Photocatalytic degradation of organic pollutants coupled with simultaneous photocatalytic H2 evolution over graphene quantum dots/Mn-N-TiO2/g-C3N4 composite catalysts: Performance and mechanism
Abstract
Graphene quantum dots/Mn-N-TiO2/g-C3N4 (GQDs/TCN) composite photocatalysts have been designed, synthesized and characterized by XRD, SEM, TEM, Raman, BET, and XPS. The photodegradation of organic pollutants (p-nitrophenol, diethyl phthalate and ciprofloxacin, called as 4-NP, CIP and DEP, respectively) coupled with simultaneous photocatalytic production of hydrogen was successfully achieved using the GQDs/TCN catalysts. The 5%GQDs/TCN-0.4 sample shows the best photocatalytic hydrogen production and organic pollutant degradation rate under simulated solar irradiation in the simultaneous photocatalytic oxidation and reduction system. Furthermore, the photocatalytic H2 evolution rates in the solution of 4-NP, CIP and DEP are all larger than that in pure water system over the 5%GQDs/TCN-0.4 catalyst. And the H2 evolution rate in the solution of 4-NP is smaller than that in the solutions of CIP and DEP. Accordingly, the photodegradation rate of 4-NP is larger than that of CIP and DEP. The analyses of density functional theory and liquid chromatography mass spectrometry indicate that some photogenerated electrons were used in the photodegradation process of 4-NP but not in that of CIP and DEP. And it leads to the photocatalytic rate of H2 evolution in the 4-NP solution smaller than that in the solution of CIP and DEP. For the first time, themore »
- Authors:
-
- Nanchang Hangkong Univ., Nanchang (China). Key Lab. of Jiangxi Province for Persistent Pollutants Control and Resources Recycle
- Xiangtan Univ. (China). Key Lab. of Environmentally Friendly Chemistry and Applications of Ministry of Education
- East China Univ. of Science and Technology, Shanghai (China). School of Chemistry & Molecular Engineering
- Univ. of Connecticut, Storrs, CT (United States)
- Publication Date:
- Research Org.:
- Univ. of Connecticut, Storrs, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- OSTI Identifier:
- 1597843
- Grant/Contract Number:
- FG02-86ER-13622
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Catalysis. B, Environmental
- Additional Journal Information:
- Journal Volume: 227; Journal Issue: C; Journal ID: ISSN 0926-3373
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; Degradation; Graphitic carbon nitride; Hydrogen evolution; Organic pollutants; Photocatalysis
Citation Formats
Nie, Yu-Chun, Yu, Fan, Wang, Lai-Chun, Xing, Qiu-Ju, Liu, Xia, Pei, Yong, Zou, Jian-Ping, Dai, Wei-Li, Li, Yan, and Suib, Steven L. Photocatalytic degradation of organic pollutants coupled with simultaneous photocatalytic H2 evolution over graphene quantum dots/Mn-N-TiO2/g-C3N4 composite catalysts: Performance and mechanism. United States: N. p., 2018.
Web. doi:10.1016/j.apcatb.2018.01.033.
Nie, Yu-Chun, Yu, Fan, Wang, Lai-Chun, Xing, Qiu-Ju, Liu, Xia, Pei, Yong, Zou, Jian-Ping, Dai, Wei-Li, Li, Yan, & Suib, Steven L. Photocatalytic degradation of organic pollutants coupled with simultaneous photocatalytic H2 evolution over graphene quantum dots/Mn-N-TiO2/g-C3N4 composite catalysts: Performance and mechanism. United States. https://doi.org/10.1016/j.apcatb.2018.01.033
Nie, Yu-Chun, Yu, Fan, Wang, Lai-Chun, Xing, Qiu-Ju, Liu, Xia, Pei, Yong, Zou, Jian-Ping, Dai, Wei-Li, Li, Yan, and Suib, Steven L. Sun .
"Photocatalytic degradation of organic pollutants coupled with simultaneous photocatalytic H2 evolution over graphene quantum dots/Mn-N-TiO2/g-C3N4 composite catalysts: Performance and mechanism". United States. https://doi.org/10.1016/j.apcatb.2018.01.033. https://www.osti.gov/servlets/purl/1597843.
@article{osti_1597843,
title = {Photocatalytic degradation of organic pollutants coupled with simultaneous photocatalytic H2 evolution over graphene quantum dots/Mn-N-TiO2/g-C3N4 composite catalysts: Performance and mechanism},
author = {Nie, Yu-Chun and Yu, Fan and Wang, Lai-Chun and Xing, Qiu-Ju and Liu, Xia and Pei, Yong and Zou, Jian-Ping and Dai, Wei-Li and Li, Yan and Suib, Steven L.},
abstractNote = {Graphene quantum dots/Mn-N-TiO2/g-C3N4 (GQDs/TCN) composite photocatalysts have been designed, synthesized and characterized by XRD, SEM, TEM, Raman, BET, and XPS. The photodegradation of organic pollutants (p-nitrophenol, diethyl phthalate and ciprofloxacin, called as 4-NP, CIP and DEP, respectively) coupled with simultaneous photocatalytic production of hydrogen was successfully achieved using the GQDs/TCN catalysts. The 5%GQDs/TCN-0.4 sample shows the best photocatalytic hydrogen production and organic pollutant degradation rate under simulated solar irradiation in the simultaneous photocatalytic oxidation and reduction system. Furthermore, the photocatalytic H2 evolution rates in the solution of 4-NP, CIP and DEP are all larger than that in pure water system over the 5%GQDs/TCN-0.4 catalyst. And the H2 evolution rate in the solution of 4-NP is smaller than that in the solutions of CIP and DEP. Accordingly, the photodegradation rate of 4-NP is larger than that of CIP and DEP. The analyses of density functional theory and liquid chromatography mass spectrometry indicate that some photogenerated electrons were used in the photodegradation process of 4-NP but not in that of CIP and DEP. And it leads to the photocatalytic rate of H2 evolution in the 4-NP solution smaller than that in the solution of CIP and DEP. For the first time, the present work illuminates the photocatalytic enhancement of the GQDs/TCN-0.4 catalyst and the mechanism of the effect of different organic pollutants on photocatalytic H2 evolution.},
doi = {10.1016/j.apcatb.2018.01.033},
journal = {Applied Catalysis. B, Environmental},
number = C,
volume = 227,
place = {United States},
year = {Sun Jul 01 00:00:00 EDT 2018},
month = {Sun Jul 01 00:00:00 EDT 2018}
}
Web of Science
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