Thermally Responsive Hyperbranched Poly(ionic liquid)s: Assembly and Phase Transformations
Abstract
Here, a library of linear and branched amphiphilic poly(ionic liquid)s based on hydrophobic cores and peripheral thermally sensitive shells was synthesized and studied with regard to their ability to form stimuli-responsive, organized assemblies in aqueous media. The thermally responsive derivatives of poly(ionic liquid)s were synthesized by neutralizing 32 terminal carboxyl groups of functionalized polyester cores by amine-terminated poly(N-isopropylacrylamide)s (PNIPAM) (50% and 100%). We observed that these hyperbranched poly(ionic liquid)s possessed a narrow low critical solution transition (LCST) window with LCST for hyperbranched compounds being consistently lower than that for linear PNIPAM containing counterparts. We found that the poly(ionic liquid)s form spherical micellar assemblies with diverse morphologies, such as micelles and their aggregates, depending on the terminal compositions with reduced sizes for hyperbranched poly(ionic liquid)s. Increasing temperature above LCST promoted formation of network-like aggregates, large vesicles, and spherical micelles. Moreover, all PNIPAM-terminated compounds exhibited distinct unimolecular prolate nanodomain morphology in contrast to common spherical domains of initial cores. We proposed a multilength scale organized morphology to describe the thermoresponsive poly(ionic liquid)s micellar assemblies and discussed their morphological transformations during phase transitions associated with changes in hydrophobic–hydrophilic balance of poly(ionic liquid)s with distinct hydrophobic cores and variable peripheral shells.
- Authors:
-
[3];
[1]
- Georgia Inst. of Technology, Atlanta, GA (United States)
- National Academy of Sciences of Ukraine, Kyiv (Ukraine)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Taras Shevchenko National University of Kyiv, Kyiv (Ukraine)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1484126
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Macromolecules
- Additional Journal Information:
- Journal Volume: 51; Journal Issue: 13; Journal ID: ISSN 0024-9297
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; hyperbranched poly(ionic liquid)s; grafted PNIPAM macrocations; reversible micellar assembly; LCST thermal response
Citation Formats
Korolovych, Volodymyr F., Erwin, Andrew, Stryutsky, Alexandr, Lee, Hansol, Heller, William T., Shevchenko, Valery V., Bulavin, Leonid A., and Tsukruk, Vladimir V. Thermally Responsive Hyperbranched Poly(ionic liquid)s: Assembly and Phase Transformations. United States: N. p., 2018.
Web. doi:10.1021/acs.macromol.8b00845.
Korolovych, Volodymyr F., Erwin, Andrew, Stryutsky, Alexandr, Lee, Hansol, Heller, William T., Shevchenko, Valery V., Bulavin, Leonid A., & Tsukruk, Vladimir V. Thermally Responsive Hyperbranched Poly(ionic liquid)s: Assembly and Phase Transformations. United States. https://doi.org/10.1021/acs.macromol.8b00845
Korolovych, Volodymyr F., Erwin, Andrew, Stryutsky, Alexandr, Lee, Hansol, Heller, William T., Shevchenko, Valery V., Bulavin, Leonid A., and Tsukruk, Vladimir V. Mon .
"Thermally Responsive Hyperbranched Poly(ionic liquid)s: Assembly and Phase Transformations". United States. https://doi.org/10.1021/acs.macromol.8b00845. https://www.osti.gov/servlets/purl/1484126.
@article{osti_1484126,
title = {Thermally Responsive Hyperbranched Poly(ionic liquid)s: Assembly and Phase Transformations},
author = {Korolovych, Volodymyr F. and Erwin, Andrew and Stryutsky, Alexandr and Lee, Hansol and Heller, William T. and Shevchenko, Valery V. and Bulavin, Leonid A. and Tsukruk, Vladimir V.},
abstractNote = {Here, a library of linear and branched amphiphilic poly(ionic liquid)s based on hydrophobic cores and peripheral thermally sensitive shells was synthesized and studied with regard to their ability to form stimuli-responsive, organized assemblies in aqueous media. The thermally responsive derivatives of poly(ionic liquid)s were synthesized by neutralizing 32 terminal carboxyl groups of functionalized polyester cores by amine-terminated poly(N-isopropylacrylamide)s (PNIPAM) (50% and 100%). We observed that these hyperbranched poly(ionic liquid)s possessed a narrow low critical solution transition (LCST) window with LCST for hyperbranched compounds being consistently lower than that for linear PNIPAM containing counterparts. We found that the poly(ionic liquid)s form spherical micellar assemblies with diverse morphologies, such as micelles and their aggregates, depending on the terminal compositions with reduced sizes for hyperbranched poly(ionic liquid)s. Increasing temperature above LCST promoted formation of network-like aggregates, large vesicles, and spherical micelles. Moreover, all PNIPAM-terminated compounds exhibited distinct unimolecular prolate nanodomain morphology in contrast to common spherical domains of initial cores. We proposed a multilength scale organized morphology to describe the thermoresponsive poly(ionic liquid)s micellar assemblies and discussed their morphological transformations during phase transitions associated with changes in hydrophobic–hydrophilic balance of poly(ionic liquid)s with distinct hydrophobic cores and variable peripheral shells.},
doi = {10.1021/acs.macromol.8b00845},
journal = {Macromolecules},
number = 13,
volume = 51,
place = {United States},
year = {Mon Jun 25 00:00:00 EDT 2018},
month = {Mon Jun 25 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 22 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Scheme 1: Linear and hyperbranched amphiphilic carboxylate poly(ionic liquid)s with thermally responsive PNIPAM macrocations studied in this work.
All figures and tables
(15 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ionic Liquids in Polymer Design
journal, July 2016
- Long, Timothy E.; Elabd, Yossef A.; Yuan, Jiayin
- Macromolecular Rapid Communications, Vol. 37, Issue 14
Poly(ionic liquid)s: An update
journal, July 2013
- Yuan, Jiayin; Mecerreyes, David; Antonietti, Markus
- Progress in Polymer Science, Vol. 38, Issue 7
Frontiers in poly(ionic liquid)s: syntheses and applications
journal, January 2017
- Qian, Wenjing; Texter, John; Yan, Feng
- Chemical Society Reviews, Vol. 46, Issue 4
Architecture, Assembly, and Emerging Applications of Branched Functional Polyelectrolytes and Poly(ionic liquid)s
journal, March 2015
- Xu, Weinan; Ledin, Petr A.; Shevchenko, Valery V.
- ACS Applied Materials & Interfaces, Vol. 7, Issue 23
Redox-active poly(ionic liquid)s as active materials for energy storage applications
journal, January 2017
- Hernández, G.; Işik, M.; Mantione, D.
- Journal of Materials Chemistry A, Vol. 5, Issue 31
Synthesis and self-assembly of temperature and anion double responsive ionic liquid block copolymers
journal, June 2015
- Liang, Ju; Wu, Wenlan; Li, Junbo
- Frontiers of Materials Science, Vol. 9, Issue 3
Polymeric Vesicles and Micelles Obtained by Self-Assembly of Ionic Liquid-Based Block Copolymers Triggered by Anion or Solvent Exchange
journal, July 2009
- Vijayakrishna, Kari; Mecerreyes, David; Gnanou, Yves
- Macromolecules, Vol. 42, Issue 14
Synthesis by RAFT and Ionic Responsiveness of Double Hydrophilic Block Copolymers Based on Ionic Liquid Monomer Units
journal, September 2008
- Vijayakrishna, Kari; Jewrajka, Suresh K.; Ruiz, Alaitz
- Macromolecules, Vol. 41, Issue 17
Internal Morphology-Controllable Self-Assembly in Poly(Ionic Liquid) Nanoparticles
journal, July 2016
- Zhang, Weiyi; Kochovski, Zdravko; Lu, Yan
- ACS Nano, Vol. 10, Issue 8
Crosslinked 1,2,4-triazolium-type poly(ionic liquid) nanoparticles
journal, December 2016
- Zhang, Weiyi; Kochovski, Zdravko; Schmidt, Bernhard V. K. J.
- Polymer, Vol. 107
Self-Assembly of Poly(ionic liquid)s: Polymerization, Mesostructure Formation, and Directional Alignment in One Step
journal, November 2011
- Yuan, Jiayin; Soll, Sebastian; Drechsler, Markus
- Journal of the American Chemical Society, Vol. 133, Issue 44
Protic Ionic Liquids: Evolving Structure–Property Relationships and Expanding Applications
journal, September 2015
- Greaves, Tamar L.; Drummond, Calum J.
- Chemical Reviews, Vol. 115, Issue 20
Functional dendrimers, hyperbranched and star polymers
journal, May 2000
- Inoue, K.
- Progress in Polymer Science, Vol. 25, Issue 4
Hyperbranched polymers: advances from synthesis to applications
journal, January 2015
- Zheng, Yaochen; Li, Sipei; Weng, Zhulin
- Chemical Society Reviews, Vol. 44, Issue 12
Dramatic toughness enhancement of benzoxazine/epoxy thermosets with a novel hyperbranched polymeric ionic liquid
journal, February 2018
- Chen, Shiyuan; Zhang, Junheng; Zhou, Jiliang
- Chemical Engineering Journal, Vol. 334
Preparation of anion-exchangeable polymer vesicles through the self-assembly of hyperbranched polymeric ionic liquids
journal, January 2015
- Fan, Yujiao; Zhang, Dapeng; Wang, Jie
- Chemical Communications, Vol. 51, Issue 33
Synthesis and application of long-chain alkyl quaternary ammonium-functionalized hyperbranched polyester
journal, March 2011
- Du, Yingying; Chen, Qianlan; Shen, Li
- Journal of Applied Polymer Science, Vol. 121, Issue 5
Nanoarchitectonics for Advanced Materials: Strategy Beyond Nanotechnology
journal, February 2016
- Ariga, Katsuhiko; Li, Junbai
- Advanced Materials, Vol. 28, Issue 6
Cationic Poly(ionic liquid) with Tunable Lower Critical Solution Temperature-Type Phase Transition
journal, April 2013
- Men, Yongjun; Schlaad, Helmut; Yuan, Jiayin
- ACS Macro Letters, Vol. 2, Issue 5
Thermal Switching of Thermoresponsive Polymer Aqueous Solutions
journal, December 2017
- Li, Chen; Ma, Yunwei; Tian, Zhiting
- ACS Macro Letters, Vol. 7, Issue 1
Block Copolymer Micelle Shuttles with Tunable Transfer Temperatures between Ionic Liquids and Aqueous Solutions
journal, April 2008
- Bai, Zhifeng; He, Yiyong; Lodge, Timothy P.
- Langmuir, Vol. 24, Issue 10
Self-Assembly of Hyperbranched Protic Poly(ionic liquid)s with Variable Peripheral Amphiphilicity
journal, August 2017
- Korolovych, Volodymyr F.; Erwin, Andrew J.; Stryutsky, Alexandr
- Bulletin of the Chemical Society of Japan, Vol. 90, Issue 8
Assembly of Amphiphilic Hyperbranched Polymeric Ionic Liquids in Aqueous Media at Different pH and Ionic Strength
journal, November 2016
- Korolovych, Volodymyr F.; Ledin, Petr A.; Stryutsky, Alexandr
- Macromolecules, Vol. 49, Issue 22
Synthesis and applications of stimuli-responsive hyperbranched polymers
journal, January 2017
- Wang, Dali; Jin, Yue; Zhu, Xinyuan
- Progress in Polymer Science, Vol. 64
Hyperbranched Polymeric Ionic Liquids with Onion-like Topology as Transporters and Compartmentalized Systems
journal, November 2012
- Schüler, Fabian; Kerscher, Benjamin; Beckert, Fabian
- Angewandte Chemie International Edition, Vol. 52, Issue 1
Synthesis and ionic conductivity of a novel ionic liquid polymer electrolyte
journal, January 2014
- Zheng, Tao; Ren, Shitong; Zhou, Qian
- Journal of Polymer Research, Vol. 21, Issue 2
Hydrophobic Brønsted Acid−Base Ionic Liquids Based on PAMAM Dendrimers with High Proton Conductivity and Blue Photoluminescence
journal, September 2005
- Huang, Jing-Fang; Luo, Huimin; Liang, Chengdu
- Journal of the American Chemical Society, Vol. 127, Issue 37
Amphoteric hyperbranched polymers with multistimuli-responsive behavior in the application of polymer flooding
journal, January 2015
- Pu, Wan-Fen; Liu, Rui; Li, Bin
- RSC Advances, Vol. 5, Issue 107
Supercapacitor devices for energy storage and capacitive dye removal from aqueous solutions
journal, January 2015
- Shi, Kaiyuan; Zhitomirsky, Igor
- RSC Advances, Vol. 5, Issue 1
Template-Guided Assembly of Silk Fibroin on Cellulose Nanofibers for Robust Nanostructures with Ultrafast Water Transport
journal, October 2016
- Xiong, Rui; Kim, Ho Shin; Zhang, Shuaidi
- ACS Nano, Vol. 11, Issue 12
The extended Q -range small-angle neutron scattering diffractometer at the SNS
journal, July 2010
- Zhao, J. K.; Gao, C. Y.; Liu, D.
- Journal of Applied Crystallography, Vol. 43, Issue 5
Mantid—Data analysis and visualization package for neutron scattering and SR experiments
journal, November 2014
- Arnold, O.; Bilheux, J. C.; Borreguero, J. M.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 764
Thermo-Induced Limited Aggregation of Responsive Star Polyelectrolytes
journal, March 2014
- Xu, Weinan; Choi, Ikjun; Plamper, Felix A.
- Macromolecules, Vol. 47, Issue 6
Real-Time Observation of Bimodal Proton Transfer in Acid-Base Pairs in Water
journal, July 2003
- Rini, M.
- Science, Vol. 301, Issue 5631
Correlation of the Base Strengths of Amines 1
journal, October 1957
- Hall, H. K.
- Journal of the American Chemical Society, Vol. 79, Issue 20
Thermal properties of hyperbranched polyesters
journal, April 2017
- Dumitrascu, Adina; Sarkar, Abhijit; Chai, Jianfang
- Journal of Thermal Analysis and Calorimetry, Vol. 131, Issue 1
Study of the chain microstructure effects on the resulting thermal properties of poly(l-lactide)/poly(N-isopropylacrylamide) biomedical materials
journal, May 2015
- Lizundia, E.; Meaurio, E.; Laza, J. M.
- Materials Science and Engineering: C, Vol. 50
A novel amphiphilic copolymer poly(ethylene oxide-co-allyl glycidyl ether)-graft-poly(ε-caprolactone): synthesis, self-assembly, and protein encapsulation behavior
journal, January 2012
- Li, Bin; Chen, Gao; Meng, Fanbo
- Polymer Chemistry, Vol. 3, Issue 9
Fabrication of AIE-active amphiphilic fluorescent polymeric nanoparticles through host–guest interaction
journal, January 2016
- Chen, Junyu; Luo, Songsong; Xu, Dazhuang
- RSC Advances, Vol. 6, Issue 60
Self-Assembly of Hyperbranched Polymers and Its Biomedical Applications
journal, September 2010
- Zhou, Yongfeng; Huang, Wei; Liu, Jinyao
- Advanced Materials, Vol. 22, Issue 41
Self-assembly and disassembly of a redox-responsive ferrocene-containing amphiphilic block copolymer for controlled release
journal, January 2015
- Liu, Lichao; Rui, Leilei; Gao, Yun
- Polymer Chemistry, Vol. 6, Issue 10
Temperature-Sensitive Properties of Poly( N -isopropylacrylamide) Mesoglobules Formed in Dilute Aqueous Solutions Heated above Their Demixing Point
journal, October 2006
- Kujawa, Piotr; Aseyev, Vladimir; Tenhu, Heikki
- Macromolecules, Vol. 39, Issue 22
A Neutron Scattering Study of the Structure and Water Partitioning of Selectively Deuterated Copolymer Micelles
journal, October 2004
- Stancik, Cheryl M.; Lavoie, Adrien R.; Achurra, Paulina A.
- Langmuir, Vol. 20, Issue 21
Self-assembly of amphiphilic random co-poly(ionic liquid)s: the effect of anions, molecular weight, and molecular weight distribution
journal, January 2013
- Guo, Jiangna; Zhou, Yinxia; Qiu, Lihua
- Polymer Chemistry, Vol. 4, Issue 14
RAFT Polymerization of N -Vinylimidazolium Salts and Synthesis of Thermoresponsive Ionic Liquid Block Copolymers
journal, November 2009
- Mori, Hideharu; Yahagi, Masahito; Endo, Takeshi
- Macromolecules, Vol. 42, Issue 21
LCST Behavior of Symmetrical PNiPAm- b -PEtOx- b -PNiPAm Triblock Copolymers
journal, September 2016
- Sahn, Martin; Yildirim, Turgay; Dirauf, Michael
- Macromolecules, Vol. 49, Issue 19
Study of Cationic N -Isopropylacrylamide−Styrene Copolymer Latex Particles Using Fluorescent Probes
journal, September 1999
- Castanheira, E. M. S.; Martinho, J. M. G.; Duracher, D.
- Langmuir, Vol. 15, Issue 20
Structural analysis of dendrimers based on polyhedral oligomeric silsesquioxane and their assemblies in solution by small-angle neutron scattering: Fits to a modified two correlation lengths model
journal, September 2016
- Yuan, Guangcui; Wang, Xing; Wu, Decheng
- Polymer, Vol. 100
Structural aspects of the LCST phase behavior of poly(benzyl methacrylate) in room-temperature ionic liquid
journal, March 2011
- Fujii, Kenta; Ueki, Takeshi; Niitsuma, Kazuyuki
- Polymer, Vol. 52, Issue 7
Small-angle scattering from porous solids with fractal geometry
journal, August 1986
- Mildner, D. F. R.; Hall, P. L.
- Journal of Physics D: Applied Physics, Vol. 19, Issue 8
Thermoresponsive aggregation of PS–PNIPAM–PS triblock copolymer: A combined study of light scattering and small angle neutron scattering
journal, July 2014
- Papagiannopoulos, Aristeidis; Zhao, Junpeng; Zhang, Guangzhao
- European Polymer Journal, Vol. 56
Understanding inelastically scattered neutrons from water on a time-of-flight small-angle neutron scattering (SANS) instrument
journal, February 2014
- Do, Changwoo; Heller, William T.; Stanley, Christopher
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 737
Interaction and Conformation of Aqueous Poly( N -isopropylacrylamide) (PNIPAM) Star Polymers below the LCST
journal, February 2017
- Lang, Xiaolong; Lenart, William R.; Sun, Jessie E. P.
- Macromolecules, Vol. 50, Issue 5
Controlling the Intermediate Structure of an Ionic Liquid for f-Block Element Separations
journal, April 2017
- Abney, Carter W.; Do, Changwoo; Luo, Huimin
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 9
Structure Analysis by Small-Angle X-Ray and Neutron Scattering
book, January 1987
- Feigin, L. A.; Svergun, D. I.
Thermodynamic Description of the LCST of Charged Thermoresponsive Copolymers
journal, March 2014
- Heyda, Jan; Soll, Sebastian; Yuan, Jiayin
- Macromolecules, Vol. 47, Issue 6
Effects of Hofmeister Anions on the LCST of PNIPAM as a Function of Molecular Weight †
journal, June 2007
- Zhang, Yanjie; Furyk, Steven; Sagle, Laura B.
- The Journal of Physical Chemistry C, Vol. 111, Issue 25
Double hydrophilic diblock copolymers containing a poly(ionic liquid) segment: Controlled synthesis, solution property, and application as carbon precursor
journal, April 2011
- Yuan, Jiayin; Schlaad, Helmut; Giordano, Cristina
- European Polymer Journal, Vol. 47, Issue 4
Tunable LCST behavior of poly(N-isopropylacrylamide/ionic liquid) copolymers
journal, January 2015
- Jain, Kamiya; Vedarajan, Raman; Watanabe, Masaki
- Polymer Chemistry, Vol. 6, Issue 38
Enhanced Optical Sensitivity in Thermoresponsive Photonic Crystal Hydrogels by Operating Near the Phase Transition
journal, August 2017
- Jung, Sukwon; MacConaghy, Kelsey I.; Kaar, Joel L.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 33
Effect of Micellization on the Thermoresponsive Behavior of Polymeric Assemblies
journal, October 2015
- Blackman, Lewis D.; Wright, Daniel B.; Robin, Mathew P.
- ACS Macro Letters, Vol. 4, Issue 11
Diblock copolymers consisting of a polymerized ionic liquid and poly(N-isopropylacrylamide). Effects of PNIPAM block length and counter ion on self-assembling and thermal properties
journal, January 2013
- Karjalainen, Erno; Chenna, Naveen; Laurinmäki, Pasi
- Polym. Chem., Vol. 4, Issue 4
Self-assembly of polymeric micelles into complex but regular superstructures based on highly controllable core–core fusion between the micelles
journal, January 2016
- Wang, Liangyan; Wang, Yafen; Miao, Han
- Soft Matter, Vol. 12, Issue 22
Supramolecular Self-Assembly of Giant Polymer Vesicles with Controlled Sizes
journal, September 2004
- Zhou, Yongfeng; Yan, Deyue
- Angewandte Chemie International Edition, Vol. 43, Issue 37
Facile Fabrication of pH-Responsive and Size-Controllable Polymer Vesicles From a Commercially Available Hyperbranched Polyester
journal, March 2008
- Shi, Zengqian; Zhou, Yongfeng; Yan, Deyue
- Macromolecular Rapid Communications, Vol. 29, Issue 5
Polymer vesicles: Mechanism, preparation, application, and responsive behavior
journal, January 2017
- Zhu, Yunqing; Yang, Bo; Chen, Shuai
- Progress in Polymer Science, Vol. 64
Influence of PIL segment on solution properties of poly(N-isopropylacrylamide)-b-poly(ionic liquid) copolymer: micelles, thermal phase behavior and microdynamics
journal, January 2012
- Wang, Zhangwei; Lai, Hengjie; Wu, Peiyi
- Soft Matter, Vol. 8, Issue 46
Double Stimuli-Responsive Copolymer Stabilizers for Multiwalled Carbon Nanotubes
journal, November 2011
- Soll, Sebastian; Antonietti, Markus; Yuan, Jiayin
- ACS Macro Letters, Vol. 1, Issue 1
Two-Stage Collapse of Unimolecular Micelles with Double Thermoresponsive Coronas
journal, January 2006
- Xu, Jian; Luo, Shizhong; Shi, Wenfang
- Langmuir, Vol. 22, Issue 3
Unusual thermal phase transition behavior of an ionic liquid and poly(ionic liquid) in water with significantly different LCST and dynamic mechanism
journal, January 2014
- Li, Wenlong; Wu, Peiyi
- Polymer Chemistry, Vol. 5, Issue 19
Thermoresponsive polyelectrolytes derived from ionic liquids
journal, January 2015
- Kohno, Yuki; Saita, Shohei; Men, Yongjun
- Polymer Chemistry, Vol. 6, Issue 12
CO 2 /N 2 -Switchable Thermoresponsive Ionic Liquid Copolymer
journal, October 2017
- Zhou, Yin-Ning; Lei, Lei; Luo, Zheng-Hong
- Macromolecules, Vol. 50, Issue 21
Theory of Linear–Dendritic Block Copolymer Micelles
journal, December 2017
- Lebedeva, Inna O.; Zhulina, Ekaterina B.; Borisov, Oleg V.
- ACS Macro Letters, Vol. 7, Issue 1
Study of the Polymer Length Dependence of the Single Chain Transition Temperature in Syndiotactic Poly( N -isopropylacrylamide) Oligomers in Water
journal, July 2012
- Tucker, Ashley K.; Stevens, Mark J.
- Macromolecules, Vol. 45, Issue 16
Works referencing / citing this record:
Hyperbranched poly(ionic liquid) functionalized poly(ether sulfone) membranes as healable antifouling coatings for osmotic power generation
journal, January 2019
- Li, Jia Le; Zhang, Yu; Zhang, Sui
- Journal of Materials Chemistry A, Vol. 7, Issue 14
Toxicity of C60 fullerene–cisplatin nanocomplex against Lewis lung carcinoma cells
journal, April 2019
- Prylutska, Svitlana; Grynyuk, Iryna; Skaterna, Tetiana
- Archives of Toxicology, Vol. 93, Issue 5
A polyelectrolyte-containing copolymer with a gas-switchable lower critical solution temperature-type phase transition
journal, January 2019
- Li, Jin-Jin; Zhou, Yin-Ning; Luo, Zheng-Hong
- Polymer Chemistry, Vol. 10, Issue 2
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.