Accelerating Membrane-based CO2 Separation by Soluble Nanoporous Polymer Networks Produced by Mechanochemical Oxidative Coupling
Abstract
Achieving homogeneous dispersion of nanoporous fillers within membrane architectures remains a great challenge for mixed-matrix membrane (MMMs) technology. Imparting solution processability of nanoporous materials would help advance the development of MMMs for membrane-based gas separations. A mechanochemically assisted oxidative coupling polymerization strategy was used to create a new family of soluble nanoporous polymer networks. The solid-state ball-milling method affords inherent molecular weight control over polymer growth and therefore provides unexpected solubility for the resulting nanoporous frameworks. MMM-based CO2/CH4 separation performance was significantly accelerated by these new soluble fillers. In conclusion, we anticipate this facile method will facilitate new possibilities for the rational design and synthesis of soluble nanoporous polymer networks and promote their applications in membrane-based gas separations.
- Authors:
-
[1];
[4];
[7];
[7];
[8]
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
- Nanjing Tech Univ., Nanjing (China). State Key Lab. of Materials-Oriented Chemical Engineering Jiangsu National Synergetic Innovation Center for Advanced Materials
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
- Nanjing Tech Univ., Nanjing (China). State Key Lab. of Materials-Oriented Chemical Engineering Jiangsu National Synergetic Innovation Center for Advanced Materials
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1462862
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 57; Journal Issue: 11; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; CO2/CH4 separation; mechanochemistry; mixed-matrix membranes; oxidative coupling polymerization; soluble nanoporous polymer networks
Citation Formats
Zhu, Xiang, Hua, Yinying, Tian, Chengcheng C., Abney, Carter W., Zhang, Peng, Jin, Tian, Liu, Gongping, Browning, Katie L., Sacci, Robert L., Veith, Gabriel M., Zhou, Hong-Cai, Jin, Wanqin Q., and Dai, Sheng. Accelerating Membrane-based CO2 Separation by Soluble Nanoporous Polymer Networks Produced by Mechanochemical Oxidative Coupling. United States: N. p., 2017.
Web. doi:10.1002/anie.201710420.
Zhu, Xiang, Hua, Yinying, Tian, Chengcheng C., Abney, Carter W., Zhang, Peng, Jin, Tian, Liu, Gongping, Browning, Katie L., Sacci, Robert L., Veith, Gabriel M., Zhou, Hong-Cai, Jin, Wanqin Q., & Dai, Sheng. Accelerating Membrane-based CO2 Separation by Soluble Nanoporous Polymer Networks Produced by Mechanochemical Oxidative Coupling. United States. https://doi.org/10.1002/anie.201710420
Zhu, Xiang, Hua, Yinying, Tian, Chengcheng C., Abney, Carter W., Zhang, Peng, Jin, Tian, Liu, Gongping, Browning, Katie L., Sacci, Robert L., Veith, Gabriel M., Zhou, Hong-Cai, Jin, Wanqin Q., and Dai, Sheng. Fri .
"Accelerating Membrane-based CO2 Separation by Soluble Nanoporous Polymer Networks Produced by Mechanochemical Oxidative Coupling". United States. https://doi.org/10.1002/anie.201710420. https://www.osti.gov/servlets/purl/1462862.
@article{osti_1462862,
title = {Accelerating Membrane-based CO2 Separation by Soluble Nanoporous Polymer Networks Produced by Mechanochemical Oxidative Coupling},
author = {Zhu, Xiang and Hua, Yinying and Tian, Chengcheng C. and Abney, Carter W. and Zhang, Peng and Jin, Tian and Liu, Gongping and Browning, Katie L. and Sacci, Robert L. and Veith, Gabriel M. and Zhou, Hong-Cai and Jin, Wanqin Q. and Dai, Sheng},
abstractNote = {Achieving homogeneous dispersion of nanoporous fillers within membrane architectures remains a great challenge for mixed-matrix membrane (MMMs) technology. Imparting solution processability of nanoporous materials would help advance the development of MMMs for membrane-based gas separations. A mechanochemically assisted oxidative coupling polymerization strategy was used to create a new family of soluble nanoporous polymer networks. The solid-state ball-milling method affords inherent molecular weight control over polymer growth and therefore provides unexpected solubility for the resulting nanoporous frameworks. MMM-based CO2/CH4 separation performance was significantly accelerated by these new soluble fillers. In conclusion, we anticipate this facile method will facilitate new possibilities for the rational design and synthesis of soluble nanoporous polymer networks and promote their applications in membrane-based gas separations.},
doi = {10.1002/anie.201710420},
journal = {Angewandte Chemie (International Edition)},
number = 11,
volume = 57,
place = {United States},
year = {Fri Dec 29 00:00:00 EST 2017},
month = {Fri Dec 29 00:00:00 EST 2017}
}
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Figures / Tables:
Figure 1.: (a) Photographs of soluble performance of MC-OCP-NPN-1 in various solvents; (b) THF solution of MC-OCP-NPN-1 shows bright luminescence under UV irradiation (λ=365 nm); (c) Photoluminescence spectrum of MC-OCP-NPN-1.
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Works referenced in this record:
New Tricks for Old Molecules: Development and Application of Porous N-doped, Carbonaceous Membranes for CO 2 Separation
journal, May 2013
- Zhu, Xiang; Tian, Chengcheng; Chai, Songhai
- Advanced Materials, Vol. 25, Issue 30
Size-Controlled Synthesis of Conjugated Polymer Nanoparticles in Confined Nanoreactors
journal, October 2014
- Deng, Sheng; Zhi, Jian; Zhang, Xianmei
- Angewandte Chemie International Edition, Vol. 53, Issue 51
Two-Dimensional Materials as Prospective Scaffolds for Mixed-Matrix Membrane-Based CO 2 Separation
journal, August 2017
- Zhu, Xiang; Tian, Chengcheng; Do-Thanh, Chi-Linh
- ChemSusChem, Vol. 10, Issue 17
State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): An overview on current status and future directions
journal, May 2014
- Rezakazemi, Mashallah; Ebadi Amooghin, Abtin; Montazer-Rahmati, Mohammad Mehdi
- Progress in Polymer Science, Vol. 39, Issue 5
Hypercrosslinked Additives for Ageless Gas-Separation Membranes
journal, January 2016
- Lau, Cher Hon; Mulet, Xavier; Konstas, Kristina
- Angewandte Chemie, Vol. 128, Issue 6
Porous Organic Polymers for Post-Combustion Carbon Capture
journal, July 2017
- Zou, Lanfang; Sun, Yujia; Che, Sai
- Advanced Materials, Vol. 29, Issue 37
Oxidative coupling reactions of phenols with iron(III) chloride in the solid state
journal, June 1989
- Toda, Fumio; Tanaka, Koichi; Iwata, Shinji
- The Journal of Organic Chemistry, Vol. 54, Issue 13
Two-Dimensional-Material Membranes: A New Family of High-Performance Separation Membranes
journal, July 2016
- Liu, Gongping; Jin, Wanqin; Xu, Nanping
- Angewandte Chemie International Edition, Vol. 55, Issue 43, p. 13384-13397
Mechanochemical Friedel-Crafts Alkylation-A Sustainable Pathway Towards Porous Organic Polymers
journal, May 2017
- Troschke, Erik; Grätz, Sven; Lübken, Tilo
- Angewandte Chemie, Vol. 129, Issue 24
Carbon Dioxide Capture: Prospects for New Materials
journal, July 2010
- D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R.
- Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082
Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles
journal, September 2017
- Zhu, Xiang; Tian, Chengcheng; Jin, Tian
- ACS Macro Letters, Vol. 6, Issue 10
Gas-Separation Membranes Loaded with Porous Aromatic Frameworks that Improve with Age
journal, January 2015
- Lau, Cher Hon; Konstas, Kristina; Thornton, Aaron W.
- Angewandte Chemie International Edition, Vol. 54, Issue 9
Enhanced selectivity in mixed matrix membranes for CO2 capture through efficient dispersion of amine-functionalized MOF nanoparticles
journal, June 2017
- Ghalei, Behnam; Sakurai, Kento; Kinoshita, Yosuke
- Nature Energy, Vol. 2, Issue 7
Polymeric Gas Separation Membranes
journal, March 2012
- Yampolskii, Yuri
- Macromolecules, Vol. 45, Issue 8
Advances in high permeability polymeric membrane materials for CO2 separations
journal, January 2012
- Du, Naiying; Park, Ho Bum; Dal-Cin, Mauro M.
- Energy & Environmental Science, Vol. 5, Issue 6, p. 7306-7322
Mechanochemical Friedel-Crafts Alkylation-A Sustainable Pathway Towards Porous Organic Polymers
journal, May 2017
- Troschke, Erik; Grätz, Sven; Lübken, Tilo
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Membranen aus zweidimensionalen Materialien: eine neue Familie hochleistungsfähiger Trennmembranen
journal, July 2016
- Liu, Gongping; Jin, Wanqin; Xu, Nanping
- Angewandte Chemie, Vol. 128, Issue 43
Polymers of Intrinsic Microporosity (PIMs): Bridging the Void between Microporous and Polymeric Materials
journal, April 2005
- McKeown, Neil B.; Budd, Peter M.; Msayib, Kadhum J.
- Chemistry - A European Journal, Vol. 11, Issue 9, p. 2610-2620
Abscheidung von Kohlendioxid: Perspektiven für neue Materialien
journal, July 2010
- D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R.
- Angewandte Chemie, Vol. 122, Issue 35
Metal–organic frameworks for membrane-based separations
journal, November 2016
- Denny, Michael S.; Moreton, Jessica C.; Benz, Lauren
- Nature Reviews Materials, Vol. 1, Issue 12
Gas-Separation Membranes Loaded with Porous Aromatic Frameworks that Improve with Age
journal, January 2015
- Lau, Cher Hon; Konstas, Kristina; Thornton, Aaron W.
- Angewandte Chemie, Vol. 127, Issue 9
Conjugated Microporous Poly(aryleneethynylene) Networks
journal, November 2007
- Jiang, Jia-Xing; Su, Fabing; Trewin, Abbie
- Angewandte Chemie, Vol. 119, Issue 45
A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO2 Separation
journal, June 2012
- Zhu, Xiang; Tian, Chengcheng; Mahurin, Shannon M.
- Journal of the American Chemical Society, Vol. 134, Issue 25, p. 10478-10484
Ionothermalsynthese von porösen kovalenten Triazin- Polymernetzwerken
journal, April 2008
- Kuhn, Pierre; Antonietti, Markus; Thomas, Arne
- Angewandte Chemie, Vol. 120, Issue 18
Function-led design of new porous materials
journal, May 2015
- Slater, A. G.; Cooper, A. I.
- Science, Vol. 348, Issue 6238
Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage
journal, January 2006
- McKeown, Neil B.; Budd, Peter M.
- Chemical Society Reviews, Vol. 35, Issue 8, p. 675-683
Substitution Effect Guided Synthesis of Task-Specific Nanoporous Polycarbazoles with Enhanced Carbon Capture
journal, July 2016
- Jiang, Feng; Jin, Tian; Zhu, Xiang
- Macromolecules, Vol. 49, Issue 15
Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation
journal, April 2007
- Chung, Tai-Shung; Jiang, Lan Ying; Li, Yi
- Progress in Polymer Science, Vol. 32, Issue 4, p. 483-507
Nanoporous Organic Polymer/Cage Composite Membranes
journal, December 2012
- Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P.
- Angewandte Chemie International Edition, Vol. 52, Issue 4
Metal-organic framework nanosheets as building blocks for molecular sieving membranes
journal, December 2014
- Peng, Y.; Li, Y.; Ban, Y.
- Science, Vol. 346, Issue 6215
Advances in high permeability polymer-based membrane materials for CO 2 separations
journal, January 2016
- Wang, Shaofei; Li, Xueqin; Wu, Hong
- Energy & Environmental Science, Vol. 9, Issue 6
Rational design and synthesis of a porous, task-specific polycarbazole for efficient CO 2 capture
journal, January 2016
- Jin, Tian; Xiong, Yan; Zhu, Xiang
- Chemical Communications, Vol. 52, Issue 24
Soluble Porous Coordination Polymers by Mechanochemistry: From Metal-Containing Films/Membranes to Active Catalysts for Aerobic Oxidation
journal, November 2014
- Zhang, Pengfei; Li, Haiying; Veith, Gabriel M.
- Advanced Materials, Vol. 27, Issue 2
Materials for next-generation molecularly selective synthetic membranes
journal, January 2017
- Koros, William J.; Zhang, Chen
- Nature Materials, Vol. 16, Issue 3
Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks
journal, March 2013
- Biswal, Bishnu P.; Chandra, Suman; Kandambeth, Sharath
- Journal of the American Chemical Society, Vol. 135, Issue 14
Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis
journal, April 2008
- Kuhn, Pierre; Antonietti, Markus; Thomas, Arne
- Angewandte Chemie International Edition, Vol. 47, Issue 18
Simulated swelling during low-temperature N 2 adsorption in polymers of intrinsic microporosity
journal, January 2013
- Hart, Kyle E.; Springmeier, Jeffrey M.; McKeown, Neil B.
- Phys. Chem. Chem. Phys., Vol. 15, Issue 46
Energy-efficient polymeric gas separation membranes for a sustainable future: A review
journal, August 2013
- Sanders, David F.; Smith, Zachary P.; Guo, Ruilan
- Polymer, Vol. 54, Issue 18
Mechanochemistry: A Force of Synthesis
journal, December 2016
- Do, Jean-Louis; Friščić, Tomislav
- ACS Central Science, Vol. 3, Issue 1
Soluble Conjugated Microporous Polymers
journal, November 2012
- Cheng, Ge; Hasell, Tom; Trewin, Abbie
- Angewandte Chemie, Vol. 124, Issue 51
Conjugated Microporous Poly(aryleneethynylene) Networks
journal, September 2007
- Jiang, Jia-Xing; Su, Fabing; Trewin, Abbie
- Angewandte Chemie International Edition, Vol. 46, Issue 45
Soluble Metal-Nanoparticle-Decorated Porous Coordination Polymers for the Homogenization of Heterogeneous Catalysis
journal, August 2016
- Huang, Yuan-Biao; Wang, Qiang; Liang, Jun
- Journal of the American Chemical Society, Vol. 138, Issue 32
Mechanochemistry: opportunities for new and cleaner synthesis
journal, January 2012
- James, Stuart L.; Adams, Christopher J.; Bolm, Carsten
- Chem. Soc. Rev., Vol. 41, Issue 1
Nanoporous Organic Polymer/Cage Composite Membranes
journal, December 2012
- Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P.
- Angewandte Chemie, Vol. 125, Issue 4
In Situ Doping Strategy for the Preparation of Conjugated Triazine Frameworks Displaying Efficient CO 2 Capture Performance
journal, September 2016
- Zhu, Xiang; Tian, Chengcheng; Veith, Gabriel M.
- Journal of the American Chemical Society, Vol. 138, Issue 36
Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation
journal, March 2012
- Chen, Qi; Luo, Min; Hammershøj, Peter
- Journal of the American Chemical Society, Vol. 134, Issue 14
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015
- McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
- Nature, Vol. 519, Issue 7543
Hypercrosslinked Additives for Ageless Gas-Separation Membranes
journal, January 2016
- Lau, Cher Hon; Mulet, Xavier; Konstas, Kristina
- Angewandte Chemie International Edition, Vol. 55, Issue 6
Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO 2 capture?
journal, January 2015
- Seoane, Beatriz; Coronas, Joaquin; Gascon, Ignacio
- Chemical Society Reviews, Vol. 44, Issue 8
The Chemistry of CO 2 Capture in an Amine-Functionalized Metal–Organic Framework under Dry and Humid Conditions
journal, August 2017
- Flaig, Robinson W.; Osborn Popp, Thomas M.; Fracaroli, Alejandro M.
- Journal of the American Chemical Society, Vol. 139, Issue 35
Covalent Organic Frameworks for CO 2 Capture
journal, February 2016
- Zeng, Yongfei; Zou, Ruqiang; Zhao, Yanli
- Advanced Materials, Vol. 28, Issue 15
Size-Controlled Synthesis of Conjugated Polymer Nanoparticles in Confined Nanoreactors
journal, October 2014
- Deng, Sheng; Zhi, Jian; Zhang, Xianmei
- Angewandte Chemie, Vol. 126, Issue 51
Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO 2 Capture
journal, November 2014
- Shen, Jie; Liu, Gongping; Huang, Kang
- Angewandte Chemie, Vol. 127, Issue 2
Soluble Conjugated Microporous Polymers
journal, November 2012
- Cheng, Ge; Hasell, Tom; Trewin, Abbie
- Angewandte Chemie International Edition, Vol. 51, Issue 51
Conjugated Polymers of Intrinsic Microporosity (C-PIMs)
journal, June 2014
- Cheng, Ge; Bonillo, Baltasar; Sprick, Reiner S.
- Advanced Functional Materials, Vol. 24, Issue 33
Highly permeable polymers for gas separation membranes
journal, January 2010
- Budd, Peter M.; McKeown, Neil B.
- Polymer Chemistry, Vol. 1, Issue 1
Works referencing / citing this record:
Accelerating CO 2 capture of highly permeable polymer through incorporating highly selective hollow zeolite imidazolate framework
journal, October 2019
- Wu, Xingyu; Ren, Yanxiong; Sui, Guomin
- AIChE Journal, Vol. 66, Issue 2
Orientation of an Amphiphilic Copolymer to a Lamellar Structure on a Hydrophobic Surface and Implications for CO 2 Capture Membranes
journal, December 2018
- Park, Cheol Hun; Lee, Jae Hun; Jung, Jung Pyo
- Angewandte Chemie, Vol. 131, Issue 4
Electropolymerization of Molecular‐Sieving Polythiophene Membranes for H 2 Separation
journal, May 2019
- Zhang, Mengxi; Jing, Xuechun; Zhao, Shuang
- Angewandte Chemie, Vol. 131, Issue 26
Electropolymerization of Molecular‐Sieving Polythiophene Membranes for H 2 Separation
journal, June 2019
- Zhang, Mengxi; Jing, Xuechun; Zhao, Shuang
- Angewandte Chemie International Edition, Vol. 58, Issue 26
Functional group effect of isoreticular metal–organic frameworks on heavy metal ion adsorption
journal, January 2018
- Esrafili, Leili; Safarifard, Vahid; Tahmasebi, Elham
- New Journal of Chemistry, Vol. 42, Issue 11
A stable polymeric chain configuration producing high performance PEBAX-1657 membranes for CO 2 separation
journal, January 2019
- Sharma, Pankaj; Kim, Young-Jin; Kim, Min-Zy
- Nanoscale Advances, Vol. 1, Issue 7
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors
journal, January 2019
- Grätz, Sven; Zink, Sebastian; Kraffczyk, Hanna
- Beilstein Journal of Organic Chemistry, Vol. 15
Orientation of an Amphiphilic Copolymer to a Lamellar Structure on a Hydrophobic Surface and Implications for CO 2 Capture Membranes
journal, January 2019
- Park, Cheol Hun; Lee, Jae Hun; Jung, Jung Pyo
- Angewandte Chemie International Edition, Vol. 58, Issue 4
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors
text, January 2021
- Grätz, Sven; Zink, Sebastian; Kraffczyk, Hanna
- Beilstein-Institut zur Förderung der Chemischen Wissenschaften
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors
journal, January 2019
- Grätz, Sven; Zink, Sebastian; Kraffczyk, Hanna
- Beilstein Journal of Organic Chemistry, Vol. 15
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