High-Z Sensitized Plastic Scintillators: A Review
Abstract
The need for affordable and reliable radiation detectors has prompted significant investment in new radiation detector materials, due to concerns about national security and nuclear nonproliferation. Plastic scintillators provide an affordable approach to large volume detectors, yet their performance for high-energy gamma radiation is severely limited by the small radiation stopping power inherent to their low atomic number. Although some sensitization attempts with organometallics were made in the 1950s to 1960s, the concomitant decrease in light yield has limited the usefulness of these sensitized detectors. Recently, with new knowledge gained during the rapid development of organic optoelectronics and nanotechnology, there has been a revived interest in the field of heavy element sensitized plastic scintillators. In this paper, the recent efforts on sensitized plastic scintillators are summarized. Basic scintillator physics is first reviewed. The discussion then focuses on two major thrusts in the field: sensitization with: (1) organometallics and (2) oxide and fluoride nanoparticles. The design rationales and major results are examined in detail, with existing limitations and possible future pathways discussed. Lastly, special attention is paid to the underlying energy deposition and transfer processes, as these determine the key performance metrics such as light yield and radioluminescence decay lifetime.
- Authors:
-
- Univ. of California, Los Angeles, CA (United States)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1543075
- Alternate Identifier(s):
- OSTI ID: 1436355
- Report Number(s):
- LLNL-JRNL-781719
Journal ID: ISSN 0935-9648; 976556
- Grant/Contract Number:
- AC52-07NA27344; AC03‐76SF00098; AC03-76SF00098
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 27; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; gamma; high‐Z; nanocomposite; scintillator
Citation Formats
Hajagos, Tibor Jacob, Liu, Chao, Cherepy, Nerine J., and Pei, Qibing. High-Z Sensitized Plastic Scintillators: A Review. United States: N. p., 2018.
Web. doi:10.1002/adma.201706956.
Hajagos, Tibor Jacob, Liu, Chao, Cherepy, Nerine J., & Pei, Qibing. High-Z Sensitized Plastic Scintillators: A Review. United States. https://doi.org/10.1002/adma.201706956
Hajagos, Tibor Jacob, Liu, Chao, Cherepy, Nerine J., and Pei, Qibing. Mon .
"High-Z Sensitized Plastic Scintillators: A Review". United States. https://doi.org/10.1002/adma.201706956. https://www.osti.gov/servlets/purl/1543075.
@article{osti_1543075,
title = {High-Z Sensitized Plastic Scintillators: A Review},
author = {Hajagos, Tibor Jacob and Liu, Chao and Cherepy, Nerine J. and Pei, Qibing},
abstractNote = {The need for affordable and reliable radiation detectors has prompted significant investment in new radiation detector materials, due to concerns about national security and nuclear nonproliferation. Plastic scintillators provide an affordable approach to large volume detectors, yet their performance for high-energy gamma radiation is severely limited by the small radiation stopping power inherent to their low atomic number. Although some sensitization attempts with organometallics were made in the 1950s to 1960s, the concomitant decrease in light yield has limited the usefulness of these sensitized detectors. Recently, with new knowledge gained during the rapid development of organic optoelectronics and nanotechnology, there has been a revived interest in the field of heavy element sensitized plastic scintillators. In this paper, the recent efforts on sensitized plastic scintillators are summarized. Basic scintillator physics is first reviewed. The discussion then focuses on two major thrusts in the field: sensitization with: (1) organometallics and (2) oxide and fluoride nanoparticles. The design rationales and major results are examined in detail, with existing limitations and possible future pathways discussed. Lastly, special attention is paid to the underlying energy deposition and transfer processes, as these determine the key performance metrics such as light yield and radioluminescence decay lifetime.},
doi = {10.1002/adma.201706956},
journal = {Advanced Materials},
number = 27,
volume = 30,
place = {United States},
year = {Mon May 07 00:00:00 EDT 2018},
month = {Mon May 07 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites
journal, September 1993
- Murray, C. B.; Norris, D. J.; Bawendi, M. G.
- Journal of the American Chemical Society, Vol. 115, Issue 19, p. 8706-8715
Study of porous glass doped with quantum dots or laser dyes under alpha irradiation
journal, March 2006
- Létant, S. E.; Wang, T. -F.
- Applied Physics Letters, Vol. 88, Issue 10
Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility
journal, July 1997
- Peng, Xiaogang; Schlamp, Michael C.; Kadavanich, Andreas V.
- Journal of the American Chemical Society, Vol. 119, Issue 30, p. 7019-7029
Influence of bismuth loading in polystyrene-based plastic scintillators for low energy gamma spectroscopy
journal, January 2014
- Bertrand, G. H. V.; Sguerra, F.; Dehé-Pittance, C.
- Journal of Materials Chemistry C, Vol. 2, Issue 35
A general strategy for nanocrystal synthesis
journal, September 2005
- Wang, Xun; Zhuang, Jing; Peng, Qing
- Nature, Vol. 437, Issue 7055
High energy resolution plastic scintillator
conference, September 2016
- van Loef, Edgar V.; Feng, Patrick; Markosyan, Gary
- SPIE Optical Engineering + Applications, SPIE Proceedings
Synthesis of bulk-size transparent gadolinium oxide–polymer nanocomposites for gamma ray spectroscopy
journal, January 2013
- Cai, Wen; Chen, Qi; Cherepy, Nerine
- Journal of Materials Chemistry C, Vol. 1, Issue 10
Multifunctional Role of Rare Earth Doping in Optical Materials: Nonaqueous Sol–Gel Synthesis of Stabilized Cubic HfO 2 Luminescent Nanoparticles
journal, July 2013
- Lauria, Alessandro; Villa, Irene; Fasoli, Mauro
- ACS Nano, Vol. 7, Issue 8
Bismuth- and lithium-loaded plastic scintillators for gamma and neutron detection
journal, April 2015
- Cherepy, Nerine J.; Sanner, Robert D.; Beck, Patrick R.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 778, p. 126-132
The luminescence decay of organic scintillators
journal, June 1968
- Laustriat, G.
- Molecular Crystals, Vol. 4, Issue 1-4, p. 127-145
Highly efficient luminescent solar concentrators based on earth-abundant indirect-bandgap silicon quantum dots
journal, February 2017
- Meinardi, Francesco; Ehrenberg, Samantha; Dhamo, Lorena
- Nature Photonics, Vol. 11, Issue 3
Non-Aqueous Synthesis of High-Purity Metal Oxide Nanopowders Using an Ether Elimination Process
journal, December 2004
- Pinna, N.; Garnweitner, G.; Antonietti, M.
- Advanced Materials, Vol. 16, Issue 23-24
Influence of the Nature of Ionizing Particles on the Specific Luminescence of Organic Scintillators
journal, November 1966
- Voltz, R.; da Silva, J. Lopes; Laustriat, G.
- The Journal of Chemical Physics, Vol. 45, Issue 9
HfO 2 :X (X = Eu 3+ , Ce 3+ , Y 3+ ) Sol Gel Powders for Ultradense Scintillating Materials
journal, October 2008
- LeLuyer, C.; Villanueva-Ibañez, M.; Pillonnet, A.
- The Journal of Physical Chemistry A, Vol. 112, Issue 41
Preparation and luminescent properties of GdOF:Ce, Tb nanoparticles and their transparent PMMA nanocomposites
journal, May 2015
- Cai, Wen; Wang, Aiwu; Fu, Li
- Optical Materials, Vol. 43
The Scintillation Process in Organic Systems
journal, June 1960
- Birks, J. B.
- IRE Transactions on Nuclear Science, Vol. 7, Issue 2-3
Semiconductor Quantum Dot Scintillation under γ-Ray Irradiation
journal, December 2006
- Létant, S. E.; Wang, T. -F.
- Nano Letters, Vol. 6, Issue 12
From Trifluoroacetate Complex Precursors to Monodisperse Rare-Earth Fluoride and Oxyfluoride Nanocrystals with Diverse Shapes through Controlled Fluorination in Solution Phase
journal, March 2007
- Sun, Xiao; Zhang, Ya-Wen; Du, Ya-Ping
- Chemistry - A European Journal, Vol. 13, Issue 8
Nanocomposite scintillators for radiation detection and nuclear spectroscopy
journal, August 2007
- McKigney, Edward A.; Del Sesto, Rico E.; Jacobsohn, Luiz G.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 579, Issue 1
Facile Single-Precursor Synthesis and Surface Modification of Hafnium Oxide Nanoparticles for Nanocomposite γ-Ray Scintillators
journal, June 2015
- Liu, Chao; Hajagos, Tibor Jacob; Kishpaugh, David
- Advanced Functional Materials, Vol. 25, Issue 29
Zero-Reabsorption Doped-Nanocrystal Luminescent Solar Concentrators
journal, March 2014
- Erickson, Christian S.; Bradshaw, Liam R.; McDowall, Stephen
- ACS Nano, Vol. 8, Issue 4
Ligand Engineering of Polymer Nanocomposites: From the Simple to the Complex
journal, February 2014
- Li, Ying; Krentz, Timothy M.; Wang, Lei
- ACS Applied Materials & Interfaces, Vol. 6, Issue 9
Luminescent and kinetic properties of the polystyrene composites based on BaF2 nanoparticles
journal, February 2016
- Demkiv, T. M.; Halyatkin, O. O.; Vistovskyy, V. V.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 810
Properties of Composite Scintillators in Static and Dynamic States
journal, November 2003
- Vasil'chenko, V. G.; Solov'ev, A. S.
- Instruments and Experimental Techniques, Vol. 46, Issue 6
CdTe quantum dots and polymer nanocomposites for x-ray scintillation and imaging
journal, May 2011
- Kang, Zhitao; Zhang, Yuelan; Menkara, Hisham
- Applied Physics Letters, Vol. 98, Issue 18
Quantum-Dot/Organic Semiconductor Composites for Radiation Detection
journal, January 2006
- Campbell, I. H.; Crone, B. K.
- Advanced Materials, Vol. 18, Issue 1
The First Fluoride One-Dimensional Nanostructures: Microemulsion-Mediated Hydrothermal Synthesis of BaF 2 Whiskers
journal, September 2003
- Cao, Minhua; Hu, Changwen; Wang, Enbo
- Journal of the American Chemical Society, Vol. 125, Issue 37
Single-Crystalline and Monodisperse LaF 3 Triangular Nanoplates from a Single-Source Precursor
journal, March 2005
- Zhang, Ya-Wen; Sun, Xiao; Si, Rui
- Journal of the American Chemical Society, Vol. 127, Issue 10
The surface science of nanocrystals
journal, January 2016
- Boles, Michael A.; Ling, Daishun; Hyeon, Taeghwan
- Nature Materials, Vol. 15, Issue 2
Quantum Dot-Organic Polymer Composite Materials for Radiation Detection and Imaging
journal, February 2012
- Lawrence, William G.; Thacker, Samta; Palamakumbura, Senerath
- IEEE Transactions on Nuclear Science, Vol. 59, Issue 1
Luminescence and scintillation properties of LuPO4-Ce nanoparticles
journal, January 2014
- Vistovskyy, V.; Malyy, T.; Pushak, A.
- Journal of Luminescence, Vol. 145
Modelling energy deposition in nanoscintillators to predict the efficiency of the X-ray-induced photodynamic effect
journal, January 2015
- Bulin, Anne-Laure; Vasil'ev, Andrey; Belsky, Andrei
- Nanoscale, Vol. 7, Issue 13
LaF 3 :Ce nanocomposite scintillator for gamma-ray detection
conference, September 2007
- McKigney, E. A.; Muenchausen, R. E.; Cooke, D. W.
- Optical Engineering + Applications, SPIE Proceedings
Nearly 100% internal phosphorescence efficiency in an organic light-emitting device
journal, November 2001
- Adachi, Chihaya; Baldo, Marc A.; Thompson, Mark E.
- Journal of Applied Physics, Vol. 90, Issue 10
High refractive index organic–inorganic nanocomposites: design, synthesis and application
journal, January 2009
- Lü, Changli; Yang, Bai
- Journal of Materials Chemistry, Vol. 19, Issue 19
Low-cost extruded plastic scintillator
journal, July 2001
- Pla-Dalmau, Anna; Bross, Alan D.; Mellott, Kerry L.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 466, Issue 3
Lanthanum halide nanoparticle scintillators for nuclear radiation detection
journal, February 2013
- Guss, Paul; Guise, Ronald; Yuan, Ding
- Journal of Applied Physics, Vol. 113, Issue 6
Development of New Technologies for the Manufacturing of Nanocrystalline Scintillation Materials
journal, June 2008
- Jalabadze, Nikoloz V.; Chedia, Roin; Kukava, Tengiz
- IEEE Transactions on Nuclear Science, Vol. 55, Issue 3
Evaluation of organometallics in plastic scintillators toward γ-radiation
journal, July 1964
- Sandler, S. R.; Tsou, K. C.
- The International Journal of Applied Radiation and Isotopes, Vol. 15, Issue 7
Synthesis of BaF2:Ce nanophosphor and epoxy encapsulated transparent nanocomposite
journal, October 2011
- Kang, Zhitao; Barta, Meredith; Nadler, Jason
- Journal of Luminescence, Vol. 131, Issue 10
Hybrid Nanocomposite Materials?between inorganic glasses and organic polymers
journal, June 1993
- Novak, Bruce M.
- Advanced Materials, Vol. 5, Issue 6
Transparent Ultra-High-Loading Quantum Dot/Polymer Nanocomposite Monolith for Gamma Scintillation
journal, May 2017
- Liu, Chao; Li, Zhou; Hajagos, Tibor Jacob
- ACS Nano, Vol. 11, Issue 6
Partial ligand exchange as a critical approach to the synthesis of transparent ytterbium fluoride–polymer nanocomposite monoliths for gamma ray scintillation
journal, January 2016
- Jin, Yunxia; Kishpaugh, David; Liu, Chao
- Journal of Materials Chemistry C, Vol. 4, Issue 16
Large-scale synthesis of CexLa1−xF3 nanocomposite scintillator materials
journal, January 2011
- Feller, Russell K.; Purdy, Geraldine M.; Ortiz-Acosta, Denisse
- Journal of Materials Chemistry, Vol. 21, Issue 15
Hybrid materials from organophosphorus coupling molecules
journal, January 2005
- Mutin, P. Hubert; Guerrero, Gilles; Vioux, André
- Journal of Materials Chemistry, Vol. 15, Issue 35-36
Nanoparticle Polymer Composites: Where Two Small Worlds Meet
journal, November 2006
- Balazs, A. C.; Emrick, T.; Russell, T. P.
- Science, Vol. 314, Issue 5802, p. 1107-1110
Bismuth-loaded plastic scintillators for gamma-ray spectroscopy
journal, January 2012
- Rupert, B. L.; Cherepy, N. J.; Sturm, B. W.
- EPL (Europhysics Letters), Vol. 97, Issue 2
Works referencing / citing this record:
Gleaming Uranium: An Emerging Emitter for Building X‐ray Scintillators
journal, November 2019
- Wang, Yumin; Yin, Xuemiao; Chen, Junfeng
- Chemistry – A European Journal, Vol. 26, Issue 9
The Bright X‐Ray Stimulated Luminescence of HfO 2 Nanocrystals Activated by Ti Ions
journal, November 2019
- Villa, Irene; Moretti, Federico; Fasoli, Mauro
- Advanced Optical Materials, Vol. 8, Issue 1
Heat-resistant Pb( ii )-based X-ray scintillating metal–organic frameworks for sensitive dosage detection via an aggregation-induced luminescent chromophore
journal, January 2020
- Lu, Jian; Wang, Shuai-Hua; Li, Yan
- Dalton Transactions, Vol. 49, Issue 22
Real‐Time Optical Response of Polysiloxane/Quantum Dot Nanocomposites under 2 MeV Proton Irradiation: Luminescence Enhancement of Polysiloxane Emission through Quantum Dot Sensitization
journal, December 2019
- Zanazzi, Enrico; Favaro, Matteo; Ficorella, Andrea
- physica status solidi (a), Vol. 217, Issue 5