Dissociative photoionization of NO across a shape resonance in the XUV range using circularly polarized synchrotron radiation
Abstract
We report benchmark results for dissociative photoionization (DPI) spectroscopy and dynamics of the NO molecule in the region of the σ* shape resonance in the ionization leading to the NO+(c3Π) ionic state. The experimental study combines well characterized extreme ultraviolet (XUV) circularly polarized synchrotron radiation, delivered at the DESIRS beamline (SOLEIL), with ion-electron coincidence 3D momentum spectroscopy. The measured (N+, e) kinetic energy correlation diagrams reported at four discrete photon energies in the extended 23-33 eV energy range allow for resolving the different active DPI reactions and underline the importance of spectrally resolved studies using synchrotron radiation in the context of time-resolved studies where photoionization is induced by broadband XUV attosecond pulses. In the dominant DPI reaction which leads to the NO+(c3Π) ionic state, photoionization dynamics across the σ* shape resonance are probed by molecular frame photoelectron angular distributions where the parallel and perpendicular transitions are highlighted, as well as the circular dichroism CDAD(θe) in the molecular frame. The latter also constitute benchmark references for molecular polarimetry. The measured dynamical parameters are well described by multichannel Schwinger configuration interaction calculations. Finally, similar results are obtained for the DPI spectroscopy of highly excited NO+ electronic states populated in the explored XUVmore »
- Authors:
-
[1];
[1];
[3];
- Univ. Paris-Sud, Orsay (France); Univ. Paris-Saclay, Orsay (France). Inst. des Sciences Moléculaires d’Orsay (ISMO)
- Univ. of Copenhagen (Denmark). Niels Bohr Inst.
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- OSTI Identifier:
- 1603539
- Alternate Identifier(s):
- OSTI ID: 1573427
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Volume: 151; Journal Issue: 17; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Veyrinas, K., Saquet, N., Marggi Poullain, S., Lebech, M., Houver, J. -C., Lucchese, R. R., and Dowek, D. Dissociative photoionization of NO across a shape resonance in the XUV range using circularly polarized synchrotron radiation. United States: N. p., 2019.
Web. doi:10.1063/1.5121620.
Veyrinas, K., Saquet, N., Marggi Poullain, S., Lebech, M., Houver, J. -C., Lucchese, R. R., & Dowek, D. Dissociative photoionization of NO across a shape resonance in the XUV range using circularly polarized synchrotron radiation. United States. https://doi.org/10.1063/1.5121620
Veyrinas, K., Saquet, N., Marggi Poullain, S., Lebech, M., Houver, J. -C., Lucchese, R. R., and Dowek, D. Thu .
"Dissociative photoionization of NO across a shape resonance in the XUV range using circularly polarized synchrotron radiation". United States. https://doi.org/10.1063/1.5121620. https://www.osti.gov/servlets/purl/1603539.
@article{osti_1603539,
title = {Dissociative photoionization of NO across a shape resonance in the XUV range using circularly polarized synchrotron radiation},
author = {Veyrinas, K. and Saquet, N. and Marggi Poullain, S. and Lebech, M. and Houver, J. -C. and Lucchese, R. R. and Dowek, D.},
abstractNote = {We report benchmark results for dissociative photoionization (DPI) spectroscopy and dynamics of the NO molecule in the region of the σ* shape resonance in the ionization leading to the NO+(c3Π) ionic state. The experimental study combines well characterized extreme ultraviolet (XUV) circularly polarized synchrotron radiation, delivered at the DESIRS beamline (SOLEIL), with ion-electron coincidence 3D momentum spectroscopy. The measured (N+, e) kinetic energy correlation diagrams reported at four discrete photon energies in the extended 23-33 eV energy range allow for resolving the different active DPI reactions and underline the importance of spectrally resolved studies using synchrotron radiation in the context of time-resolved studies where photoionization is induced by broadband XUV attosecond pulses. In the dominant DPI reaction which leads to the NO+(c3Π) ionic state, photoionization dynamics across the σ* shape resonance are probed by molecular frame photoelectron angular distributions where the parallel and perpendicular transitions are highlighted, as well as the circular dichroism CDAD(θe) in the molecular frame. The latter also constitute benchmark references for molecular polarimetry. The measured dynamical parameters are well described by multichannel Schwinger configuration interaction calculations. Finally, similar results are obtained for the DPI spectroscopy of highly excited NO+ electronic states populated in the explored XUV photon energy range.},
doi = {10.1063/1.5121620},
journal = {Journal of Chemical Physics},
number = 17,
volume = 151,
place = {United States},
year = {Thu Nov 07 00:00:00 EST 2019},
month = {Thu Nov 07 00:00:00 EST 2019}
}
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