All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries
Abstract
A star-shape polymer of 3-armed poly(ethylene glycol) methyl ether methacrylate-co-glycidyl methacrylate copolymer (3PPEGM-co-GMA) was synthesized using an atom transfer radical polymerization (ATRP) technique. All-solid-state interpenetrating network polymer electrolytes (INSPEs) were fabricated by simultaneous reaction of 3PPEGM-co-GMA and bisphenol A diglycidyl ether (BPDE) with polyetherdiamine (ED2003) in the presence of lithium bis(trifluoromethane) sulfonamide (LiTFSI). The INSPEs exhibited ionic conductivities higher than 10-5 S cm-1 at room temperature, a high oxidation stability of 4.5 vs. Li/Li+ and remarkable stability towards lithium metal. Li metal batteries with LiFePO4 as the cathode and INSPEs as the electrolyte cycled at a current rate of 0.1C at 60 °C showed a high initial discharge capacity of 156.2 mA h g-1 and a stable cycling performance over 200 cycles with a high coulombic efficiency of 99%. In conclusion, the results demonstrate that the interpenetrating network polymer electrolytes are promising electrolytes for next generation lithium-based batteries with high ionic conductivity, improved safety, and stable electrochemical performance.
- Authors:
-
[2];
[4]
- Nanchang Hangkong Univ., Nanchang (China). School of Environmental and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division
- Nanchang Hangkong Univ., Nanchang (China). School of Environmental and Chemical Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1462867
- Alternate Identifier(s):
- OSTI ID: 1460879
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 30; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Tong, Yongfen, Lyu, Hailong, Xu, Yuzhong, Prasad Thapaliya, Bishnu, Li, Peipei, Sun, Xiao-Guang, and Dai, Sheng. All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries. United States: N. p., 2018.
Web. doi:10.1039/C8TA03062F.
Tong, Yongfen, Lyu, Hailong, Xu, Yuzhong, Prasad Thapaliya, Bishnu, Li, Peipei, Sun, Xiao-Guang, & Dai, Sheng. All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries. United States. https://doi.org/10.1039/C8TA03062F
Tong, Yongfen, Lyu, Hailong, Xu, Yuzhong, Prasad Thapaliya, Bishnu, Li, Peipei, Sun, Xiao-Guang, and Dai, Sheng. Mon .
"All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries". United States. https://doi.org/10.1039/C8TA03062F. https://www.osti.gov/servlets/purl/1462867.
@article{osti_1462867,
title = {All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries},
author = {Tong, Yongfen and Lyu, Hailong and Xu, Yuzhong and Prasad Thapaliya, Bishnu and Li, Peipei and Sun, Xiao-Guang and Dai, Sheng},
abstractNote = {A star-shape polymer of 3-armed poly(ethylene glycol) methyl ether methacrylate-co-glycidyl methacrylate copolymer (3PPEGM-co-GMA) was synthesized using an atom transfer radical polymerization (ATRP) technique. All-solid-state interpenetrating network polymer electrolytes (INSPEs) were fabricated by simultaneous reaction of 3PPEGM-co-GMA and bisphenol A diglycidyl ether (BPDE) with polyetherdiamine (ED2003) in the presence of lithium bis(trifluoromethane) sulfonamide (LiTFSI). The INSPEs exhibited ionic conductivities higher than 10-5 S cm-1 at room temperature, a high oxidation stability of 4.5 vs. Li/Li+ and remarkable stability towards lithium metal. Li metal batteries with LiFePO4 as the cathode and INSPEs as the electrolyte cycled at a current rate of 0.1C at 60 °C showed a high initial discharge capacity of 156.2 mA h g-1 and a stable cycling performance over 200 cycles with a high coulombic efficiency of 99%. In conclusion, the results demonstrate that the interpenetrating network polymer electrolytes are promising electrolytes for next generation lithium-based batteries with high ionic conductivity, improved safety, and stable electrochemical performance.},
doi = {10.1039/C8TA03062F},
journal = {Journal of Materials Chemistry. A},
number = 30,
volume = 6,
place = {United States},
year = {Mon Jul 02 00:00:00 EDT 2018},
month = {Mon Jul 02 00:00:00 EDT 2018}
}
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