Significantly Improved Cyclability of Conversion-Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction
Abstract
Electrode stabilization by surface passivation has been explored as the most crucial step to develop long-cycle lithium-ion batteries (LIBs). In this work, functionally graded materials consisting of “conversion-type” iron-doped nickel oxyfluoride (NiFeOF) cathode covered with a homologous passivation layer (HPL) are rationally designed for long-cycle LIBs. The compact and fluorine-rich HPL plays dual roles in suppressing the volume change of NiFeOF porous cathode and minimizing the dissolution of transition metals during LIBs cycling by forming a structure/composition gradient. The structure and composition of HPL reconstructs during lithiation/delithiation, buffering the volume change and trapping the dissolved transition metals. As a result, a high capacity of 175 mAh g-1 (equal to an outstanding volumetric capacity of 936 Ah L-1) with a greatly reduced capacity decay rate of 0.012% per cycle for 1000 cycles is achieved, which is superior to the NiFeOF porous film without HPL and commercially available NiF2-FeF3 powders. Finally, the proposed chemical and structure reconstruction mechanism of HPL opens a new avenue for the novel materials development for long-cycle LIBs.
- Authors:
-
[1]
- Univ. of Central Florida, Orlando, FL (United States). NanoScience Technology Center
- Univ. of Central Florida, Orlando, FL (United States)
- Oregon State Univ., Corvallis, OR (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States). X‐Ray Science Division
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF)
- OSTI Identifier:
- 1607992
- Alternate Identifier(s):
- OSTI ID: 1596383
- Grant/Contract Number:
- AC02-06CH11357; CMMI-1851674
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 9; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; functionally graded materials; “conversion-type” cathode; homologous passivation layers; surface reconstruction; long-cycle battery; long‐cycle batteries
Citation Formats
Ju, Licheng, Wang, Guanzhi, Liang, Kun, Wang, Maoyu, Sterbinsky, George E., Feng, Zhenxing, and Yang, Yang. Significantly Improved Cyclability of Conversion-Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction. United States: N. p., 2020.
Web. doi:10.1002/aenm.201903333.
Ju, Licheng, Wang, Guanzhi, Liang, Kun, Wang, Maoyu, Sterbinsky, George E., Feng, Zhenxing, & Yang, Yang. Significantly Improved Cyclability of Conversion-Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction. United States. https://doi.org/10.1002/aenm.201903333
Ju, Licheng, Wang, Guanzhi, Liang, Kun, Wang, Maoyu, Sterbinsky, George E., Feng, Zhenxing, and Yang, Yang. Thu .
"Significantly Improved Cyclability of Conversion-Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction". United States. https://doi.org/10.1002/aenm.201903333. https://www.osti.gov/servlets/purl/1607992.
@article{osti_1607992,
title = {Significantly Improved Cyclability of Conversion-Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction},
author = {Ju, Licheng and Wang, Guanzhi and Liang, Kun and Wang, Maoyu and Sterbinsky, George E. and Feng, Zhenxing and Yang, Yang},
abstractNote = {Electrode stabilization by surface passivation has been explored as the most crucial step to develop long-cycle lithium-ion batteries (LIBs). In this work, functionally graded materials consisting of “conversion-type” iron-doped nickel oxyfluoride (NiFeOF) cathode covered with a homologous passivation layer (HPL) are rationally designed for long-cycle LIBs. The compact and fluorine-rich HPL plays dual roles in suppressing the volume change of NiFeOF porous cathode and minimizing the dissolution of transition metals during LIBs cycling by forming a structure/composition gradient. The structure and composition of HPL reconstructs during lithiation/delithiation, buffering the volume change and trapping the dissolved transition metals. As a result, a high capacity of 175 mAh g-1 (equal to an outstanding volumetric capacity of 936 Ah L-1) with a greatly reduced capacity decay rate of 0.012% per cycle for 1000 cycles is achieved, which is superior to the NiFeOF porous film without HPL and commercially available NiF2-FeF3 powders. Finally, the proposed chemical and structure reconstruction mechanism of HPL opens a new avenue for the novel materials development for long-cycle LIBs.},
doi = {10.1002/aenm.201903333},
journal = {Advanced Energy Materials},
number = 9,
volume = 10,
place = {United States},
year = {Thu Jan 30 00:00:00 EST 2020},
month = {Thu Jan 30 00:00:00 EST 2020}
}
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