Design and Synthesis of Multigraft Copolymer Thermoplastic Elastomers: Superelastomers
Abstract
Abstract Thermoplastic elastomers (TPEs) have been widely studied because of their recyclability, good processibility, low production cost, and unique performance. The building of graft‐type architectures can greatly improve mechanical properties of TPEs. This review focuses on the advances in different approaches to synthesize multigraft copolymer TPEs. Anionic polymerization techniques allow for the synthesis of well‐defined macromolecular structures and compositions, with great control over the molecular weight, polydispersity, branch spacing, number of branch points, and branch point functionality. Progress in emulsion polymerization offers potential approaches to commercialize these types of materials with low production cost via simple operations. Moreover, the use of multigraft architectures provides a solution to the limited elongational properties of all‐acrylic TPEs, which can greatly expand their potential application range. The combination of different polymerization techniques, the introduction of new chemical compositions, and the incorporation of sustainable sources are expected to be further investigated in this area in coming years.
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE
- OSTI Identifier:
- 1435248
- Alternate Identifier(s):
- OSTI ID: 1395408
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Macromolecular Chemistry and Physics
- Additional Journal Information:
- Journal Volume: 219; Journal Issue: 1; Journal ID: ISSN 1022-1352
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Living anionic polymerization; well-defined multigraft copolymer; thermoplastic elastomer; emulsion polymerization
Citation Formats
Wang, Huiqun, Lu, Wei, Wang, Weiyu, Shah, Priyank N., Misichronis, Konstantinos, Kang, Nam-Goo, and Mays, Jimmy W. Design and Synthesis of Multigraft Copolymer Thermoplastic Elastomers: Superelastomers. United States: N. p., 2017.
Web. doi:10.1002/macp.201700254.
Wang, Huiqun, Lu, Wei, Wang, Weiyu, Shah, Priyank N., Misichronis, Konstantinos, Kang, Nam-Goo, & Mays, Jimmy W. Design and Synthesis of Multigraft Copolymer Thermoplastic Elastomers: Superelastomers. United States. https://doi.org/10.1002/macp.201700254
Wang, Huiqun, Lu, Wei, Wang, Weiyu, Shah, Priyank N., Misichronis, Konstantinos, Kang, Nam-Goo, and Mays, Jimmy W. Thu .
"Design and Synthesis of Multigraft Copolymer Thermoplastic Elastomers: Superelastomers". United States. https://doi.org/10.1002/macp.201700254. https://www.osti.gov/servlets/purl/1435248.
@article{osti_1435248,
title = {Design and Synthesis of Multigraft Copolymer Thermoplastic Elastomers: Superelastomers},
author = {Wang, Huiqun and Lu, Wei and Wang, Weiyu and Shah, Priyank N. and Misichronis, Konstantinos and Kang, Nam-Goo and Mays, Jimmy W.},
abstractNote = {Abstract Thermoplastic elastomers (TPEs) have been widely studied because of their recyclability, good processibility, low production cost, and unique performance. The building of graft‐type architectures can greatly improve mechanical properties of TPEs. This review focuses on the advances in different approaches to synthesize multigraft copolymer TPEs. Anionic polymerization techniques allow for the synthesis of well‐defined macromolecular structures and compositions, with great control over the molecular weight, polydispersity, branch spacing, number of branch points, and branch point functionality. Progress in emulsion polymerization offers potential approaches to commercialize these types of materials with low production cost via simple operations. Moreover, the use of multigraft architectures provides a solution to the limited elongational properties of all‐acrylic TPEs, which can greatly expand their potential application range. The combination of different polymerization techniques, the introduction of new chemical compositions, and the incorporation of sustainable sources are expected to be further investigated in this area in coming years.},
doi = {10.1002/macp.201700254},
journal = {Macromolecular Chemistry and Physics},
number = 1,
volume = 219,
place = {United States},
year = {Thu Sep 28 00:00:00 EDT 2017},
month = {Thu Sep 28 00:00:00 EDT 2017}
}
Web of Science
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