Electrokinetic Phenomena Enhanced Lithium-Ion Transport in Leaky Film for Stable Lithium Metal Anodes
Abstract
The application of lithium (Li) metal anodes in Li metal batteries has been hindered by growth of Li dendrite which leads to short cycling life. Here a Li-ion-affinity leaky film as a protection layer is reported to promote a dendrite-free Li metal anode. The leaky film induces electrokinetic phenomena to enhance Li-ion transport, leading to a reduced Li-ion concentration polarization and homogenous Li-ion distribution. As a result, the dendrite-free Li metal anode during Li plating/stripping is demonstrated even at an extremely high deposition capacity (6 mA h cm-2) and current density (40 mA cm-2) with improved Coulombic efficiencies. A full-cell battery with the leaky-film protected Li metal as anode and high-areal-capacity LiNi0.8Co0.1Mn0.1O2 (NCM-811) (~4.2 mA h cm-2) or LiFePO4 (~3.8 mA h cm-2) as cathode shows improved cycling stability and capacity retention, even at lean electrolyte conditions.
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office
- OSTI Identifier:
- 1657241
- Alternate Identifier(s):
- OSTI ID: 1510093
- Grant/Contract Number:
- EE0007795; EE0007803
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 22; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; lithium metal anodes; batteries; electrokinetic phenomena; lithium-ion transport; leaky film
Citation Formats
Li, Guoxing, Liu, Zhe, Wang, Daiwei, He, Xin, Liu, Shuai, Gao, Yue, AlZahrani, Atif, Kim, Seong H., Chen, Long‐Qing, and Wang, Donghai. Electrokinetic Phenomena Enhanced Lithium-Ion Transport in Leaky Film for Stable Lithium Metal Anodes. United States: N. p., 2019.
Web. doi:10.1002/aenm.201900704.
Li, Guoxing, Liu, Zhe, Wang, Daiwei, He, Xin, Liu, Shuai, Gao, Yue, AlZahrani, Atif, Kim, Seong H., Chen, Long‐Qing, & Wang, Donghai. Electrokinetic Phenomena Enhanced Lithium-Ion Transport in Leaky Film for Stable Lithium Metal Anodes. United States. https://doi.org/10.1002/aenm.201900704
Li, Guoxing, Liu, Zhe, Wang, Daiwei, He, Xin, Liu, Shuai, Gao, Yue, AlZahrani, Atif, Kim, Seong H., Chen, Long‐Qing, and Wang, Donghai. Mon .
"Electrokinetic Phenomena Enhanced Lithium-Ion Transport in Leaky Film for Stable Lithium Metal Anodes". United States. https://doi.org/10.1002/aenm.201900704. https://www.osti.gov/servlets/purl/1657241.
@article{osti_1657241,
title = {Electrokinetic Phenomena Enhanced Lithium-Ion Transport in Leaky Film for Stable Lithium Metal Anodes},
author = {Li, Guoxing and Liu, Zhe and Wang, Daiwei and He, Xin and Liu, Shuai and Gao, Yue and AlZahrani, Atif and Kim, Seong H. and Chen, Long‐Qing and Wang, Donghai},
abstractNote = {The application of lithium (Li) metal anodes in Li metal batteries has been hindered by growth of Li dendrite which leads to short cycling life. Here a Li-ion-affinity leaky film as a protection layer is reported to promote a dendrite-free Li metal anode. The leaky film induces electrokinetic phenomena to enhance Li-ion transport, leading to a reduced Li-ion concentration polarization and homogenous Li-ion distribution. As a result, the dendrite-free Li metal anode during Li plating/stripping is demonstrated even at an extremely high deposition capacity (6 mA h cm-2) and current density (40 mA cm-2) with improved Coulombic efficiencies. A full-cell battery with the leaky-film protected Li metal as anode and high-areal-capacity LiNi0.8Co0.1Mn0.1O2 (NCM-811) (~4.2 mA h cm-2) or LiFePO4 (~3.8 mA h cm-2) as cathode shows improved cycling stability and capacity retention, even at lean electrolyte conditions.},
doi = {10.1002/aenm.201900704},
journal = {Advanced Energy Materials},
number = 22,
volume = 9,
place = {United States},
year = {Mon Apr 29 00:00:00 EDT 2019},
month = {Mon Apr 29 00:00:00 EDT 2019}
}
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