Reaction Kinetics of Mixed CuO–Fe2O3 with Methane as Oxygen Carriers for Chemical Looping Combustion
Abstract
Reduction kinetics of alumina supported mixed Cu–ferrite oxide by methane was investigated for chemical looping combustion by the thermogravimetric analyzer (TGA) in the temperature range of 750–900 °C using continuous streams of 10%, 20%, and 30% CH4 concentrations balanced by helium. The rate of reduction was determined by weight change. The variations of activation energies and n values (JMA exponent) during the reduction conversion indicate that the methane combustion with CuO and Fe2O3 proceeds via a multistage reaction process. A kinetic model based on three parallel reactions was applied to the reduction data. In conclusion, the analysis of reduction showed that three reduction steps proceed simultaneously with the activation energies of 55.32 ± 3.11, 70.0 ± 2.0, and 165.0 ± 5.4 kJ/mol, respectively.
- Authors:
-
- National Energy Technology Lab. (NETL), Morgantown, WV (United States); REM Engineering Services, PLLC, Morgantown, WV (United States)
- National Energy Technology Lab. (NETL), Morgantown, WV (United States)
- West Virginia Univ., Morgantown, WV (United States)
- Publication Date:
- Research Org.:
- National Energy Technology Lab. (NETL), Morgantown, WV (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1483264
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Industrial and Engineering Chemistry Research
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 48; Journal ID: ISSN 0888-5885
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Monazam, Esmail R., Breault, Ronald W., Tian, Hanjing, and Siriwardane, Ranjani. Reaction Kinetics of Mixed CuO–Fe2O3 with Methane as Oxygen Carriers for Chemical Looping Combustion. United States: N. p., 2015.
Web. doi:10.1021/acs.iecr.5b02848.
Monazam, Esmail R., Breault, Ronald W., Tian, Hanjing, & Siriwardane, Ranjani. Reaction Kinetics of Mixed CuO–Fe2O3 with Methane as Oxygen Carriers for Chemical Looping Combustion. United States. https://doi.org/10.1021/acs.iecr.5b02848
Monazam, Esmail R., Breault, Ronald W., Tian, Hanjing, and Siriwardane, Ranjani. Mon .
"Reaction Kinetics of Mixed CuO–Fe2O3 with Methane as Oxygen Carriers for Chemical Looping Combustion". United States. https://doi.org/10.1021/acs.iecr.5b02848. https://www.osti.gov/servlets/purl/1483264.
@article{osti_1483264,
title = {Reaction Kinetics of Mixed CuO–Fe2O3 with Methane as Oxygen Carriers for Chemical Looping Combustion},
author = {Monazam, Esmail R. and Breault, Ronald W. and Tian, Hanjing and Siriwardane, Ranjani},
abstractNote = {Reduction kinetics of alumina supported mixed Cu–ferrite oxide by methane was investigated for chemical looping combustion by the thermogravimetric analyzer (TGA) in the temperature range of 750–900 °C using continuous streams of 10%, 20%, and 30% CH4 concentrations balanced by helium. The rate of reduction was determined by weight change. The variations of activation energies and n values (JMA exponent) during the reduction conversion indicate that the methane combustion with CuO and Fe2O3 proceeds via a multistage reaction process. A kinetic model based on three parallel reactions was applied to the reduction data. In conclusion, the analysis of reduction showed that three reduction steps proceed simultaneously with the activation energies of 55.32 ± 3.11, 70.0 ± 2.0, and 165.0 ± 5.4 kJ/mol, respectively.},
doi = {10.1021/acs.iecr.5b02848},
journal = {Industrial and Engineering Chemistry Research},
number = 48,
volume = 54,
place = {United States},
year = {Mon Nov 16 00:00:00 EST 2015},
month = {Mon Nov 16 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
EU energy and climate change strategy
journal, April 2012
- da Graça Carvalho, Maria
- Energy, Vol. 40, Issue 1
Evaluation of a chemical-looping-combustion power-generation system by graphic exergy analysis
journal, February 1987
- Ishida, M.; Zheng, D.; Akehata, T.
- Energy, Vol. 12, Issue 2, p. 147-154
Chemical looping combustion of ultra low concentration of methane with Fe2O3/Al2O3 and CuO/SiO2
journal, January 2014
- Zhang, Yongxing; Doroodchi, Elham; Moghtaderi, Behdad
- Applied Energy, Vol. 113
Copper–Alumina Spinel Catalysts for Steam Reforming of Methanol
journal, May 1988
- Matsukata, Masahiko; Uemiya, Shigeyuki; Kikuchi, Eiichi
- Chemistry Letters, Vol. 17, Issue 5
Steam reforming of dimethyl ether over composite catalysts of γ-Al2O3 and Cu-based spinel
journal, May 2005
- Tanaka, Yohei; Kikuchi, Ryuji; Takeguchi, Tatsuya
- Applied Catalysis B: Environmental, Vol. 57, Issue 3
Effect of Carbon Deposition on the Oxidation Rate of Copper/Bentonite in the Chemical Looping Process
journal, October 2012
- Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani
- Energy & Fuels, Vol. 26, Issue 11
Ilmenite Activation during Consecutive Redox Cycles in Chemical-Looping Combustion
journal, February 2010
- Adánez, Juan; Cuadrat, Ana; Abad, Alberto
- Energy & Fuels, Vol. 24, Issue 2, p. 1402-1413
The use of iron oxide as oxygen carrier in a chemical-looping reactor
journal, May 2007
- Abad, A.; Mattisson, T.; Lyngfelt, A.
- Fuel, Vol. 86, Issue 7-8, p. 1021-1035
Effect of Pressure on the Behavior of Copper-, Iron-, and Nickel-Based Oxygen Carriers for Chemical-Looping Combustion
journal, January 2006
- García-Labiano, Francisco; Adánez, Juan; de Diego, Luis F.
- Energy & Fuels, Vol. 20, Issue 1
Kinetics of the reduction of hematite (Fe2O3) by methane (CH4) during chemical looping combustion: A global mechanism
journal, October 2013
- Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani
- Chemical Engineering Journal, Vol. 232
Thermogravimetric Analysis of Modified Hematite by Methane (CH 4 ) for Chemical-Looping Combustion: A Global Kinetics Mechanism
journal, October 2013
- Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 42
Reduction characteristics of CuFe2O4 and Fe3O4 by methane; CuFe2O4 as an oxidant for two-step thermochemical methane reforming
journal, September 2008
- Kang, Kyoung-Soo; Kim, Chang-Hee; Cho, Won-Chul
- International Journal of Hydrogen Energy, Vol. 33, Issue 17
Kinetics of the reaction in Cu-Fe and Cu-Cr mixed oxides
journal, July 1990
- El-Bellihi, A. A.; Abdel-Badei, A. M.; Diefallah, El-H. M.
- Thermochimica Acta, Vol. 165, Issue 1
Self-assembled porous nano-composite with high catalytic performance by reduction of tetragonal spinel CuFe2O4
journal, February 2010
- Kameoka, Satoshi; Tanabe, Toyokazu; Tsai, An Pang
- Applied Catalysis A: General, Vol. 375, Issue 1
Interaction of iron–copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal
journal, July 2013
- Siriwardane, Ranjani V.; Ksepko, Ewelina; Tian, Hanjing
- Applied Energy, Vol. 107
Synergetic effects of mixed copper–iron oxides oxygen carriers in chemical looping combustion
journal, June 2013
- Siriwardane, Ranjani; Tian, Hanjing; Simonyi, Thomas
- Fuel, Vol. 108
Reduction of iron oxide in carbon monoxide atmosphere—reaction controlled kinetics
journal, November 2004
- Mondal, K.; Lorethova, H.; Hippo, E.
- Fuel Processing Technology, Vol. 86, Issue 1
Kinetics of the Reduction of CuO/Bentonite by Methane (CH 4 ) during Chemical Looping Combustion
journal, December 2011
- Monazam, Esmail R.; Siriwardane, Ranjani; Breault, Ronald W.
- Energy & Fuels, Vol. 26, Issue 5
Analysis of fixed bed data for the extraction of a rate mechanism for the reaction of hematite with methane
journal, September 2015
- Breault, Ronald W.; Monazam, Esmail R.
- Journal of Industrial and Engineering Chemistry, Vol. 29
Fixed bed reduction of hematite under alternating reduction and oxidation cycles
journal, May 2015
- Breault, Ronald W.; Monazam, Esmail R.
- Applied Energy, Vol. 145
Kinetics of Hematite to Wüstite by Hydrogen for Chemical Looping Combustion
journal, July 2014
- Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani
- Energy & Fuels, Vol. 28, Issue 8
A unified approach to kinetic processing of nonisothermal data
journal, January 1996
- Vyazovkin, Sergey
- International Journal of Chemical Kinetics, Vol. 28, Issue 2
Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic
journal, January 1964
- Friedman, Henry L.
- Journal of Polymer Science Part C: Polymer Symposia, Vol. 6, Issue 1
A New Method of Analyzing Thermogravimetric Data
journal, November 1965
- Ozawa, Takeo
- Bulletin of the Chemical Society of Japan, Vol. 38, Issue 11
General treatment of the thermogravimetry of polymers
journal, November 1966
- Flynn, Joseph H.; Wall, Leo A.
- Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, Vol. 70A, Issue 6
Computational aspects of kinetic analysis.
journal, July 2000
- Roduit, B.
- Thermochimica Acta, Vol. 355, Issue 1-2
Iron oxide reduction kinetics by hydrogen
journal, January 1980
- Bessieres, J.; Bessieres, A.; Heizmann, J.
- International Journal of Hydrogen Energy, Vol. 5, Issue 6
Crystallization kinetics of polyetheretherketone (peek) matrices
journal, December 1986
- Velisaris, Chris N.; Seferis, James C.
- Polymer Engineering and Science, Vol. 26, Issue 22
The applicability of Johnson-Mehl-Avrami model in the thermal analysis of the crystallization kinetics of glasses
journal, December 1995
- Málek, Jiří
- Thermochimica Acta, Vol. 267
Works referencing / citing this record:
Chemical looping gasification of pyrolyzed biomass and coal char with copper ferrite as an oxygen carrier
journal, November 2018
- Liu, Chenlong; Wang, Wenju
- Journal of Renewable and Sustainable Energy, Vol. 10, Issue 6
Utilization of converter off-gas based on a chemical-looping combustion process
journal, April 2019
- Wu, Yongjian; Luo, Chunhuan; Zhang, Xiuli
- Energy Sources, Part A: Recovery, Utilization, and Environmental Effects
Utilization of converter off-gas based on a chemical-looping combustion process
text, January 2019
- Wu, Yongjian; Luo, Chunhuan; Zhang, Xiuli
- Taylor & Francis