Impact of Sn substitution on the structure and magnetism of
Abstract
Here, the magnetic behavior of Sn-substituted Sr2IrO4 has been examined through magnetization measurements and single-crystal neutron diffraction on Sr2Ir1-xSnxO4 for 0.05≲x≲0.35. For all x examined, the magnetic ground state is similar to that induced in Sr2IrO4 by application of a magnetic field. This magnetic state is characterized by a small net moment due to the alignment of canted moments within an otherwise antiferromagnetic structure. The weak ferromagnetic behavior is observed in the magnetization data for both unique crystallographic orientations. Diffraction data reveal an anisotropic response in the lattice parameters, with an overall lattice expansion, as well as a small reduction in the rotation of the IrO6 octahedra. Lastly, the magnetic ordering temperature is continually suppressed with increasing x, and long-range magnetic order persists to the highest Sn concentrations synthesized.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1490606
- Alternate Identifier(s):
- OSTI ID: 1471152
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Materials
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 9; Journal ID: ISSN 2475-9953
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
May, Andrew F., Cao, Huibo, and Calder, Stuart A. Impact of Sn substitution on the structure and magnetism of Sr2IrO4. United States: N. p., 2018.
Web. doi:10.1103/PhysRevMaterials.2.094406.
May, Andrew F., Cao, Huibo, & Calder, Stuart A. Impact of Sn substitution on the structure and magnetism of Sr2IrO4. United States. https://doi.org/10.1103/PhysRevMaterials.2.094406
May, Andrew F., Cao, Huibo, and Calder, Stuart A. Mon .
"Impact of Sn substitution on the structure and magnetism of Sr2IrO4". United States. https://doi.org/10.1103/PhysRevMaterials.2.094406. https://www.osti.gov/servlets/purl/1490606.
@article{osti_1490606,
title = {Impact of Sn substitution on the structure and magnetism of Sr2IrO4},
author = {May, Andrew F. and Cao, Huibo and Calder, Stuart A.},
abstractNote = {Here, the magnetic behavior of Sn-substituted Sr2IrO4 has been examined through magnetization measurements and single-crystal neutron diffraction on Sr2Ir1-xSnxO4 for 0.05≲x≲0.35. For all x examined, the magnetic ground state is similar to that induced in Sr2IrO4 by application of a magnetic field. This magnetic state is characterized by a small net moment due to the alignment of canted moments within an otherwise antiferromagnetic structure. The weak ferromagnetic behavior is observed in the magnetization data for both unique crystallographic orientations. Diffraction data reveal an anisotropic response in the lattice parameters, with an overall lattice expansion, as well as a small reduction in the rotation of the IrO6 octahedra. Lastly, the magnetic ordering temperature is continually suppressed with increasing x, and long-range magnetic order persists to the highest Sn concentrations synthesized.},
doi = {10.1103/PhysRevMaterials.2.094406},
journal = {Physical Review Materials},
number = 9,
volume = 2,
place = {United States},
year = {Mon Sep 17 00:00:00 EDT 2018},
month = {Mon Sep 17 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Magnetic phase diagram of synthesized by mechanical alloying
journal, February 2018
- Horigane, K.; Fujii, M.; Okabe, H.
- Physical Review B, Vol. 97, Issue 6
Spin-orbit tuned metal-insulator transitions in single-crystal Sr Ir Rh O ( )
journal, September 2012
- Qi, T. F.; Korneta, O. B.; Li, L.
- Physical Review B, Vol. 86, Issue 12
Structural and magnetic studies of
journal, April 1994
- Crawford, M. K.; Subramanian, M. A.; Harlow, R. L.
- Physical Review B, Vol. 49, Issue 13
Neutron scattering study of correlated phase behavior in Sr IrO
journal, April 2013
- Dhital, Chetan; Hogan, Tom; Yamani, Z.
- Physical Review B, Vol. 87, Issue 14
Decoupling of the antiferromagnetic and insulating states in Tb-doped
journal, December 2015
- Wang, J. C.; Aswartham, S.; Ye, Feng
- Physical Review B, Vol. 92, Issue 21
Magnetic and crystal structures of : A neutron diffraction study
journal, April 2013
- Ye, Feng; Chi, Songxue; Chakoumakos, Bryan C.
- Physical Review B, Vol. 87, Issue 14
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Disruption of antiferromagnetic order in Zn-doped La2CuO4
journal, September 1991
- Lichti, R. L.; Boekema, C.; Lam, J. C.
- Physica C: Superconductivity, Vol. 180, Issue 5-6
Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993
- Rodríguez-Carvajal, Juan
- Physica B: Condensed Matter, Vol. 192, Issue 1-2
Structure, magnetism, and transport properties for Ca doping in Sr 2 IrO 4
journal, May 2017
- Zhou, Guotai; Gu, Xiaomin; Yang, Xingming
- AIP Advances, Vol. 7, Issue 5
Structural Distortion-Induced Magnetoelastic Locking in Revealed through Nonlinear Optical Harmonic Generation
journal, March 2015
- Torchinsky, D. H.; Chu, H.; Zhao, L.
- Physical Review Letters, Vol. 114, Issue 9
Efficient Monte Carlo Algorithm and High-Precision Results for Percolation
journal, November 2000
- Newman, M. E. J.; Ziff, R. M.
- Physical Review Letters, Vol. 85, Issue 19
Crystal growth and intrinsic magnetic behaviour of Sr 2 IrO 4
journal, January 2016
- Sung, N. H.; Gretarsson, H.; Proepper, D.
- Philosophical Magazine, Vol. 96, Issue 4
Anisotropic magnetic couplings and structure-driven canted to collinear transitions in by magnetically constrained noncollinear DFT
journal, August 2015
- Liu, Peitao; Khmelevskyi, Sergii; Kim, Bongjae
- Physical Review B, Vol. 92, Issue 5
Near room-temperature formation of a skyrmion crystal in thin-films of the helimagnet FeGe
journal, December 2010
- Yu, X. Z.; Kanazawa, N.; Onose, Y.
- Nature Materials, Vol. 10, Issue 2
Phase-Sensitive Observation of a Spin-Orbital Mott State in Sr2IrO4
journal, March 2009
- Kim, B. J.; Ohsumi, H.; Komesu, T.
- Science, Vol. 323, Issue 5919
Giant magnetoelectric effect in the Mott insulator
journal, October 2009
- Chikara, S.; Korneta, O.; Crummett, W. P.
- Physical Review B, Vol. 80, Issue 14
Dimensionality-Controlled Insulator-Metal Transition and Correlated Metallic State in Transition Metal Oxides ( , 2, and )
journal, November 2008
- Moon, S. J.; Jin, H.; Kim, K. W.
- Physical Review Letters, Vol. 101, Issue 22
Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling
journal, October 2016
- Cui, Q.; Cheng, J. -G.; Fan, W.
- Physical Review Letters, Vol. 117, Issue 17
Evolution of competing magnetic order in the insulating state of
journal, October 2015
- Calder, S.; Kim, J. W.; Cao, G. -X.
- Physical Review B, Vol. 92, Issue 16
Dilute magnetism and spin-orbital percolation effects in
journal, February 2014
- Clancy, J. P.; Lupascu, A.; Gretarsson, H.
- Physical Review B, Vol. 89, Issue 5
Magnetic structural change of Sr IrO upon Mn doping
journal, December 2012
- Calder, S.; Cao, G. -X.; Lumsden, M. D.
- Physical Review B, Vol. 86, Issue 22
Neutron powder diffraction study of phase transitions in Sr2SnO4
journal, November 2004
- Fu, W. T.; Visser, D.; Knight, K. S.
- Journal of Solid State Chemistry, Vol. 177, Issue 11
Influence of electron doping on the ground state of
journal, August 2015
- Chen, Xiang; Hogan, Tom; Walkup, D.
- Physical Review B, Vol. 92, Issue 7
Locking of iridium magnetic moments to the correlated rotation of oxygen octahedra in Sr 2 IrO 4 revealed by x-ray resonant scattering
journal, September 2013
- Boseggia, S.; Walker, H. C.; Vale, J.
- Journal of Physics: Condensed Matter, Vol. 25, Issue 42
Monte Carlo Study of an Unconventional Superconducting Phase in Iridium Oxide Mott Insulators Induced by Carrier Doping
journal, January 2013
- Watanabe, Hiroshi; Shirakawa, Tomonori; Yunoki, Seiji
- Physical Review Letters, Vol. 110, Issue 2
Pressure Tuning of the Spin-Orbit Coupled Ground State in
journal, July 2012
- Haskel, D.; Fabbris, G.; Zhernenkov, Mikhail
- Physical Review Letters, Vol. 109, Issue 2
Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models
journal, January 2009
- Jackeli, G.; Khaliullin, G.
- Physical Review Letters, Vol. 102, Issue 1
Enhanced electrical conductivity and diluted Ir 4+ spin orders in electron doped iridates Sr 2– x Ga x IrO 4
journal, November 2016
- Han, Tao; Wang, Yongjian; Yang, Jun
- Applied Physics Letters, Vol. 109, Issue 19
Works referencing / citing this record:
The J eff = 1/2 Antiferromagnet Sr 2 IrO 4 : A Golden Avenue toward New Physics and Functions
journal, October 2019
- Lu, Chengliang; Liu, Jun‐Ming
- Advanced Materials
The Jeff=1/2 antiferromagnet Sr2IrO4: A golden avenue toward new physics and functions
text, January 2021
- Lu, Chengliang; Liu, Jun-Ming
- arXiv