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Title: Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium

Abstract

Here, we identify measurements of the Kβ diagram, valence-to-core (VtC), and hypersatellite X-ray spectra induced in metallic Cr by photon single and double K-shell ionization. The experiment was carried out at the Stanford Synchrotron Radiation Lightsource using the seven-crystal Johann-type hard X-ray spectrometer of the beamline 6-2. For the Kβ diagram and VtC transitions, the present study confirms the line shape features observed in previous works, whereas the Khβ hypersatellite transition was found to exhibit a complex spectral line shape and a characteristic low-energy shoulder. The energy shift of the hypersatellite relative to the parent diagram line was deduced from the measurements and compared with the result of extensive multiconfiguration Dirac–Fock (MCDF) calculations. A signifcant agreement between experiment and theory was found. The MCDF calculations were also used to compute the theoretical line shape of the hypersatellite. A satisfactory agreement was obtained between the overall shapes of the experimental and theoretical spectra, but deviations were observed on the low- and high-energy flanks of the hypersatellite line. The discrepancies were explained by chemical effects, which were not considered in the MCDF calculations performed for isolated atoms.

Authors:
 [1]; ORCiD logo [1];  [1];  [2];  [2];  [2];  [3];  [4];  [5];  [6];  [7]; ORCiD logo [8];  [4]
+ Show Author Affiliations
  1. Univ. of Fribourg (Switzerland)
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  3. Jozef Stefan Inst. (IJS), Ljubljana (Slovenia)
  4. New Univ. of Lisbon (NOVA), Caparica (Portugal)
  5. LIP-Laboratório de Instrumentação e Física Experimental de Partículas, Lisboa (Portugal)
  6. New University of Lisbon (NOVA), Caparica (Portugal); Sorbonne Universités, Paris (France)
  7. Sorbonne Universités, Paris (France)
  8. Univ. of Lisbon (Portugal)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
Swiss National Science Foundation (SNSF); USDOE
OSTI Identifier:
1529495
Grant/Contract Number:  
AC02-76SF00515; 2000020-146739; PTDC/FIS-AQM/31969/2017; SFRH/BPD/92455/2013; UID/FIS/04559/2013; UID/MULTI/04046/2013
Resource Type:
Accepted Manuscript
Journal Name:
X-Ray Spectrometry, XRS
Additional Journal Information:
Journal Volume: 48; Journal Issue: 5; Journal ID: ISSN 0049-8246
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats

Zeeshan, Faisal, Hoszowska, Joanna, Dousse, Jean-Claude, Sokaras, Dimosthenis, Weng, Tsu-Chien, Alonso-Mori, Roberto, Kavčič, Matjaz, Guerra, Mauro, Sampaio, Jorge Miguel, Parente, Fernando, Indelicato, Paul, Marques, José Pires, and Santos, José Paulo. Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium. United States: N. p., 2019. Web. doi:10.1002/xrs.3019.
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Zeeshan, Faisal, Hoszowska, Joanna, Dousse, Jean-Claude, Sokaras, Dimosthenis, Weng, Tsu-Chien, Alonso-Mori, Roberto, Kavčič, Matjaz, Guerra, Mauro, Sampaio, Jorge Miguel, Parente, Fernando, Indelicato, Paul, Marques, José Pires, & Santos, José Paulo. Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium. United States. https://doi.org/10.1002/xrs.3019
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Zeeshan, Faisal, Hoszowska, Joanna, Dousse, Jean-Claude, Sokaras, Dimosthenis, Weng, Tsu-Chien, Alonso-Mori, Roberto, Kavčič, Matjaz, Guerra, Mauro, Sampaio, Jorge Miguel, Parente, Fernando, Indelicato, Paul, Marques, José Pires, and Santos, José Paulo. Wed . "Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium". United States. https://doi.org/10.1002/xrs.3019. https://www.osti.gov/servlets/purl/1529495.
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@article{osti_1529495,
title = {Diagram, valence-to-core, and hypersatellite Kβ X-ray transitions in metallic chromium},
author = {Zeeshan, Faisal and Hoszowska, Joanna and Dousse, Jean-Claude and Sokaras, Dimosthenis and Weng, Tsu-Chien and Alonso-Mori, Roberto and Kavčič, Matjaz and Guerra, Mauro and Sampaio, Jorge Miguel and Parente, Fernando and Indelicato, Paul and Marques, José Pires and Santos, José Paulo},
abstractNote = {Here, we identify measurements of the Kβ diagram, valence-to-core (VtC), and hypersatellite X-ray spectra induced in metallic Cr by photon single and double K-shell ionization. The experiment was carried out at the Stanford Synchrotron Radiation Lightsource using the seven-crystal Johann-type hard X-ray spectrometer of the beamline 6-2. For the Kβ diagram and VtC transitions, the present study confirms the line shape features observed in previous works, whereas the Khβ hypersatellite transition was found to exhibit a complex spectral line shape and a characteristic low-energy shoulder. The energy shift of the hypersatellite relative to the parent diagram line was deduced from the measurements and compared with the result of extensive multiconfiguration Dirac–Fock (MCDF) calculations. A signifcant agreement between experiment and theory was found. The MCDF calculations were also used to compute the theoretical line shape of the hypersatellite. A satisfactory agreement was obtained between the overall shapes of the experimental and theoretical spectra, but deviations were observed on the low- and high-energy flanks of the hypersatellite line. The discrepancies were explained by chemical effects, which were not considered in the MCDF calculations performed for isolated atoms.},
doi = {10.1002/xrs.3019},
journal = {X-Ray Spectrometry, XRS},
number = 5,
volume = 48,
place = {United States},
year = {Wed Feb 13 00:00:00 EST 2019},
month = {Wed Feb 13 00:00:00 EST 2019}
}
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