Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi2Se3/MoS2 2D Heterostructures

Hennighausen, Zachariah; Lane, Christopher; Benabbas, Abdelkrim; Mendez, Kevin; Eggenberger, Monika; Champion, Paul M.; Robinson, Jeremy T.; Bansil, Arun; Kar, Swastik

doi:10.1021/acsami.9b02929

Title: Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi₂Se₃/MoS₂ 2D Heterostructures

Abstract

Two-dimensional (2D) heterostructures are more than a sum of the parent 2D materials, but are also a product of the interlayer coupling, which can induce new properties. In this paper, we present a method to tune the interlayer coupling in Bi₂Se₃/MoS₂ 2D heterostructures by regulating the oxygen presence in the atmosphere, while applying laser or thermal energy. Our data suggest that the interlayer coupling is tuned through the diffusive intercalation and deintercalation of oxygen molecules. When one layer of Bi₂Se₃ is grown on monolayer MoS₂, an influential interlayer coupling is formed, which quenches the signature photoluminescence (PL) peaks. However, thermally treating in the presence of oxygen disrupts the interlayer coupling, facilitating the emergence of the MoS₂ PL peak. Our density functional theory calculations predict that intercalated oxygen increases the interlayer separation ∼17%, disrupting the interlayer coupling and inducing the layers to behave more electronically independent. The interlayer coupling can then be restored by thermally treating in N₂ or Ar, where the peaks will requench. Hence, this is an interesting oxygen-induced switching between “non-radiative” and “radiative” exciton recombination. This switching can also be accomplished locally, controllably, and reversibly using a low-power focused laser, while changing the environment from pure N₂ tomore »« less

Authors:

^[1];

^[1]; Benabbas, Abdelkrim ^[2]; Mendez, Kevin ^[1]; Eggenberger, Monika ^[1]; Champion, Paul M. ^[2];

^[3]; Bansil, Arun ^[2]; Kar, Swastik ^[1]

Northeastern Univ., Boston, MA (United States). Dept. of Physics
Northeastern Univ., Boston, MA (United States). Physics Dept. and Center for Interdisciplinary Research on Complex Systems
Naval Research Lab. (NRL), Washington, DC (United States)

Publication Date:: Mon Apr 08 00:00:00 EDT 2019

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Complex Materials from First Principles (CCM); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1527368

Grant/Contract Number:: FG02-07ER46352; AC02-05CH11231; SC0012575

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Materials and Interfaces

Additional Journal Information:: Journal Volume: 11; Journal Issue: 17; Journal ID: ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; transition metal dichalcogenides; bismuth selenide; 2D materials; interlayer coupling; intercalation

Citation Formats


                    Hennighausen, Zachariah, Lane, Christopher, Benabbas, Abdelkrim, Mendez, Kevin, Eggenberger, Monika, Champion, Paul M., Robinson, Jeremy T., Bansil, Arun, and Kar, Swastik. Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi2Se3/MoS2 2D Heterostructures.  United States: N. p., 2019. 
Web.  doi:10.1021/acsami.9b02929.

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                    Hennighausen, Zachariah, Lane, Christopher, Benabbas, Abdelkrim, Mendez, Kevin, Eggenberger, Monika, Champion, Paul M., Robinson, Jeremy T., Bansil, Arun, & Kar, Swastik. Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi2Se3/MoS2 2D Heterostructures.  United States.  https://doi.org/10.1021/acsami.9b02929

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                    Hennighausen, Zachariah, Lane, Christopher, Benabbas, Abdelkrim, Mendez, Kevin, Eggenberger, Monika, Champion, Paul M., Robinson, Jeremy T., Bansil, Arun, and Kar, Swastik. Mon .  
"Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi2Se3/MoS2 2D Heterostructures".  United States.  https://doi.org/10.1021/acsami.9b02929.  https://www.osti.gov/servlets/purl/1527368.

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@article{osti_1527368,

  title        = {Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi2Se3/MoS2 2D Heterostructures},

  author       = {Hennighausen, Zachariah and Lane, Christopher and Benabbas, Abdelkrim and Mendez, Kevin and Eggenberger, Monika and Champion, Paul M. and Robinson, Jeremy T. and Bansil, Arun and Kar, Swastik},

  abstractNote = {Two-dimensional (2D) heterostructures are more than a sum of the parent 2D materials, but are also a product of the interlayer coupling, which can induce new properties. In this paper, we present a method to tune the interlayer coupling in Bi2Se3/MoS2 2D heterostructures by regulating the oxygen presence in the atmosphere, while applying laser or thermal energy. Our data suggest that the interlayer coupling is tuned through the diffusive intercalation and deintercalation of oxygen molecules. When one layer of Bi2Se3 is grown on monolayer MoS2, an influential interlayer coupling is formed, which quenches the signature photoluminescence (PL) peaks. However, thermally treating in the presence of oxygen disrupts the interlayer coupling, facilitating the emergence of the MoS2 PL peak. Our density functional theory calculations predict that intercalated oxygen increases the interlayer separation ∼17%, disrupting the interlayer coupling and inducing the layers to behave more electronically independent. The interlayer coupling can then be restored by thermally treating in N2 or Ar, where the peaks will requench. Hence, this is an interesting oxygen-induced switching between “non-radiative” and “radiative” exciton recombination. This switching can also be accomplished locally, controllably, and reversibly using a low-power focused laser, while changing the environment from pure N2 to air. This allows for the interlayer coupling to be precisely manipulated with submicron spatial resolution, facilitating site-programmable 2D light-emitting pixels whose emission intensity could be precisely varied by a factor exceeding 200×. Our results show that these atomically thin 2D heterostructures may be excellent candidates for oxygen sensing.},

  doi          = {10.1021/acsami.9b02929},

  journal      = {ACS Applied Materials and Interfaces},

  number       = 17,

  volume       = 11,

  place        = {United States},

  year         = {Mon Apr 08 00:00:00 EDT 2019},

  month        = {Mon Apr 08 00:00:00 EDT 2019}

}

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Title: Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi2Se3/MoS2 2D Heterostructures

Abstract

Citation Formats

Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures journal, February 2012

Vertically stacked multi-heterostructures of layered materials for logic transistors and complementary inverters journal, December 2012

Strong Light-Matter Interactions in Heterostructures of Atomically Thin Films journal, May 2013

Highly efficient gate-tunable photocurrent generation in vertical heterostructures of layered materials journal, October 2013

Tunable and laser-reconfigurable 2D heterocrystals obtained by epitaxial stacking of crystallographically incommensurate Bi 2 Se 3 and MoS 2 atomic layers journal, July 2017

Nonvolatile Memory Cells Based on MoS 2 /Graphene Heterostructures journal, March 2013

Plasmonics with two-dimensional semiconductors: from basic research to technological applications journal, January 2018

Interlayer Coupling Induced Infrared Response in WS 2 /MoS 2 Heterostructures Enhanced by Surface Plasmon Resonance journal, April 2018

Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus/Bismuth Vanadate Using Visible Light journal, January 2018

Ultrathin Two-Dimensional MnO 2 /Graphene Hybrid Nanostructures for High-Performance, Flexible Planar Supercapacitors journal, April 2013

Graphene/MoS 2 Heterostructures for Ultrasensitive Detection of DNA Hybridisation journal, May 2014

Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures journal, May 2018

Reversible superdense ordering of lithium between two graphene sheets journal, November 2018

Ultrafast lithium diffusion in bilayer graphene journal, June 2017

Unconventional superconductivity in magic-angle graphene superlattices journal, March 2018

Dynamic band-structure tuning of graphene moiré superlattices with pressure journal, May 2018

Probing the interlayer interaction between dissimilar 2D heterostructures by in situ rearrangement of their interface journal, May 2019

Imaging of Interlayer Coupling in van der Waals Heterostructures Using a Bright-Field Optical Microscope journal, August 2017

Tuning Coupling Behavior of Stacked Heterostructures Based on MoS2, WS2, and WSe2 journal, March 2017

Monolayer atomic crystal molecular superlattices journal, March 2018

Oxygen Intercalation under Graphene on Ir(111): Energetics, Kinetics, and the Role of Graphene Edges journal, October 2012

Quasi-freestanding epitaxial silicene on Ag(111) by oxygen intercalation journal, July 2016

Tuning of Interlayer Coupling in Large-Area Graphene/WSe 2 van der Waals Heterostructure via Ion Irradiation: Optical Evidences and Photonic Applications journal, May 2017

Strain-Mediated Interlayer Coupling Effects on the Excitonic Behaviors in an Epitaxially Grown MoS 2 /WS 2 van der Waals Heterobilayer journal, August 2017

Coupling-Assisted Renormalization of Excitons and Vibrations in Compressed MoSe 2 –WSe 2 Heterostructure journal, February 2018

Strain engineering in semiconducting two-dimensional crystals journal, July 2015

Interlayer Coupling and Gate-Tunable Excitons in Transition Metal Dichalcogenide Heterostructures journal, November 2017

Tightly bound trions in monolayer MoS2 journal, December 2012

Electrochemical Control of Photoluminescence in Two-Dimensional MoS 2 Nanoflakes journal, October 2013

Oxidation Mechanisms of Copper under Graphene: The Role of Oxygen Encapsulation journal, March 2017

New X-ray insight into oxygen intercalation in epitaxial graphene grown on 4 H -SiC(0001) journal, March 2015

Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation journal, June 2010

Photoemission investigation of oxygen intercalated epitaxial graphene on Ru(0001) journal, December 2018

Key role of rotated domains in oxygen intercalation at graphene on Ni(1 1 1) journal, May 2017

Li Intercalation in MoS 2 : In Situ Observation of Its Dynamics and Tuning Optical and Electrical Properties journal, September 2015

Massive Dirac Fermion on the Surface of a Magnetically Doped Topological Insulator journal, August 2010

Surface oxidation of the topological insulator Bi 2 Se 3 journal, November 2016

Rapid Surface Oxidation as a Source of Surface Degradation Factor for Bi 2 Se 3 journal, May 2011

Epitaxial growth of topological insulator Bi2Se3 film on Si(111) with atomically sharp interface journal, October 2011

Chemical Vapor Deposition Synthesized Atomically Thin Molybdenum Disulfide with Optoelectronic-Grade Crystalline Quality journal, August 2015

van der Waals epitaxy: 2D materials and topological insulators journal, December 2017

Coherent topological transport on the surface of Bi2Se3 journal, June 2013

Interlayer Coupling Affected Structural Stability in Ultrathin MoS 2 : An Investigation by High Pressure Raman Spectroscopy journal, October 2016

Formation of high-quality quasi-free-standing bilayer graphene on SiC(0001) by oxygen intercalation upon annealing in air journal, February 2013

Emerging Photoluminescence in Monolayer MoS2 journal, April 2010

Negligible Surface Reactivity of Topological Insulators Bi 2 Se 3 and Bi 2 Te 3 towards Oxygen and Water journal, May 2013

Growth of the Bi 2 Se 3 Surface Oxide for Metal–Semiconductor–Metal Device Applications journal, February 2016

Unveiling the atomistic mechanisms for oxygen intercalation in a strongly interacting graphene–metal interface journal, January 2018

Oxygen intercalation at the graphene/Ni(111) interface: Evidences of non-metal islands underneath graphene layer journal, April 2016

Oxygen Intercalation of Graphene on Transition Metal Substrate: An Edge-Limited Mechanism journal, September 2015

Fe intercalation under graphene and hexagonal boron nitride in-plane heterostructure on Pt(111) journal, August 2018

Growth Mechanism of Graphene on Ru(0001) and O 2 Adsorption on the Graphene/Ru(0001) Surface journal, April 2009

Intercalation and desorption of oxygen between graphene and Ru(0001) studied with helium ion scattering journal, October 2017

A note on the characterization of bismuth black by Raman microspectroscopy journal, May 2009

The molecular structure of bismuth oxide by Raman spectroscopy journal, April 1992

Superconductivity and spin–orbit coupling in non-centrosymmetric materials: a review journal, January 2017

Excitons in atomically thin 2D semiconductors and their applications journal, June 2017

Monolayer excitonic laser journal, October 2015

Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal, January 2006

Evidence of a purely electronic two-dimensional lattice at the interface of TMD/Bi 2 Se 3 heterostructures journal, January 2019

Widely tunable Bi 2 Se 3 /transition metal dichalcogenide 2D heterostructures for write-read-erase-reuse applications journal, August 2019

Title: Oxygen-Induced In Situ Manipulation of the Interlayer Coupling and Exciton Recombination in Bi₂Se₃/MoS₂ 2D Heterostructures

Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures
journal, February 2012

Vertically stacked multi-heterostructures of layered materials for logic transistors and complementary inverters
journal, December 2012

Strong Light-Matter Interactions in Heterostructures of Atomically Thin Films
journal, May 2013

Highly efficient gate-tunable photocurrent generation in vertical heterostructures of layered materials
journal, October 2013

Tunable and laser-reconfigurable 2D heterocrystals obtained by epitaxial stacking of crystallographically incommensurate Bi ₂ Se ₃ and MoS ₂ atomic layers
journal, July 2017

Nonvolatile Memory Cells Based on MoS ₂ /Graphene Heterostructures
journal, March 2013

Plasmonics with two-dimensional semiconductors: from basic research to technological applications
journal, January 2018

Interlayer Coupling Induced Infrared Response in WS ₂ /MoS ₂ Heterostructures Enhanced by Surface Plasmon Resonance
journal, April 2018

Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus/Bismuth Vanadate Using Visible Light
journal, January 2018

Ultrathin Two-Dimensional MnO ₂ /Graphene Hybrid Nanostructures for High-Performance, Flexible Planar Supercapacitors
journal, April 2013

Graphene/MoS ₂ Heterostructures for Ultrasensitive Detection of DNA Hybridisation
journal, May 2014

Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures
journal, May 2018

Reversible superdense ordering of lithium between two graphene sheets
journal, November 2018

Ultrafast lithium diffusion in bilayer graphene
journal, June 2017

Unconventional superconductivity in magic-angle graphene superlattices
journal, March 2018

Dynamic band-structure tuning of graphene moiré superlattices with pressure
journal, May 2018

Probing the interlayer interaction between dissimilar 2D heterostructures by in situ rearrangement of their interface
journal, May 2019

Imaging of Interlayer Coupling in van der Waals Heterostructures Using a Bright-Field Optical Microscope
journal, August 2017

Tuning Coupling Behavior of Stacked Heterostructures Based on MoS2, WS2, and WSe2
journal, March 2017

Monolayer atomic crystal molecular superlattices
journal, March 2018

Oxygen Intercalation under Graphene on Ir(111): Energetics, Kinetics, and the Role of Graphene Edges
journal, October 2012

Quasi-freestanding epitaxial silicene on Ag(111) by oxygen intercalation
journal, July 2016

Tuning of Interlayer Coupling in Large-Area Graphene/WSe ₂ van der Waals Heterostructure via Ion Irradiation: Optical Evidences and Photonic Applications
journal, May 2017

Strain-Mediated Interlayer Coupling Effects on the Excitonic Behaviors in an Epitaxially Grown MoS ₂ /WS ₂ van der Waals Heterobilayer
journal, August 2017

Coupling-Assisted Renormalization of Excitons and Vibrations in Compressed MoSe ₂ –WSe ₂ Heterostructure
journal, February 2018

Strain engineering in semiconducting two-dimensional crystals
journal, July 2015

Interlayer Coupling and Gate-Tunable Excitons in Transition Metal Dichalcogenide Heterostructures
journal, November 2017

Tightly bound trions in monolayer MoS2
journal, December 2012

Electrochemical Control of Photoluminescence in Two-Dimensional MoS ₂ Nanoflakes
journal, October 2013

Oxidation Mechanisms of Copper under Graphene: The Role of Oxygen Encapsulation
journal, March 2017

New X-ray insight into oxygen intercalation in epitaxial graphene grown on 4 H -SiC(0001)
journal, March 2015

Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation
journal, June 2010

Photoemission investigation of oxygen intercalated epitaxial graphene on Ru(0001)
journal, December 2018

Key role of rotated domains in oxygen intercalation at graphene on Ni(1 1 1)
journal, May 2017

Li Intercalation in MoS ₂ : In Situ Observation of Its Dynamics and Tuning Optical and Electrical Properties
journal, September 2015

Massive Dirac Fermion on the Surface of a Magnetically Doped Topological Insulator
journal, August 2010

Surface oxidation of the topological insulator Bi ₂ Se ₃
journal, November 2016

Rapid Surface Oxidation as a Source of Surface Degradation Factor for Bi ₂ Se ₃
journal, May 2011

Epitaxial growth of topological insulator Bi2Se3 film on Si(111) with atomically sharp interface
journal, October 2011

Chemical Vapor Deposition Synthesized Atomically Thin Molybdenum Disulfide with Optoelectronic-Grade Crystalline Quality
journal, August 2015

van der Waals epitaxy: 2D materials and topological insulators
journal, December 2017

Coherent topological transport on the surface of Bi2Se3
journal, June 2013

Interlayer Coupling Affected Structural Stability in Ultrathin MoS ₂ : An Investigation by High Pressure Raman Spectroscopy
journal, October 2016

Formation of high-quality quasi-free-standing bilayer graphene on SiC(0001) by oxygen intercalation upon annealing in air
journal, February 2013

Emerging Photoluminescence in Monolayer MoS₂
journal, April 2010

Negligible Surface Reactivity of Topological Insulators Bi ₂ Se ₃ and Bi ₂ Te ₃ towards Oxygen and Water
journal, May 2013

Growth of the Bi ₂ Se ₃ Surface Oxide for Metal–Semiconductor–Metal Device Applications
journal, February 2016

Unveiling the atomistic mechanisms for oxygen intercalation in a strongly interacting graphene–metal interface
journal, January 2018

Oxygen intercalation at the graphene/Ni(111) interface: Evidences of non-metal islands underneath graphene layer
journal, April 2016

Oxygen Intercalation of Graphene on Transition Metal Substrate: An Edge-Limited Mechanism
journal, September 2015

Fe intercalation under graphene and hexagonal boron nitride in-plane heterostructure on Pt(111)
journal, August 2018

Growth Mechanism of Graphene on Ru(0001) and O ₂ Adsorption on the Graphene/Ru(0001) Surface
journal, April 2009

Intercalation and desorption of oxygen between graphene and Ru(0001) studied with helium ion scattering
journal, October 2017

A note on the characterization of bismuth black by Raman microspectroscopy
journal, May 2009

The molecular structure of bismuth oxide by Raman spectroscopy
journal, April 1992

Superconductivity and spin–orbit coupling in non-centrosymmetric materials: a review
journal, January 2017

Excitons in atomically thin 2D semiconductors and their applications
journal, June 2017

Monolayer excitonic laser
journal, October 2015

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

Evidence of a purely electronic two-dimensional lattice at the interface of TMD/Bi ₂ Se ₃ heterostructures
journal, January 2019

Widely tunable Bi ₂ Se ₃ /transition metal dichalcogenide 2D heterostructures for write-read-erase-reuse applications
journal, August 2019