A photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting
Abstract
The conversion of solar energy into chemical fuels can potentially address many of the energy and environment related challenges we face today. In this study, we have demonstrated a photochemical diode artificial photosynthesis system that can enable efficient, unassisted overall pure water splitting without using any sacrificial reagent. By precisely controlling charge carrier flow at the nanoscale, the wafer-level photochemical diode arrays exhibited solar-to-hydrogen efficiency ~3.3% in neutral (pH ~ 7.0) overall water splitting reaction. In part of the visible spectrum (400–485 nm), the energy conversion efficiency and apparent quantum yield reaches ~8.75% and ~20%, respectively, which are the highest values ever reported for one-step visible-light driven photocatalytic overall pure water splitting. The effective manipulation and control of charge carrier flow in nanostructured photocatalysts provides critical insight in achieving high efficiency artificial photosynthesis, including the efficient and selective reduction of CO2 to hydrocarbon fuels.
- Authors:
-
- McGill Univ., Montreal, QC (Canada)
- Center of Excellence in Transportation Electrification and Energy Storage (CETEES), Varennes, QC (United States)
- Univ. of Michigan, Ann Arbor, MI (United States); McGill Univ., Montreal, QC (Canada)
- Publication Date:
- Research Org.:
- Univ. of Michigan, Ann Arbor, MI (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office
- OSTI Identifier:
- 1500016
- Grant/Contract Number:
- EE0008086
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING
Citation Formats
Chowdhury, Faqrul A., Trudeau, Michel L., Guo, Hong, and Mi, Zetian. A photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-04067-1.
Chowdhury, Faqrul A., Trudeau, Michel L., Guo, Hong, & Mi, Zetian. A photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting. United States. https://doi.org/10.1038/s41467-018-04067-1
Chowdhury, Faqrul A., Trudeau, Michel L., Guo, Hong, and Mi, Zetian. Fri .
"A photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting". United States. https://doi.org/10.1038/s41467-018-04067-1. https://www.osti.gov/servlets/purl/1500016.
@article{osti_1500016,
title = {A photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting},
author = {Chowdhury, Faqrul A. and Trudeau, Michel L. and Guo, Hong and Mi, Zetian},
abstractNote = {The conversion of solar energy into chemical fuels can potentially address many of the energy and environment related challenges we face today. In this study, we have demonstrated a photochemical diode artificial photosynthesis system that can enable efficient, unassisted overall pure water splitting without using any sacrificial reagent. By precisely controlling charge carrier flow at the nanoscale, the wafer-level photochemical diode arrays exhibited solar-to-hydrogen efficiency ~3.3% in neutral (pH ~ 7.0) overall water splitting reaction. In part of the visible spectrum (400–485 nm), the energy conversion efficiency and apparent quantum yield reaches ~8.75% and ~20%, respectively, which are the highest values ever reported for one-step visible-light driven photocatalytic overall pure water splitting. The effective manipulation and control of charge carrier flow in nanostructured photocatalysts provides critical insight in achieving high efficiency artificial photosynthesis, including the efficient and selective reduction of CO2 to hydrocarbon fuels.},
doi = {10.1038/s41467-018-04067-1},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {Fri Apr 27 00:00:00 EDT 2018},
month = {Fri Apr 27 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Group III-nitride nanowire structures for photocatalytic hydrogen evolution under visible light irradiation
journal, October 2015
- Chowdhury, Faqrul A.; Mi, Zetian; Kibria, Md G.
- APL Materials, Vol. 3, Issue 10
Acid Treatment Enables Suppression of Electron-Hole Recombination in Hematite for Photoelectrochemical Water Splitting
journal, February 2016
- Yang, Yi; Forster, Mark; Ling, Yichuan
- Angewandte Chemie, Vol. 128, Issue 10
Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%
journal, March 2016
- Wang, Qian; Hisatomi, Takashi; Jia, Qingxin
- Nature Materials, Vol. 15, Issue 6
Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006
- Lewis, N. S.; Nocera, D. G.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
Surface potential of n- and p-type GaN measured by Kelvin force microscopy
journal, November 2008
- Barbet, S.; Aubry, R.; di Forte-Poisson, M. -A.
- Applied Physics Letters, Vol. 93, Issue 21
Recent developments in solar water-splitting photocatalysis
journal, January 2011
- Osterloh, Frank E.; Parkinson, Bruce A.
- MRS Bulletin, Vol. 36, Issue 1
Semiconductor Composites: Strategies for Enhancing Charge Carrier Separation to Improve Photocatalytic Activity
journal, December 2013
- Marschall, Roland
- Advanced Functional Materials, Vol. 24, Issue 17
A Place in the Sun for Artificial Photosynthesis?
journal, May 2016
- Su, Jinzhan; Vayssieres, Lionel
- ACS Energy Letters, Vol. 1, Issue 1
Enhancing charge separation on high symmetry SrTiO 3 exposed with anisotropic facets for photocatalytic water splitting
journal, January 2016
- Mu, Linchao; Zhao, Yue; Li, Ailong
- Energy & Environmental Science, Vol. 9, Issue 7
Visible light-driven efficient overall water splitting using p-type metal-nitride nanowire arrays
journal, April 2015
- Kibria, M. G.; Chowdhury, F. A.; Zhao, S.
- Nature Communications, Vol. 6, Issue 1
p-Type InP Nanopillar Photocathodes for Efficient Solar-Driven Hydrogen Production
journal, September 2012
- Lee, Min Hyung; Takei, Kuniharu; Zhang, Junjun
- Angewandte Chemie International Edition, Vol. 51, Issue 43
Computational investigation of structural and electronic properties of aqueous interfaces of GaN, ZnO, and a GaN/ZnO alloy
journal, January 2014
- Kharche, Neerav; Hybertsen, Mark S.; Muckerman, James T.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 24
Graphene-induced spatial charge separation for selective water splitting over TiO2 photocatalyst
journal, May 2016
- Min, Shixiong; Wang, Fang; Lu, Gongxuan
- Catalysis Communications, Vol. 80
Water Splitting Progress in Tandem Devices: Moving Photolysis beyond Electrolysis
journal, June 2016
- Zhang, Kan; Ma, Ming; Li, Ping
- Advanced Energy Materials, Vol. 6, Issue 15
Artificial photosynthesis for solar water-splitting
journal, July 2012
- Tachibana, Yasuhiro; Vayssieres, Lionel; Durrant, James R.
- Nature Photonics, Vol. 6, Issue 8
When group-III nitrides go infrared: New properties and perspectives
journal, July 2009
- Wu, Junqiao
- Journal of Applied Physics, Vol. 106, Issue 1
Role of photoexcited electrons in hydrogen evolution from platinum co-catalysts loaded on anatase TiO2: a first-principles study
journal, January 2013
- Boonchun, Adisak; Umezawa, Naoto; Ohno, Takahisa
- Journal of Materials Chemistry A, Vol. 1, Issue 22
Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4
journal, February 2013
- Li, Rengui; Zhang, Fuxiang; Wang, Donge
- Nature Communications, Vol. 4, Issue 1
Fundamental aspects of surface engineering of transition metal oxide photocatalysts
journal, January 2011
- Batzill, Matthias
- Energy & Environmental Science, Vol. 4, Issue 9
Limiting and realizable efficiencies of solar photolysis of water
journal, August 1985
- Bolton, James R.; Strickler, Stewart J.; Connolly, John S.
- Nature, Vol. 316, Issue 6028, p. 495-500
Ten-percent solar-to-fuel conversion with nonprecious materials
journal, September 2014
- Cox, Casandra R.; Lee, Jungwoo Z.; Nocera, Daniel G.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 39
Atomic-Scale Origin of Long-Term Stability and High Performance of p -GaN Nanowire Arrays for Photocatalytic Overall Pure Water Splitting
journal, July 2016
- Kibria, Md Golam; Qiao, Ruimin; Yang, Wanli
- Advanced Materials, Vol. 28, Issue 38
High Efficiency Solar-to-Hydrogen Conversion on a Monolithically Integrated InGaN/GaN/Si Adaptive Tunnel Junction Photocathode
journal, March 2015
- Fan, Shizhao; AlOtaibi, Bandar; Woo, Steffi Y.
- Nano Letters, Vol. 15, Issue 4
Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals
journal, January 2011
- Chen, X.; Liu, L.; Yu, P. Y.
- Science, Vol. 331, Issue 6018
How Surface Potential Determines the Kinetics of the First Hole Transfer of Photocatalytic Water Oxidation
journal, July 2014
- Waegele, Matthias M.; Chen, Xihan; Herlihy, David M.
- Journal of the American Chemical Society, Vol. 136, Issue 30
Photoelectrochemical Tandem Cells for Solar Water Splitting
journal, July 2013
- Prévot, Mathieu S.; Sivula, Kevin
- The Journal of Physical Chemistry C, Vol. 117, Issue 35
Fabrication of a GaN p/n lateral polarity junction by polar doping selectivity
journal, May 2008
- Collazo, Ramón; Mita, Seiji; Rice, Anthony
- physica status solidi (c), Vol. 5, Issue 6
The dependence of photocatalytic activity on the selective and nonselective deposition of noble metal cocatalysts on the facets of rutile TiO2
journal, May 2016
- Zhang, Qiao; Li, Rengui; Li, Zheng
- Journal of Catalysis, Vol. 337
Electron transfer dynamics in fuel producing photosystems
journal, April 2017
- Godin, Robert; Kafizas, Andreas; Durrant, James R.
- Current Opinion in Electrochemistry, Vol. 2, Issue 1
Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts
journal, September 2011
- Reece, S. Y.; Hamel, J. A.; Sung, K.
- Science, Vol. 334, Issue 6056
Synthesis of highly active rhodium-doped SrTiO3 powders in Z-scheme systems for visible-light-driven photocatalytic overall water splitting
journal, January 2013
- Kato, Hideki; Sasaki, Yasuyoshi; Shirakura, Nana
- Journal of Materials Chemistry A, Vol. 1, Issue 39
Solution-processed organic tandem solar cells with power conversion efficiencies >12%
journal, December 2016
- Li, Miaomiao; Gao, Ke; Wan, Xiangjian
- Nature Photonics, Vol. 11, Issue 2
When group-III nitrides go infrared: New properties and perspectives
journal, July 2009
- Wu, Junqiao
- Journal of Applied Physics, Vol. 106, Issue 1
Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures
journal, March 2017
- Young, James L.; Steiner, Myles A.; Döscher, Henning
- Nature Energy, Vol. 2, Issue 4
Band bowing and band alignment in InGaN alloys
journal, January 2010
- Moses, Poul Georg; Van de Walle, Chris G.
- Applied Physics Letters, Vol. 96, Issue 2
Highly efficient photocatalysts constructed by rational assembly of dual-cocatalysts separately on different facets of BiVO 4
journal, January 2014
- Li, Rengui; Han, Hongxian; Zhang, Fuxiang
- Energy Environ. Sci., Vol. 7, Issue 4
A Fully Integrated Nanosystem of Semiconductor Nanowires for Direct Solar Water Splitting
journal, May 2013
- Liu, Chong; Tang, Jinyao; Chen, Hao Ming
- Nano Letters, Vol. 13, Issue 6
High-Performance a -Si/c-Si Heterojunction Photoelectrodes for Photoelectrochemical Oxygen and Hydrogen Evolution
journal, April 2015
- Wang, Hsin-Ping; Sun, Ke; Noh, Sun Young
- Nano Letters, Vol. 15, Issue 5
Transient surface photovoltage in n- and p-GaN as probed by x-ray photoelectron spectroscopy
journal, March 2011
- Sezen, Hikmet; Ozbay, Ekmel; Aktas, Ozgur
- Applied Physics Letters, Vol. 98, Issue 11
Optoelectronic device physics and technology of nitride semiconductors from the UV to the terahertz
journal, September 2017
- Moustakas, Theodore D.; Paiella, Roberto
- Reports on Progress in Physics, Vol. 80, Issue 10
Role of photoexcited electrons in hydrogen evolution from platinum co-catalysts loaded on anatase TiO2: a first-principles study
journal, January 2013
- Boonchun, Adisak; Umezawa, Naoto; Ohno, Takahisa
- Journal of Materials Chemistry A, Vol. 1, Issue 22
An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
journal, February 2013
- Mubeen, Syed; Lee, Joun; Singh, Nirala
- Nature Nanotechnology, Vol. 8, Issue 4
Effect of Redox Cocatalysts Location on Photocatalytic Overall Water Splitting over Cubic NaTaO 3 Semiconductor Crystals Exposed with Equivalent Facets
journal, February 2016
- Zhang, Qiao; Li, Zheng; Wang, Shengyang
- ACS Catalysis, Vol. 6, Issue 4
p-Type InP Nanopillar Photocathodes for Efficient Solar-Driven Hydrogen Production
journal, September 2012
- Lee, Min Hyung; Takei, Kuniharu; Zhang, Junjun
- Angewandte Chemie International Edition, Vol. 51, Issue 43
Acid Treatment Enables Suppression of Electron-Hole Recombination in Hematite for Photoelectrochemical Water Splitting
journal, February 2016
- Yang, Yi; Forster, Mark; Ling, Yichuan
- Angewandte Chemie International Edition, Vol. 55, Issue 10
Transient optical diffraction of GaN/aqueous interfaces: Interfacial carrier mobility dependence on surface reactivity
journal, April 2016
- Doan, Hoang Q.; Pollock, Kevin L.; Cuk, Tanja
- Chemical Physics Letters, Vol. 649
Review of photoluminescence performance of nano-sized semiconductor materials and its relationships with photocatalytic activity
journal, July 2006
- Liqiang, Jing; Yichun, Qu; Baiqi, Wang
- Solar Energy Materials and Solar Cells, Vol. 90, Issue 12
Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst
journal, December 2001
- Zou, Zhigang; Ye, Jinhua; Sayama, Kazuhiro
- Nature, Vol. 414, Issue 6864
Group III-nitride nanowire structures for photocatalytic hydrogen evolution under visible light irradiation
journal, October 2015
- Chowdhury, Faqrul A.; Mi, Zetian; Kibria, Md G.
- APL Materials, Vol. 3, Issue 10
Heterogeneous photocatalyst materials for water splitting
journal, January 2009
- Kudo, Akihiko; Miseki, Yugo
- Chem. Soc. Rev., Vol. 38, Issue 1
Some recent developments in surface and interface design for photocatalytic and electrocatalytic hybrid structures
journal, January 2015
- Bai, Song; Xiong, Yujie
- Chemical Communications, Vol. 51, Issue 51
Photocatalytic reactivity of {121} and {211} facets of brookite TiO 2 crystals
journal, January 2015
- Zhao, Ming; Xu, Hua; Chen, Hungru
- Journal of Materials Chemistry A, Vol. 3, Issue 5
Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006
- Lewis, N. S.; Nocera, D. G.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
Atomic-Scale Origin of Long-Term Stability and High Performance of p -GaN Nanowire Arrays for Photocatalytic Overall Pure Water Splitting
journal, July 2016
- Kibria, Md Golam; Qiao, Ruimin; Yang, Wanli
- Advanced Materials, Vol. 28, Issue 38
Surface potential of n- and p-type GaN measured by Kelvin force microscopy
journal, November 2008
- Barbet, S.; Aubry, R.; di Forte-Poisson, M. -A.
- Applied Physics Letters, Vol. 93, Issue 21
Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%
journal, March 2016
- Wang, Qian; Hisatomi, Takashi; Jia, Qingxin
- Nature Materials, Vol. 15, Issue 6
Limiting and realizable efficiencies of solar photolysis of water
journal, August 1985
- Bolton, James R.; Strickler, Stewart J.; Connolly, John S.
- Nature, Vol. 316, Issue 6028, p. 495-500
Inorganic Materials as Catalysts for Photochemical Splitting of Water
journal, January 2008
- Osterloh, Frank E.
- Chemistry of Materials, Vol. 20, Issue 1
Ten-percent solar-to-fuel conversion with nonprecious materials
journal, September 2014
- Cox, Casandra R.; Lee, Jungwoo Z.; Nocera, Daniel G.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 39
Achieving overall water splitting using titanium dioxide-based photocatalysts of different phases
journal, January 2015
- Li, Rengui; Weng, Yuxiang; Zhou, Xin
- Energy & Environmental Science, Vol. 8, Issue 8
Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and Interfaces
journal, June 2012
- Zhang, Zhen; Yates, John T.
- Chemical Reviews, Vol. 112, Issue 10
High-Performance a -Si/c-Si Heterojunction Photoelectrodes for Photoelectrochemical Oxygen and Hydrogen Evolution
journal, April 2015
- Wang, Hsin-Ping; Sun, Ke; Noh, Sun Young
- Nano Letters, Vol. 15, Issue 5
Effect of Internal Electric Fields on Charge Carrier Dynamics in a Ferroelectric Material for Solar Energy Conversion
journal, June 2016
- Morris, Madeleine R.; Pendlebury, Stephanie R.; Hong, Jongin
- Advanced Materials, Vol. 28, Issue 33
Physical Chemistry of Semiconductor−Liquid Interfaces
journal, January 1996
- Nozik, Arthur J.; Memming, Rüdiger
- The Journal of Physical Chemistry, Vol. 100, Issue 31
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
journal, February 2015
- Liu, Juan; Liu, Yang; Liu, Naiyun
- Science, Vol. 347, Issue 6225
Semiconductor Composites: Strategies for Enhancing Charge Carrier Separation to Improve Photocatalytic Activity
journal, December 2013
- Marschall, Roland
- Advanced Functional Materials, Vol. 24, Issue 17
A Place in the Sun for Artificial Photosynthesis?
journal, May 2016
- Su, Jinzhan; Vayssieres, Lionel
- ACS Energy Letters, Vol. 1, Issue 1
p-Type InP Nanopillar Photocathodes for Efficient Solar-Driven Hydrogen Production
journal, September 2012
- Lee, Min Hyung; Takei, Kuniharu; Zhang, Junjun
- Angewandte Chemie, Vol. 124, Issue 43
Electron transfer dynamics in fuel producing photosystems
journal, April 2017
- Godin, Robert; Kafizas, Andreas; Durrant, James R.
- Current Opinion in Electrochemistry, Vol. 2, Issue 1
Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement
journal, May 2011
- Blankenship, R. E.; Tiede, D. M.; Barber, J.
- Science, Vol. 332, Issue 6031, p. 805-809
How Surface Potential Determines the Kinetics of the First Hole Transfer of Photocatalytic Water Oxidation
journal, July 2014
- Waegele, Matthias M.; Chen, Xihan; Herlihy, David M.
- Journal of the American Chemical Society, Vol. 136, Issue 30
Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals
journal, January 2011
- Chen, X.; Liu, L.; Yu, P. Y.
- Science, Vol. 331, Issue 6018
Solution-processed organic tandem solar cells with power conversion efficiencies >12%
journal, December 2016
- Li, Miaomiao; Gao, Ke; Wan, Xiangjian
- Nature Photonics, Vol. 11, Issue 2
Spatial Separation of Photochemical Oxidation and Reduction Reactions on the Surface of Ferroelectric BaTiO 3
journal, September 2001
- Giocondi, Jennifer L.; Rohrer, Gregory S.
- The Journal of Physical Chemistry B, Vol. 105, Issue 35
Fabrication of a GaN p/n lateral polarity junction by polar doping selectivity
journal, May 2008
- Collazo, Ramón; Mita, Seiji; Rice, Anthony
- physica status solidi (c), Vol. 5, Issue 6
Synthesis of highly active rhodium-doped SrTiO3 powders in Z-scheme systems for visible-light-driven photocatalytic overall water splitting
journal, January 2013
- Kato, Hideki; Sasaki, Yasuyoshi; Shirakura, Nana
- Journal of Materials Chemistry A, Vol. 1, Issue 39
Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement
journal, May 2011
- Blankenship, R. E.; Tiede, D. M.; Barber, J.
- Science, Vol. 332, Issue 6031, p. 805-809
Efficient solar water-splitting using a nanocrystalline CoO photocatalyst
journal, December 2013
- Liao, Longb; Zhang, Qiuhui; Su, Zhihua
- Nature Nanotechnology, Vol. 9, Issue 1
Fe 2 O 3 -TiO 2 Nano-heterostructure Photoanodes for Highly Efficient Solar Water Oxidation
journal, September 2015
- Barreca, Davide; Carraro, Giorgio; Gasparotto, Alberto
- Advanced Materials Interfaces, Vol. 2, Issue 17
Highly efficient water splitting by a dual-absorber tandem cell
journal, November 2012
- Brillet, Jeremie; Yum, Jun-Ho; Cornuz, Maurin
- Nature Photonics, Vol. 6, Issue 12
Tuning the surface Fermi level on p-type gallium nitride nanowires for efficient overall water splitting
journal, April 2014
- Kibria, M. G.; Zhao, S.; Chowdhury, F. A.
- Nature Communications, Vol. 5, Issue 1
Tuning the surface Fermi level on p-type gallium nitride nanowires for efficient overall water splitting
journal, April 2014
- Kibria, M. G.; Zhao, S.; Chowdhury, F. A.
- Nature Communications, Vol. 5, Issue 1
An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
journal, February 2013
- Mubeen, Syed; Lee, Joun; Singh, Nirala
- Nature Nanotechnology, Vol. 8, Issue 4
Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4
journal, February 2013
- Li, Rengui; Zhang, Fuxiang; Wang, Donge
- Nature Communications, Vol. 4, Issue 1
High Efficiency Solar-to-Hydrogen Conversion on a Monolithically Integrated InGaN/GaN/Si Adaptive Tunnel Junction Photocathode
journal, March 2015
- Fan, Shizhao; AlOtaibi, Bandar; Woo, Steffi Y.
- Nano Letters, Vol. 15, Issue 4
Transient optical diffraction of GaN/aqueous interfaces: Interfacial carrier mobility dependence on surface reactivity
journal, April 2016
- Doan, Hoang Q.; Pollock, Kevin L.; Cuk, Tanja
- Chemical Physics Letters, Vol. 649
Optoelectronic device physics and technology of nitride semiconductors from the UV to the terahertz
journal, September 2017
- Moustakas, Theodore D.; Paiella, Roberto
- Reports on Progress in Physics, Vol. 80, Issue 10
Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and Interfaces
journal, June 2012
- Zhang, Zhen; Yates, John T.
- Chemical Reviews, Vol. 112, Issue 10
Fundamental aspects of surface engineering of transition metal oxide photocatalysts
journal, January 2011
- Batzill, Matthias
- Energy & Environmental Science, Vol. 4, Issue 9
Band bowing and band alignment in InGaN alloys
journal, January 2010
- Moses, Poul Georg; Van de Walle, Chris G.
- Applied Physics Letters, Vol. 96, Issue 2
Transient surface photovoltage in n- and p-GaN as probed by x-ray photoelectron spectroscopy
journal, March 2011
- Sezen, Hikmet; Ozbay, Ekmel; Aktas, Ozgur
- Applied Physics Letters, Vol. 98, Issue 11
Effect of Redox Cocatalysts Location on Photocatalytic Overall Water Splitting over Cubic NaTaO 3 Semiconductor Crystals Exposed with Equivalent Facets
journal, February 2016
- Zhang, Qiao; Li, Zheng; Wang, Shengyang
- ACS Catalysis, Vol. 6, Issue 4
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting
journal, April 1998
- Khaselev, O.
- Science, Vol. 280, Issue 5362
Wafer-Level Photocatalytic Water Splitting on GaN Nanowire Arrays Grown by Molecular Beam Epitaxy
journal, June 2011
- Wang, Defa; Pierre, Adrien; Kibria, Md Golam
- Nano Letters, Vol. 11, Issue 6
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
journal, February 2015
- Liu, Juan; Liu, Yang; Liu, Naiyun
- Science, Vol. 347, Issue 6225
Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures
journal, March 2017
- Young, James L.; Steiner, Myles A.; Döscher, Henning
- Nature Energy, Vol. 2, Issue 4
Physical Chemistry of Semiconductor−Liquid Interfaces
journal, January 1996
- Nozik, Arthur J.; Memming, Rüdiger
- The Journal of Physical Chemistry, Vol. 100, Issue 31
Inorganic Materials as Catalysts for Photochemical Splitting of Water
journal, January 2008
- Osterloh, Frank E.
- Chemistry of Materials, Vol. 20, Issue 1
Research opportunities to advance solar energy utilization
journal, January 2016
- Lewis, N. S.
- Science, Vol. 351, Issue 6271
Photocatalyst releasing hydrogen from water
journal, March 2006
- Maeda, Kazuhiko; Teramura, Kentaro; Lu, Daling
- Nature, Vol. 440, Issue 7082
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
journal, January 2015
- Moniz, Savio J. A.; Shevlin, Stephen A.; Martin, David James
- Energy & Environmental Science, Vol. 8, Issue 3
Water Splitting Progress in Tandem Devices: Moving Photolysis beyond Electrolysis
journal, June 2016
- Zhang, Kan; Ma, Ming; Li, Ping
- Advanced Energy Materials, Vol. 6, Issue 15
Acid Treatment Enables Suppression of Electron-Hole Recombination in Hematite for Photoelectrochemical Water Splitting
journal, February 2016
- Yang, Yi; Forster, Mark; Ling, Yichuan
- Angewandte Chemie, Vol. 128, Issue 10
Hydrogen Economy Based on Renewable Energy Sources
journal, September 2004
- Turner, John A.; Williams, Mark C.; Rajeshwar, Krishnan
- The Electrochemical Society Interface, Vol. 13, Issue 3
Works referencing / citing this record:
Artificial Photosynthesis with Polymeric Carbon Nitride: When Meeting Metal Nanoparticles, Single Atoms, and Molecular Complexes
journal, March 2019
- Li, Yanrui; Kong, Tingting; Shen, Shaohua
- Small, Vol. 15, Issue 32
Artificial inflation of apparent photocatalytic activity induced by catalyst-mass-normalization and a method to fairly compare heterojunction systems
journal, January 2019
- Kunz, Larissa Y.; Diroll, Benjamin T.; Wrasman, Cody J.
- Energy & Environmental Science, Vol. 12, Issue 5
Surface‐Polarity‐Induced Spatial Charge Separation Boosts Photocatalytic Overall Water Splitting on GaN Nanorod Arrays
journal, January 2020
- Li, Zheng; Zhang, Liang; Liu, Yong
- Angewandte Chemie International Edition, Vol. 59, Issue 2
A quadruple-band metal–nitride nanowire artificial photosynthesis system for high efficiency photocatalytic overall solar water splitting
journal, January 2019
- Wang, Yongjie; Wu, Yuanpeng; Sun, Kai
- Materials Horizons, Vol. 6, Issue 7
Recent advances and demonstrated potentials for clean hydrogen via overall solar water splitting
journal, January 2019
- Chowdhury, Faqrul A.
- MRS Advances, Vol. 4, Issue 51-52
A methodological review on material growth and synthesis of solar-driven water splitting photoelectrochemical cells
journal, January 2019
- Park, Kwangwook; Kim, Yeong Jae; Yoon, Taeho
- RSC Advances, Vol. 9, Issue 52
Photocatalytic and Photoelectrochemical Systems: Similarities and Differences
journal, December 2019
- Wu, Hao; Tan, Hui Ling; Toe, Cui Ying
- Advanced Materials, Vol. 32, Issue 18
Continuous artificial synthesis of glucose precursor using enzyme-immobilized microfluidic reactors
journal, September 2019
- Zhu, Yujiao; Huang, Ziyu; Chen, Qingming
- Nature Communications, Vol. 10, Issue 1
Continuous artificial synthesis of glucose precursor using enzyme-immobilized microfluidic reactors
journal, September 2019
- Zhu, Yujiao; Huang, Ziyu; Chen, Qingming
- Nature Communications, Vol. 10, Issue 1
Probing the large bandgap-bowing and signature of antimony (Sb) in dilute-antimonide III-nitride using micro-Raman scattering
journal, August 2019
- Chowdhury, Faqrul A.; Mi, Zetian
- Journal of Applied Physics, Vol. 126, Issue 8
Plasmon-enhanced photoelectrochemical water splitting by InGaN/GaN nano-photoanodes
journal, January 2020
- Sang, Yimeng; Liu, Bin; Tao, Tao
- Semiconductor Science and Technology, Vol. 35, Issue 2
Mini-review on an engineering approach towards the selection of transition metal complex-based catalysts for photocatalytic H 2 production
journal, January 2019
- Huo, Jingpei; Zhang, Yu-Bang; Zou, Wan-Ying
- Catalysis Science & Technology, Vol. 9, Issue 11
Ultrafast carrier dynamics of conformally grown semi-polar (112̄2) GaN/InGaN multiple quantum well co-axial nanowires on m-axial GaN core nanowires
journal, January 2019
- Johar, Muhammad Ali; Song, Hyun-Gyu; Waseem, Aadil
- Nanoscale, Vol. 11, Issue 22
Toward practical solar hydrogen production – an artificial photosynthetic leaf-to-farm challenge
journal, January 2019
- Kim, Jin Hyun; Hansora, Dharmesh; Sharma, Pankaj
- Chemical Society Reviews, Vol. 48, Issue 7
Surface‐Polarity‐Induced Spatial Charge Separation Boosts Photocatalytic Overall Water Splitting on GaN Nanorod Arrays
journal, November 2019
- Li, Zheng; Zhang, Liang; Liu, Yong
- Angewandte Chemie, Vol. 132, Issue 2
Review of strategies for the fabrication of heterojunctional nanocomposites as efficient visible-light catalysts by modulating excited electrons with appropriate thermodynamic energy
journal, January 2019
- Zhang, Ziqing; Bai, Linlu; Li, Zhijun
- Journal of Materials Chemistry A, Vol. 7, Issue 18
Quantum dot activated indium gallium nitride on silicon as photoanode for solar hydrogen generation
journal, January 2019
- Kumar, Praveen; Devi, Pooja; Jain, Rishabh
- Communications Chemistry, Vol. 2, Issue 1
Facile development of CoAl-LDHs/RGO nanocomposites as photocatalysts for efficient hydrogen generation from water splitting under visible-light irradiation
journal, January 2019
- Kumaresan, Anbu; Yang, Shuo; Zhao, Kun
- Inorganic Chemistry Frontiers, Vol. 6, Issue 7
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