Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration
Abstract
Hexagonal boron nitride (h-BN) has been predicted to exhibit an in-plane thermal conductivity as high as ~ 550 W m–1 K–1 at room temperature, making it a promising thermal management material. However, current experimental results (220–420 m–1 K–1) have been well below the prediction. Here, we report on the modulation of h-BN thermal conductivity by controlling the B isotope concentration. For monoisotopic 10B h-BN, an in-plane thermal conductivity as high as 585 W m–1 K–1 is measured at room temperature, ~ 80% higher than that of h-BN with a disordered isotope concentration (52%:48% mixture of 10B and 11B). The temperature-dependent thermal conductivities of monoisotopic h-BN agree well with first principles calculations including only intrinsic phonon-phonon scattering. Our results illustrate the potential to achieve high thermal conductivity in h-BN and control its thermal conductivity, opening avenues for the wide application of h-BN as a next-generation thin-film material for thermal management, metamaterials and metadevices.
- Authors:
-
- Bristol Univ. (United Kingdom)
- Kansas State Univ., Manhattan, KS (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1511942
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Communications Physics
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 1; Journal ID: ISSN 2399-3650
- Publisher:
- Springer Nature
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Yuan, Chao, Li, Jiahan, Lindsay, Lucas, Cherns, David, Pomeroy, James W., Liu, Song, Edgar, James H., and Kuball, Martin. Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration. United States: N. p., 2019.
Web. doi:10.1038/s42005-019-0145-5.
Yuan, Chao, Li, Jiahan, Lindsay, Lucas, Cherns, David, Pomeroy, James W., Liu, Song, Edgar, James H., & Kuball, Martin. Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration. United States. https://doi.org/10.1038/s42005-019-0145-5
Yuan, Chao, Li, Jiahan, Lindsay, Lucas, Cherns, David, Pomeroy, James W., Liu, Song, Edgar, James H., and Kuball, Martin. Thu .
"Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration". United States. https://doi.org/10.1038/s42005-019-0145-5. https://www.osti.gov/servlets/purl/1511942.
@article{osti_1511942,
title = {Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration},
author = {Yuan, Chao and Li, Jiahan and Lindsay, Lucas and Cherns, David and Pomeroy, James W. and Liu, Song and Edgar, James H. and Kuball, Martin},
abstractNote = {Hexagonal boron nitride (h-BN) has been predicted to exhibit an in-plane thermal conductivity as high as ~ 550 W m–1 K–1 at room temperature, making it a promising thermal management material. However, current experimental results (220–420 m–1 K–1) have been well below the prediction. Here, we report on the modulation of h-BN thermal conductivity by controlling the B isotope concentration. For monoisotopic 10B h-BN, an in-plane thermal conductivity as high as 585 W m–1 K–1 is measured at room temperature, ~ 80% higher than that of h-BN with a disordered isotope concentration (52%:48% mixture of 10B and 11B). The temperature-dependent thermal conductivities of monoisotopic h-BN agree well with first principles calculations including only intrinsic phonon-phonon scattering. Our results illustrate the potential to achieve high thermal conductivity in h-BN and control its thermal conductivity, opening avenues for the wide application of h-BN as a next-generation thin-film material for thermal management, metamaterials and metadevices.},
doi = {10.1038/s42005-019-0145-5},
journal = {Communications Physics},
number = 1,
volume = 2,
place = {United States},
year = {Thu May 02 00:00:00 EDT 2019},
month = {Thu May 02 00:00:00 EDT 2019}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Recent Development of Boron Nitride towards Electronic Applications
journal, April 2017
- Izyumskaya, Natalia; Demchenko, Denis O.; Das, Saikat
- Advanced Electronic Materials, Vol. 3, Issue 5
Thermal diffusivity of isotopically enriched diamond
journal, July 1990
- Anthony, T. R.; Banholzer, W. F.; Fleischer, J. F.
- Physical Review B, Vol. 42, Issue 2
Thermal conductivity of InN with point defects from first principles
journal, July 2018
- Polanco, Carlos A.; Lindsay, Lucas
- Physical Review B, Vol. 98, Issue 1
Experimental Demonstration of a Multiphysics Cloak: Manipulating Heat Flux and Electric Current Simultaneously
journal, November 2014
- Ma, Yungui; Liu, Yichao; Raza, Muhammad
- Physical Review Letters, Vol. 113, Issue 20
Phonon-isotope scattering and thermal conductivity in materials with a large isotope effect: A first-principles study
journal, October 2013
- Lindsay, L.; Broido, D. A.; Reinecke, T. L.
- Physical Review B, Vol. 88, Issue 14
A transient thermal cloak experimentally realized through a rescaled diffusion equation with anisotropic thermal diffusivity
journal, November 2013
- Ma, Yungui; Lan, Lu; Jiang, Wei
- NPG Asia Materials, Vol. 5, Issue 11
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009
- Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
- Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
Heat guiding and focusing using ballistic phonon transport in phononic nanostructures
journal, May 2017
- Anufriev, Roman; Ramiere, Aymeric; Maire, Jeremie
- Nature Communications, Vol. 8, Issue 1
Pulsed photothermal modeling of composite samples based on transmission-line theory of heat conduction
journal, February 1999
- Chen, George; Hui, Ping
- Thin Solid Films, Vol. 339, Issue 1-2
Ultralow-loss polaritons in isotopically pure boron nitride
journal, December 2017
- Giles, Alexander J.; Dai, Siyuan; Vurgaftman, Igor
- Nature Materials, Vol. 17, Issue 2
Pulse accumulation, radial heat conduction, and anisotropic thermal conductivity in pump-probe transient thermoreflectance
journal, November 2008
- Schmidt, Aaron J.; Chen, Xiaoyuan; Chen, Gang
- Review of Scientific Instruments, Vol. 79, Issue 11
Thermal conductivity of isotopically modified graphene
journal, January 2012
- Chen, Shanshan; Wu, Qingzhi; Mishra, Columbia
- Nature Materials, Vol. 11, Issue 3
Isotope effect in the thermal conductivity of germanium single crystals
journal, March 1996
- Ozhogin, V. I.; Inyushkin, A. V.; Taldenkov, A. N.
- Journal of Experimental and Theoretical Physics Letters, Vol. 63, Issue 6
Enhanced thermal conductivity and isotope effect in single-layer hexagonal boron nitride
journal, October 2011
- Lindsay, L.; Broido, D. A.
- Physical Review B, Vol. 84, Issue 15
Flexural phonons and thermal transport in multilayer graphene and graphite
journal, June 2011
- Lindsay, L.; Broido, D. A.; Mingo, Natalio
- Physical Review B, Vol. 83, Issue 23
Hyperbolic phonon-polaritons in boron nitride for near-field optical imaging and focusing
journal, June 2015
- Li, Peining; Lewin, Martin; Kretinin, Andrey V.
- Nature Communications, Vol. 6, Issue 1
Thermal Conductivity of Graphene and Graphite: Collective Excitations and Mean Free Paths
journal, October 2014
- Fugallo, Giorgia; Cepellotti, Andrea; Paulatto, Lorenzo
- Nano Letters, Vol. 14, Issue 11
Time-domain thermoreflectance (TDTR) measurements of anisotropic thermal conductivity using a variable spot size approach
journal, July 2017
- Jiang, Puqing; Qian, Xin; Yang, Ronggui
- Review of Scientific Instruments, Vol. 88, Issue 7
Far-ultraviolet plane-emission handheld device based on hexagonal boron nitride
journal, September 2009
- Watanabe, Kenji; Taniguchi, Takashi; Niiyama, Takahiro
- Nature Photonics, Vol. 3, Issue 10
Heat Flux Manipulation with Engineered Thermal Materials
journal, May 2012
- Narayana, Supradeep; Sato, Yuki
- Physical Review Letters, Vol. 108, Issue 21
Heat capacity and thermal conductivity of hexagonal pyrolytic boron nitride
journal, May 1976
- Sichel, E. K.; Miller, R. E.; Abrahams, M. S.
- Physical Review B, Vol. 13, Issue 10
Anisotropic thermal transport in bulk hexagonal boron nitride
journal, June 2018
- Jiang, Puqing; Qian, Xin; Yang, Ronggui
- Physical Review Materials, Vol. 2, Issue 6
The thermal conductivity of highly oriented pyrolytic boron nitride
journal, September 1971
- Simpson, A.; Stuckes, A. D.
- Journal of Physics C: Solid State Physics, Vol. 4, Issue 13
A bifunctional cloak using transformation media
journal, October 2010
- Li, J. Y.; Gao, Y.; Huang, J. P.
- Journal of Applied Physics, Vol. 108, Issue 7
Thermal conductivity of isotopically enriched 71 GaAs crystal
journal, June 2003
- Inyushkin, A. V.; Taldenkov, A. N.; Yakubovsky, A. Yu
- Semiconductor Science and Technology, Vol. 18, Issue 7
Lattice parameters and anisotropic thermal expansion of hexagonal boron nitride in the 10?297.5�K temperature range
journal, September 2002
- Paszkowicz, W.; Pelka, J. B.; Knapp, M.
- Applied Physics A: Materials Science & Processing, Vol. 75, Issue 3
Three-phonon phase space and lattice thermal conductivity in semiconductors
journal, March 2008
- Lindsay, L.; Broido, D. A.
- Journal of Physics: Condensed Matter, Vol. 20, Issue 16
Phonons and related crystal properties from density-functional perturbation theory
journal, July 2001
- Baroni, Stefano; de Gironcoli, Stefano; Dal Corso, Andrea
- Reviews of Modern Physics, Vol. 73, Issue 2
Single Crystal Growth of Millimeter-Sized Monoisotopic Hexagonal Boron Nitride
journal, September 2018
- Liu, Song; He, Rui; Xue, Lianjie
- Chemistry of Materials, Vol. 30, Issue 18
Assessment of Thermal Properties via Nanosecond Thermoreflectance Method
journal, October 2015
- Garrelts, Richard; Marconnet, Amy; Xu, Xianfan
- Nanoscale and Microscale Thermophysical Engineering, Vol. 19, Issue 4
Targeting Cooling for Quantum Dots in White QDs-LEDs by Hexagonal Boron Nitride Platelets with Electrostatic Bonding
journal, June 2018
- Xie, Bin; Liu, Haochen; Hu, Run
- Advanced Functional Materials, Vol. 28, Issue 30
Bulk Hexagonal Boron Nitride with a Quasi-Isotropic Thermal Conductivity
journal, May 2018
- Mateti, Srikanth; Yang, Keqin; Liu, Xuan
- Advanced Functional Materials, Vol. 28, Issue 28
Exceptionally Strong Phonon Scattering by B Substitution in Cubic SiC
journal, August 2017
- Katre, Ankita; Carrete, Jesús; Dongre, Bonny
- Physical Review Letters, Vol. 119, Issue 7
Inhomogeneous Electron Gas
journal, November 1964
- Hohenberg, P.; Kohn, W.
- Physical Review, Vol. 136, Issue 3B, p. B864-B871
Hexagonal boron nitride: a promising substrate for graphene with high heat dissipation
journal, May 2017
- Zhang, Zhongwei; Hu, Shiqian; Chen, Jie
- Nanotechnology, Vol. 28, Issue 22
Probing anisotropic heat transport using time-domain thermoreflectance with offset laser spots
journal, October 2012
- Feser, Joseph P.; Cahill, David G.
- Review of Scientific Instruments, Vol. 83, Issue 10
Isotope engineering of van der Waals interactions in hexagonal boron nitride
journal, December 2017
- Vuong, T. Q. P.; Liu, S.; Van der Lee, A.
- Nature Materials, Vol. 17, Issue 2
Illusory spirals and loops in crystal growth
journal, October 2013
- Shtukenberg, A. G.; Zhu, Z.; An, Z.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 43
Isotope scattering of large-wave-vector phonons in GaAs and InSb: Deformation-dipole and overlap-shell models
journal, July 1984
- Tamura, Shin-ichiro
- Physical Review B, Vol. 30, Issue 2
Estimation of the isotope effect on the lattice thermal conductivity of group IV and group III-V semiconductors
journal, November 2002
- Morelli, D. T.; Heremans, J. P.; Slack, G. A.
- Physical Review B, Vol. 66, Issue 19
Experimental investigation of thermal conduction normal to diamond‐silicon boundaries
journal, February 1995
- Goodson, K. E.; Käding, O. W.; Rösler, M.
- Journal of Applied Physics, Vol. 77, Issue 4
Heat-Transport Mechanisms in Superlattices
journal, February 2009
- Koh, Yee Kan; Cao, Yu; Cahill, David G.
- Advanced Functional Materials, Vol. 19, Issue 4
First Principles Peierls-Boltzmann Phonon Thermal Transport: A Topical Review
journal, April 2016
- Lindsay, Lucas
- Nanoscale and Microscale Thermophysical Engineering, Vol. 20, Issue 2
Thermal Conductivity of Polymer-Based Composites with Magnetic Aligned Hexagonal Boron Nitride Platelets
journal, March 2015
- Yuan, Chao; Duan, Bin; Li, Lan
- ACS Applied Materials & Interfaces, Vol. 7, Issue 23
Two-dimensional flexible nanoelectronics
journal, December 2014
- Akinwande, Deji; Petrone, Nicholas; Hone, James
- Nature Communications, Vol. 5, Issue 1
A transmission-line theory for heat conduction in multilayer thin films
journal, January 1994
- Hui, P.; Tan, H. S.
- IEEE Transactions on Components, Packaging, and Manufacturing Technology: Part B, Vol. 17, Issue 3
On the isotope effect in thermal conductivity of silicon
journal, November 2004
- Inyushkin, A. V.; Taldenkov, A. N.; Gibin, A. M.
- physica status solidi (c), Vol. 1, Issue 11
Nanoscale thermal transport
journal, January 2003
- Cahill, David G.; Ford, Wayne K.; Goodson, Kenneth E.
- Journal of Applied Physics, Vol. 93, Issue 2, p. 793-818
Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration
dataset, January 2019
- Yuan, Chao; Pomeroy, James
- University of Bristol
Hyperbolic phonon-polaritons in boron nitride for near-field optical imaging and focusing
text, January 2015
- Li, Peining; Lewin, Martin; Kretinin, Andrey V.
- RWTH Aachen University
Covalently interconnected transition metal dichalcogenide networks via defect engineering for high-performance electronic devices.
text, January 2021
- Ippolito, Stefano; Kelly, Adam G.; Furlan De Oliveira, Rafael
- Apollo - University of Cambridge Repository
Hexagonal Boron Nitride: a Promising Substrate for Graphene with high heat Dissipation
conference, January 2018
- Zhang, Zhongwei; Hu, Shiqian; Chen, Jie
- International Heat Transfer Conference 16
Exceptionally strong phonon scattering by B substitution in cubic SiC
text, January 2017
- Katre, Ankita; Carrete, Jesús; Dongre, Bonny
- arXiv
Works referencing / citing this record:
Spherical filler‐promoting thermally conductive pathway in graphite‐containing polymer composites for high heat radiation
journal, January 2020
- Takafuji, Makoto; Kawamoto, Naoki; Hano, Nanami
- Journal of Polymer Science, Vol. 58, Issue 4
Photonics with hexagonal boron nitride
journal, July 2019
- Caldwell, Joshua D.; Aharonovich, Igor; Cassabois, Guillaume
- Nature Reviews Materials, Vol. 4, Issue 8
Nanosecond transient thermoreflectance method for characterizing anisotropic thermal conductivity
journal, November 2019
- Yuan, Chao; Waller, William M.; Kuball, Martin
- Review of Scientific Instruments, Vol. 90, Issue 11
Simultaneous characterization of cross- and in-plane thermal transport in insulator patterned by directionally aligned nano-channels
journal, January 2020
- Chauhan, Vinay S.; Abdullaev, Azat; Utegulov, Zhandos
- AIP Advances, Vol. 10, Issue 1
Ultrahigh thermal conductivity in isotope-enriched cubic boron nitride
journal, January 2020
- Chen, Ke; Song, Bai; Ravichandran, Navaneetha K.
- Science, Vol. 367, Issue 6477