Infrared, diode laser spectroscopy of the Ar–N2O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode

Hu, T. A.; Chappell, E. L.; Sharpe, S. W.

doi:10.1063/1.465101

Title: Infrared, diode laser spectroscopy of the Ar–N₂O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode

Abstract

Rotationally resolved vibrational spectra consisting of a-type transitions have been observed for the low-frequency, intermolecular bending mode in combination with the highest frequency, intramolecular stretching mode of Ar-N₂O.

Authors:

Hu, T. A. ^[1]; Chappell, E. L. ^[1]; Sharpe, S. W. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Publication Date:: Thu Apr 15 00:00:00 EDT 1993

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1560135

Report Number(s):: PNNL-SA-21747
Journal ID: ISSN 0021-9606; TRN: US2000461

Grant/Contract Number:: AC05-76RL01830

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Chemical Physics

Additional Journal Information:: Journal Volume: 98; Journal Issue: 8; Journal ID: ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats


                    Hu, T. A., Chappell, E. L., and Sharpe, S. W. Infrared, diode laser spectroscopy of the Ar–N2O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode.  United States: N. p., 1993. 
Web.  doi:10.1063/1.465101.

Copy to clipboard


                    Hu, T. A., Chappell, E. L., & Sharpe, S. W. Infrared, diode laser spectroscopy of the Ar–N2O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode.  United States.  https://doi.org/10.1063/1.465101

Copy to clipboard


                    Hu, T. A., Chappell, E. L., and Sharpe, S. W. Thu .  
"Infrared, diode laser spectroscopy of the Ar–N2O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode".  United States.  https://doi.org/10.1063/1.465101.  https://www.osti.gov/servlets/purl/1560135.

Copy to clipboard


                    
@article{osti_1560135,

  title        = {Infrared, diode laser spectroscopy of the Ar–N2O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode},

  author       = {Hu, T. A. and Chappell, E. L. and Sharpe, S. W.},

  abstractNote = {Rotationally resolved vibrational spectra consisting of a-type transitions have been observed for the low-frequency, intermolecular bending mode in combination with the highest frequency, intramolecular stretching mode of Ar-N2O.},

  doi          = {10.1063/1.465101},

  journal      = {Journal of Chemical Physics},

  number       = 8,

  volume       = 98,

  place        = {United States},

  year         = {Thu Apr 15 00:00:00 EDT 1993},

  month        = {Thu Apr 15 00:00:00 EDT 1993}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1063/1.465101

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 56 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Theory of Centrifugal Distortion Constants of Polyatomic Rotor Molecules
journal, July 1953

Kivelson, Daniel; Wilson, E. Bright
The Journal of Chemical Physics, Vol. 21, Issue 7
DOI: 10.1063/1.1699170

Molecular-beam infrared spectroscopy of the Ar–N ₂ O van der Waals molecule
journal, January 1986

Hodge, Jeremy; Hayman, Garry D.; Dyke, Thomas R.
J. Chem. Soc., Faraday Trans. 2, Vol. 82, Issue 8
DOI: 10.1039/F29868201137

Matrix formulations in the theory of centrifugal distortion
journal, September 1970

Sørensen, G. O.; Hagen, G.; Cyvin, S. J.
Journal of Molecular Spectroscopy, Vol. 35, Issue 3
DOI: 10.1016/0022-2852(70)90189-X

On the apparent spectroscopic rigidity of floppy molecular systems
journal, October 1989

Nesbitt, David J.; Naaman, Ron
The Journal of Chemical Physics, Vol. 91, Issue 7
DOI: 10.1063/1.456865

Extension of the 106 samples Fourier spectrometry to the Indium Antimonide region: Vibration-rotation bands of 14N2 16O: 3.3–5.5 μm region
journal, February 1976

Amiot, C.; Guelachvili, G.
Journal of Molecular Spectroscopy, Vol. 59, Issue 2
DOI: 10.1016/0022-2852(76)90289-7

Pulsed molecular beam infrared absorption spectroscopy of CO2 dimer
journal, December 1987

Walsh, M. A.; England, T. H.; Dyke, T. R.
Chemical Physics Letters, Vol. 142, Issue 3-4
DOI: 10.1016/0009-2614(87)80935-1

Optothermal‐infrared and pulsed‐nozzle Fourier‐transform microwave spectroscopy of rare gas–CO ₂ complexes
journal, May 1988

Fraser, G. T.; Pine, A. S.; Suenram, R. D.
The Journal of Chemical Physics, Vol. 88, Issue 10
DOI: 10.1063/1.454454

Rotational spectrum, structure, and intramolecular force field of the ArClCN van der Waals complex
journal, July 1981

Keenan, M. R.; Wozniak, D. B.; Flygare, W. H.
The Journal of Chemical Physics, Vol. 75, Issue 2
DOI: 10.1063/1.442080

Pulsed molecular‐beam, diode‐laser spectrometry using rapid scanning techniques
journal, May 1989

De Piante, A.; Campbell, E. J.; Buelow, S. J.
Review of Scientific Instruments, Vol. 60, Issue 5
DOI: 10.1063/1.1140335

Molecular-beam infrared absorption studies of rare gas-ocs complexes
journal, July 1985

Hayman, G. D.; Hodge, J.; Howard, B. J.
Chemical Physics Letters, Vol. 118, Issue 1
DOI: 10.1016/0009-2614(85)85256-8

Vibration—Rotation Interaction in Polyatomic Molecules. I. The Zeta Matrices
journal, June 1956

Meal, Janet Hawkins; Polo, S. R.
The Journal of Chemical Physics, Vol. 24, Issue 6
DOI: 10.1063/1.1742728

Infrared absorption spectroscopy of the CO ₂ –Ar complex in the 2376 cm ⁻¹ combination band region: The intermolecular bend
journal, January 1991

Sharpe, S. W.; Reifschneider, D.; Wittig, C.
The Journal of Chemical Physics, Vol. 94, Issue 1
DOI: 10.1063/1.460380

Infrared laser spectroscopy of molecular beams
journal, April 1977

Gough, T. E.; Miller, R. E.; Scoles, G.
Applied Physics Letters, Vol. 30, Issue 7
DOI: 10.1063/1.89390

Submillimeter wave spectrum and molecular constants of N2O
journal, August 1976

Andreev, B. A.; Burenin, A. V.; Karyakin, E. N.
Journal of Molecular Spectroscopy, Vol. 62, Issue 2
DOI: 10.1016/0022-2852(76)90344-1

Tunable far infrared laser spectrometers
journal, July 1991

Blake, G. A.; Laughlin, K. B.; Cohen, R. C.
Review of Scientific Instruments, Vol. 62, Issue 7
DOI: 10.1063/1.1142409

Influence of Vibrations on Molecular Structure Determinations. I. General Formulation of Vibration—Rotation Interactions
journal, October 1962

Herschbach, Dudley R.; Laurie, Victor W.
The Journal of Chemical Physics, Vol. 37, Issue 8
DOI: 10.1063/1.1733357

The rotational Zeeman effect in the ArOCS van der Waals complex
journal, September 1983

Shea, J. A.; Read, W. G.; Campbell, E. J.
The Journal of Chemical Physics, Vol. 79, Issue 6
DOI: 10.1063/1.446167

cw planar supersonic jet spectroscopy of ν2 OCHCl using a computer-controlled tunable diode laser
journal, September 1989

Wang, Zhongcheng; Eliades, Michael; Bevan, John W.
Chemical Physics Letters, Vol. 161, Issue 1
DOI: 10.1016/S0009-2614(89)87021-6

Fourier transform microwave spectroscopy of Hg–CO ₂
journal, October 1991

Iida, Minoru; Ohshima, Yasuhiro; Endo, Yasuki
The Journal of Chemical Physics, Vol. 95, Issue 7
DOI: 10.1063/1.461719

The structure of Ar–N2O
journal, December 1981

Joyner, C. H.; Dixon, T. A.; Baiocchi, F. A.
The Journal of Chemical Physics, Vol. 75, Issue 11
DOI: 10.1063/1.441968

Determination of the structure of ArCO ₂ by radio frequency and microwave spectroscopy
journal, May 1979

Steed, J. M.; Dixon, T. A.; Klemperer, W.
The Journal of Chemical Physics, Vol. 70, Issue 9
DOI: 10.1063/1.438033

Slit pulsed valve for generation of long‐path‐length supersonic expansions
journal, May 1987

Lovejoy, Christopher M.; Nesbitt, David J.
Review of Scientific Instruments, Vol. 58, Issue 5
DOI: 10.1063/1.1139636

Infrared absorption spectroscopy of CO ₂ –HX complexes using the CO ₂ asymmetric stretch chromophore: CO ₂ HF(DF) and CO ₂ HCl(DCl) linear and CO ₂ HBr bent equilibrium geometries
journal, January 1990

Sharpe, S. W.; Zeng, Y. P.; Wittig, C.
The Journal of Chemical Physics, Vol. 92, Issue 2
DOI: 10.1063/1.458077

Infrared absorption spectroscopy of rare-gas ? CO2 clusters produced in supersonic expansions
journal, January 1988

Randall, Robert W.; Walsh, Michael A.; Howard, Brian J.
Faraday Discussions of the Chemical Society, Vol. 85
DOI: 10.1039/dc9888500013

Works referencing / citing this record:

Rovibrational laser jet-cooled spectroscopy of SF ₆ –rare gas complexes in the ν ₃ region of SF ₆
journal, January 2018

Asselin, Pierre; Turner, Andrew C.; Bruel, Laurent
Physical Chemistry Chemical Physics, Vol. 20, Issue 44
DOI: 10.1039/c8cp04387f

A three-dimensional ab initio potential energy surface and predicted infrared spectra for the He–N2O complex
journal, April 2006

Zhou, Yanzi; Xie, Daiqian; Zhang, Dong Hui
The Journal of Chemical Physics, Vol. 124, Issue 14
DOI: 10.1063/1.2189227

Infrared diode laser spectroscopy of the Kr–N ₂ O van der Waals complex: the v ₁ symmetric stretch region of N ₂ O
journal, March 2011

Zheng, Rui; Zhu, Yu; Li, Song
Molecular Physics, Vol. 109, Issue 6
DOI: 10.1080/00268976.2011.554330

Similar Records in DOE PAGES and OSTI.GOV collections:

Infrared, diode laser spectroscopy of the Ar--N[sub 2]O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode

Journal Article Hu, T A ; Chappell, E L ; Sharpe, S W - Journal of Chemical Physics

Rotationally resolved vibrational spectra consisting of [ital a]-type transitions have been observed for the low-frequency, intermolecular bending mode in combination with the highest frequency, intramolecular stretching mode of Ar--N[sub 2]O. Analysis of the spectral data places the origin of the combination band at 2256.1 cm [sup [minus]1] while the origin of the intramolecular stretching fundamental is at 2223.9 cm[sup [minus]1]. The difference between these two origins is approximately 32.2 cm[sup [minus]1] and agrees well with our calculated frequency of 31.5 cm[sup [minus]1] for the intermolecular bending mode, which was obtained by analysis of the centrifugal distortion constants. In addition, argon--nitrousmore »« less
https://doi.org/10.1063/1.465101
High resolution spectroscopy of jet cooled phenyl radical: The ν₁ and ν₂ a₁ symmetry C–H stretching modes

Journal Article Chang, Chih-Hsuan ; Nesbitt, David J. - Journal of Chemical Physics

A series of CH stretch modes in phenyl radical (C₆H₅) has been investigated via high resolution infrared spectroscopy at sub-Doppler resolution (~60 MHz) in a supersonic discharge slit jet expansion. Two fundamental vibrations of a1 symmetry, ν₁ and ν₂, are observed and rotationally analyzed for the first time, corresponding to in-phase and out-of-phase symmetric CH stretch excitation at the ortho/meta/para and ortho/para C atoms with respect to the radical center. The ν₁ and ν₂ band origins are determined to be 3073.968 50(8) cm^–1 and 3062.264 80(7) cm^–1, respectively, which both agree within 5 cm^–1 with theoretical anharmonic scaling predictions basedmore »« less
Cited by 5
https://doi.org/10.1063/1.4955295

Full Text Available
High resolution spectroscopy of jet cooled phenyl radical: The ν{sub 1} and ν{sub 2} a{sub 1} symmetry C–H stretching modes

Journal Article Chang, Chih-Hsuan ; Nesbitt, David J. - Journal of Chemical Physics

A series of CH stretch modes in phenyl radical (C{sub 6}H{sub 5}) has been investigated via high resolution infrared spectroscopy at sub-Doppler resolution (∼60 MHz) in a supersonic discharge slit jet expansion. Two fundamental vibrations of a{sub 1} symmetry, ν{sub 1} and ν{sub 2}, are observed and rotationally analyzed for the first time, corresponding to in-phase and out-of-phase symmetric CH stretch excitation at the ortho/meta/para and ortho/para C atoms with respect to the radical center. The ν{sub 1} and ν{sub 2} band origins are determined to be 3073.968 50(8) cm{sup −1} and 3062.264 80(7) cm{sup −1}, respectively, which both agree within 5more »« less
https://doi.org/10.1063/1.4955295
Far-infrared vibration--rotation-tunneling spectroscopy of Ar--NH sub 3 : Intermolecular vibrations and effective angular potential energy surface

Journal Article Schmuttenmaer, C A ; Cohen, R C ; Loeser, J G ; ... - Journal of Chemical Physics; (USA)

Two new intermolecular vibration--rotation-tunneling (VRT) bands of Ar--NH{sub 3} have been measured using tunable far infrared laser spectroscopy. We have unambiguously assigned these and a previously measured FIR band (Gwo {ital et} {ital al}., Mol. Phys. {bold 71}, 453 (1990)) as {Pi}(1{sub 0}, {ital n}=0){l arrow}{Sigma}(0{sub 0}, {ital n}=0), {Sigma}(1{sub 0}, {ital n}=0){l arrow}{Sigma}(0{sub 0}, {ital n}=0), and {Sigma}(0{sub 0}, {ital n}=1){l arrow}{Sigma}(0{sub 0}, {ital n}=0). The three upper states of these are found to be strongly mixed by anisotropy and Coriolis effects. A simultaneous least squares fit of all transitions has yielded vibrational frequencies, rotational and centrifugal distortion constants,more »« less
https://doi.org/10.1063/1.461430
Infrared spectroscopy and time-resolved dynamics of the ortho-H{sub 2}{endash}OH entrance channel complex

Journal Article Anderson, D T ; Schwartz, R L ; Todd, M W ; ... - Journal of Chemical Physics

The rotationally resolved infrared spectrum of the prereactive o-H{sub 2}{endash}OH complex in its ground electronic state is obtained in the OH overtone region at {approximately}1.4 {mu}m using an IR-UV double resonance fluorescence enhancement technique. The pure OH overtone band of o-H{sub 2}{endash}OH is observed as well as approximately 20 additional rovibrational transitions extending out to the OH (Xthinsp{sup 2}{Pi},v=2)+o-H{sub 2}(Xthinsp{sup 1}{Sigma}{sub g}{sup +}) dissociation limit. These transitions are assigned as combination bands involving the simultaneous excitation of the OH vibrational overtone and intermolecular bending (internal rotor) states. The assignment of the experimental spectrum is aided by a detailed comparison withmore »« less
https://doi.org/10.1063/1.476941

Similar Records

Title: Infrared, diode laser spectroscopy of the Ar–N2O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode

Abstract

Citation Formats

Theory of Centrifugal Distortion Constants of Polyatomic Rotor Molecules journal, July 1953

Molecular-beam infrared spectroscopy of the Ar–N 2 O van der Waals molecule journal, January 1986

Matrix formulations in the theory of centrifugal distortion journal, September 1970

On the apparent spectroscopic rigidity of floppy molecular systems journal, October 1989

Extension of the 106 samples Fourier spectrometry to the Indium Antimonide region: Vibration-rotation bands of 14N2 16O: 3.3–5.5 μm region journal, February 1976

Pulsed molecular beam infrared absorption spectroscopy of CO2 dimer journal, December 1987

Optothermal‐infrared and pulsed‐nozzle Fourier‐transform microwave spectroscopy of rare gas–CO 2 complexes journal, May 1988

Rotational spectrum, structure, and intramolecular force field of the ArClCN van der Waals complex journal, July 1981

Pulsed molecular‐beam, diode‐laser spectrometry using rapid scanning techniques journal, May 1989

Molecular-beam infrared absorption studies of rare gas-ocs complexes journal, July 1985

Vibration—Rotation Interaction in Polyatomic Molecules. I. The Zeta Matrices journal, June 1956

Infrared absorption spectroscopy of the CO 2 –Ar complex in the 2376 cm −1 combination band region: The intermolecular bend journal, January 1991

Infrared laser spectroscopy of molecular beams journal, April 1977

Submillimeter wave spectrum and molecular constants of N2O journal, August 1976

Tunable far infrared laser spectrometers journal, July 1991

Influence of Vibrations on Molecular Structure Determinations. I. General Formulation of Vibration—Rotation Interactions journal, October 1962

The rotational Zeeman effect in the ArOCS van der Waals complex journal, September 1983

cw planar supersonic jet spectroscopy of ν2 OCHCl using a computer-controlled tunable diode laser journal, September 1989

Fourier transform microwave spectroscopy of Hg–CO 2 journal, October 1991

The structure of Ar–N2O journal, December 1981

Determination of the structure of ArCO 2 by radio frequency and microwave spectroscopy journal, May 1979

Slit pulsed valve for generation of long‐path‐length supersonic expansions journal, May 1987

Infrared absorption spectroscopy of CO 2 –HX complexes using the CO 2 asymmetric stretch chromophore: CO 2 HF(DF) and CO 2 HCl(DCl) linear and CO 2 HBr bent equilibrium geometries journal, January 1990

Infrared absorption spectroscopy of rare-gas ? CO2 clusters produced in supersonic expansions journal, January 1988

Rovibrational laser jet-cooled spectroscopy of SF 6 –rare gas complexes in the ν 3 region of SF 6 journal, January 2018

A three-dimensional ab initio potential energy surface and predicted infrared spectra for the He–N2O complex journal, April 2006

Infrared diode laser spectroscopy of the Kr–N 2 O van der Waals complex: the v 1 symmetric stretch region of N 2 O journal, March 2011

Title: Infrared, diode laser spectroscopy of the Ar–N₂O complex: Observation of the intermolecular bending mode in combination with the highest frequency intramolecular stretching mode

Theory of Centrifugal Distortion Constants of Polyatomic Rotor Molecules
journal, July 1953

Molecular-beam infrared spectroscopy of the Ar–N ₂ O van der Waals molecule
journal, January 1986

Matrix formulations in the theory of centrifugal distortion
journal, September 1970

On the apparent spectroscopic rigidity of floppy molecular systems
journal, October 1989

Extension of the 106 samples Fourier spectrometry to the Indium Antimonide region: Vibration-rotation bands of 14N2 16O: 3.3–5.5 μm region
journal, February 1976

Pulsed molecular beam infrared absorption spectroscopy of CO2 dimer
journal, December 1987

Optothermal‐infrared and pulsed‐nozzle Fourier‐transform microwave spectroscopy of rare gas–CO ₂ complexes
journal, May 1988

Rotational spectrum, structure, and intramolecular force field of the ArClCN van der Waals complex
journal, July 1981

Pulsed molecular‐beam, diode‐laser spectrometry using rapid scanning techniques
journal, May 1989

Molecular-beam infrared absorption studies of rare gas-ocs complexes
journal, July 1985

Vibration—Rotation Interaction in Polyatomic Molecules. I. The Zeta Matrices
journal, June 1956

Infrared absorption spectroscopy of the CO ₂ –Ar complex in the 2376 cm ⁻¹ combination band region: The intermolecular bend
journal, January 1991

Infrared laser spectroscopy of molecular beams
journal, April 1977

Submillimeter wave spectrum and molecular constants of N2O
journal, August 1976

Tunable far infrared laser spectrometers
journal, July 1991

Influence of Vibrations on Molecular Structure Determinations. I. General Formulation of Vibration—Rotation Interactions
journal, October 1962

The rotational Zeeman effect in the ArOCS van der Waals complex
journal, September 1983

cw planar supersonic jet spectroscopy of ν2 OCHCl using a computer-controlled tunable diode laser
journal, September 1989

Fourier transform microwave spectroscopy of Hg–CO ₂
journal, October 1991

The structure of Ar–N2O
journal, December 1981

Determination of the structure of ArCO ₂ by radio frequency and microwave spectroscopy
journal, May 1979

Slit pulsed valve for generation of long‐path‐length supersonic expansions
journal, May 1987

Infrared absorption spectroscopy of CO ₂ –HX complexes using the CO ₂ asymmetric stretch chromophore: CO ₂ HF(DF) and CO ₂ HCl(DCl) linear and CO ₂ HBr bent equilibrium geometries
journal, January 1990

Infrared absorption spectroscopy of rare-gas ? CO2 clusters produced in supersonic expansions
journal, January 1988

Rovibrational laser jet-cooled spectroscopy of SF ₆ –rare gas complexes in the ν ₃ region of SF ₆
journal, January 2018

A three-dimensional ab initio potential energy surface and predicted infrared spectra for the He–N2O complex
journal, April 2006

Infrared diode laser spectroscopy of the Kr–N ₂ O van der Waals complex: the v ₁ symmetric stretch region of N ₂ O
journal, March 2011