Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds

Taddei, Keith; Sanjeewa, Liurukara D.; Xing, Jie; Zhang, Qiang; Parker, David S.; Podlesnyak, Andrey A.; Dela Cruz, Clarina R.; Sefat, Athena Safa

doi:10.1103/physrevmaterials.4.024410

Title: Tunable magnetic order in low-symmetry SeO₃ ligand linked TM₃(SeO₃)₃H₂O (TM=Mn , Co, and Ni) compounds

Abstract

The ability to design crystal lattices with specific sublattice geometries has long been sought after especially in the context of harnessing magnetic frustration to elicit emergent physics. One approach which has seen some success recently is to design magnetic sublattices chemically through the use of nonmagnetic linker ligands as scaffolding for the magnetic ions. In this work we report the magnetic properties of one such family of materials, the transition metal (TM) selenite hydrates with chemical formula TM₃(SeO₃)₃H₂O. These materials link highly distorted TMO₆ octahedra via nonmagnetic [SeO₃]²⁺ linkers. Studying members with TM = Mn, Co, and Ni we use magnetic susceptibility and neutron powder diffraction to identify antiferromagnetic order in all three compounds with moderate frustration indexes. A comparison of the magnetic structures suggests that while the overall structure of the SeO₃ scaffolding remains unchanged the TM effects changes in the magnetic properties through tuning the internal bonding parameters and the single-ion physics. Changing from Mn to Co is found to be particularly consequential manifesting changes in both the ordered-moment direction and in the direction of the ordering vector. Field-dependent measurements of the susceptibility and heat capacity reveal metamagnetic transitions in both Mn₃(SeO₃)₃H₂O and Co₃(SeO₃)₃H₂O indicating nearby magnetic groundmore »« less

Authors:

^[1]; Sanjeewa, Liurukara D. ^[1];

^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Tue Feb 18 00:00:00 EST 2020

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1731072

Alternate Identifier(s):: OSTI ID: 1600066

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Volume: 4; Journal Issue: 2; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; magnetism; metamagnetism; crystal structures; crystal growth; density functional theory; neutron diffraction

Citation Formats


                    Taddei, Keith, Sanjeewa, Liurukara D., Xing, Jie, Zhang, Qiang, Parker, David S., Podlesnyak, Andrey A., Dela Cruz, Clarina R., and Sefat, Athena Safa. Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds.  United States: N. p., 2020. 
Web.  doi:10.1103/physrevmaterials.4.024410.

Copy to clipboard


                    Taddei, Keith, Sanjeewa, Liurukara D., Xing, Jie, Zhang, Qiang, Parker, David S., Podlesnyak, Andrey A., Dela Cruz, Clarina R., & Sefat, Athena Safa. Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds.  United States.  https://doi.org/10.1103/physrevmaterials.4.024410

Copy to clipboard


                    Taddei, Keith, Sanjeewa, Liurukara D., Xing, Jie, Zhang, Qiang, Parker, David S., Podlesnyak, Andrey A., Dela Cruz, Clarina R., and Sefat, Athena Safa. Tue .  
"Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds".  United States.  https://doi.org/10.1103/physrevmaterials.4.024410.  https://www.osti.gov/servlets/purl/1731072.

Copy to clipboard


                    
@article{osti_1731072,

  title        = {Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds},

  author       = {Taddei, Keith and Sanjeewa, Liurukara D. and Xing, Jie and Zhang, Qiang and Parker, David S. and Podlesnyak, Andrey A. and Dela Cruz, Clarina R. and Sefat, Athena Safa},

  abstractNote = {The ability to design crystal lattices with specific sublattice geometries has long been sought after especially in the context of harnessing magnetic frustration to elicit emergent physics. One approach which has seen some success recently is to design magnetic sublattices chemically through the use of nonmagnetic linker ligands as scaffolding for the magnetic ions. In this work we report the magnetic properties of one such family of materials, the transition metal (TM) selenite hydrates with chemical formula TM3(SeO3)3H2O. These materials link highly distorted TMO6 octahedra via nonmagnetic [SeO3]2+ linkers. Studying members with TM = Mn, Co, and Ni we use magnetic susceptibility and neutron powder diffraction to identify antiferromagnetic order in all three compounds with moderate frustration indexes. A comparison of the magnetic structures suggests that while the overall structure of the SeO3 scaffolding remains unchanged the TM effects changes in the magnetic properties through tuning the internal bonding parameters and the single-ion physics. Changing from Mn to Co is found to be particularly consequential manifesting changes in both the ordered-moment direction and in the direction of the ordering vector. Field-dependent measurements of the susceptibility and heat capacity reveal metamagnetic transitions in both Mn3(SeO3)3H2O and Co3(SeO3)3H2O indicating nearby magnetic ground states accessible under relatively small applied fields. Density functional theory calculations broadly confirm these results, showing both a sensitivity of the magnetic structure to the TM and its local environment. Although no spin liquid behavior is achieved, these results suggest the fruitfulness of such synthesis philosophies and encourage future work to engender higher frustration in these materials via doping, field, pressure, or larger linker ligands.},

  doi          = {10.1103/physrevmaterials.4.024410},

  journal      = {Physical Review Materials},

  number       = 2,

  volume       = 4,

  place        = {United States},

  year         = {Tue Feb 18 00:00:00 EST 2020},

  month        = {Tue Feb 18 00:00:00 EST 2020}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/physrevmaterials.4.024410

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Long-range antiferromagnetic order in the frustrated XY pyrochlore antiferromagnet ${Er}_{2}$ ${Ge}_{2}$ $O_{7}$
journal, February 2014

Li, X.; Li, W. M.; Matsubayashi, K.
Physical Review B, Vol. 89, Issue 6
DOI: 10.1103/PhysRevB.89.064409

Local-Ising-type magnetic order and metamagnetism in the rare-earth pyrogermanate ${Er}_{2} {Ge}_{2} O_{7}$
journal, January 2019

Taddei, K. M.; Sanjeewa, L.; Kolis, J. W.
Physical Review Materials, Vol. 3, Issue 1
DOI: 10.1103/PhysRevMaterials.3.014405

Spin liquids in frustrated magnets
journal, March 2010

Balents, Leon
Nature, Vol. 464, Issue 7286
DOI: 10.1038/nature08917

Crystal structures of Co3(SeO3)3�H2O and Ni3(SeO3)3�H2O, two new isotypic compounds
journal, January 1991

Wildner, Manfred
Monatshefte f�r Chemie Chemical Monthly, Vol. 122, Issue 8-9
DOI: 10.1007/BF00811457

Magnetic pyrochlore oxides
journal, January 2010

Gardner, Jason S.; Gingras, Michel J. P.; Greedan, John E.
Reviews of Modern Physics, Vol. 82, Issue 1
DOI: 10.1103/RevModPhys.82.53

Critical behavior of the metallic triangular-lattice Heisenberg antiferromagnet ${PdCrO}_{2}$
journal, March 2009

Takatsu, Hiroshi; Yoshizawa, Hideki; Yonezawa, Shingo
Physical Review B, Vol. 79, Issue 10
DOI: 10.1103/PhysRevB.79.104424

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Shannon, R. D.
Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
DOI: 10.1107/S0567739476001551

The synthesis and crystal structure of a new nickel selenite hydrate, Ni3(SeO3)3 · H2O
journal, June 1991

Mcmanus, Adrian V. P.; Harrison, William T. A.; Cheetham, Anthony K.
Journal of Solid State Chemistry, Vol. 92, Issue 2
DOI: 10.1016/0022-4596(91)90333-D

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
journal, September 2018

Calder, S.; An, K.; Boehler, R.
Review of Scientific Instruments, Vol. 89, Issue 9
DOI: 10.1063/1.5033906

Negative thermal expansion and magnetoelastic coupling in the breathing pyrochlore lattice material ${LiGaCr}_{4} S_{8}$
journal, April 2018

Pokharel, G.; May, A. F.; Parker, D. S.
Physical Review B, Vol. 97, Issue 13
DOI: 10.1103/PhysRevB.97.134117

Spin-Liquid Ground State of the S = 1/2 Kagome Heisenberg Antiferromagnet
journal, April 2011

Yan, S.; Huse, D. A.; White, S. R.
Science, Vol. 332, Issue 6034
DOI: 10.1126/science.1201080

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Rodríguez-Carvajal, Juan
Physica B: Condensed Matter, Vol. 192, Issue 1-2
DOI: 10.1016/0921-4526(93)90108-I

Antiferromagnetic order in the pyrochlores $R_{2} {Ge}_{2} O_{7} (R = Er, Yb)$
journal, October 2015

Dun, Z. L.; Li, X.; Freitas, R. S.
Physical Review B, Vol. 92, Issue 14
DOI: 10.1103/PhysRevB.92.140407

Magnetic structure and susceptibility of ${CoSe}_{2} O_{5}$ : An antiferromagnetic chain compound
journal, July 2010

Melot, Brent C.; Paden, Brian; Seshadri, Ram
Physical Review B, Vol. 82, Issue 1
DOI: 10.1103/PhysRevB.82.014411

Two trimeric tri-TiIV-substituted Keggin tungstogermanates based on tetrahedral linkers
journal, November 2008

Ren, Yuan-Hang; Liu, Shu-Xia; Cao, Rui-Ge
Inorganic Chemistry Communications, Vol. 11, Issue 11
DOI: 10.1016/j.inoche.2008.08.009

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

Toby, Brian H.; Von Dreele, Robert B.
Journal of Applied Crystallography, Vol. 46, Issue 2
DOI: 10.1107/S0021889813003531

Bilbao Crystallographic Server: I. Databases and crystallographic computing programs
journal, January 2006

Aroyo, Mois Ilia; Perez-Mato, Juan Manuel; Capillas, Cesar
Zeitschrift für Kristallographie - Crystalline Materials, Vol. 221, Issue 1
DOI: 10.1524/zkri.2006.221.1.15

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Momma, Koichi; Izumi, Fujio
Journal of Applied Crystallography, Vol. 44, Issue 6
DOI: 10.1107/S0021889811038970

Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups
journal, March 2006

Aroyo, Mois I.; Kirov, Asen; Capillas, Cesar
Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 2
DOI: 10.1107/S0108767305040286

Quantification of local Ising magnetism in rare-earth pyrogermanates ${Er}_{2} {Ge}_{2} O_{7}$ and ${Yb}_{2} {Ge}_{2} O_{7}$
journal, January 2020

Pajerowski, Daniel M.; Taddei, K. M.; Sanjeewa, L. D.
Physical Review B, Vol. 101, Issue 1
DOI: 10.1103/PhysRevB.101.014420

Simple frustrated systems: chains, strips and squares
journal, December 1978

Derrida, B.; Vannimenus, J.; Pomeau, Y.
Journal of Physics C: Solid State Physics, Vol. 11, Issue 23
DOI: 10.1088/0022-3719/11/23/019

Recent progress on synthesis and structural aspects of rare-earth phosphates
journal, June 2017

Achary, S. N.; Bevara, S.; Tyagi, A. K.
Coordination Chemistry Reviews, Vol. 340
DOI: 10.1016/j.ccr.2017.03.006

A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh)
journal, March 2000

Wills, A. S.
Physica B: Condensed Matter, Vol. 276-278
DOI: 10.1016/S0921-4526(99)01722-6

On the allowed values for the triclinic unit-cell angles
journal, November 2010

Foadi, James; Evans, Gwyndaf
Acta Crystallographica Section A Foundations of Crystallography, Vol. 67, Issue 1
DOI: 10.1107/S0108767310044296

Suppression of the antiferromagnetic metallic state in the pressurized $MnB i_{2} T e_{4}$ single crystal
journal, September 2019

Chen, K. Y.; Wang, B. S.; Yan, J. -Q.
Physical Review Materials, Vol. 3, Issue 9
DOI: 10.1103/PHysRevMaterials.3.094201

Classification of topological quantum matter with symmetries
journal, August 2016

Chiu, Ching-Kai; Teo, Jeffrey C. Y.; Schnyder, Andreas P.
Reviews of Modern Physics, Vol. 88, Issue 3
DOI: 10.1103/RevModPhys.88.035005

Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites
journal, January 2002

Choudhury, Amitava; Kumar D., Udaya; Rao, C. N. R.
Angewandte Chemie International Edition, Vol. 41, Issue 1
DOI: 10.1002/1521-3773(20020104)41:1%3C158::AID-ANIE158%3E3.0.CO;2-%23

Structural and magnetic characterization of the one-dimensional $S = 5 / 2$ antiferromagnetic chain system $SrMn (V O_{4}) (OH)$
journal, June 2016

Sanjeewa, Liurukara D.; Garlea, Vasile O.; McGuire, Michael A.
Physical Review B, Vol. 93, Issue 22
DOI: 10.1103/PhysRevB.93.224407

Hydrothermal synthesis, crystal structure, spectroscopic and magnetic properties of Mn ₄ (H ₂ O) ₃ (SeO ₃ ) ₄ and Mn ₃ (H ₂ O)(SeO ₃ ) ₃
journal, January 2002

Larrañaga, Aitor; Mesa, José L.; Pizarro, José L.
J. Chem. Soc., Dalton Trans., Issue 18
DOI: 10.1039/B206515K

Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides
journal, March 2019

Kovrugin, Vadim M.; Colmont, Marie; Siidra, Oleg I.
Zeitschrift für Kristallographie - Crystalline Materials, Vol. 234, Issue 3
DOI: 10.1515/zkri-2018-2088

Exchange interactions in insulators and semiconductors
journal, September 1990

Geertsma, W.
Physica B: Condensed Matter, Vol. 164, Issue 3
DOI: 10.1016/0921-4526(90)90812-9

Strongly Geometrically Frustrated Magnets
journal, August 1994

Ramirez, A. P.
Annual Review of Materials Science, Vol. 24, Issue 1
DOI: 10.1146/annurev.ms.24.080194.002321

Magnetic monopoles in spin ice
journal, January 2008

Castelnovo, C.; Moessner, R.; Sondhi, S. L.
Nature, Vol. 451, Issue 7174
DOI: 10.1038/nature06433

An extreme case of ZnO ₆ octahedral distortion in trizinc tris(selenite) hydrate, Zn ₃ (SeO ₃ ) ₃
journal, December 1999

Harrison, W. T. A.
Acta Crystallographica Section C Crystal Structure Communications, Vol. 55, Issue 12
DOI: 10.1107/S0108270199011099

Exotic Magnetic Field-Induced Spin-Superstructures in a Mixed Honeycomb-Triangular Lattice System
journal, February 2019

Garlea, V. Ovidiu; Sanjeewa, Liurukara D.; McGuire, Michael A.
Physical Review X, Vol. 9, Issue 1
DOI: 10.1103/PhysRevX.9.011038

Similar Records in DOE PAGES and OSTI.GOV collections:

Variable dimensionality and framework found in a series of quaternary zinc selenites, A{sub 2}Zn{sub 3}(SeO{sub 3}){sub 4}·xH{sub 2}O (A = Na, Rb, and Cs; 0≤x≤1) and Cs{sub 2}Zn{sub 2}(SeO{sub 3}){sub 3}·2H{sub 2}O

Journal Article Lü, Minfeng ; Jo, Hongil ; Oh, Seung-Jin ; ... - Journal of Solid State Chemistry

Five new alkali metal zinc selenites, A{sub 2}Zn{sub 3}(SeO{sub 3}){sub 4}·xH{sub 2}O (A = Na, Rb, and Cs; 0≤x≤1) and Cs{sub 2}Zn{sub 2}(SeO{sub 3}){sub 3}·2H{sub 2}O have been synthesized by heating a mixture of ZnO, SeO{sub 2} and A{sub 2}CO{sub 3} (A = Na, Rb, and Cs), and characterized by X-ray diffraction (XRD) and spectroscopic analyses techniques. All of the reported materials revealed a rich structural chemistry with different frameworks and connection modes of Zn{sup 2+}. While Rb{sub 2}Zn{sub 3}(SeO{sub 3}){sub 4} and Cs{sub 2}Zn{sub 3}(SeO{sub 3}){sub 4}·H{sub 2}O revealed three-dimensional frameworks consisting of isolated ZnO{sub 4} tetrahedra and SeO{submore »« less
https://doi.org/10.1016/J.JSSC.2016.09.031
Crystal structure and magnetic properties of two new cobalt selenite halides: Co{sub 5}(SeO{sub 3}){sub 4} X {sub 2} (X=Cl, Br)

Journal Article Becker, Richard ; Prester, Mladen ; Berger, Helmuth ; ... - Journal of Solid State Chemistry

Two new isostructural cobalt selenite halides Co{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2} and Co{sub 5}(SeO{sub 3}){sub 4}Br{sub 2} have been synthesized. They crystallize in the triclinic system space group P-1 with the following lattice parameters for Co{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2}: a=6.4935(8) A, b=7.7288(8) A, c=7.7443(10) A, {alpha}=66.051(11){sup o}, {beta}=73.610(11){sup o}, {gamma}=81.268(9){sup o}, and Z=1. The crystal structures were solved from single-crystal X-ray data, R1=3.73 and 4.03 for Co{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2} and Co{sub 5}(SeO{sub 3}){sub 4}Br{sub 2}, respectively. The new compounds are isostructural to Ni{sub 5}(SeO{sub 3}){sub 4}Br{sub 2}. Magnetic susceptibility measurements on oriented single-crystalline samples show anisotropic responsemore »« less
https://doi.org/10.1016/j.jssc.2006.12.035
Sr{sub 3}Bi{sub 2}(SeO{sub 3}){sub 6}·H{sub 2}O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

Journal Article Ahn, Hyun Sun ; Lee, Eun Pyo ; Chang, Hong-Young ; ... - Journal of Solid State Chemistry

A new layered bismuth selenite hydrate material, Sr{sub 3}Bi{sub 2}(SeO{sub 3}){sub 6}·H{sub 2}O has been synthesized through a hydrothermal reaction using SrCO{sub 3}, Bi{sub 2}O{sub 3}, SeO{sub 2}, and water as reagents. The crystal structure of the reported material has been determined by single crystal X-ray diffraction analysis. The anionic layered framework of Sr{sub 3}Bi{sub 2}(SeO{sub 3}){sub 6}·H{sub 2}O consists of polyhedra of second-order Jahn–Teller (SOJT) distortive cations, Bi{sup 3+} and Se{sup 4+}. Attributable to the variable and asymmetric coordination geometry of the constituent cations, a rich structural chemistry including uni-dimensional bands and linkers is observed in the layer. Themore »« less
https://doi.org/10.1016/J.JSSC.2014.09.018
NaCo₂(SeO₃)₂(OH): competing magnetic ground states of a new sawtooth structure with 3d⁷ Co²⁺ ions

Journal Article Sanjeewa, Liurukara D. ; Garlea, Vasile O. ; Taddei, Keith ; ... - Inorganic Chemistry Frontiers (Online)

While certain magnetic sublattices have long been known theoretically to give rise to emergent physics via competing magnetic interactions and quantum effects, finding such configurations in real materials is often deeply challenging. Here we report the synthesis and characterization of a new such material, NaCo₂(SeO₃)₂(OH) which crystallizes with a highly frustrated sublattice of sawtooth Co²⁺ chains. Single crystals of NaCo₂(SeO₃)₂(OH) were synthesized using a low-temperature hydrothermal method. X-ray single crystal structure analysis reveals that the material crystallizes in orthorhombic space group of Pnma (no. 62). Its crystal structure exhibits one-dimensional chains of corner-sharing isosceles triangles that are made of twomore »« less
https://doi.org/10.1039/D2QI01072K

Full Text Available
Frustrated magnetism in the layered triangular lattice materials K₂Co(SeO₃)₂ and Rb₂Co(SeO₃)₂

Journal Article Zhong, Ruidan ; Guo, Shu ; Cava, R. J. - Physical Review Materials

A study of the layered triangular lattice materials K₂Co(SeO₃)₂ and Rb₂Co(SeO₃)₂ is reported here. These isostructural compounds crystallize in the trigonal space group R-3m (No. 166). The magnetic Co²⁺ ions form a spin-1/2 triangular lattice and display strongly frustrated magnetism. We find no evidence in the susceptibility or heat capacity for in-plane ordering of the spins; rather the in-plane inverse susceptibility is typical of that seen for frustrated magnets. At around 10 K, a ferromagnetic component appears in the magnetic susceptibility perpendicular to the triangular planes. The heat capacity at low applied fields does not show sharp features, but inmore »« less
https://doi.org/10.1103/physrevmaterials.4.084406

Full Text Available

Similar Records

Title: Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Long-range antiferromagnetic order in the frustrated XY pyrochlore antiferromagnet Er 2 Ge 2 O 7 journal, February 2014

Local-Ising-type magnetic order and metamagnetism in the rare-earth pyrogermanate Er 2 Ge 2 O 7 journal, January 2019

Spin liquids in frustrated magnets journal, March 2010

Crystal structures of Co3(SeO3)3�H2O and Ni3(SeO3)3�H2O, two new isotypic compounds journal, January 1991

Magnetic pyrochlore oxides journal, January 2010

Critical behavior of the metallic triangular-lattice Heisenberg antiferromagnet PdCrO 2 journal, March 2009

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

The synthesis and crystal structure of a new nickel selenite hydrate, Ni3(SeO3)3 · H2O journal, June 1991

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory journal, September 2018

Negative thermal expansion and magnetoelastic coupling in the breathing pyrochlore lattice material LiGaCr 4 S 8 journal, April 2018

Spin-Liquid Ground State of the S = 1/2 Kagome Heisenberg Antiferromagnet journal, April 2011

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Antiferromagnetic order in the pyrochlores R 2 Ge 2 O 7 ( R = Er , Yb ) journal, October 2015

Magnetic structure and susceptibility of CoSe 2 O 5 : An antiferromagnetic chain compound journal, July 2010

Two trimeric tri-TiIV-substituted Keggin tungstogermanates based on tetrahedral linkers journal, November 2008

GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal, March 2013

Bilbao Crystallographic Server: I. Databases and crystallographic computing programs journal, January 2006

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups journal, March 2006

Quantification of local Ising magnetism in rare-earth pyrogermanates Er 2 Ge 2 O 7 and Yb 2 Ge 2 O 7 journal, January 2020

Simple frustrated systems: chains, strips and squares journal, December 1978

Recent progress on synthesis and structural aspects of rare-earth phosphates journal, June 2017

A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh) journal, March 2000

On the allowed values for the triclinic unit-cell angles journal, November 2010

Suppression of the antiferromagnetic metallic state in the pressurized MnB i 2 T e 4 single crystal journal, September 2019

Classification of topological quantum matter with symmetries journal, August 2016

Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites journal, January 2002

Structural and magnetic characterization of the one-dimensional S = 5 / 2 antiferromagnetic chain system SrMn ( V O 4 ) ( OH ) journal, June 2016

Hydrothermal synthesis, crystal structure, spectroscopic and magnetic properties of Mn 4 (H 2 O) 3 (SeO 3 ) 4 and Mn 3 (H 2 O)(SeO 3 ) 3 journal, January 2002

Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides journal, March 2019

Exchange interactions in insulators and semiconductors journal, September 1990

Strongly Geometrically Frustrated Magnets journal, August 1994

Magnetic monopoles in spin ice journal, January 2008

An extreme case of ZnO 6 octahedral distortion in trizinc tris(selenite) hydrate, Zn 3 (SeO 3 ) 3 journal, December 1999

Exotic Magnetic Field-Induced Spin-Superstructures in a Mixed Honeycomb-Triangular Lattice System journal, February 2019

Title: Tunable magnetic order in low-symmetry SeO₃ ligand linked TM₃(SeO₃)₃H₂O (TM=Mn , Co, and Ni) compounds

Generalized Gradient Approximation Made Simple
journal, October 1996

Long-range antiferromagnetic order in the frustrated XY pyrochlore antiferromagnet ${Er}_{2}$ ${Ge}_{2}$ $O_{7}$
journal, February 2014

Local-Ising-type magnetic order and metamagnetism in the rare-earth pyrogermanate ${Er}_{2} {Ge}_{2} O_{7}$
journal, January 2019

Spin liquids in frustrated magnets
journal, March 2010

Crystal structures of Co3(SeO3)3�H2O and Ni3(SeO3)3�H2O, two new isotypic compounds
journal, January 1991

Magnetic pyrochlore oxides
journal, January 2010

Critical behavior of the metallic triangular-lattice Heisenberg antiferromagnet ${PdCrO}_{2}$
journal, March 2009

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

The synthesis and crystal structure of a new nickel selenite hydrate, Ni3(SeO3)3 · H2O
journal, June 1991

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
journal, September 2018

Negative thermal expansion and magnetoelastic coupling in the breathing pyrochlore lattice material ${LiGaCr}_{4} S_{8}$
journal, April 2018

Spin-Liquid Ground State of the S = 1/2 Kagome Heisenberg Antiferromagnet
journal, April 2011

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Antiferromagnetic order in the pyrochlores $R_{2} {Ge}_{2} O_{7} (R = Er, Yb)$
journal, October 2015

Magnetic structure and susceptibility of ${CoSe}_{2} O_{5}$ : An antiferromagnetic chain compound
journal, July 2010

Two trimeric tri-TiIV-substituted Keggin tungstogermanates based on tetrahedral linkers
journal, November 2008

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

Bilbao Crystallographic Server: I. Databases and crystallographic computing programs
journal, January 2006

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups
journal, March 2006

Quantification of local Ising magnetism in rare-earth pyrogermanates ${Er}_{2} {Ge}_{2} O_{7}$ and ${Yb}_{2} {Ge}_{2} O_{7}$
journal, January 2020

Simple frustrated systems: chains, strips and squares
journal, December 1978

Recent progress on synthesis and structural aspects of rare-earth phosphates
journal, June 2017

A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh)
journal, March 2000

On the allowed values for the triclinic unit-cell angles
journal, November 2010

Suppression of the antiferromagnetic metallic state in the pressurized $MnB i_{2} T e_{4}$ single crystal
journal, September 2019

Classification of topological quantum matter with symmetries
journal, August 2016

Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites
journal, January 2002

Structural and magnetic characterization of the one-dimensional $S = 5 / 2$ antiferromagnetic chain system $SrMn (V O_{4}) (OH)$
journal, June 2016

Hydrothermal synthesis, crystal structure, spectroscopic and magnetic properties of Mn ₄ (H ₂ O) ₃ (SeO ₃ ) ₄ and Mn ₃ (H ₂ O)(SeO ₃ ) ₃
journal, January 2002

Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides
journal, March 2019

Exchange interactions in insulators and semiconductors
journal, September 1990

Strongly Geometrically Frustrated Magnets
journal, August 1994

Magnetic monopoles in spin ice
journal, January 2008

An extreme case of ZnO ₆ octahedral distortion in trizinc tris(selenite) hydrate, Zn ₃ (SeO ₃ ) ₃
journal, December 1999

Exotic Magnetic Field-Induced Spin-Superstructures in a Mixed Honeycomb-Triangular Lattice System
journal, February 2019