Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn1.5+xNi0.5-xO4 (x = 0.1)

Xu, Yun; Zhao, Mingyang; Khalid, Syed; Luo, Hongmei; Brinkman, Kyle S.

doi:10.1115/1.4036386

Title: Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn_1.5+xNi_0.5-xO₄ (x = 0.1)

Abstract

The high voltage cathode material, LiMn_1.6Ni_0.4O₄, was prepared by a polymer-assisted method. The novelty of this paper is the substitution of Ni with Mn, which already exists in the crystal structure instead of other isovalent metal ion dopants which would result in capacity loss. The electrochemical performance testing including stability and rate capability was evaluated. The temperature was found to impose a change on the valence and structure of the cathode materials. Specifically, manganese tends to be reduced at a high temperature of 800 °C and leads to structural changes. The manganese substituted LiMn_1.5Ni_0.5O₄ (LMN) has proved to be a good candidate material for Li-ion battery cathodes displaying good rate capability and capacity retention. Finally, the cathode materials processed at 550 °C showed a stable performance with negligible capacity loss for 400 cycles.

Authors:

Xu, Yun ^[1]; Zhao, Mingyang ^[1]; Khalid, Syed ^[2]; Luo, Hongmei ^[3]; Brinkman, Kyle S. ^[1]

Clemson Univ., SC (United States). Dept. of Materials Science and Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Photon Science Directorate
New Mexico State Univ., Las Cruces, NM (United States). Dept. of Chemical & Materials Engineering

Publication Date:: Tue May 09 00:00:00 EDT 2017

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1425086

Report Number(s):: BNL-203267-2018-JAAM
Journal ID: ISSN 2381-6872; TRN: US1802038

Grant/Contract Number:: SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Electrochemical Energy Conversion and Storage

Additional Journal Information:: Journal Volume: 14; Journal Issue: 2; Journal ID: ISSN 2381-6872

Publisher:: ASME

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Xu, Yun, Zhao, Mingyang, Khalid, Syed, Luo, Hongmei, and Brinkman, Kyle S. Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn1.5+xNi0.5-xO4 (x = 0.1).  United States: N. p., 2017. 
Web.  doi:10.1115/1.4036386.

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                    Xu, Yun, Zhao, Mingyang, Khalid, Syed, Luo, Hongmei, & Brinkman, Kyle S. Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn1.5+xNi0.5-xO4 (x = 0.1).  United States.  https://doi.org/10.1115/1.4036386

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                    Xu, Yun, Zhao, Mingyang, Khalid, Syed, Luo, Hongmei, and Brinkman, Kyle S. Tue .  
"Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn1.5+xNi0.5-xO4 (x = 0.1)".  United States.  https://doi.org/10.1115/1.4036386.  https://www.osti.gov/servlets/purl/1425086.

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@article{osti_1425086,

  title        = {Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn1.5+xNi0.5-xO4 (x = 0.1)},

  author       = {Xu, Yun and Zhao, Mingyang and Khalid, Syed and Luo, Hongmei and Brinkman, Kyle S.},

  abstractNote = {The high voltage cathode material, LiMn1.6Ni0.4O4, was prepared by a polymer-assisted method. The novelty of this paper is the substitution of Ni with Mn, which already exists in the crystal structure instead of other isovalent metal ion dopants which would result in capacity loss. The electrochemical performance testing including stability and rate capability was evaluated. The temperature was found to impose a change on the valence and structure of the cathode materials. Specifically, manganese tends to be reduced at a high temperature of 800 °C and leads to structural changes. The manganese substituted LiMn1.5Ni0.5O4 (LMN) has proved to be a good candidate material for Li-ion battery cathodes displaying good rate capability and capacity retention. Finally, the cathode materials processed at 550 °C showed a stable performance with negligible capacity loss for 400 cycles.},

  doi          = {10.1115/1.4036386},

  journal      = {Journal of Electrochemical Energy Conversion and Storage},

  number       = 2,

  volume       = 14,

  place        = {United States},

  year         = {Tue May 09 00:00:00 EDT 2017},

  month        = {Tue May 09 00:00:00 EDT 2017}

}

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Title: Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn1.5+xNi0.5-xO4 (x = 0.1)

Abstract

Citation Formats

Understanding the Improved Electrochemical Performances of Fe-Substituted 5 V Spinel Cathode LiMn 1.5 Ni 0.5 O 4 journal, July 2009

Role of Cation Ordering and Surface Segregation in High-Voltage Spinel LiMn 1.5 Ni 0.5– x M x O 4 (M = Cr, Fe, and Ga) Cathodes for Lithium-Ion Batteries journal, September 2012

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Influence of Lattice Parameter Differences on the Electrochemical Performance of the 5 V Spinel LiMn1.5 − yNi0.5 − zMy + zO4 (M = Li , Mg, Fe, Co, and Zn) journal, January 2005

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Title: Self-Substitution and the Temperature Effects on the Electrochemical Performance in the High Voltage Cathode System LiMn_1.5+xNi_0.5-xO₄ (x = 0.1)

Understanding the Improved Electrochemical Performances of Fe-Substituted 5 V Spinel Cathode LiMn _1.5 Ni _0.5 O ₄
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Role of Cation Ordering and Surface Segregation in High-Voltage Spinel LiMn _1.5 Ni _{0.5– x} M _x O ₄ (M = Cr, Fe, and Ga) Cathodes for Lithium-Ion Batteries
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