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Title: Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions

Abstract

Catalytic transformation of CH4 under a mild condition is significant for efficient utilization of shale gas under the circumstance of switching raw materials of chemical industries to shale gas. Here, we report the transformation of CH4 to acetic acid and methanol through coupling of CH4, CO and O2 on single-site Rh1O5 anchored in microporous aluminosilicates in solution at ≤150 °C. The activity of these singly dispersed precious metal sites for production of organic oxygenates can reach about 0.10 acetic acid molecules on a Rh1O5 site per second at 150 °C with a selectivity of ~70% for production of acetic acid. It is higher than the activity of free Rh cations by >1000 times. Computational studies suggest that the first C–H bond of CH4 is activated by Rh1O5 anchored on the wall of micropores of ZSM-5; the formed CH3 then couples with CO and OH, to produce acetic acid over a low activation barrier.

Authors:
ORCiD logo [1];  [1];  [2]; ORCiD logo [2];  [3];  [3];  [4];  [4];  [3];  [5];  [6]; ORCiD logo [3]
+ Show Author Affiliations
  1. Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering. Dept. of Chemistry
  2. Univ. of California, Riverside, CA (United States). Dept. of Chemistry
  3. Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering. Dept. of Chemistry; Univ. of Notre Dame, IN (United States). Dept. of Chemistry and Biochemistry
  4. Univ. of Electro-Communications, Chofu (Japan). Innovation Research Center for Fuel Cells. Graduate School of Informatics and Engineering
  5. Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering. Dept. of Chemistry; Fuzhou Univ. (China). State Key Lab. of Photocatalysis on Energy and Environment. College of Chemistry
  6. Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry
Publication Date:
Research Org.:
Univ. of Kansas, Lawrence, KS (United States); Stony Brook Univ., NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1499949
Grant/Contract Number:  
FG02-03ER15476; SC0014561
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 9; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; carbon capture and storage; catalytic mechanisms; heterogeneous catalysis

Citation Formats

Tang, Yu, Li, Yuting, Fung, Victor, Jiang, De-en, Huang, Weixin, Zhang, Shiran, Iwasawa, Yasuhiro, Sakata, Tomohiro, Nguyen, Luan, Zhang, Xiaoyan, Frenkel, Anatoly I., and Tao, Franklin. Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions. United States: N. p., 2018. Web. doi:10.1038/s41467-018-03235-7.
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Tang, Yu, Li, Yuting, Fung, Victor, Jiang, De-en, Huang, Weixin, Zhang, Shiran, Iwasawa, Yasuhiro, Sakata, Tomohiro, Nguyen, Luan, Zhang, Xiaoyan, Frenkel, Anatoly I., & Tao, Franklin. Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions. United States. https://doi.org/10.1038/s41467-018-03235-7
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Tang, Yu, Li, Yuting, Fung, Victor, Jiang, De-en, Huang, Weixin, Zhang, Shiran, Iwasawa, Yasuhiro, Sakata, Tomohiro, Nguyen, Luan, Zhang, Xiaoyan, Frenkel, Anatoly I., and Tao, Franklin. Mon . "Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions". United States. https://doi.org/10.1038/s41467-018-03235-7. https://www.osti.gov/servlets/purl/1499949.
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@article{osti_1499949,
title = {Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions},
author = {Tang, Yu and Li, Yuting and Fung, Victor and Jiang, De-en and Huang, Weixin and Zhang, Shiran and Iwasawa, Yasuhiro and Sakata, Tomohiro and Nguyen, Luan and Zhang, Xiaoyan and Frenkel, Anatoly I. and Tao, Franklin},
abstractNote = {Catalytic transformation of CH4 under a mild condition is significant for efficient utilization of shale gas under the circumstance of switching raw materials of chemical industries to shale gas. Here, we report the transformation of CH4 to acetic acid and methanol through coupling of CH4, CO and O2 on single-site Rh1O5 anchored in microporous aluminosilicates in solution at ≤150 °C. The activity of these singly dispersed precious metal sites for production of organic oxygenates can reach about 0.10 acetic acid molecules on a Rh1O5 site per second at 150 °C with a selectivity of ~70% for production of acetic acid. It is higher than the activity of free Rh cations by >1000 times. Computational studies suggest that the first C–H bond of CH4 is activated by Rh1O5 anchored on the wall of micropores of ZSM-5; the formed CH3 then couples with CO and OH, to produce acetic acid over a low activation barrier.},
doi = {10.1038/s41467-018-03235-7},
journal = {Nature Communications},
number = ,
volume = 9,
place = {United States},
year = {Mon Mar 26 00:00:00 EDT 2018},
month = {Mon Mar 26 00:00:00 EDT 2018}
}
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https://doi.org/10.1038/s41467-018-03235-7
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Cited by: 161 works
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Figures / Tables:

Fig. 1 Fig. 1: Structural characterization of isolated rhodium atoms in ZSM-5. a TEM image of particles of 0.10 wt%Rh/ZSM-5; scale bar: 10 nm. b TEM image of particles of 0.50wt%Rh/ZSM-5; scale bar: 10 nm. c Rh 3d XPS peak of 0.l0 wt%Rh/ZSM-5 and 0.50wt%Rh/ZSM-5. d Energy space of Rh K-edge ofmore » 0.l0 wt% Rh/ZSM-5 and Rh foil (reference sample) of X-ray absorption near edge spectra (XANES). e r-space of Rh K-edge of experimental (black) and calculated (red) data of the k2-weighted Rh K-edge EXAFS spectra of used 0.10 wt%Rh/ZSM-5. f Coordination number and bond length on average of the used 0.10wt%Rh/ ZSM-5. g r-space of Rh K-edge of experimental (black) and calculated (red) data of the k2-weighted Rh K-edge EXAFS spectra of Rh metal foil. h r-space of Rh K-edge of experimental (black) and calculated (red) data of the k2-weighted Rh K-edge EXAFS spectra of Rh2O3 nanoparticles supported on Al2O3« less
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Works referenced in this record:

Nanosized rhodium oxide particles in the MCM-41 mesoporous molecular sieve
journal, January 1998

  • Mulukutla, Ravichandra S.; Iwasawa, Yasuhiro; Asakura, Kiyotaka
  • Chemical Communications, Issue 14
  • DOI: 10.1039/a802259c

Mechanistic Insight into the Formation of Acetic Acid from the Direct Conversion of Methane and Carbon Dioxide on Zinc-Modified H–ZSM-5 Zeolite
journal, August 2013

  • Wu, Jian-Feng; Yu, Si-Min; Wang, Wei David
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja406978q

Brønsted/Lewis Acid Synergy in H–ZSM-5 and H–MOR Zeolites Studied by 1 H and 27 Al DQ-MAS Solid-State NMR Spectroscopy
journal, October 2011

  • Yu, Zhiwu; Li, Shenhui; Wang, Qiang
  • The Journal of Physical Chemistry C, Vol. 115, Issue 45
  • DOI: 10.1021/jp203923z

Zeolite-Supported Rhodium Complexes and Clusters: Switching Catalytic Selectivity by Controlling Structures of Essentially Molecular Species
journal, April 2011

  • Serna, Pedro; Gates, B. C.
  • Journal of the American Chemical Society, Vol. 133, Issue 13
  • DOI: 10.1021/ja111749s

Direct catalytic conversion of methane to acetic acid in an aqueous medium
journal, April 1994

Direct Methane−Methanol and Benzene−Phenol Conversions on Fe−ZSM-5 Zeolite:  Theoretical Predictions on the Reaction Pathways and Energetics
journal, February 2000

  • Yoshizawa, Kazunari; Shiota, Yoshihito; Yumura, Takashi
  • The Journal of Physical Chemistry B, Vol. 104, Issue 4
  • DOI: 10.1021/jp991844b

Catalysis on singly dispersed bimetallic sites
journal, August 2015

  • Zhang, Shiran; Nguyen, Luan; Liang, Jin-Xia
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8938

Review of Acetic Acid Synthesis from Various Feedstocks Through Different Catalytic Processes
journal, June 2016

  • Budiman, Anatta Wahyu; Nam, Ji Su; Park, Jae Hyun
  • Catalysis Surveys from Asia, Vol. 20, Issue 3
  • DOI: 10.1007/s10563-016-9215-9

Efficient Conversion of Methane to Aromatics by Coupling Methylation Reaction
journal, July 2016

Catalytic, Oxidative Condensation of CH4 to CH3COOH in One Step via CH Activation
journal, August 2003

Direct Catalytic Conversion of Methane to Methanol in an Aqueous Medium by using Copper-Promoted Fe-ZSM-5
journal, April 2012

  • Hammond, Ceri; Forde, Michael M.; Ab Rahim, Mohd Hasbi
  • Angewandte Chemie International Edition, Vol. 51, Issue 21
  • DOI: 10.1002/anie.201108706

Methanol carbonylation revisited: thirty years on
journal, January 1996

  • Maitlis, Peter M.; Haynes, Anthony; Sunley, Glenn J.
  • Journal of the Chemical Society, Dalton Transactions, Issue 11
  • DOI: 10.1039/dt9960002187

Direct oxidation of methane to acetic acid catalyzed by Pd2+ and Cu2+ in the presence of molecular oxygen
journal, January 2004

  • Zerella, Mark; Mukhopadhyay, Sudip; Bell, Alexis T.
  • Chemical Communications, Issue 17
  • DOI: 10.1039/b405549g

Characterization of rhodium oxide nanoparticles in MCM-41 and their catalytic performances for NO–CO reactions in excess O2
journal, March 2002

  • Mulukutla, Ravichandra S.; Shido, Takafumi; Asakura, Kiyotaka
  • Applied Catalysis A: General, Vol. 228, Issue 1-2
  • DOI: 10.1016/S0926-860X(01)00992-9

Tracking Rh Atoms in Zeolite HY: First Steps of Metal Cluster Formation and Influence of Metal Nuclearity on Catalysis of Ethylene Hydrogenation and Ethylene Dimerization
journal, June 2016

  • Yang, Dong; Xu, Pinghong; Browning, Nigel D.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
  • DOI: 10.1021/acs.jpclett.6b01153

Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles
journal, November 2008

Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation
journal, April 2012

  • Mattos, Lisiane V.; Jacobs, Gary; Davis, Burtron H.
  • Chemical Reviews, Vol. 112, Issue 7
  • DOI: 10.1021/cr2000114

On the possibility of AgZSM-5 zeolite being a partial oxidation catalyst for methane
journal, May 2009

  • Kuroda, Yasushige; Mori, Toshinori; Sugiyama, Hiroyuki
  • Journal of Colloid and Interface Science, Vol. 333, Issue 1
  • DOI: 10.1016/j.jcis.2009.01.015

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012

Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities
journal, January 2016

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Rhodium Dispersion during NO/CO Conversions
journal, July 2007

  • Dent, Andrew J.; Evans, John; Fiddy, Steven G.
  • Angewandte Chemie International Edition, Vol. 46, Issue 28
  • DOI: 10.1002/anie.200701419

A Site-Isolated Rhodium−Diethylene Complex Supported on Highly Dealuminated Y Zeolite:  Synthesis and Characterization
journal, December 2005

  • Liang, Ann J.; Bhirud, Vinesh A.; Ehresmann, Justin O.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 51
  • DOI: 10.1021/jp054623g

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
journal, March 2016

Conversion of Methane to Methanol with a Bent Mono(μ-oxo)dinickel Anchored on the Internal Surfaces of Micropores
journal, July 2014

  • Shan, Junjun; Huang, Weixin; Nguyen, Luan
  • Langmuir, Vol. 30, Issue 28
  • DOI: 10.1021/la501184b

Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011

  • Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
  • Nature Chemistry, Vol. 3, Issue 8
  • DOI: 10.1038/nchem.1095

Direct Conversion of Methane to Methanol by Metal-Exchanged ZSM-5 Zeolite (Metal = Fe, Co, Ni, Cu)
journal, November 2016

  • Mahyuddin, M. Haris; Staykov, Aleksandar; Shiota, Yoshihito
  • ACS Catalysis, Vol. 6, Issue 12
  • DOI: 10.1021/acscatal.6b01721

Molecular Metal Catalysts on Supports: Organometallic Chemistry Meets Surface Science
journal, July 2014

  • Serna, Pedro; Gates, Bruce C.
  • Accounts of Chemical Research, Vol. 47, Issue 8
  • DOI: 10.1021/ar500170k

Computationally Exploring Confinement Effects in the Methane-to-Methanol Conversion Over Iron-Oxo Centers in Zeolites
journal, November 2016

  • Göltl, Florian; Michel, Carine; Andrikopoulos, Prokopis C.
  • ACS Catalysis, Vol. 6, Issue 12
  • DOI: 10.1021/acscatal.6b02640

Isostructural Zeolite-Supported Rhodium and Iridium Complexes: Tuning Catalytic Activity and Selectivity by Ligand Modification
journal, August 2015

Low-Temperature Transformation of Methane to Methanol on Pd 1 O 4 Single Sites Anchored on the Internal Surface of Microporous Silicate
journal, September 2016

  • Huang, Weixin; Zhang, Shiran; Tang, Yu
  • Angewandte Chemie International Edition, Vol. 55, Issue 43
  • DOI: 10.1002/anie.201604708

State of Pd on H-ZSM-5 and other acidic supports during the selective reduction of NO by CH4 studied by EXAFS/XANES
journal, December 1997

Rhodium Dispersion during NO/CO Conversions
journal, July 2007

  • Dent, Andrew J.; Evans, John; Fiddy, Steven G.
  • Angewandte Chemie, Vol. 119, Issue 28
  • DOI: 10.1002/ange.200701419

Direct Catalytic Conversion of Methane to Methanol in an Aqueous Medium by using Copper-Promoted Fe-ZSM-5
journal, April 2012

  • Hammond, Ceri; Forde, Michael M.; Ab Rahim, Mohd Hasbi
  • Angewandte Chemie, Vol. 124, Issue 21
  • DOI: 10.1002/ange.201108706

Low-Temperature Transformation of Methane to Methanol on Pd 1 O 4 Single Sites Anchored on the Internal Surface of Microporous Silicate
journal, September 2016

Rhodium Dispersion during NO/CO Conversions
journal, July 2007

  • Dent, Andrew J.; Evans, John; Fiddy, Steven G.
  • Angewandte Chemie International Edition, Vol. 46, Issue 28
  • DOI: 10.1002/anie.200701419

Direct Catalytic Conversion of Methane to Methanol in an Aqueous Medium by using Copper-Promoted Fe-ZSM-5
journal, April 2012

  • Hammond, Ceri; Forde, Michael M.; Ab Rahim, Mohd Hasbi
  • Angewandte Chemie International Edition, Vol. 51, Issue 21
  • DOI: 10.1002/anie.201108706

Review of Acetic Acid Synthesis from Various Feedstocks Through Different Catalytic Processes
journal, June 2016

  • Budiman, Anatta Wahyu; Nam, Ji Su; Park, Jae Hyun
  • Catalysis Surveys from Asia, Vol. 20, Issue 3
  • DOI: 10.1007/s10563-016-9215-9

Reaction mechanism of the reductive elimination in the catalytic carbonylation of methanol. A density functional study
journal, May 2001

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
journal, March 2016

Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities
journal, January 2016

Isostructural Zeolite-Supported Rhodium and Iridium Complexes: Tuning Catalytic Activity and Selectivity by Ligand Modification
journal, August 2015

Efficient Conversion of Methane to Aromatics by Coupling Methylation Reaction
journal, July 2016

Direct Conversion of Methane to Methanol by Metal-Exchanged ZSM-5 Zeolite (Metal = Fe, Co, Ni, Cu)
journal, November 2016

  • Mahyuddin, M. Haris; Staykov, Aleksandar; Shiota, Yoshihito
  • ACS Catalysis, Vol. 6, Issue 12
  • DOI: 10.1021/acscatal.6b01721

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Molecular Metal Catalysts on Supports: Organometallic Chemistry Meets Surface Science
journal, July 2014

  • Serna, Pedro; Gates, Bruce C.
  • Accounts of Chemical Research, Vol. 47, Issue 8
  • DOI: 10.1021/ar500170k

Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation
journal, April 2012

  • Mattos, Lisiane V.; Jacobs, Gary; Davis, Burtron H.
  • Chemical Reviews, Vol. 112, Issue 7
  • DOI: 10.1021/cr2000114

A Site-Isolated Rhodium−Diethylene Complex Supported on Highly Dealuminated Y Zeolite:  Synthesis and Characterization
journal, December 2005

  • Liang, Ann J.; Bhirud, Vinesh A.; Ehresmann, Justin O.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 51
  • DOI: 10.1021/jp054623g

Brønsted/Lewis Acid Synergy in H–ZSM-5 and H–MOR Zeolites Studied by 1 H and 27 Al DQ-MAS Solid-State NMR Spectroscopy
journal, October 2011

  • Yu, Zhiwu; Li, Shenhui; Wang, Qiang
  • The Journal of Physical Chemistry C, Vol. 115, Issue 45
  • DOI: 10.1021/jp203923z

Conversion of Methane to Methanol with a Bent Mono(μ-oxo)dinickel Anchored on the Internal Surfaces of Micropores
journal, July 2014

  • Shan, Junjun; Huang, Weixin; Nguyen, Luan
  • Langmuir, Vol. 30, Issue 28
  • DOI: 10.1021/la501184b

Direct catalytic conversion of methane to acetic acid in an aqueous medium
journal, April 1994

Catalysis on singly dispersed bimetallic sites
journal, August 2015

  • Zhang, Shiran; Nguyen, Luan; Liang, Jin-Xia
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8938

Catalytic, Oxidative Condensation of CH4 to CH3COOH in One Step via CH Activation
journal, August 2003

Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles
journal, November 2008

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