Ruddlesden–Popper Phase in Two-Dimensional Inorganic Halide Perovskites: A Plausible Model and the Supporting Observations
Abstract
A Ruddlesden-Popper (RP) type structure is well-known in oxide perovskites and is related to many interesting properties such as superconductivity and ferroelectricity. However, the RP phase has not yet been discovered in inorganic halide perovskites. Here, we report the direct observation of unusual structure in two-dimensional CsPbBr3 nanosheets which could be interpreted as the RP phase based on model simulations. Structural details of the plausible RP domains and domain boundaries between the RP and conventional perovskite phases have been revealed on the atomic level using aberration-corrected scanning transmission electron microscopy. The finding marks a major advance toward future inorganic halide RP phase synthesis and theoretical modeling, as well as unraveling their structure-property relationship.
- Authors:
-
[1];
[2]
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Div.
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Div.; Kavli Energy NanoScience Institute, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1601162
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 17; Journal Issue: 9; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Ruddlesden-Popper phase; inorganic halide perovskite; aberration-corrected scanning transmission electron microscopy; two-dimensional; domain
Citation Formats
Yu, Yi, Zhang, Dandan, and Yang, Peidong. Ruddlesden–Popper Phase in Two-Dimensional Inorganic Halide Perovskites: A Plausible Model and the Supporting Observations. United States: N. p., 2017.
Web. doi:10.1021/acs.nanolett.7b02146.
Yu, Yi, Zhang, Dandan, & Yang, Peidong. Ruddlesden–Popper Phase in Two-Dimensional Inorganic Halide Perovskites: A Plausible Model and the Supporting Observations. United States. https://doi.org/10.1021/acs.nanolett.7b02146
Yu, Yi, Zhang, Dandan, and Yang, Peidong. Tue .
"Ruddlesden–Popper Phase in Two-Dimensional Inorganic Halide Perovskites: A Plausible Model and the Supporting Observations". United States. https://doi.org/10.1021/acs.nanolett.7b02146. https://www.osti.gov/servlets/purl/1601162.
@article{osti_1601162,
title = {Ruddlesden–Popper Phase in Two-Dimensional Inorganic Halide Perovskites: A Plausible Model and the Supporting Observations},
author = {Yu, Yi and Zhang, Dandan and Yang, Peidong},
abstractNote = {A Ruddlesden-Popper (RP) type structure is well-known in oxide perovskites and is related to many interesting properties such as superconductivity and ferroelectricity. However, the RP phase has not yet been discovered in inorganic halide perovskites. Here, we report the direct observation of unusual structure in two-dimensional CsPbBr3 nanosheets which could be interpreted as the RP phase based on model simulations. Structural details of the plausible RP domains and domain boundaries between the RP and conventional perovskite phases have been revealed on the atomic level using aberration-corrected scanning transmission electron microscopy. The finding marks a major advance toward future inorganic halide RP phase synthesis and theoretical modeling, as well as unraveling their structure-property relationship.},
doi = {10.1021/acs.nanolett.7b02146},
journal = {Nano Letters},
number = 9,
volume = 17,
place = {United States},
year = {Tue Aug 08 00:00:00 EDT 2017},
month = {Tue Aug 08 00:00:00 EDT 2017}
}
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Works referenced in this record:
New compounds of the K 2 NIF 4 type
journal, August 1957
- Ruddlesden, S. N.; Popper, P.
- Acta Crystallographica, Vol. 10, Issue 8
Crystal chemistry of Ruddlesden-Popper type structures in highT c ceramic superconductors
journal, June 1991
- Dwivedi, Anurag; Cormack, A. N.
- Bulletin of Materials Science, Vol. 14, Issue 3
Colossal magnetoresistance in ( x = 0.0, 0.1)
journal, August 1996
- Battle, P. D.; Blundell, S. J.; Green, M. A.
- Journal of Physics: Condensed Matter, Vol. 8, Issue 32
Interface Control of Emergent Ferroic Order in Ruddlesden-Popper
journal, December 2011
- Birol, Turan; Benedek, Nicole A.; Fennie, Craig J.
- Physical Review Letters, Vol. 107, Issue 25
Experimental demonstration of hybrid improper ferroelectricity and the presence of abundant charged walls in (Ca,Sr)3Ti2O7 crystals
journal, January 2015
- Oh, Yoon Seok; Luo, Xuan; Huang, Fei-Ting
- Nature Materials, Vol. 14, Issue 4
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016
- Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
- Nature, Vol. 536, Issue 7616
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016
- Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
- Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
Atomically thin two-dimensional organic-inorganic hybrid perovskites
journal, September 2015
- Dou, L.; Wong, A. B.; Yu, Y.
- Science, Vol. 349, Issue 6255
Systematic Studies on Chain Lengths, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskite Thin Films
journal, October 2006
- Takeoka, Yuko; Asai, Keisuke; Rikukawa, Masahiro
- Bulletin of the Chemical Society of Japan, Vol. 79, Issue 10
Aberration corrected STEM of defects in epitaxial n=4 Ruddlesden-Popper phase Can+1MnnO3n+1
journal, August 2008
- Wang, P.; Bleloch, A. L.; Yan, L.
- Journal of Physics: Conference Series, Vol. 126
Atomic Scale Chemical Mapping in SrO(SrTiO3)6 Ruddlesden-Popper Thin Film
journal, July 2011
- Zhu, Y.; Lee, C-H; Schlom, D.
- Microscopy and Microanalysis, Vol. 17, Issue S2
ELNES study of chemical solution deposited SrO ( SrTiO 3 ) n
journal, December 2009
- Riedl, T.; Gemming, T.; Weissbach, T.
- Ultramicroscopy, Vol. 110, Issue 1
ABINIT: First-principles approach to material and nanosystem properties
journal, December 2009
- Gonze, X.; Amadon, B.; Anglade, P. -M.
- Computer Physics Communications, Vol. 180, Issue 12
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires
journal, July 2015
- Zhang, Dandan; Eaton, Samuel W.; Yu, Yi
- Journal of the American Chemical Society, Vol. 137, Issue 29
Atomic Resolution Imaging of Halide Perovskites
journal, November 2016
- Yu, Yi; Zhang, Dandan; Kisielowski, Christian
- Nano Letters, Vol. 16, Issue 12
Morphology, structure, and nucleation of out-of-phase boundaries (OPBs) in epitaxial films of layered oxides
journal, June 2007
- Zurbuchen, M. A.; Tian, W.; Pan, X. Q.
- Journal of Materials Research, Vol. 22, Issue 6
Quantitative Atomic Resolution Scanning Transmission Electron Microscopy
journal, May 2008
- LeBeau, James M.; Findlay, Scott D.; Allen, Leslie J.
- Physical Review Letters, Vol. 100, Issue 20
Quantitative atomic resolution mapping using high-angle annular dark field scanning transmission electron microscopy
journal, September 2009
- Van Aert, S.; Verbeeck, J.; Erni, R.
- Ultramicroscopy, Vol. 109, Issue 10
Towards full-structure determination of bimetallic nanoparticles with an aberration-corrected electron microscope
journal, November 2010
- Ortalan, Volkan; Uzun, Alper; Gates, Bruce C.
- Nature Nanotechnology, Vol. 5, Issue 12
Atom Column Indexing: Atomic Resolution Image Analysis Through a Matrix Representation
journal, November 2014
- Sang, Xiahan; Oni, Adedapo A.; LeBeau, James M.
- Microscopy and Microanalysis, Vol. 20, Issue 6
Termination Dependence of Tetragonal CH 3 NH 3 PbI 3 Surfaces for Perovskite Solar Cells
journal, August 2014
- Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 16
Works referencing / citing this record:
Metal Halide Perovskite Nanocrystals: Synthesis, Post-Synthesis Modifications and Their Optical Properties
text, January 2020
- Shamsi, Javad; Urban, Alexander S.; Imran, Muhammad
- arXiv