Achieving 5.9% elastic strain in kilograms of metallic glasses: Nanoscopic strain engineering goes macro
Abstract
The ideal elastic limit is the upper bound of the achievable strength and elastic strain of solids. However, the elastic strains that bulk materials can sustain are usually below 2%, due to the localization of inelastic deformations at the lattice scale. In this study, we achieved >5% elastic strain in bulk quantity of metallic glass, by exploiting the more uniform and smaller-magnitude atomic-scale lattice strains of martensitic transformation as a loading medium in a bulk metallic nanocomposite. The self-limiting nature of martensitic transformation helps to prevent lattice strain transfer that leads to the localization of deformation and damage. This lattice strain egalitarian strategy enables bulk metallic materials in kilogram-quantity to achieve near-ideal elastic limit. This concept is verified in a model in situ bulk amorphous (TiNiFe)-nanocrystalline (TiNi(Fe)) composite, in which the TiNiFe amorphous matrix exhibits a maximum tensile elastic strain of similar to 5.9%, which approaches its theoretical elastic limit. As a result, the model bulk composite possesses a large recoverable strain of similar to 7%, a maximum tensile strength of above 2 GPa, and a large elastic resilience of similar to 79.4 MJ/m3. The recoverable strain and elastic resilience are unmatched by known high strength bulk metallic materials. Thismore »
- Authors:
-
- Univ. of Western Australia, Perth, WA (Australia)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- China Univ. of Petroleum, Beijing (China)
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- Australian Research Council; National Natural Science Foundation of China (NSFC); US Office of Naval Research (ONR); USDOE Office of Science (SC), Advanced Scientific Computing Research (ASCR)
- OSTI Identifier:
- 1780696
- Grant/Contract Number:
- AC02-06CH11357; DP180101955; DP190102990; 51601069; 51731010; 51571212; 51771082; 51831006; N00014-17-1-2661
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials Today
- Additional Journal Information:
- Journal Volume: 37; Journal ID: ISSN 1369-7021
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; elastic strain
Citation Formats
Zhang, Junsong, Liu, Yinong, Yang, Hong, Ren, Yang, Cui, Lishan, Jiang, Daqiang, Wu, Zhigang, Ma, Zhiyuan, Guo, Fangmin, Bakhtiari, Sam, Motazedian, Fakhrodin, and Li, Ju. Achieving 5.9% elastic strain in kilograms of metallic glasses: Nanoscopic strain engineering goes macro. United States: N. p., 2020.
Web. doi:10.1016/j.mattod.2020.02.020.
Zhang, Junsong, Liu, Yinong, Yang, Hong, Ren, Yang, Cui, Lishan, Jiang, Daqiang, Wu, Zhigang, Ma, Zhiyuan, Guo, Fangmin, Bakhtiari, Sam, Motazedian, Fakhrodin, & Li, Ju. Achieving 5.9% elastic strain in kilograms of metallic glasses: Nanoscopic strain engineering goes macro. United States. https://doi.org/10.1016/j.mattod.2020.02.020
Zhang, Junsong, Liu, Yinong, Yang, Hong, Ren, Yang, Cui, Lishan, Jiang, Daqiang, Wu, Zhigang, Ma, Zhiyuan, Guo, Fangmin, Bakhtiari, Sam, Motazedian, Fakhrodin, and Li, Ju. Tue .
"Achieving 5.9% elastic strain in kilograms of metallic glasses: Nanoscopic strain engineering goes macro". United States. https://doi.org/10.1016/j.mattod.2020.02.020. https://www.osti.gov/servlets/purl/1780696.
@article{osti_1780696,
title = {Achieving 5.9% elastic strain in kilograms of metallic glasses: Nanoscopic strain engineering goes macro},
author = {Zhang, Junsong and Liu, Yinong and Yang, Hong and Ren, Yang and Cui, Lishan and Jiang, Daqiang and Wu, Zhigang and Ma, Zhiyuan and Guo, Fangmin and Bakhtiari, Sam and Motazedian, Fakhrodin and Li, Ju},
abstractNote = {The ideal elastic limit is the upper bound of the achievable strength and elastic strain of solids. However, the elastic strains that bulk materials can sustain are usually below 2%, due to the localization of inelastic deformations at the lattice scale. In this study, we achieved >5% elastic strain in bulk quantity of metallic glass, by exploiting the more uniform and smaller-magnitude atomic-scale lattice strains of martensitic transformation as a loading medium in a bulk metallic nanocomposite. The self-limiting nature of martensitic transformation helps to prevent lattice strain transfer that leads to the localization of deformation and damage. This lattice strain egalitarian strategy enables bulk metallic materials in kilogram-quantity to achieve near-ideal elastic limit. This concept is verified in a model in situ bulk amorphous (TiNiFe)-nanocrystalline (TiNi(Fe)) composite, in which the TiNiFe amorphous matrix exhibits a maximum tensile elastic strain of similar to 5.9%, which approaches its theoretical elastic limit. As a result, the model bulk composite possesses a large recoverable strain of similar to 7%, a maximum tensile strength of above 2 GPa, and a large elastic resilience of similar to 79.4 MJ/m3. The recoverable strain and elastic resilience are unmatched by known high strength bulk metallic materials. This design concept opens new opportunities for the development of high-performance bulk materials and elastic strain engineering of the physiochemical properties of glasses.},
doi = {10.1016/j.mattod.2020.02.020},
journal = {Materials Today},
number = ,
volume = 37,
place = {United States},
year = {Tue Mar 24 00:00:00 EDT 2020},
month = {Tue Mar 24 00:00:00 EDT 2020}
}
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Works referenced in this record:
Uniform tensile elongation in framed submicron metallic glass specimen in the limit of suppressed shear banding
journal, October 2011
- Deng, Qingsong; Cheng, Yongqiang; Yue, Yonghai
- Acta Materialia, Vol. 59, Issue 17
Ultra-strength materials
journal, September 2010
- Zhu, Ting; Li, Ju
- Progress in Materials Science, Vol. 55, Issue 7
Intrinsic shear strength of metallic glass
journal, February 2011
- Cheng, Y. Q.; Ma, E.
- Acta Materialia, Vol. 59, Issue 4
Study of relaxation and crystallization kinetics of NiTi made amorphous by repeated cold rolling
journal, December 2010
- Peterlechner, M.; Bokeloh, J.; Wilde, G.
- Acta Materialia, Vol. 58, Issue 20
Mechanical properties of bulk metallic glasses
journal, November 2010
- Trexler, Morgana Martin; Thadhani, Naresh N.
- Progress in Materials Science, Vol. 55, Issue 8
Transformation-mediated ductility in CuZr-based bulk metallic glasses
journal, May 2010
- Pauly, S.; Gorantla, S.; Wang, G.
- Nature Materials, Vol. 9, Issue 6
Effect of stacking fault energy on mechanical behavior of bulk nanocrystalline Cu and Cu alloys
journal, August 2011
- Youssef, Khaled; Sakaliyska, Miroslava; Bahmanpour, Hamed
- Acta Materialia, Vol. 59, Issue 14
Super elastic strain limit in metallic glass films
journal, November 2012
- Jiang, Q. K.; Liu, P.; Ma, Y.
- Scientific Reports, Vol. 2, Issue 1
Tensile properties of a nanocrystalline 316L austenitic stainless steel
journal, May 2005
- Chen, X. H.; Lu, J.; Lu, L.
- Scripta Materialia, Vol. 52, Issue 10
Approaching the ideal elastic limit of metallic glasses
journal, January 2012
- Tian, Lin; Cheng, Yong-Qiang; Shan, Zhi-Wei
- Nature Communications, Vol. 3, Issue 1
Sample size matters for Al88Fe7Gd5 metallic glass: Smaller is stronger
journal, August 2012
- Wang, C. -C.; Ding, J.; Cheng, Y. -Q.
- Acta Materialia, Vol. 60, Issue 13-14
Multiscale mechanics of TRIP-assisted multiphase steels: I. Characterization and mechanical testing
journal, June 2007
- Jacques, P. J.; Furnémont, Q.; Lani, F.
- Acta Materialia, Vol. 55, Issue 11
Deep elastic strain engineering of bandgap through machine learning
journal, February 2019
- Shi, Zhe; Tsymbalov, Evgenii; Dao, Ming
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 10
Retaining Large and Adjustable Elastic Strains of Kilogram-Scale Nb Nanowires
journal, February 2016
- Hao, Shijie; Cui, Lishan; Wang, Hua
- ACS Applied Materials & Interfaces, Vol. 8, Issue 5
Elastic strain engineering for unprecedented materials properties
journal, February 2014
- Li, Ju; Shan, Zhiwei; Ma, Evan
- MRS Bulletin, Vol. 39, Issue 2
Structural aspects of elastic deformation of a metallic glass
journal, February 2006
- Hufnagel, T. C.; Ott, R. T.; Almer, J.
- Physical Review B, Vol. 73, Issue 6
Theory of Slip-Band Formation
journal, September 1952
- Fisher, John C.; Hart, Edward W.; Pry, Robert H.
- Physical Review, Vol. 87, Issue 6
Ultralarge elastic deformation of nanoscale diamond
journal, April 2018
- Banerjee, Amit; Bernoulli, Daniel; Zhang, Hongti
- Science, Vol. 360, Issue 6386
Revealing the Maximum Strength in Nanotwinned Copper
journal, January 2009
- Lu, L.; Chen, X.; Huang, X.
- Science, Vol. 323, Issue 5914
Bulk metallic glasses
journal, June 2004
- Wang, W. H.; Dong, C.; Shek, C. H.
- Materials Science and Engineering: R: Reports, Vol. 44, Issue 2-3
Formation and properties of new Ni-based amorphous alloys with critical casting thickness up to 5 mm
journal, July 2004
- Xu, Donghua; Duan, Gang; Johnson, William L.
- Acta Materialia, Vol. 52, Issue 12
Approaching the Theoretical Elastic Strain Limit in Copper Nanowires
journal, August 2011
- Yue, Yonghai; Liu, Pan; Zhang, Ze
- Nano Letters, Vol. 11, Issue 8
A Transforming Metal Nanocomposite with Large Elastic Strain, Low Modulus, and High Strength
journal, March 2013
- Hao, Shijie; Cui, Lishan; Jiang, Daqiang
- Science, Vol. 339, Issue 6124, p. 1191-1194
Synchrotron high energy X-ray diffraction study of microstructure evolution of severely cold drawn NiTi wire during annealing
journal, August 2016
- Yu, Cun; Aoun, Bachir; Cui, Lishan
- Acta Materialia, Vol. 115
Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys
journal, November 2018
- Yang, T.; Zhao, Y. L.; Tong, Y.
- Science, Vol. 362, Issue 6417
Physical metallurgy of Ti–Ni-based shape memory alloys
journal, July 2005
- Otsuka, K.; Ren, X.
- Progress in Materials Science, Vol. 50, Issue 5
Softening of nanocrystalline metals at very small grain sizes
journal, February 1998
- Schiøtz, Jakob; Di Tolla, Francesco D.; Jacobsen, Karsten W.
- Nature, Vol. 391, Issue 6667
Extended defects, ideal strength and actual strengths of finite-sized metallic glasses
journal, July 2014
- Zhao, Pengyang; Li, Ju; Wang, Yunzhi
- Acta Materialia, Vol. 73
High-content ductile coherent nanoprecipitates achieve ultrastrong high-entropy alloys
journal, October 2018
- Liang, Yao-Jian; Wang, Linjing; Wen, Yuren
- Nature Communications, Vol. 9, Issue 1
Ideal Pure Shear Strength of Aluminum and Copper
journal, October 2002
- Ogata, S.
- Science, Vol. 298, Issue 5594
Tensile behavior of a nanocrystalline Ni–Fe alloy
journal, June 2006
- Li, H.; Ebrahimi, F.
- Acta Materialia, Vol. 54, Issue 10
Measuring strain distributions in amorphous materials
journal, December 2004
- Poulsen, Henning F.; Wert, John A.; Neuefeind, Jörg
- Nature Materials, Vol. 4, Issue 1
How thermally activated deformation starts in metallic glass
journal, September 2014
- Fan, Yue; Iwashita, Takuya; Egami, Takeshi
- Nature Communications, Vol. 5, Issue 1
Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation
journal, April 2017
- Jiang, Suihe; Wang, Hui; Wu, Yuan
- Nature, Vol. 544, Issue 7651
Super-high strength of over 4000 MPa for Fe-based bulk glassy alloys in [(Fe1−xCox)0.75B0.2Si0.05]96Nb4 system
journal, August 2004
- Inoue, A.; Shen, B. L.; Chang, C. T.
- Acta Materialia, Vol. 52, Issue 14
Nanocrystalline Al–Mg alloy with ultrahigh strength and good ductility
journal, January 2006
- Youssef, K. M.; Scattergood, R. O.; Murty, K. L.
- Scripta Materialia, Vol. 54, Issue 2
Ultrafine composite microstructure in a bulk Ti alloy for high strength, strain hardening and tensile ductility
journal, March 2006
- Sun, B. B.; Sui, M. L.; Wang, Y. M.
- Acta Materialia, Vol. 54, Issue 5
Stochastic deformation and shear transformation zones of the glassy matrix in CuZr-based metallic-glass composites
journal, February 2020
- Jiang, S. S.; Gan, K. F.; Huang, Y. J.
- International Journal of Plasticity, Vol. 125
High dislocation density–induced large ductility in deformed and partitioned steels
journal, August 2017
- He, B. B.; Hu, B.; Yen, H. W.
- Science, Vol. 357, Issue 6355
Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties
journal, September 2003
- Inoue, Akihisa; Shen, Baolong; Koshiba, Hisato
- Nature Materials, Vol. 2, Issue 10
Zur Theorie der Elastizit�tsgrenze und der Festigkeit kristallinischer K�rper
journal, July 1926
- Frenkel, J.
- Zeitschrift f�r Physik, Vol. 37, Issue 7-8
Investigation of early stage deformation mechanisms in a metastable β titanium alloy showing combined twinning-induced plasticity and transformation-induced plasticity effects
journal, October 2013
- Sun, F.; Zhang, J. Y.; Marteleur, M.
- Acta Materialia, Vol. 61, Issue 17
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008
- Lee, C.; Wei, X.; Kysar, J. W.
- Science, Vol. 321, Issue 5887, p. 385-388
High tensile ductility of Ti-based amorphous matrix composites modified from conventional Ti–6Al–4V titanium alloy
journal, May 2013
- Jeon, C.; Kim, C. P.; Joo, S. -H.
- Acta Materialia, Vol. 61, Issue 8
Designing metallic glass matrix composites with high toughness and tensile ductility
journal, February 2008
- Hofmann, Douglas C.; Suh, Jin-Yoo; Wiest, Aaron
- Nature, Vol. 451, Issue 7182
Bulk Metallic Glass Composites with Transformation-Mediated Work-Hardening and Ductility
journal, April 2010
- Wu, Yuan; Xiao, Yuehua; Chen, Guoliang
- Advanced Materials, Vol. 22, Issue 25
Criteria for tensile plasticity in Cu–Zr–Al bulk metallic glasses
journal, August 2010
- Pauly, S.; Liu, G.; Gorantla, S.
- Acta Materialia, Vol. 58, Issue 14