An Analysis of Limiting Cases for the Metal Oxide Film Growth Kinetics Using an Oxygen Defects Model Accounting for Transport and Interfacial Reactions
Abstract
This work was motivated by the need to understand the passivation of metal surfaces to provide resistance against chemical degradation, given that corrosion is a major limiting factor in the operational lifetime of metals and their alloys. Here, a unified analysis for an oxide growth model was presented. The oxide growth model was consistent with the literature and accounted for the transport of oxygen defects through a growing oxide film, as well as the electrochemical reactions of oxygen defects at the metal/oxide and oxide/environment interfaces. A linear potential profile across the oxide film was assumed. The model was analyzed for different rate limiting steps in the physicochemical process and perturbation techniques were utilized when necessary. In conclusion, the investigation yielded the well-known linear, parabolic, logarithmic and integral rate laws and the conditions that led to these rate laws were discussed.
- Authors:
-
[1];
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- The Ohio State Univ., Columbus, OH (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1565835
- Report Number(s):
- LA-UR-19-29354
Journal ID: ISSN 0340-0204
- Grant/Contract Number:
- 89233218CNA000001; SC0016584
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Non-Equilibrium Thermodynamics
- Additional Journal Information:
- Journal Volume: 43; Journal Issue: 4; Journal ID: ISSN 0340-0204
- Publisher:
- Walter de Gruyter GmbH
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; oxide growth; limiting cases; corrosion
Citation Formats
Samin, Adib Jamil, and Taylor, Christopher D. An Analysis of Limiting Cases for the Metal Oxide Film Growth Kinetics Using an Oxygen Defects Model Accounting for Transport and Interfacial Reactions. United States: N. p., 2018.
Web. doi:10.1515/jnet-2018-0018.
Samin, Adib Jamil, & Taylor, Christopher D. An Analysis of Limiting Cases for the Metal Oxide Film Growth Kinetics Using an Oxygen Defects Model Accounting for Transport and Interfacial Reactions. United States. https://doi.org/10.1515/jnet-2018-0018
Samin, Adib Jamil, and Taylor, Christopher D. Fri .
"An Analysis of Limiting Cases for the Metal Oxide Film Growth Kinetics Using an Oxygen Defects Model Accounting for Transport and Interfacial Reactions". United States. https://doi.org/10.1515/jnet-2018-0018. https://www.osti.gov/servlets/purl/1565835.
@article{osti_1565835,
title = {An Analysis of Limiting Cases for the Metal Oxide Film Growth Kinetics Using an Oxygen Defects Model Accounting for Transport and Interfacial Reactions},
author = {Samin, Adib Jamil and Taylor, Christopher D.},
abstractNote = {This work was motivated by the need to understand the passivation of metal surfaces to provide resistance against chemical degradation, given that corrosion is a major limiting factor in the operational lifetime of metals and their alloys. Here, a unified analysis for an oxide growth model was presented. The oxide growth model was consistent with the literature and accounted for the transport of oxygen defects through a growing oxide film, as well as the electrochemical reactions of oxygen defects at the metal/oxide and oxide/environment interfaces. A linear potential profile across the oxide film was assumed. The model was analyzed for different rate limiting steps in the physicochemical process and perturbation techniques were utilized when necessary. In conclusion, the investigation yielded the well-known linear, parabolic, logarithmic and integral rate laws and the conditions that led to these rate laws were discussed.},
doi = {10.1515/jnet-2018-0018},
journal = {Journal of Non-Equilibrium Thermodynamics},
number = 4,
volume = 43,
place = {United States},
year = {Fri Aug 17 00:00:00 EDT 2018},
month = {Fri Aug 17 00:00:00 EDT 2018}
}
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Figure 1: An illustration of the model used in the study
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Works referencing / citing this record:
Degradation and regeneration mechanisms of NiO protective layers deposited by ALD on photoanodes
journal, January 2019
- Ros, Carles; Andreu, Teresa; David, Jérémy
- Journal of Materials Chemistry A, Vol. 7, Issue 38
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.