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Title: Combination of atomic lines and molecular bands for uranium optical isotopic analysis in laser induced plasma spectrometry

Abstract

Through computer simulation on experimentally acquired optical spectra, uranium isotopic analysis by laser ablation molecular isotopic spectrometry and laser induced breakdown spectroscopy were studied. The use of only one spectral feature, either the strong UO band at 593.55 nm or the nearby U I 593.382 nm line, are similar in precisions (~ 1.5% in absolute 235U abundances). Precision improves to 0.72% with the use of a group of U atomic lines from 591.6 to 596.5 nm. The use of both molecular bands and atomic lines further advances the precision to 0.42% and compares well with the U II 424.437 nm single-line benchmark (0.48% precision).

Authors:
 [1];  [1];  [2];  [1];  [1]
+ Show Author Affiliations
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Korea Inst. of Nuclear Safety, Daejeon (South Korea)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation; USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1532238
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Radioanalytical and Nuclear Chemistry
Additional Journal Information:
Journal Volume: 312; Journal Issue: 1; Journal ID: ISSN 0236-5731
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; Optical isotopic analysis; Uranium Laser ablation molecular isotopic spectrometry; Laser induced breakdown spectroscopy; Isotope shift

Citation Formats

Mao, Xianglei, Chan, George C. -Y., Choi, Inhee, Zorba, Vassilia, and Russo, Richard E. Combination of atomic lines and molecular bands for uranium optical isotopic analysis in laser induced plasma spectrometry. United States: N. p., 2017. Web. doi:10.1007/s10967-017-5197-y.
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Mao, Xianglei, Chan, George C. -Y., Choi, Inhee, Zorba, Vassilia, & Russo, Richard E. Combination of atomic lines and molecular bands for uranium optical isotopic analysis in laser induced plasma spectrometry. United States. https://doi.org/10.1007/s10967-017-5197-y
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Mao, Xianglei, Chan, George C. -Y., Choi, Inhee, Zorba, Vassilia, and Russo, Richard E. Sat . "Combination of atomic lines and molecular bands for uranium optical isotopic analysis in laser induced plasma spectrometry". United States. https://doi.org/10.1007/s10967-017-5197-y. https://www.osti.gov/servlets/purl/1532238.
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@article{osti_1532238,
title = {Combination of atomic lines and molecular bands for uranium optical isotopic analysis in laser induced plasma spectrometry},
author = {Mao, Xianglei and Chan, George C. -Y. and Choi, Inhee and Zorba, Vassilia and Russo, Richard E.},
abstractNote = {Through computer simulation on experimentally acquired optical spectra, uranium isotopic analysis by laser ablation molecular isotopic spectrometry and laser induced breakdown spectroscopy were studied. The use of only one spectral feature, either the strong UO band at 593.55 nm or the nearby U I 593.382 nm line, are similar in precisions (~ 1.5% in absolute 235U abundances). Precision improves to 0.72% with the use of a group of U atomic lines from 591.6 to 596.5 nm. The use of both molecular bands and atomic lines further advances the precision to 0.42% and compares well with the U II 424.437 nm single-line benchmark (0.48% precision).},
doi = {10.1007/s10967-017-5197-y},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
number = 1,
volume = 312,
place = {United States},
year = {Sat Feb 11 00:00:00 EST 2017},
month = {Sat Feb 11 00:00:00 EST 2017}
}
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https://doi.org/10.1007/s10967-017-5197-y
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Works referenced in this record:

A PLS model based on dominant factor for coal analysis using laser-induced breakdown spectroscopy
journal, March 2011

  • Feng, Jie; Wang, Zhe; West, Logan
  • Analytical and Bioanalytical Chemistry, Vol. 400, Issue 10
  • DOI: 10.1007/s00216-011-4865-y

Isotopic abundance determinations by inductively coupled plasma atomic emission spectroscopy
journal, December 1981

  • Edelson, Martin C.; Fassel, Velmer A.
  • Analytical Chemistry, Vol. 53, Issue 14
  • DOI: 10.1021/ac00237a049

Laser Ablation Molecular Isotopic Spectrometry
journal, February 2011

  • Russo, Richard E.; Bol'shakov, Alexander A.; Mao, Xianglei
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 66, Issue 2
  • DOI: 10.1016/j.sab.2011.01.007

Rotationally resolved electronic spectra for uranium monoxide
journal, August 1985

  • Heaven, Michael C.; Nicolai, Jean-Philippe; Riley, Stephen J.
  • Chemical Physics Letters, Vol. 119, Issue 2-3
  • DOI: 10.1016/0009-2614(85)80065-8

Spectroscopy and Structure of the Simplest Actinide Bonds
journal, October 2014

  • Heaven, Michael C.; Barker, Beau J.; Antonov, Ivan O.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 46
  • DOI: 10.1021/jp507283n

Laser Ablation Molecular Isotopic Spectrometry: Parameter influence on boron isotope measurements
journal, August 2011

  • Mao, Xianglei; Bol'shakov, Alexander A.; Perry, Dale L.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 66, Issue 8
  • DOI: 10.1016/j.sab.2011.06.007

Isotope ratio determination of uranium by optical emission spectroscopy on a laser-produced plasma - basic investigations and analytical results
journal, May 1998

  • Pietsch, W.; Petit, A.; Briand, A.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 53, Issue 5, p. 751-761
  • DOI: 10.1016/S0584-8547(97)00123-7

Monitoring Uranium, Hydrogen, and Lithium and Their Isotopes Using a Compact Laser-Induced Breakdown Spectroscopy (LIBS) Probe and High-Resolution Spectrometer
journal, March 2012

  • Cremers, David A.; Beddingfield, Alan; Smithwick, Robert
  • Applied Spectroscopy, Vol. 66, Issue 3
  • DOI: 10.1366/11-06314

Temporal Gating for the Optimization of Laser-Induced Breakdown Spectroscopy Detection and Analysis of Toxic Metals
journal, October 2001

  • Fisher, Brian T.; Johnsen, Howard A.; Buckley, Steven G.
  • Applied Spectroscopy, Vol. 55, Issue 10
  • DOI: 10.1366/0003702011953667

Atlas of uranium emission intensities in a hollow cathode discharge
report, July 1980

Evaluation of the prediction precision capability of partial least squares regression approach for analysis of high alloy steel by laser induced breakdown spectroscopy
journal, June 2015

  • Sarkar, Arnab; Karki, Vijay; Aggarwal, Suresh K.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 108
  • DOI: 10.1016/j.sab.2015.04.002

Pu-239/Pu-240 isotope ratios determined using high resolution emission spectroscopy in a laser-induced plasma
journal, May 2002

  • Smith, Coleman A.; Martinez, Max A.; Veirs, D. Kirk
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 57, Issue 5, p. 929-937
  • DOI: 10.1016/S0584-8547(02)00023-X

Energy levels of neutral atomic uranium (Ui)
journal, January 1976

  • Blaise, Jean; Radziemski, Leon J.
  • Journal of the Optical Society of America, Vol. 66, Issue 7
  • DOI: 10.1364/JOSA.66.000644

Determination of the deuterium/hydrogen ratio in gas reaction products by laser-induced breakdown spectroscopy
journal, July 2006

  • D'Ulivo, A.; Onor, M.; Pitzalis, E.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 61, Issue 7
  • DOI: 10.1016/j.sab.2006.06.001

Brightness-normalized Partial Least Squares Regression for hyperspectral data
journal, August 2010

  • Feilhauer, Hannes; Asner, Gregory P.; Martin, Roberta E.
  • Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 111, Issue 12-13
  • DOI: 10.1016/j.jqsrt.2010.03.007

Accurate Atomic Transition Probabilities for Hydrogen, Helium, and Lithium
journal, September 2009

  • Wiese, W. L.; Fuhr, J. R.
  • Journal of Physical and Chemical Reference Data, Vol. 38, Issue 3
  • DOI: 10.1063/1.3077727

Comparative study of femtosecond and nanosecond laser-induced breakdown spectroscopy of depleted uranium
journal, January 2011

  • Emmert, Luke A.; Chinni, Rosemarie C.; Cremers, David A.
  • Applied Optics, Vol. 50, Issue 3
  • DOI: 10.1364/AO.50.000313

Multiple emission line analysis for improved isotopic determination of uranium — a computer simulation study
journal, November 2013

  • Chan, George C. -Y.; Mao, Xianglei; Choi, Inhee
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 89
  • DOI: 10.1016/j.sab.2013.09.001

Femtosecond Laser Ablation Molecular Isotopic Spectrometry for Zirconium Isotope Analysis
journal, April 2015

Validation of isotopic analysis of depleted, natural and enriched uranium using high resolution ICP-OES
journal, January 2011

  • Krachler, Michael; Carbol, Paul
  • J. Anal. At. Spectrom., Vol. 26, Issue 2
  • DOI: 10.1039/C0JA00083C

Electronic Spectroscopy of UO
journal, September 1997

  • Kaledin, Leonid A.; Heaven, Michael C.
  • Journal of Molecular Spectroscopy, Vol. 185, Issue 1
  • DOI: 10.1006/jmsp.1997.7383

Line Selection and Parameter Optimization for Trace Analysis of Uranium in Glass Matrices by Laser-Induced Breakdown Spectroscopy (LIBS)
journal, November 2013

  • Choi, Inhee; Chan, George C. -Y.; Mao, Xianglei
  • Applied Spectroscopy, Vol. 67, Issue 11
  • DOI: 10.1366/13-07066

Quantitative laser induced breakdown spectroscopy analysis of ancient marbles and corrections for the variability of plasma parameters and of ablation rate
journal, January 2004

  • Lazic, Violeta; Fantoni, Roberta; Colao, Francesco
  • Journal of Analytical Atomic Spectrometry, Vol. 19, Issue 4
  • DOI: 10.1039/b315606k

Laser ablation molecular isotopic spectrometry of carbon isotopes
journal, November 2015

  • Bol′shakov, Alexander A.; Mao, Xianglei; Jain, Jinesh
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 113
  • DOI: 10.1016/j.sab.2015.08.007

Probing actinide electronic structure using fluorescence and multi-photon ionization spectroscopy
journal, January 2006

  • Heaven, Michael C.
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 39
  • DOI: 10.1039/b607486c

Laser ablation molecular isotopic spectrometry of water for 1D2/1H1 ratio analysis
journal, October 2013

  • Sarkar, Arnab; Mao, Xianglei; Chan, George C. -Y.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 88
  • DOI: 10.1016/j.sab.2013.08.002

Quantitative analysis of pharmaceutical products by laser-induced breakdown spectroscopy
journal, July 2002

Energy levels and isotope shifts for singly ionized uranium (U II)
journal, January 1994

  • Blaise, J.; Wyart, J. -F.; Vergès, J.
  • Journal of the Optical Society of America B, Vol. 11, Issue 10
  • DOI: 10.1364/JOSAB.11.001897

Hybrid interferometric/dispersive atomic spectroscopy of laser-induced uranium plasma
journal, February 2016

  • Morgan, Phyllis K.; Scott, Jill R.; Jovanovic, Igor
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 116
  • DOI: 10.1016/j.sab.2015.12.006

Influence of Ambient Gas on Laser-Induced Breakdown Spectroscopy of Uranium Metal
journal, November 2015

Laser Ablation Molecular Isotopic Spectrometry: Strontium and its isotopes
journal, November 2011

  • Mao, Xianglei; Bol'shakov, Alexander A.; Choi, Inhee
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 66, Issue 11-12
  • DOI: 10.1016/j.sab.2011.12.002

Laser Spectroscopy of UO: Characterization and Assignment of States in the 0- to 3-eV Range, with a Comparison to the Electronic Structure of ThO
journal, March 1994

  • Kaledin, L. A.; Mccord, J. E.; Heaven, M. C.
  • Journal of Molecular Spectroscopy, Vol. 164, Issue 1
  • DOI: 10.1006/jmsp.1994.1055

Electronic Spectrum of the UO and UO + Molecules
journal, December 2014

  • Tyagi, Rajni; Zhang, Zhiyong; Pitzer, Russell M.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 50
  • DOI: 10.1021/jp505722y

Advancing the analytical capabilities of laser ablation molecular isotopic spectrometry for boron isotopic analysis
journal, February 2014

  • Sarkar, Arnab; Mao, Xianglei; Russo, Richard E.
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 92
  • DOI: 10.1016/j.sab.2013.12.001

Reduction of spectral interferences and noise effects in laser ablation molecular isotopic spectrometry with partial least square regression – a computer simulation study
journal, August 2016

  • Mao, Xianglei; Chan, George C. -Y.; Zorba, Vassilia
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 122
  • DOI: 10.1016/j.sab.2016.05.013

Isotopic determination of uranium in soil by laser induced breakdown spectroscopy
journal, August 2016

  • Chan, George C. -Y.; Choi, Inhee; Mao, Xianglei
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 122
  • DOI: 10.1016/j.sab.2016.05.014

Line strengths and lifetimes of levels in neutral uranium
journal, January 1976

  • Corliss, Charles H.
  • Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, Vol. 80A, Issue 1
  • DOI: 10.6028/jres.080A.002

Femtosecond filament-laser ablation molecular isotopic spectrometry
journal, November 2015

  • Hou, Huaming; Chan, George C. -Y.; Mao, Xianglei
  • Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 113
  • DOI: 10.1016/j.sab.2015.09.014

Uranium Isotope Analysis by Optical Emission Spectrometry.
journal, July 1966

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    • Journal of Analytical Atomic Spectrometry, Vol. 33, Issue 11
    • DOI: 10.1039/c8ja90039f

    Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis
    journal, June 2018

    • Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.
    • Applied Physics Reviews, Vol. 5, Issue 2
    • DOI: 10.1063/1.5016053

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    journal, August 2018

    • Finko, Mikhail S.; Curreli, Davide
    • Physics of Plasmas, Vol. 25, Issue 8
    • DOI: 10.1063/1.5034470

    Plume dynamics and gas-phase molecular formation in transient laser-produced uranium plasmas
    journal, August 2019

    • Skrodzki, P. J.; Burger, M.; Jovanovic, I.
    • Physics of Plasmas, Vol. 26, Issue 8
    • DOI: 10.1063/1.5087704

    Laser-produced uranium plasma characterization and Stark broadening measurements
    journal, September 2019

    • Burger, M.; Skrodzki, P. J.; Jovanovic, I.
    • Physics of Plasmas, Vol. 26, Issue 9
    • DOI: 10.1063/1.5099643

    Mapping of Uranium in Surrogate Nuclear Debris Using Laser-Induced Breakdown Spectroscopy (LIBS)
    journal, March 2019

    • Shattan, Michael B.; Gragston, Mark; Zhang, Zhili
    • Applied Spectroscopy, Vol. 73, Issue 6
    • DOI: 10.1177/0003702819842871

    Spreading a water droplet through filter paper on the metal substrate for surface-enhanced laser-induced breakdown spectroscopy
    journal, January 2018

    • Yang, Xinyan; Yi, Rongxing; Li, Xiangyou
    • Optics Express, Vol. 26, Issue 23
    • DOI: 10.1364/oe.26.030456

    Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials
    journal, January 2020

    • Carter, Simon; Clough, Robert; Fisher, Andy
    • Journal of Analytical Atomic Spectrometry, Vol. 35, Issue 11
    • DOI: 10.1039/d0ja90067b

    Atomic spectrometry update. Review of advances in the analysis of metals, chemicals and materials
    journal, January 2013

    • Carter, Simon; Fisher, Andy S.; Hinds, Michael W.
    • Journal of Analytical Atomic Spectrometry, Vol. 28, Issue 12
    • DOI: 10.1039/c3ja90051g

    Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials
    journal, January 2017

    • Carter, Simon; Fisher, Andy; Gibson, Bridget
    • Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 11
    • DOI: 10.1039/c7ja90046e
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