A Polymer-Oriented Self-Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas
Abstract
Mesoporous metal oxides (MMOs) have attracted comprehensive attention in many fields, including energy storage, catalysis, and separation. Current synthesis of MMOs mainly involve use of surfactants as templates to generate mesopores and organic reagents as solvents to hinder hydrolysis and condensation of inorganic precursors, which is adverse to adjusting the interactions between surfactants and inorganic precursors. The resulting products have uncontrollable pore structure, crystallinity, and relatively lower surface areas. Here, a facile and general polymer-oriented self-assembly strategy to synthesize a series of MMOs (e.g., TiO2, ZrO2, NbO5, Al2O3, Ta2O5, HfO2, and SnO2) by using cationic polymers as porogens and metal alkoxides as metal oxide precursors in a robust aqueous synthesis system are reported. Nitrogen adsorption analysis and transmission electron microscopy confirm that the obtained MMOs have ultrahigh specific surface areas and large pore volumes (i.e., 733 m2 g–1 and 0.485 cm3 g–1 for mesoporous TiO2). Moreover, the structural parameters (surface area, pore size, and pore volume) and crystallinity can be readily controlled by tuning the interactions between cationic polymers and precursors. The as-synthesized crystalline mesoporous TiO2 exhibits promising performance in photocatalytic water splitting of hydrogen production and a high hydrogen production rate of 3.68 mol h–1 g–1.
- Authors:
-
[1];
- Jilin Univ., Changchun (China). State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
- Chinese Academy of Sciences (CAS), Changchun (China). Changchun Inst. of Applied Chemistry, Key Lab. of Rare Earth Chemistry and Physics
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; Young Thousand Talented Program; National Natural Science Foundation of China (NSFC); Ministry of Education of China
- OSTI Identifier:
- 1623470
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Science
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2198-3844
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; chemistry; science & technology - other topics; materials science; high crystallinity; mesoporous metal oxides; photocatalytic hydrogen production; polymer‐oriented self‐assembly strategy; ultrahigh surface area
Citation Formats
Xiong, Hailong, Gao, Tunan, Li, Kaiqian, Liu, Yali, Ma, Yali, Liu, Jingwei, Qiao, Zhen‐An, Song, Shuyan, and Dai, Sheng. A Polymer-Oriented Self-Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas. United States: N. p., 2019.
Web. doi:10.1002/advs.201801543.
Xiong, Hailong, Gao, Tunan, Li, Kaiqian, Liu, Yali, Ma, Yali, Liu, Jingwei, Qiao, Zhen‐An, Song, Shuyan, & Dai, Sheng. A Polymer-Oriented Self-Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas. United States. https://doi.org/10.1002/advs.201801543
Xiong, Hailong, Gao, Tunan, Li, Kaiqian, Liu, Yali, Ma, Yali, Liu, Jingwei, Qiao, Zhen‐An, Song, Shuyan, and Dai, Sheng. Mon .
"A Polymer-Oriented Self-Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas". United States. https://doi.org/10.1002/advs.201801543. https://www.osti.gov/servlets/purl/1623470.
@article{osti_1623470,
title = {A Polymer-Oriented Self-Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas},
author = {Xiong, Hailong and Gao, Tunan and Li, Kaiqian and Liu, Yali and Ma, Yali and Liu, Jingwei and Qiao, Zhen‐An and Song, Shuyan and Dai, Sheng},
abstractNote = {Mesoporous metal oxides (MMOs) have attracted comprehensive attention in many fields, including energy storage, catalysis, and separation. Current synthesis of MMOs mainly involve use of surfactants as templates to generate mesopores and organic reagents as solvents to hinder hydrolysis and condensation of inorganic precursors, which is adverse to adjusting the interactions between surfactants and inorganic precursors. The resulting products have uncontrollable pore structure, crystallinity, and relatively lower surface areas. Here, a facile and general polymer-oriented self-assembly strategy to synthesize a series of MMOs (e.g., TiO2, ZrO2, NbO5, Al2O3, Ta2O5, HfO2, and SnO2) by using cationic polymers as porogens and metal alkoxides as metal oxide precursors in a robust aqueous synthesis system are reported. Nitrogen adsorption analysis and transmission electron microscopy confirm that the obtained MMOs have ultrahigh specific surface areas and large pore volumes (i.e., 733 m2 g–1 and 0.485 cm3 g–1 for mesoporous TiO2). Moreover, the structural parameters (surface area, pore size, and pore volume) and crystallinity can be readily controlled by tuning the interactions between cationic polymers and precursors. The as-synthesized crystalline mesoporous TiO2 exhibits promising performance in photocatalytic water splitting of hydrogen production and a high hydrogen production rate of 3.68 mol h–1 g–1.},
doi = {10.1002/advs.201801543},
journal = {Advanced Science},
number = 6,
volume = 6,
place = {United States},
year = {Mon Jan 28 00:00:00 EST 2019},
month = {Mon Jan 28 00:00:00 EST 2019}
}
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