Effects of surface initial condition on aqueous corrosion of glass-A study with a model nuclear waste glass
Abstract
Being a nonequilibrium material, the structure of glass varies with the sample history. Thus, the initial surface condition of a glass can vary with the preparation condition and have a large impact on its reactivity. This paper shows that the aqueous corrosion behavior of international simple glass (ISG) varies depending on the initial surface state. The ISG glass samples were prepared as-polished-only and polished-then-annealed and they were immersed in aqueous solution saturated with soluble SiO2 at 30°C (modeling a mild condition) and at 90°C (modeling a severe condition). Molecular dynamics simulations were performed to obtain coordination numbers of network formers of ISG to assist oxygen speciation calculations. The surface structures of as-prepared and corroded ISG samples were analyzed using various imaging and spectroscopic techniques. Among these analyses, only the oxygen speciation with x-ray photoelectron spectroscopy showed discernable differences between two uncorroded surfaces with different preparation histories; all other methods could not differentiate the surface preparation history before aqueous corrosion. Such minor difference in chemical structures was found to have a profound impact on corrosion behaviors in the mild condition. In the harsh condition, the surface history dependence was not as drastic as the corrosion in the mild condition. The analysismore »
- Authors:
-
- Pennsylvania State Univ., University Park, PA (United States)
- Univ. of North Texas, Denton, TX (United States)
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States); Univ. of North Texas, Denton, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1600987
- Alternate Identifier(s):
- OSTI ID: 1469424
- Grant/Contract Number:
- SC0016584
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Volume: 102; Journal Issue: 4; Journal ID: ISSN 0002-7820
- Publisher:
- American Ceramic Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Liu, Hongshen, Ngo, Dien, Ren, Mengguo, Du, Jincheng, and Kim, Seong H. Effects of surface initial condition on aqueous corrosion of glass-A study with a model nuclear waste glass. United States: N. p., 2018.
Web. doi:10.1111/jace.16016.
Liu, Hongshen, Ngo, Dien, Ren, Mengguo, Du, Jincheng, & Kim, Seong H. Effects of surface initial condition on aqueous corrosion of glass-A study with a model nuclear waste glass. United States. https://doi.org/10.1111/jace.16016
Liu, Hongshen, Ngo, Dien, Ren, Mengguo, Du, Jincheng, and Kim, Seong H. Thu .
"Effects of surface initial condition on aqueous corrosion of glass-A study with a model nuclear waste glass". United States. https://doi.org/10.1111/jace.16016. https://www.osti.gov/servlets/purl/1600987.
@article{osti_1600987,
title = {Effects of surface initial condition on aqueous corrosion of glass-A study with a model nuclear waste glass},
author = {Liu, Hongshen and Ngo, Dien and Ren, Mengguo and Du, Jincheng and Kim, Seong H.},
abstractNote = {Being a nonequilibrium material, the structure of glass varies with the sample history. Thus, the initial surface condition of a glass can vary with the preparation condition and have a large impact on its reactivity. This paper shows that the aqueous corrosion behavior of international simple glass (ISG) varies depending on the initial surface state. The ISG glass samples were prepared as-polished-only and polished-then-annealed and they were immersed in aqueous solution saturated with soluble SiO2 at 30°C (modeling a mild condition) and at 90°C (modeling a severe condition). Molecular dynamics simulations were performed to obtain coordination numbers of network formers of ISG to assist oxygen speciation calculations. The surface structures of as-prepared and corroded ISG samples were analyzed using various imaging and spectroscopic techniques. Among these analyses, only the oxygen speciation with x-ray photoelectron spectroscopy showed discernable differences between two uncorroded surfaces with different preparation histories; all other methods could not differentiate the surface preparation history before aqueous corrosion. Such minor difference in chemical structures was found to have a profound impact on corrosion behaviors in the mild condition. In the harsh condition, the surface history dependence was not as drastic as the corrosion in the mild condition. The analysis results of the corroded surfaces suggested that the thickness and structure of the alteration layer formed on ISG in aqueous corrosion can vary with the initial surface state.},
doi = {10.1111/jace.16016},
journal = {Journal of the American Ceramic Society},
number = 4,
volume = 102,
place = {United States},
year = {Thu Aug 23 00:00:00 EDT 2018},
month = {Thu Aug 23 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Glassy Wasteforms for Nuclear Waste Immobilization
journal, November 2010
- Ojovan, Michael I.; Lee, William E.
- Metallurgical and Materials Transactions A, Vol. 42, Issue 4
Open Scientific Questions about Nuclear Glass Corrosion
journal, January 2014
- Gin, S.
- Procedia Materials Science, Vol. 7
An international initiative on long-term behavior of high-level nuclear waste glass
journal, June 2013
- Gin, S.; Abdelouas, A.; Criscenti, L. J.
- Materials Today, Vol. 16, Issue 6
Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses
journal, November 2013
- Vienna, John D.; Ryan, Joseph V.; Gin, Stéphane
- International Journal of Applied Glass Science, Vol. 4, Issue 4
SON68 glass alteration under Si-rich solutions at low temperature (35–90 °C): kinetics, secondary phases and isotopic exchange studies
journal, January 2016
- Bouakkaz, Rachid; Abdelouas, Abdesselam; El Mendili, Yassine
- RSC Advances, Vol. 6, Issue 76
SON 68 nuclear glass alteration kinetics between pH 7 and pH 11.5
journal, May 2001
- Gin, S.; Mestre, J. P.
- Journal of Nuclear Materials, Vol. 295, Issue 1
Effect of composition on the short-term and long-term dissolution rates of ten borosilicate glasses of increasing complexity from 3 to 30 oxides
journal, September 2012
- Gin, Stéphane; Beaudoux, Xavier; Angéli, Frédéric
- Journal of Non-Crystalline Solids, Vol. 358, Issue 18-19
Resumption of Alteration at High Temperature and pH: Rates Measurements and Comparison with Initial Rates
journal, January 2014
- Fournier, Maxime; Frugier, Pierre; Gin, Stéphane
- Procedia Materials Science, Vol. 7
The fate of silicon during glass corrosion under alkaline conditions: A mechanistic and kinetic study with the International Simple Glass
journal, February 2015
- Gin, Stéphane; Jollivet, Patrick; Fournier, Maxime
- Geochimica et Cosmochimica Acta, Vol. 151
Experimental investigation of aqueous corrosion of R7T7 nuclear glass at 90°C in the presence of organic species
journal, May 1994
- Gin, S.; Godon, N.; Mestre, J. P.
- Applied Geochemistry, Vol. 9, Issue 3
French SON 68 nuclear glass alteration mechanisms on contact with clay media
journal, June 2001
- Gin, S.; Jollivet, P.; Mestre, J. P.
- Applied Geochemistry, Vol. 16, Issue 7-8
An experimental study of the dissolution rates of simulated aluminoborosilicate waste glasses as a function of pH and temperature under dilute conditions
journal, September 2008
- Pierce, Eric M.; Rodriguez, Elsa A.; Calligan, L. J.
- Applied Geochemistry, Vol. 23, Issue 9
The Relationship Between Reaction Layer Thickness and Leach Rate For Nuclear Waste Glasses
journal, January 1983
- Chick, L. A.; Pederson, L. R.
- MRS Proceedings, Vol. 26
Kinetics of amorphous silica dissolution and the paradox of the silica polymorphs
journal, July 2008
- Dove, P. M.; Han, N.; Wallace, A. F.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 29
Various effects of magnetite on international simple glass (ISG) dissolution: implications for the long-term durability of nuclear glasses
journal, July 2017
- Neill, Lindsey; Gin, Stéphane; Ducasse, Thomas
- npj Materials Degradation, Vol. 1, Issue 1
The structure of abraded glass surfaces
journal, February 1922
- Preston, F. W.
- Transactions of the Optical Society, Vol. 23, Issue 3
Optical glass fabrication technology 2: Relationship between surface roughness and subsurface damage
journal, January 1987
- Hed, P. Paul; Edwards, David F.
- Applied Optics, Vol. 26, Issue 21
The Phenomena of Rupture and Flow in Solids
journal, January 1921
- Griffith, A. A.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 221, Issue 582-593
Stress-corrosion mechanisms in silicate glasses
journal, October 2009
- Ciccotti, Matteo
- Journal of Physics D: Applied Physics, Vol. 42, Issue 21
Stress Corrosion and Static Fatigue of Glass
journal, October 1970
- Wiederhorn, S. M.; Bolz, L. H.
- Journal of the American Ceramic Society, Vol. 53, Issue 10
Environmentally Enhanced Crack Growth in Soda-Lime Glass
journal, March 1985
- Freiman, S. W.; White, G. S.; Fuller, E. R.
- Journal of the American Ceramic Society, Vol. 68, Issue 3
Chemical Durability of Some Sodium Borosilicate Glasses Improved by Phase Separation*
journal, May 1987
- Taylor, Peter; Ashmore, Sheila D.; Owen, Derrek G.
- Journal of the American Ceramic Society, Vol. 70, Issue 5
Effect of annealing and other heat treatments on the pH response of the glass electrode
journal, February 1948
- Hubbard, Donald; Rynders, Gerald F.
- Journal of Research of the National Bureau of Standards, Vol. 40, Issue 2
Development of empirical potentials for sodium borosilicate glass systems
journal, September 2011
- Kieu, Le-Hai; Delaye, Jean-Marc; Cormier, Laurent
- Journal of Non-Crystalline Solids, Vol. 357, Issue 18
Development of effective empirical potentials for molecular dynamics simulations of the structures and properties of boroaluminosilicate glasses
journal, December 2016
- Deng, Lu; Du, Jincheng
- Journal of Non-Crystalline Solids, Vol. 453
Structure of International Simple Glass and properties of passivating layer formed in circumneutral pH conditions
journal, February 2018
- Collin, Marie; Fournier, Maxime; Frugier, Pierre
- npj Materials Degradation, Vol. 2, Issue 1
Surface structures of sodium borosilicate glasses from molecular dynamics simulations
journal, March 2017
- Ren, Mengguo; Deng, Lu; Du, Jincheng
- Journal of the American Ceramic Society, Vol. 100, Issue 6
Bulk, surface structures and properties of sodium borosilicate and boroaluminosilicate nuclear waste glasses from molecular dynamics simulations
journal, November 2017
- Ren, Mengguo; Deng, Lu; Du, Jincheng
- Journal of Non-Crystalline Solids, Vol. 476
Quantitative morphological and compositional evaluation of laboratory prepared aluminoborosilicate glass surfaces
journal, January 2015
- Gong, Yuxuan; Wren, Anthony W.; Mellott, Nathan P.
- Applied Surface Science, Vol. 324
Evaluation of a simple correction for the hydrocarbon contamination layer in quantitative surface analysis by XPS
journal, July 2005
- Smith, Graham C.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 148, Issue 1
Elemental areal density calculation and oxygen speciation for flat glass surfaces using x-ray photoelectron spectroscopy
journal, October 2016
- Banerjee, Joy; Kim, Seong H.; Pantano, Carlo G.
- Journal of Non-Crystalline Solids, Vol. 450
Characterization of surface structures of dealkalized soda lime silica glass using X-ray photoelectron, specular reflection infrared, attenuated total reflection infrared and sum frequency generation spectroscopies
journal, October 2017
- Sheth, Nisha; Luo, Jiawei; Banerjee, Joy
- Journal of Non-Crystalline Solids, Vol. 474
DL_POLY_2.0: A general-purpose parallel molecular dynamics simulation package
journal, June 1996
- Smith, W.; Forester, T. R.
- Journal of Molecular Graphics, Vol. 14, Issue 3, p. 136-141
Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy
journal, August 2018
- Luo, Jiawei; Smith, Nicholas J.; Pantano, Carlo G.
- Journal of Non-Crystalline Solids, Vol. 494
Specular reflectance (SR) and attenuated total reflectance (ATR) infrared (IR) spectroscopy of transparent flat glass surfaces: A case study for soda lime float glass
journal, November 2015
- Amma, Shin-ichi; Luo, Jiawei; Pantano, Carlo G.
- Journal of Non-Crystalline Solids, Vol. 428
Spectroscopic ellipsometry study of thickness and porosity of the alteration layer formed on international simple glass surface in aqueous corrosion conditions
journal, July 2018
- Ngo, Dien; Liu, Hongshen; Sheth, Nisha
- npj Materials Degradation, Vol. 2, Issue 1
Molecular dynamics study of correlations between IR peak position and bond parameters of silica and silicate glasses: Effects of temperature and stress
journal, September 2017
- Luo, Jiawei; Zhou, Yuxing; Milner, Scott T.
- Journal of the American Ceramic Society, Vol. 101, Issue 1
Infrared spectroscopy in the investigation of oxide glasses structure
journal, November 1999
- Stoch, L.; Środa, M.
- Journal of Molecular Structure, Vol. 511-512
The effect of molecular structure on borosilicate glass leaching
journal, October 1986
- Bunker, B. C.; Arnold, G. W.; Day, D. E.
- Journal of Non-Crystalline Solids, Vol. 87, Issue 1-2
Hydrothermal reactions of soda lime silica glass – Revealing subsurface damage and alteration of mechanical properties and chemical structure of glass surfaces
journal, November 2016
- Luo, Jiawei; Huynh, Hoang; Pantano, Carlo G.
- Journal of Non-Crystalline Solids, Vol. 452
Chemical processes in glass polishing
journal, April 1990
- Cook, Lee M.
- Journal of Non-Crystalline Solids, Vol. 120, Issue 1-3
Empirical atomic sensitivity factors for quantitative analysis by electron spectroscopy for chemical analysis
journal, October 1981
- Wagner, C. D.; Davis, L. E.; Zeller, M. V.
- Surface and Interface Analysis, Vol. 3, Issue 5
Effect of heat treatment on the surface chemical structure of glass: Oxygen speciation from in situ XPS analysis
journal, September 2017
- Banerjee, Joy; Bojan, Vincent; Pantano, Carlo G.
- Journal of the American Ceramic Society, Vol. 101, Issue 2
SON68 nuclear glass dissolution kinetics: Current state of knowledge and basis of the new GRAAL model
journal, October 2008
- Frugier, P.; Gin, S.; Minet, Y.
- Journal of Nuclear Materials, Vol. 380, Issue 1-3
Thermal Poling of Soda-Lime Silica Glass with Nonblocking Electrodes-Part 1: Effects of Sodium Ion Migration and Water Ingress on Glass Surface Structure
journal, January 2016
- Luo, Jiawei; He, Hongtu; Podraza, Nikolas J.
- Journal of the American Ceramic Society, Vol. 99, Issue 4
Aqueous Corrosion of Soda-Silica and Soda-Lime-Silica Glass
journal, January 1976
- Clark, D. E.; Dilmore, M. F.; Ethridge, E. C.
- Journal of the American Ceramic Society, Vol. 59, Issue 1-2
Quantitative Analysis of Glass Structure with the Use of Infrared Reflection Spectra
journal, May 1974
- Sanders, D. M.; Person, W. B.; Hench, L. L.
- Applied Spectroscopy, Vol. 28, Issue 3
Investigation of surface roughness on etched glass surfaces
journal, February 2011
- Pápa, Z.; Budai, J.; Farkas, B.
- Thin Solid Films, Vol. 519, Issue 9
Etched glass surfaces, atomic force microscopy and stochastic analysis
journal, February 2007
- Jafari, G. R.; Reza Rahimi Tabar, M.; Iraji zad, A.
- Physica A: Statistical Mechanics and its Applications, Vol. 375, Issue 1
Experimental analysis of the surface roughness evolution of etched glass for micro/nanofluidic devices
journal, January 2011
- Ren, J.; Ganapathysubramanian, B.; Sundararajan, S.
- Journal of Micromechanics and Microengineering, Vol. 21, Issue 2
The mechanism of borosilicate glass corrosion revisited
journal, June 2015
- Geisler, Thorsten; Nagel, Thorsten; Kilburn, Matt R.
- Geochimica et Cosmochimica Acta, Vol. 158
Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism
journal, June 2010
- Geisler, Thorsten; Janssen, Arne; Scheiter, Daniel
- Journal of Non-Crystalline Solids, Vol. 356, Issue 28-30
Intrinsic toughening and stable crack propagation in hexagonal boron nitride
journal, June 2021
- Yang, Yingchao; Song, Zhigong; Lu, Guangyuan
- Nature, Vol. 594, Issue 7861
Aqueous Corrosion of Soda-Silica and Soda-Lime-Silica Glass
journal, September 1976
- Clark, D. E.; Dilmore, M. F.; Ethridge, E. C.
- Journal of the American Ceramic Society, Vol. 59, Issue 9-10
Etched Glass Surfaces, Atomic Force Microscopy and Stochastic Analysis
text, January 2007
- Jafari, G. R.; Tabar, M. Reza Rahimi; zad, A. Iraji
- arXiv
Works referencing / citing this record:
Hydrogen bonding interactions of H2O and SiOH on a boroaluminosilicate glass corroded in aqueous solution
journal, January 2020
- Ngo, Dien; Liu, Hongshen; Chen, Zhe
- npj Materials Degradation, Vol. 4, Issue 1
Dissolution of silica component of glass network at early stage of corrosion in initially silica‐saturated solution
journal, May 2019
- Ngo, Dien; Liu, Hongshen; Kaya, Huseyin
- Journal of the American Ceramic Society, Vol. 102, Issue 11
Searching for correlations between vibrational spectral features and structural parameters of silicate glass network
journal, February 2020
- Liu, Hongshen; Hahn, Seung Ho; Ren, Mengguo
- Journal of the American Ceramic Society, Vol. 103, Issue 6