Magnetic properties of double perovskite Ln2CoIrO6 (Ln=Eu, Tb, Ho) : Hetero-tri-spin 3d-5d-4f systems

Ding, Xiaxin; Gao, Bin; Krenkel, Elizabeth; Dawson, Charles; Eckert, James C.; Cheong, Sang-Wook; Zapf, Vivien

doi:10.1103/PhysRevB.99.014438

Title: Magnetic properties of double perovskite $L n_{2} {CoIrO}_{6}$ $(L n = Eu, Tb, Ho)$ : Hetero-tri-spin $3 d - 5 d - 4 f$ systems

Abstract

The field of double perovskites is now advancing to three magnetic elements on the A, B and B' sites. A series of iridium-based double perovskite compounds, Ln₂ CoIrO₆ (Ln = Eu, Tb, Ho), with three magnetic elements was synthesized as polycrystalline samples. The compounds crystalize in monoclinic structures with the space group P2₁/n. Magnetic properties of these hetero-tri-spin 3 d-5 d-4 f systems were studied by magnetic susceptibility and field dependent magnetization in both DC and pulsed magnetic fields. All these compounds show ferrimagnetic transitions at temperatures T C above 100 K, which are attributable to antiferromagnetic coupling between Co²⁺ and Ir⁴⁺ spins. For Eu₂ CoIrO₆, the magnetic properties are similar to those of La₂CoIrO₆. The Eu³⁺ spins show Van Vleck paramagnetism, and do not significantly interact with transition-metal cations. In contrast, Tb₂ CoIrO₆ and Ho₂ CoIrO₆ reveal a second transition to antiferromagnetic order below a lower temperature T_N. The temperature-induced ferrimagnetic-to-antiferromagnetic phase transition might be explained by a spin-reorientation transition. Moreover, a magnetic-field-induced spin-flop-like transition with a small hysteresis was observed below T_N in these two compounds. The magnetic moments of all three compounds do not saturate up to 60 T at low temperatures. A moderate magnetocaloric effect wasmore »« less

Authors:

^[1]; Gao, Bin ^[2]; Krenkel, Elizabeth ^[3]; Dawson, Charles ^[3]; Eckert, James C. ^[3]; Cheong, Sang-Wook ^[2];

^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Rutgers Center for Emergent Materials, Piscataway, NJ (United States). Dept. of Physics and Astronomy
Harvey Mudd College, Claremont, CA (United States). Dept. of Physics

Publication Date:: Thu Jan 31 00:00:00 EST 2019

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Laboratory Directed Research and Development (LDRD) Program; National Science Foundation (NSF)

OSTI Identifier:: 1494471

Alternate Identifier(s):: OSTI ID: 1493088

Report Number(s):: LA-UR-18-30816
Journal ID: ISSN 2469-9950; PRBMDO

Grant/Contract Number:: 89233218CNA000001; DMR-1629059; DMR-1157490; DMR-1644779

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 99; Journal Issue: 1; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; High Magnetic Field Science

Citation Formats


                    Ding, Xiaxin, Gao, Bin, Krenkel, Elizabeth, Dawson, Charles, Eckert, James C., Cheong, Sang-Wook, and Zapf, Vivien. Magnetic properties of double perovskite Ln2CoIrO6 (Ln=Eu, Tb, Ho) : Hetero-tri-spin 3d-5d-4f systems.  United States: N. p., 2019. 
Web.  doi:10.1103/PhysRevB.99.014438.

Copy to clipboard


                    Ding, Xiaxin, Gao, Bin, Krenkel, Elizabeth, Dawson, Charles, Eckert, James C., Cheong, Sang-Wook, & Zapf, Vivien. Magnetic properties of double perovskite Ln2CoIrO6 (Ln=Eu, Tb, Ho) : Hetero-tri-spin 3d-5d-4f systems.  United States.  https://doi.org/10.1103/PhysRevB.99.014438

Copy to clipboard


                    Ding, Xiaxin, Gao, Bin, Krenkel, Elizabeth, Dawson, Charles, Eckert, James C., Cheong, Sang-Wook, and Zapf, Vivien. Thu .  
"Magnetic properties of double perovskite Ln2CoIrO6 (Ln=Eu, Tb, Ho) : Hetero-tri-spin 3d-5d-4f systems".  United States.  https://doi.org/10.1103/PhysRevB.99.014438.  https://www.osti.gov/servlets/purl/1494471.

Copy to clipboard


                    
@article{osti_1494471,

  title        = {Magnetic properties of double perovskite Ln2CoIrO6 (Ln=Eu, Tb, Ho) : Hetero-tri-spin 3d-5d-4f systems},

  author       = {Ding, Xiaxin and Gao, Bin and Krenkel, Elizabeth and Dawson, Charles and Eckert, James C. and Cheong, Sang-Wook and Zapf, Vivien},

  abstractNote = {The field of double perovskites is now advancing to three magnetic elements on the A, B and B' sites. A series of iridium-based double perovskite compounds, Ln2 CoIrO6 (Ln = Eu, Tb, Ho), with three magnetic elements was synthesized as polycrystalline samples. The compounds crystalize in monoclinic structures with the space group P21/n. Magnetic properties of these hetero-tri-spin 3 d-5 d-4 f systems were studied by magnetic susceptibility and field dependent magnetization in both DC and pulsed magnetic fields. All these compounds show ferrimagnetic transitions at temperatures T C above 100 K, which are attributable to antiferromagnetic coupling between Co2+ and Ir4+ spins. For Eu2 CoIrO6, the magnetic properties are similar to those of La2CoIrO6. The Eu3+ spins show Van Vleck paramagnetism, and do not significantly interact with transition-metal cations. In contrast, Tb2 CoIrO6 and Ho2 CoIrO6 reveal a second transition to antiferromagnetic order below a lower temperature TN. The temperature-induced ferrimagnetic-to-antiferromagnetic phase transition might be explained by a spin-reorientation transition. Moreover, a magnetic-field-induced spin-flop-like transition with a small hysteresis was observed below TN in these two compounds. The magnetic moments of all three compounds do not saturate up to 60 T at low temperatures. A moderate magnetocaloric effect was also observed in all three compounds. Our results should motivate further investigation of the spin configuration on single crystals of these iridium-based double perovskites.},

  doi          = {10.1103/PhysRevB.99.014438},

  journal      = {Physical Review B},

  number       = 1,

  volume       = 99,

  place        = {United States},

  year         = {Thu Jan 31 00:00:00 EST 2019},

  month        = {Thu Jan 31 00:00:00 EST 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevB.99.014438

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 13 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

A2B′B″O6 perovskites: A review
journal, May 2015

Vasala, Sami; Karppinen, Maarit
Progress in Solid State Chemistry, Vol. 43, Issue 1-2
DOI: 10.1016/j.progsolidstchem.2014.08.001

Double perovskites with ferromagnetism above room temperature
journal, December 2006

Serrate, D.; Teresa, J. M. De; Ibarra, M. R.
Journal of Physics: Condensed Matter, Vol. 19, Issue 2
DOI: 10.1088/0953-8984/19/2/023201

Design and Crystal Growth of Magnetic Double Perovskite Iridates: Ln ₂ MIrO ₆ ( Ln = La, Pr, Nd, Sm-Gd; M = Mg, Ni)
journal, April 2016

Ferreira, Timothy; Morrison, Gregory; Yeon, Jeongho
Crystal Growth & Design, Vol. 16, Issue 5
DOI: 10.1021/acs.cgd.6b00121

Investigation of the magnetic properties in double perovskite R ₂ CoMnO ₆ single crystals ( R = rare earth: La to Lu)
journal, October 2015

Kim, M. K.; Moon, J. Y.; Choi, H. Y.
Journal of Physics: Condensed Matter, Vol. 27, Issue 42
DOI: 10.1088/0953-8984/27/42/426002

Magnetic and structural features of the NdNi _{1 − x} Mn _x O ₃ perovskite series investigated by neutron diffraction
journal, May 2011

Sánchez-Benítez, J.; Martínez-Lope, M. J.; Alonso, J. A.
Journal of Physics: Condensed Matter, Vol. 23, Issue 22
DOI: 10.1088/0953-8984/23/22/226001

Phase-Sensitive Observation of a Spin-Orbital Mott State in Sr2IrO4
journal, March 2009

Kim, B. J.; Ohsumi, H.; Komesu, T.
Science, Vol. 323, Issue 5919
DOI: 10.1126/science.1167106

Novel $J_{eff} = 1 / 2$ Mott State Induced by Relativistic Spin-Orbit Coupling in ${Sr}_{2} {IrO}_{4}$
journal, August 2008

Kim, B. J.; Jin, Hosub; Moon, S. J.
Physical Review Letters, Vol. 101, Issue 7
DOI: 10.1103/PhysRevLett.101.076402

Exotic phases induced by strong spin-orbit coupling in ordered double perovskites
journal, November 2010

Chen, Gang; Pereira, Rodrigo; Balents, Leon
Physical Review B, Vol. 82, Issue 17
DOI: 10.1103/PhysRevB.82.174440

Magnetism and spin-orbit coupling in Ir-based double perovskites La $_{2 - x}$ Sr $_{x}$ CoIrO $_{6}$
journal, June 2012

Kolchinskaya, A.; Komissinskiy, P.; Yazdi, M. Baghaie
Physical Review B, Vol. 85, Issue 22
DOI: 10.1103/PhysRevB.85.224422

Stabilization of ferromagnetic ordering in cobaltite double perovskites of La ₂ CoIrO ₆ and La ₂ CoPtO ₆
journal, August 2015

Lee, Min-Cheol; Sohn, C. H.; Kim, S. Y.
Journal of Physics: Condensed Matter, Vol. 27, Issue 33
DOI: 10.1088/0953-8984/27/33/336002

Temperature and composition dependence of crystal structures and magnetic and electronic properties of the double perovskites ${La}_{2 - x} {Sr}_{x} {CoIrO}_{6}$ $(0 \leq x \leq 2)$
journal, July 2010

Narayanan, N.; Mikhailova, D.; Senyshyn, A.
Physical Review B, Vol. 82, Issue 2
DOI: 10.1103/PhysRevB.82.024403

Reentrant spin glass behavior and magnetodielectric coupling of an Ir-based double perovskite compound, La ₂ CoIrO ₆
journal, January 2017

Song, Jiyue; Zhao, Bangchuan; Yin, Lihua
Dalton Transactions, Vol. 46, Issue 35
DOI: 10.1039/C7DT02254A

Combined texture and structure analysis of deformed limestone from time-of-flight neutron diffraction spectra
journal, January 1997

Lutterotti, L.; Matthies, S.; Wenk, H. -R.
Journal of Applied Physics, Vol. 81, Issue 2
DOI: 10.1063/1.364220

Crystal growth, structure and magnetic properties of the double perovskites Ln2MgIrO6 (Ln=Pr, Nd, Sm–Gd)
journal, February 2010

Mugavero III, Samuel J.; Fox, Adam H.; Smith, Mark D.
Journal of Solid State Chemistry, Vol. 183, Issue 2
DOI: 10.1016/j.jssc.2009.11.025

The Structures of Tb7O12 and Tb11O20
journal, May 1993

Zhang, J.; Von Dreele, R. B.; Eyring, L.
Journal of Solid State Chemistry, Vol. 104, Issue 1
DOI: 10.1006/jssc.1993.1138

Crystal Structure and Magnetic Properties of Tb ₁₁ O ₂₀
journal, January 2013

Baran, S.; Duraj, R.; Hoser, A.
Acta Physica Polonica A, Vol. 123, Issue 1
DOI: 10.12693/APhysPolA.123.98

Paramagnetic and Nuclear Scattering Cross Sections of Holmium Sesquioxide
journal, April 1958

Koehler, W. C.; Wollan, E. O.; Wilkinson, M. K.
Physical Review, Vol. 110, Issue 1
DOI: 10.1103/PhysRev.110.37

Large reversible magnetocaloric effect in antiferromagnetic Ho2O3 powders
journal, October 2017

Boutahar, A.; Moubah, R.; Hlil, E. K.
Scientific Reports, Vol. 7, Issue 1
DOI: 10.1038/s41598-017-14279-y

Van Vleck paramagnetism of the trivalent Eu ions
journal, November 2010

Takikawa, Yusuke; Ebisu, Shuji; Nagata, Shoichi
Journal of Physics and Chemistry of Solids, Vol. 71, Issue 11
DOI: 10.1016/j.jpcs.2010.08.006

Van Vleck paramagnetism of europium oxyhydroxide
journal, February 2015

Samata, Hiroaki; Wada, Naoki; Ozawa, Tadashi C.
Journal of Rare Earths, Vol. 33, Issue 2
DOI: 10.1016/S1002-0721(14)60399-9

Multiferroic behavior in the double-perovskite Lu $_{2}$ MnCoO $_{6}$
journal, October 2011

Yáñez-Vilar, S.; Mun, E. D.; Zapf, V. S.
Physical Review B, Vol. 84, Issue 13
DOI: 10.1103/PhysRevB.84.134427

Magnetoelectric and structural properties of $Y_{2} CoMn O_{6}$ : The role of antisite defects
journal, June 2016

Blasco, J.; García, J.; Subías, G.
Physical Review B, Vol. 93, Issue 21
DOI: 10.1103/PhysRevB.93.214401

Metamagnetism and Critical Fluctuations in High Quality Single Crystals of the Bilayer Ruthenate ${Sr}_{3} {Ru}_{2} O_{7}$
journal, March 2001

Perry, R. S.; Galvin, L. M.; Grigera, S. A.
Physical Review Letters, Vol. 86, Issue 12
DOI: 10.1103/PhysRevLett.86.2661

Nature of Spin-Reorientation Transitions
journal, April 1968

Horner, H.; Varma, C. M.
Physical Review Letters, Vol. 20, Issue 16
DOI: 10.1103/PhysRevLett.20.845

Review of magnetocaloric effect in perovskite-type oxides
journal, May 2013

Zhong, Wei; Au, Chak-Tong; Du, You-Wei
Chinese Physics B, Vol. 22, Issue 5
DOI: 10.1088/1674-1056/22/5/057501

The Structure and Magnetic Properties of La2MLrO6 with M = Mg, Co, Ni, and Zn
journal, April 1995

Currie, R. C.; Vente, J. F.; Frikkee, E.
Journal of Solid State Chemistry, Vol. 116, Issue 1
DOI: 10.1006/jssc.1995.1202

Structural, electronic and magnetic properties of the series of double perovskites <mml:math altimg="si0012.gif" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd" xmlns:sa="http://www.elsevier.com/xml/common/struct-aff/dtd"><mml:msub><mml:mrow><mml:mo stretchy="false">(</mml:mo><mml:mi>Ca</mml:mi><mml:mo>,</mml:mo><mml:mi>Sr</mml:mi><mml:mo stretchy="false">)</mml:mo></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi>La</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi>FeIrO</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow></mml:msub></mml:math>
journal, April 2014

Bufaiçal, L.; Adriano, C.; Lora-Serrano, R.
Journal of Solid State Chemistry, Vol. 212
DOI: 10.1016/j.jssc.2014.01.007

Physical properties of disordered double-perovskite Ca2−xLaxFeIrO6
journal, April 2008

Bufaiçal, L.; Mendonça Ferreira, L.; Lora-Serrano, R.
Journal of Applied Physics, Vol. 103, Issue 7
DOI: 10.1063/1.2830719

XANES and EXAFS Studies on the Ir-O Bond Covalency in Ionic Iridium Perovskites
journal, August 1995

Choy, Jin-Ho; Kim, Dong-Kuk; Hwang, Sung-Ho
Journal of the American Chemical Society, Vol. 117, Issue 33
DOI: 10.1021/ja00138a010

Crystal structures and magnetic properties of ordered perovskites A2R3+Ir5+O6 (A=Sr, Ba; R=Sc, Y, La, Lu)
journal, June 1999

Wakeshima, Makoto; Harada, Daijitsu; Hinatsu, Yukio
Journal of Alloys and Compounds, Vol. 287, Issue 1-2
DOI: 10.1016/S0925-8388(99)00057-2

Iridium double perovskite ${Sr}_{2} {YIrO}_{6}$ : A combined structural and specific heat study
journal, February 2017

Corredor, L. T.; Aslan-Cansever, G.; Sturza, M.
Physical Review B, Vol. 95, Issue 6
DOI: 10.1103/PhysRevB.95.064418

The Role of Oxygen Stoichiometry on Phase Stability, Structure, and Magnetic Properties of Sr ₂ CoIrO _6−δ
journal, November 2010

Mikhailova, D.; Narayanan, N.; Gruner, W.
Inorganic Chemistry, Vol. 49, Issue 22
DOI: 10.1021/ic100973p

A Family of One-Dimensional Oxides: Sr3MlrO6 (M = Ni, Cu, Zn): Structure and Magnetic Properties
journal, July 1995

Nguyen, T. N.; zur Loye, H. -C.
Journal of Solid State Chemistry, Vol. 117, Issue 2
DOI: 10.1006/jssc.1995.1277

Double Perovskites with Ferromagnetism Above Room Temperature
journal, June 2007

Serrate, D.; De Teresa, J. M.; Ibarra, M. R.
ChemInform, Vol. 38, Issue 23
DOI: 10.1002/chin.200723213

Works referencing / citing this record:

Rare earth double perovskites: a fertile soil in the field of perovskite oxides
journal, January 2019

Chen, Xiaoyun; Xu, Jun; Xu, Yueshan
Inorganic Chemistry Frontiers, Vol. 6, Issue 9
DOI: 10.1039/c9qi00512a

Similar Records in DOE PAGES and OSTI.GOV collections:

Complex magnetic properties in the mixed $4 f - 5 d$ double perovskite iridates $X_{2} {ZnIrO}_{6} (X = Nd, Sm, Eu, Gd)$

Journal Article Vogl, M. ; Morrow, R. ; Aczel, A. A. ; ... - Physical Review Materials

Here in this paper, we report on the synthesis and magnetic properties of a series of double perovskites Ln₂ZnIrO₆ with Ln = Nd, Sm, Eu, Gd. These compounds present examples of the rare case of double perovskites (general formula A₂BB'O6) with a magnetic 4ƒ-ion on the A site in combination with the strongly spin-orbit coupled 5d transition-metal ion Ir⁴⁺ on the B sublattice. We discuss the impact of different rare earths on the macroscopic magnetic properties. Gd₂ZnIrO₆ and Eu₂ZnIrO₆ show ferrimagnetic or canted antiferromagnetic order below T_N = 23 and 12 K, respectively. Sm₂ZnIrO₆ orders antiferromagnetically at T_N = 13more »« less
https://doi.org/10.1103/PhysRevMaterials.4.054413

Full Text Available
Mixing $A$ -type and $G$ -type $B$ -site antiferromagnetism in $A M n_{1 - x} F e_{x} O_{3} (A = La, Nd)$

Journal Article Pajerowski, Daniel M. - Physical Review B

Using a classical Heisenberg model with anisotropic nearest-neighbor superexchange and uniaxial anisotropy, I investigate the magnetic order of the transition metals on the B sites in AMn_1-xFe_xO₃(A=La, Nd; x=[0,1]) with Monte Carlo methods. Magnetic parameters are extracted from preexisting experimental data when available and otherwise estimated with calculations. Superexchange energies are compared to density functional theory and anisotropy energies to ligand field theory, and the potential for doping-induced strain affecting these parameters is considered. I find coexistence regions of different types of magnetic order (A-type and G-type antiferromagnetism), regions with distinct magnetic transitions for the two order parameters, noncollinear groundmore »« less
Cited by 3
https://doi.org/10.1103/PhysRevB.98.134431

Full Text Available
Effects of chemical pressure on the magnetic ground states of the osmate double perovskites $SrCaCoOs O_{6}$ and $C a_{2} CoOs O_{6}$

Journal Article Morrow, Ryan ; Yan, Jiaqiang ; McGuire, Michael A. ; ... - Physical Review. B, Condensed Matter and Materials Physics

Themagnetic ground state in the double perovskite system Sr2-xCaxCoOsO6 changes from an antiferromagnet (x = 0), to a spin glass (x = 1), to a ferrimagnet (x = 2) as the Ca content increases. This crossover is driven by chemical pressure effects that control the relative strength of magnetic exchange interactions. The synthesis, crystal structure, and magnetism of SrCaCoOsO6 and Ca2CoOsO6 are investigated and compared with Sr2CoOsO6. Both compounds adopt a monoclinic crystal structure with rock-salt ordering of Co2+ and Os6+ and a(-)a(-)b(+) octahedral tilting, but the average Co-O-Os bond angle evolves from 158.0(3)degrees in SrCaCoOsO6 to 150.54(9)degrees in Ca2CoOsO6more »« less
https://doi.org/10.1103/PhysRevB.92.094435
Neutron scattering investigation of rhenium orbital ordering in the $3 d - 5 d$ double perovskite ${Ca}_{2} {FeReO}_{6}$

Journal Article Yuan, Bo ; Clancy, J. P. ; Sears, Jennifer A. ; ... - Physical Review B

Here, we have carried out inelastic neutron scattering experiments to study magnetic excitations in the ordered double perovskite Ca₂FeReO₆. We have found a well-defined magnon mode with a bandwidth of ~50 meV below the ferrimagnetic ordering temperature (T_c ~ 520 K), similar to the previously studied Ba₂FeReO₆. The spin excitation is gapless for most temperatures within the magnetically ordered phase. However, a spin gap of ~10 meV opens up below ~150 K, which is well below the magnetic ordering temperature but coincides with a previously reported metal-insulator transition and onset of structural distortion. The observed temperature dependence of the spinmore »« less
Cited by 4
https://doi.org/10.1103/PhysRevB.98.214433

Full Text Available
Spin gaps in the ordered states of ${La}_{2} Li X O_{6} (X = Ru, Os)$ and their relation to the distortion of the cubic double perovskite structure in $4 d^{3}$ and $5 d^{3}$ magnets

Journal Article Maharaj, D. D. ; Sala, G. ; Marjerrison, C. A. ; ... - Physical Review B

Time-of-flight inelastic neutron scattering measurements have been carried out on polycrystalline samples of the 4d³ and 5d³ double pervoskite antiferromagnets La₂LiRuO₆ and La₂LiOsO₆. These reveal the development of an inelastic spin gap in La₂LiRuO₆ and La₂LiOsO₆ of ~1.8(8) and 6(1) meV, below their respective ordering temperatures TN, ~23.8 and 30 K. The bandwidths of the spin excitations are shown to be ~5.7(9)and12(1)meV, respectively, at low temperatures. Spin gaps are surprising in such magnets as the t_2g levels of Ru⁵⁺ or Os⁵⁺ are expected to be half-filled, resulting in an anticipated orbital singlet for both materials. We compare these results inmore »« less
Cited by 7
https://doi.org/10.1103/PhysRevB.98.104434

Full Text Available

Similar Records

Title: Magnetic properties of double perovskite L n 2 CoIrO 6 ( L n = Eu , Tb, Ho) : Hetero-tri-spin 3 d - 5 d - 4 f systems

Abstract

Citation Formats

A2B′B″O6 perovskites: A review journal, May 2015

Double perovskites with ferromagnetism above room temperature journal, December 2006

Design and Crystal Growth of Magnetic Double Perovskite Iridates: Ln 2 MIrO 6 ( Ln = La, Pr, Nd, Sm-Gd; M = Mg, Ni) journal, April 2016

Investigation of the magnetic properties in double perovskite R 2 CoMnO 6 single crystals ( R = rare earth: La to Lu) journal, October 2015

Magnetic and structural features of the NdNi 1 − x Mn x O 3 perovskite series investigated by neutron diffraction journal, May 2011

Phase-Sensitive Observation of a Spin-Orbital Mott State in Sr2IrO4 journal, March 2009

Novel J eff = 1 / 2 Mott State Induced by Relativistic Spin-Orbit Coupling in Sr 2 IrO 4 journal, August 2008

Exotic phases induced by strong spin-orbit coupling in ordered double perovskites journal, November 2010

Magnetism and spin-orbit coupling in Ir-based double perovskites La 2 − x Sr x CoIrO 6 journal, June 2012

Stabilization of ferromagnetic ordering in cobaltite double perovskites of La 2 CoIrO 6 and La 2 CoPtO 6 journal, August 2015

Temperature and composition dependence of crystal structures and magnetic and electronic properties of the double perovskites La 2 − x Sr x CoIrO 6 ( 0 ≤ x ≤ 2 ) journal, July 2010

Reentrant spin glass behavior and magnetodielectric coupling of an Ir-based double perovskite compound, La 2 CoIrO 6 journal, January 2017

Combined texture and structure analysis of deformed limestone from time-of-flight neutron diffraction spectra journal, January 1997

Crystal growth, structure and magnetic properties of the double perovskites Ln2MgIrO6 (Ln=Pr, Nd, Sm–Gd) journal, February 2010

The Structures of Tb7O12 and Tb11O20 journal, May 1993

Crystal Structure and Magnetic Properties of Tb 11 O 20 journal, January 2013

Paramagnetic and Nuclear Scattering Cross Sections of Holmium Sesquioxide journal, April 1958

Large reversible magnetocaloric effect in antiferromagnetic Ho2O3 powders journal, October 2017

Van Vleck paramagnetism of the trivalent Eu ions journal, November 2010

Van Vleck paramagnetism of europium oxyhydroxide journal, February 2015

Multiferroic behavior in the double-perovskite Lu 2 MnCoO 6 journal, October 2011

Magnetoelectric and structural properties of Y 2 CoMn O 6 : The role of antisite defects journal, June 2016

Metamagnetism and Critical Fluctuations in High Quality Single Crystals of the Bilayer Ruthenate Sr 3 Ru 2 O 7 journal, March 2001

Nature of Spin-Reorientation Transitions journal, April 1968

Review of magnetocaloric effect in perovskite-type oxides journal, May 2013

The Structure and Magnetic Properties of La2MLrO6 with M = Mg, Co, Ni, and Zn journal, April 1995

Physical properties of disordered double-perovskite Ca2−xLaxFeIrO6 journal, April 2008

XANES and EXAFS Studies on the Ir-O Bond Covalency in Ionic Iridium Perovskites journal, August 1995

Crystal structures and magnetic properties of ordered perovskites A2R3+Ir5+O6 (A=Sr, Ba; R=Sc, Y, La, Lu) journal, June 1999

Iridium double perovskite Sr 2 YIrO 6 : A combined structural and specific heat study journal, February 2017

The Role of Oxygen Stoichiometry on Phase Stability, Structure, and Magnetic Properties of Sr 2 CoIrO 6−δ journal, November 2010

A Family of One-Dimensional Oxides: Sr3MlrO6 (M = Ni, Cu, Zn): Structure and Magnetic Properties journal, July 1995

Double Perovskites with Ferromagnetism Above Room Temperature journal, June 2007

Rare earth double perovskites: a fertile soil in the field of perovskite oxides journal, January 2019

Title: Magnetic properties of double perovskite $L n_{2} {CoIrO}_{6}$ $(L n = Eu, Tb, Ho)$ : Hetero-tri-spin $3 d - 5 d - 4 f$ systems

A2B′B″O6 perovskites: A review
journal, May 2015

Double perovskites with ferromagnetism above room temperature
journal, December 2006

Design and Crystal Growth of Magnetic Double Perovskite Iridates: Ln ₂ MIrO ₆ ( Ln = La, Pr, Nd, Sm-Gd; M = Mg, Ni)
journal, April 2016

Investigation of the magnetic properties in double perovskite R ₂ CoMnO ₆ single crystals ( R = rare earth: La to Lu)
journal, October 2015

Magnetic and structural features of the NdNi _{1 − x} Mn _x O ₃ perovskite series investigated by neutron diffraction
journal, May 2011

Phase-Sensitive Observation of a Spin-Orbital Mott State in Sr2IrO4
journal, March 2009

Novel $J_{eff} = 1 / 2$ Mott State Induced by Relativistic Spin-Orbit Coupling in ${Sr}_{2} {IrO}_{4}$
journal, August 2008

Exotic phases induced by strong spin-orbit coupling in ordered double perovskites
journal, November 2010

Magnetism and spin-orbit coupling in Ir-based double perovskites La $_{2 - x}$ Sr $_{x}$ CoIrO $_{6}$
journal, June 2012

Stabilization of ferromagnetic ordering in cobaltite double perovskites of La ₂ CoIrO ₆ and La ₂ CoPtO ₆
journal, August 2015

Temperature and composition dependence of crystal structures and magnetic and electronic properties of the double perovskites ${La}_{2 - x} {Sr}_{x} {CoIrO}_{6}$ $(0 \leq x \leq 2)$
journal, July 2010

Reentrant spin glass behavior and magnetodielectric coupling of an Ir-based double perovskite compound, La ₂ CoIrO ₆
journal, January 2017

Combined texture and structure analysis of deformed limestone from time-of-flight neutron diffraction spectra
journal, January 1997

Crystal growth, structure and magnetic properties of the double perovskites Ln2MgIrO6 (Ln=Pr, Nd, Sm–Gd)
journal, February 2010

The Structures of Tb7O12 and Tb11O20
journal, May 1993

Crystal Structure and Magnetic Properties of Tb ₁₁ O ₂₀
journal, January 2013

Paramagnetic and Nuclear Scattering Cross Sections of Holmium Sesquioxide
journal, April 1958

Large reversible magnetocaloric effect in antiferromagnetic Ho2O3 powders
journal, October 2017

Van Vleck paramagnetism of the trivalent Eu ions
journal, November 2010

Van Vleck paramagnetism of europium oxyhydroxide
journal, February 2015

Multiferroic behavior in the double-perovskite Lu $_{2}$ MnCoO $_{6}$
journal, October 2011

Magnetoelectric and structural properties of $Y_{2} CoMn O_{6}$ : The role of antisite defects
journal, June 2016

Metamagnetism and Critical Fluctuations in High Quality Single Crystals of the Bilayer Ruthenate ${Sr}_{3} {Ru}_{2} O_{7}$
journal, March 2001

Nature of Spin-Reorientation Transitions
journal, April 1968

Review of magnetocaloric effect in perovskite-type oxides
journal, May 2013

The Structure and Magnetic Properties of La2MLrO6 with M = Mg, Co, Ni, and Zn
journal, April 1995

Physical properties of disordered double-perovskite Ca2−xLaxFeIrO6
journal, April 2008

XANES and EXAFS Studies on the Ir-O Bond Covalency in Ionic Iridium Perovskites
journal, August 1995

Crystal structures and magnetic properties of ordered perovskites A2R3+Ir5+O6 (A=Sr, Ba; R=Sc, Y, La, Lu)
journal, June 1999

Iridium double perovskite ${Sr}_{2} {YIrO}_{6}$ : A combined structural and specific heat study
journal, February 2017

The Role of Oxygen Stoichiometry on Phase Stability, Structure, and Magnetic Properties of Sr ₂ CoIrO _6−δ
journal, November 2010

A Family of One-Dimensional Oxides: Sr3MlrO6 (M = Ni, Cu, Zn): Structure and Magnetic Properties
journal, July 1995

Double Perovskites with Ferromagnetism Above Room Temperature
journal, June 2007

Rare earth double perovskites: a fertile soil in the field of perovskite oxides
journal, January 2019