
Energy & Environmental Science, Vol. 11, Issue 1
DOI: 10.1039/C7EE03083E

New Insights into the Interphase between the Na Metal Anode and Sulfide Solid-State Electrolytes: A Joint Experimental and Computational Study
journal, March 2018

Wu, Erik A.; Kompella, Christopher S.; Zhu, Zhuoying
ACS Applied Materials & Interfaces, Vol. 10, Issue 12
DOI: 10.1021/acsami.7b19037

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries
journal, January 2012

Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi
Nature Communications, Vol. 3, Issue 1
DOI: 10.1038/ncomms1843

Stabilizing Na3SbS4/Na interface by rational design via Cl doping and aqueous processing
journal, April 2021

Cao, Haonan; Yu, Meiqi; Zhang, Long
Journal of Materials Science & Technology, Vol. 70
DOI: 10.1016/j.jmst.2020.08.035

Hybrid solid electrolyte enabled dendrite-free Li anodes for high-performance quasi-solid-state lithium-oxygen batteries
journal, July 2020

Wang, Jin; Huang, Gang; Yan, Jun-Min
National Science Review, Vol. 8, Issue 2
DOI: 10.1093/nsr/nwaa150

TiS 2 nanoplates: A high-rate and stable electrode material for sodium ion batteries
journal, February 2016

Liu, Yuping; Wang, Hongtao; Cheng, Liang
Nano Energy, Vol. 20
DOI: 10.1016/j.nanoen.2015.12.028

Ultrathin 2D TiS ₂ Nanosheets for High Capacity and Long-Life Sodium Ion Batteries
journal, January 2019

Hu, Zhe; Tai, Zhixin; Liu, Qiannan
Advanced Energy Materials, Vol. 9, Issue 8
DOI: 10.1002/aenm.201803210

Facile Stabilization of the Sodium Metal Anode with Additives: Unexpected Key Role of Sodium Polysulfide and Adverse Effect of Sodium Nitrate
journal, May 2018

Wang, Huan; Wang, Chuanlong; Matios, Edward
Angewandte Chemie, Vol. 130, Issue 26
DOI: 10.1002/ange.201801818

An Air-Stable Na ₃ SbS ₄ Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure
journal, June 2016

Wang, Hui; Chen, Yan; Hood, Zachary D.
Angewandte Chemie, Vol. 128, Issue 30
DOI: 10.1002/ange.201601546

Sodium Metal Anodes: Emerging Solutions to Dendrite Growth
journal, April 2019

Lee, Byeongyong; Paek, Eunsu; Mitlin, David
Chemical Reviews, Vol. 119, Issue 8
DOI: 10.1021/acs.chemrev.8b00642

Designing a self-healing protective film on a lithium metal anode for long-cycle-life lithium-oxygen batteries
journal, March 2019

Yu, Yue; Yin, Yan-Bin; Ma, Jin-Ling
Energy Storage Materials, Vol. 18
DOI: 10.1016/j.ensm.2019.01.009

Progress in the Development of Sodium-Ion Solid Electrolytes
journal, September 2017

Kim, Jung-Joon; Yoon, Kyungho; Park, Inchul
Small Methods, Vol. 1, Issue 10
DOI: 10.1002/smtd.201700219

Gradiently Sodiated Alucone as an Interfacial Stabilizing Strategy for Solid‐State Na Metal Batteries
journal, April 2020

Zhang, Shumin; Zhao, Yang; Zhao, Feipeng
Advanced Functional Materials, Vol. 30, Issue 22
DOI: 10.1002/adfm.202001118

Stabilizing the Interface between Sodium Metal Anode and Sulfide-Based Solid-State Electrolyte with an Electron-Blocking Interlayer
journal, February 2019

Hu, Pu; Zhang, Ye; Chi, Xiaowei
ACS Applied Materials & Interfaces, Vol. 11, Issue 10
DOI: 10.1021/acsami.8b19984

Electrolyte and Interface Engineering for Solid-State Sodium Batteries
journal, September 2018

Lu, Yong; Li, Lin; Zhang, Qiu
Joule, Vol. 2, Issue 9
DOI: 10.1016/j.joule.2018.07.028

Research Development on Sodium-Ion Batteries
journal, October 2014

Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
Chemical Reviews, Vol. 114, Issue 23
DOI: 10.1021/cr500192f

Engineering Materials for Progressive All-Solid-State Na Batteries
journal, August 2018

Zhou, Chengtian; Bag, Sourav; Thangadurai, Venkataraman
ACS Energy Letters, Vol. 3, Issue 9
DOI: 10.1021/acsenergylett.8b00948

Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations
journal, December 2017

Tang, Hanmei; Deng, Zhi; Lin, Zhuonan
Chemistry of Materials, Vol. 30, Issue 1
DOI: 10.1021/acs.chemmater.7b04096

Similar Records in DOE PAGES and OSTI.GOV collections:

Highly efficient interface stabilization for ambient-temperature quasi-solid-state sodium metal batteries

Journal Article Li, Yang ; Halacoglu, Selim ; Shreyas, Varun ; ... - Chemical Engineering Journal

Solid-state sodium (Na) batteries (SSSBs) using sulfide-based solid electrolytes (SSEs) hold tremendous promise due to their high theoretical specific capacity, enhanced safety and abundant resources. However, detrimental interfacial issues between SSEs and Na metal present a major challenge to the advancement of sulfide-based SSSBs. To address interfacial issues, we demonstrate an efficient approach by incorporating an ionic liquid electrolyte ((PYR/Na)TFSI) as interlayer to stabilize the Na metal/SSE interface. The presence of the (PYR/Na)TFSI interlayer enables the formation of a stable solid electrolyte interphase (SEI) to prevent the harmful reactions and inhibit Na dendrites. Combination of ab initio molecular dynamics simulationsmore »« less
https://doi.org/10.1016/j.cej.2022.134679

Full Text Available
Stabilizing the Interface between Sodium Metal Anode and Sulfide-Based Solid-State Electrolyte with an Electron-Blocking Interlayer

Journal Article Hu, Pu ; Zhang, Ye ; Chi, Xiaowei ; ... - ACS Applied Materials and Interfaces

Sulfide-based Na-ion conductors are promising electrolytes for all-solid-state sodium batteries (ASSSBs) because of high ionic conductivity and favorable formability. However, no effective strategy has been reported for long-duration Na cycling with sulfide-based electrolytes because of interfacial challenges. Here we demonstrate that a cellulose–poly(ethylene oxide) (CPEO) interlayer can stabilize the interface between sulfide electrolyte (Na₃SbS₄) and Na by shutting off the electron pathway of the electrolyte decomposition reaction. In conclusion, we achieved stable Na plating/stripping for 800 cycles at 0.1 mA cm^–2 in all-solid-state devices at 60 °C.
Cited by 40
https://doi.org/10.1021/acsami.8b19984

Full Text Available
Efficient Construction of a C₆₀ Interlayer for Mechanically Robust, Dendrite-free, and Ultrastable Solid-State Batteries

Journal Article Li, Zhenlong ; Zhang, Siwei ; Qian, Kun ; ... - iScience

Interfacial instability between solid electrolytes (SEs) and lithium metal remains a daunting challenge for solid-sate batteries. Here, a conformal C₆₀ interlayer is efficiently constructed on Li_1.5Al_0.5Ge_1.5(PO₄)₃ (LAGP) SEs by physical vapor deposition, and an ideal interfacial contact is achieved via forming an ionically conducting matrix of LixC60 with lithium metal. The obtained Li_xC₆₀ is beneficial to hinder the growth of lithium dendrites at interface and release the local stress during the lithiation and delithiation. As a result, the Li/LAGP-C₆₀/Li symmetric cells demonstrate ultra-stable cycling performance for more than 4,500 h at a current density of 0.034 mA cm^-2 . Themore »« less
https://doi.org/10.1016/j.isci.2020.101636

Full Text Available
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries

Journal Article Chi, Xiaowei ; Liang, Yanliang ; Hao, Fang ; ... - Angewandte Chemie

Abstract All‐solid‐state sodium batteries (ASSSBs) with nonflammable electrolytes and ubiquitous sodium resource are a promising solution to the safety and cost concerns for lithium‐ion batteries. However, the intrinsic mismatch between low anodic decomposition potential of superionic sulfide electrolytes and high operating potentials of sodium‐ion cathodes leads to a volatile cathode–electrolyte interface and undesirable cell performance. Here we report a high‐capacity organic cathode, Na ₄ C ₆ O ₆ , that is chemically and electrochemically compatible with sulfide electrolytes. A bulk‐type ASSSB shows high specific capacity (184 mAh g ⁻¹ ) and one of the highest specific energies (395 Wh kg ⁻¹ ) among intercalationmore »« less
https://doi.org/10.1002/ange.201712895
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries

Journal Article Chi, Xiaowei ; Liang, Yanliang ; Hao, Fang ; ... - Angewandte Chemie (International Edition)

Abstract All‐solid‐state sodium batteries (ASSSBs) with nonflammable electrolytes and ubiquitous sodium resource are a promising solution to the safety and cost concerns for lithium‐ion batteries. However, the intrinsic mismatch between low anodic decomposition potential of superionic sulfide electrolytes and high operating potentials of sodium‐ion cathodes leads to a volatile cathode–electrolyte interface and undesirable cell performance. Here we report a high‐capacity organic cathode, Na ₄ C ₆ O ₆ , that is chemically and electrochemically compatible with sulfide electrolytes. A bulk‐type ASSSB shows high specific capacity (184 mAh g ⁻¹ ) and one of the highest specific energies (395 Wh kg ⁻¹ ) among intercalationmore »« less
Cited by 128
https://doi.org/10.1002/anie.201712895

Similar Records

Title: Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte

Abstract

Citation Formats

Solid-State Sodium Batteries journal, February 2018

Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application journal, March 2019

Grain-boundary-resistance-less Na3SbS4-Se solid electrolytes for all-solid-state sodium batteries journal, December 2019

Unveiling the Advances of 2D Materials for Li/Na-S Batteries Experimentally and Theoretically journal, February 2020

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery journal, December 2018

Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy–O2 batteries journal, November 2018

Na 3 SbS 4 : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries journal, July 2016

Compatibility issues between electrodes and electrolytes in solid-state batteries journal, January 2017

Aqueous-solution synthesis of Na 3 SbS 4 solid electrolytes for all-solid-state Na-ion batteries journal, January 2018

Hybrid electrolyte with robust garnet-ceramic electrolyte for lithium anode protection in lithium-oxygen batteries journal, May 2018

Electrochemical Properties and Discharge Mechanism of Na/TiS 2 Cells with Liquid Electrolyte at Room Temperature journal, December 2012

A wide-ranging review on Nasicon type materials journal, February 2011

Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage journal, January 2019

Progress of the Interface Design in All-Solid-State Li-S Batteries journal, March 2018

Solid‐State Plastic Crystal Electrolytes: Effective Protection Interlayers for Sulfide‐Based All‐Solid‐State Lithium Metal Batteries journal, March 2019

Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective journal, October 2018

Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries journal, January 2018

Reactivity-Guided Interface Design in Na Metal Solid-State Batteries journal, April 2019

Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries journal, August 2020

TiS 2 as an Advanced Conversion Electrode for Sodium-Ion Batteries with Ultra-High Capacity and Long-Cycle Life journal, September 2018

Computational and Experimental Investigations of Na-Ion Conduction in Cubic Na 3 PSe 4 journal, December 2015

Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries journal, January 2018

Main Challenges for High Performance NAS Battery: Materials and Interfaces journal, May 2012

Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives journal, May 2010

An Adjustable‐Porosity Plastic Crystal Electrolyte Enables High‐Performance All‐Solid‐State Lithium‐Oxygen Batteries journal, April 2020

Multifunctional Sandwich-Structured Electrolyte for High-Performance Lithium-Sulfur Batteries journal, January 2018

Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries journal, August 2019

Vacancy-Contained Tetragonal Na 3 SbS 4 Superionic Conductor journal, April 2016

Na 11 Sn 2 PS 12 : a new solid state sodium superionic conductor journal, January 2018

New Insights into the Interphase between the Na Metal Anode and Sulfide Solid-State Electrolytes: A Joint Experimental and Computational Study journal, March 2018

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries journal, January 2012

Stabilizing Na3SbS4/Na interface by rational design via Cl doping and aqueous processing journal, April 2021

Hybrid solid electrolyte enabled dendrite-free Li anodes for high-performance quasi-solid-state lithium-oxygen batteries journal, July 2020

TiS 2 nanoplates: A high-rate and stable electrode material for sodium ion batteries journal, February 2016

Ultrathin 2D TiS 2 Nanosheets for High Capacity and Long-Life Sodium Ion Batteries journal, January 2019

Facile Stabilization of the Sodium Metal Anode with Additives: Unexpected Key Role of Sodium Polysulfide and Adverse Effect of Sodium Nitrate journal, May 2018

An Air-Stable Na 3 SbS 4 Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure journal, June 2016

Sodium Metal Anodes: Emerging Solutions to Dendrite Growth journal, April 2019

Designing a self-healing protective film on a lithium metal anode for long-cycle-life lithium-oxygen batteries journal, March 2019

Progress in the Development of Sodium-Ion Solid Electrolytes journal, September 2017

Gradiently Sodiated Alucone as an Interfacial Stabilizing Strategy for Solid‐State Na Metal Batteries journal, April 2020

Stabilizing the Interface between Sodium Metal Anode and Sulfide-Based Solid-State Electrolyte with an Electron-Blocking Interlayer journal, February 2019

Electrolyte and Interface Engineering for Solid-State Sodium Batteries journal, September 2018

Research Development on Sodium-Ion Batteries journal, October 2014

Engineering Materials for Progressive All-Solid-State Na Batteries journal, August 2018

Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations journal, December 2017

Solid-State Sodium Batteries
journal, February 2018

Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application
journal, March 2019

Grain-boundary-resistance-less Na3SbS4-Se solid electrolytes for all-solid-state sodium batteries
journal, December 2019

Unveiling the Advances of 2D Materials for Li/Na-S Batteries Experimentally and Theoretically
journal, February 2020

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery
journal, December 2018

Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy–O2 batteries
journal, November 2018

Na ₃ SbS ₄ : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries
journal, July 2016

Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017

Aqueous-solution synthesis of Na ₃ SbS ₄ solid electrolytes for all-solid-state Na-ion batteries
journal, January 2018

Hybrid electrolyte with robust garnet-ceramic electrolyte for lithium anode protection in lithium-oxygen batteries
journal, May 2018

Electrochemical Properties and Discharge Mechanism of Na/TiS ₂ Cells with Liquid Electrolyte at Room Temperature
journal, December 2012

A wide-ranging review on Nasicon type materials
journal, February 2011

Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage
journal, January 2019

Progress of the Interface Design in All-Solid-State Li-S Batteries
journal, March 2018

Solid‐State Plastic Crystal Electrolytes: Effective Protection Interlayers for Sulfide‐Based All‐Solid‐State Lithium Metal Batteries
journal, March 2019

Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective
journal, October 2018

Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries
journal, January 2018

Reactivity-Guided Interface Design in Na Metal Solid-State Batteries
journal, April 2019

Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries
journal, August 2020

TiS ₂ as an Advanced Conversion Electrode for Sodium-Ion Batteries with Ultra-High Capacity and Long-Cycle Life
journal, September 2018

Computational and Experimental Investigations of Na-Ion Conduction in Cubic Na ₃ PSe ₄
journal, December 2015

Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries
journal, January 2018

Main Challenges for High Performance NAS Battery: Materials and Interfaces
journal, May 2012

Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives
journal, May 2010

An Adjustable‐Porosity Plastic Crystal Electrolyte Enables High‐Performance All‐Solid‐State Lithium‐Oxygen Batteries
journal, April 2020

Multifunctional Sandwich-Structured Electrolyte for High-Performance Lithium-Sulfur Batteries
journal, January 2018

Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries
journal, August 2019

Vacancy-Contained Tetragonal Na ₃ SbS ₄ Superionic Conductor
journal, April 2016

Na ₁₁ Sn ₂ PS ₁₂ : a new solid state sodium superionic conductor
journal, January 2018

New Insights into the Interphase between the Na Metal Anode and Sulfide Solid-State Electrolytes: A Joint Experimental and Computational Study
journal, March 2018

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries
journal, January 2012

Stabilizing Na3SbS4/Na interface by rational design via Cl doping and aqueous processing
journal, April 2021

Hybrid solid electrolyte enabled dendrite-free Li anodes for high-performance quasi-solid-state lithium-oxygen batteries
journal, July 2020

TiS 2 nanoplates: A high-rate and stable electrode material for sodium ion batteries
journal, February 2016

Ultrathin 2D TiS ₂ Nanosheets for High Capacity and Long-Life Sodium Ion Batteries
journal, January 2019

Facile Stabilization of the Sodium Metal Anode with Additives: Unexpected Key Role of Sodium Polysulfide and Adverse Effect of Sodium Nitrate
journal, May 2018

An Air-Stable Na ₃ SbS ₄ Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure
journal, June 2016

Sodium Metal Anodes: Emerging Solutions to Dendrite Growth
journal, April 2019

Designing a self-healing protective film on a lithium metal anode for long-cycle-life lithium-oxygen batteries
journal, March 2019

Progress in the Development of Sodium-Ion Solid Electrolytes
journal, September 2017

Gradiently Sodiated Alucone as an Interfacial Stabilizing Strategy for Solid‐State Na Metal Batteries
journal, April 2020

Stabilizing the Interface between Sodium Metal Anode and Sulfide-Based Solid-State Electrolyte with an Electron-Blocking Interlayer
journal, February 2019

Electrolyte and Interface Engineering for Solid-State Sodium Batteries
journal, September 2018

Research Development on Sodium-Ion Batteries
journal, October 2014

Engineering Materials for Progressive All-Solid-State Na Batteries
journal, August 2018

Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations
journal, December 2017