Polymorphic, Porous, and Host–Guest Nanostructures Directed by Monolayer–Substrate Interactions: Epitaxial Self-Assembly Study of Cyclic Trinuclear Au(I) Complexes on HOPG at the Solution–Solid Interface
Abstract
Synthesis, crystallographic characterization, and molecular self-assembly of two novel cyclotrimeric gold(I) complexes, Au3[3,5-(COOEt)2Pz]3 (Au3Pz3) and Au3[(n-Pr–O)C=N(Me)]3 (Au3Cb3) was studied. Single crystal X-ray crystallography data reveal that both gold(I) complexes have one-dimensional stacking patterns caused by intermolecular Au(I)···Au(I) aurophilic interactions. The Au3Pz3 trimer units stack with two alternate and symmetrical Au(I)···Au(I) interactions while the Au3Cb3 units have three alternating and nonsymmetrical Au(I)···Au(I) interactions. Molecular self-assembly of the gold(I) complexes on the 1-phenyloctane/highly ordered pyrolytic graphite (HOPG) (0001) solution–solid interface is studied with scanning tunneling microscopy (STM). The gold(I) cyclotrimers form epitaxial nanostructures on the HOPG surface. At a concentration of ~1 × 10–4 M, Au3Pz3 complexes exhibit a single morphology, while Au3Cb3 complexes exhibit polymorphology. Two polymorphs, one nonporous and the other porous, are observed at 22.0 ± 2.0 °C for Au3Cb3 complexes. A nonporous, low-surface-density (0.82 molecules/nm2) Au3Cb3 nanostructure forms first and then transforms into a high-density (1.43 molecules/nm2) porous nanostructure. This is the first time any porous surface nanostructure is reported for an organometallic system. The porous structure is thought to be stabilized by a combination of hydrogen bonding and monolayer–substrate interactions. These pores are utilized to incorporate pyrene into the film, rendering this the first organometallic host–guest systemmore »
- Authors:
-
- Washington State Univ., Pullman, WA (United States)
- Univ. of North Texas, Denton, TX (United States)
- Publication Date:
- Research Org.:
- Washington State Univ., Pullman, WA (United States); Univ. of North Texas, Denton, TX (United States)
- Sponsoring Org.:
- National Science Foundation (NSF); Welch Foundation; USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1418553
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 119; Journal Issue: 44; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Self organization; Gold; Molecules; Monolayers; Scanning tunneling microscopy
Citation Formats
Chilukuri, Bhaskar, McDougald, Roy N., Ghimire, Mukunda M., Nesterov, Vladimir N., Mazur, Ursula, Omary, Mohammad A., and Hipps, K. W. Polymorphic, Porous, and Host–Guest Nanostructures Directed by Monolayer–Substrate Interactions: Epitaxial Self-Assembly Study of Cyclic Trinuclear Au(I) Complexes on HOPG at the Solution–Solid Interface. United States: N. p., 2015.
Web. doi:10.1021/acs.jpcc.5b08171.
Chilukuri, Bhaskar, McDougald, Roy N., Ghimire, Mukunda M., Nesterov, Vladimir N., Mazur, Ursula, Omary, Mohammad A., & Hipps, K. W. Polymorphic, Porous, and Host–Guest Nanostructures Directed by Monolayer–Substrate Interactions: Epitaxial Self-Assembly Study of Cyclic Trinuclear Au(I) Complexes on HOPG at the Solution–Solid Interface. United States. https://doi.org/10.1021/acs.jpcc.5b08171
Chilukuri, Bhaskar, McDougald, Roy N., Ghimire, Mukunda M., Nesterov, Vladimir N., Mazur, Ursula, Omary, Mohammad A., and Hipps, K. W. Fri .
"Polymorphic, Porous, and Host–Guest Nanostructures Directed by Monolayer–Substrate Interactions: Epitaxial Self-Assembly Study of Cyclic Trinuclear Au(I) Complexes on HOPG at the Solution–Solid Interface". United States. https://doi.org/10.1021/acs.jpcc.5b08171. https://www.osti.gov/servlets/purl/1418553.
@article{osti_1418553,
title = {Polymorphic, Porous, and Host–Guest Nanostructures Directed by Monolayer–Substrate Interactions: Epitaxial Self-Assembly Study of Cyclic Trinuclear Au(I) Complexes on HOPG at the Solution–Solid Interface},
author = {Chilukuri, Bhaskar and McDougald, Roy N. and Ghimire, Mukunda M. and Nesterov, Vladimir N. and Mazur, Ursula and Omary, Mohammad A. and Hipps, K. W.},
abstractNote = {Synthesis, crystallographic characterization, and molecular self-assembly of two novel cyclotrimeric gold(I) complexes, Au3[3,5-(COOEt)2Pz]3 (Au3Pz3) and Au3[(n-Pr–O)C=N(Me)]3 (Au3Cb3) was studied. Single crystal X-ray crystallography data reveal that both gold(I) complexes have one-dimensional stacking patterns caused by intermolecular Au(I)···Au(I) aurophilic interactions. The Au3Pz3 trimer units stack with two alternate and symmetrical Au(I)···Au(I) interactions while the Au3Cb3 units have three alternating and nonsymmetrical Au(I)···Au(I) interactions. Molecular self-assembly of the gold(I) complexes on the 1-phenyloctane/highly ordered pyrolytic graphite (HOPG) (0001) solution–solid interface is studied with scanning tunneling microscopy (STM). The gold(I) cyclotrimers form epitaxial nanostructures on the HOPG surface. At a concentration of ~1 × 10–4 M, Au3Pz3 complexes exhibit a single morphology, while Au3Cb3 complexes exhibit polymorphology. Two polymorphs, one nonporous and the other porous, are observed at 22.0 ± 2.0 °C for Au3Cb3 complexes. A nonporous, low-surface-density (0.82 molecules/nm2) Au3Cb3 nanostructure forms first and then transforms into a high-density (1.43 molecules/nm2) porous nanostructure. This is the first time any porous surface nanostructure is reported for an organometallic system. The porous structure is thought to be stabilized by a combination of hydrogen bonding and monolayer–substrate interactions. These pores are utilized to incorporate pyrene into the film, rendering this the first organometallic host–guest system imaged at the solid–solution interface. In conclusion, molecular and periodic density functional theory (DFT) calculations shed light on the two-dimensional topography and polymorphic self-assembly revealed by STM; these calculations suggest significant electronic hybridization of the Au3 trimer orbitals and HOPG. The multiple-technique approach used herein provides insights concerning molecule–substrate and molecule–molecule interactions.},
doi = {10.1021/acs.jpcc.5b08171},
journal = {Journal of Physical Chemistry. C},
number = 44,
volume = 119,
place = {United States},
year = {Fri Oct 23 00:00:00 EDT 2015},
month = {Fri Oct 23 00:00:00 EDT 2015}
}
Works referenced in this record:
Molecular and Supramolecular Networks on Surfaces: From Two-Dimensional Crystal Engineering to Reactivity
journal, September 2009
- Elemans, Johannes A. A. W.; Lei, Shengbin; De Feyter, Steven
- Angewandte Chemie International Edition, Vol. 48, Issue 40
Molecular Architectonic on Metal Surfaces
journal, May 2007
- Barth, Johannes V.
- Annual Review of Physical Chemistry, Vol. 58, Issue 1
Engineering atomic and molecular nanostructures at surfaces
journal, September 2005
- Barth, Johannes V.; Costantini, Giovanni; Kern, Klaus
- Nature, Vol. 437, Issue 7059
Stability of a Surface Adlayer at Elevated Temperature: Coronene and Heptanoic Acid on Au(111)
journal, February 2008
- English, William A.; Hipps, K. W.
- The Journal of Physical Chemistry C, Vol. 112, Issue 6
Expanding the Scope of Molecular Self-organization Studies through Temperature Control at the Solution/Solid Interface
journal, January 2011
- MacLeod, Jennifer M.; Rosei, Federico
- Australian Journal of Chemistry, Vol. 64, Issue 9
Steering molecular organization and host–guest interactions using two-dimensional nanoporous coordination systems
journal, March 2004
- Stepanow, Sebastian; Lingenfelder, Magalí; Dmitriev, Alexandre
- Nature Materials, Vol. 3, Issue 4
Principles of molecular assemblies leading to molecular nanostructures
journal, October 2013
- Mali, Kunal S.; De Feyter, Steven
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 371, Issue 2000
Two-dimensional supramolecular self-assembly: nanoporous networks on surfaces
journal, January 2009
- Kudernac, Tibor; Lei, Shengbin; Elemans, Johannes A. A. W.
- Chem. Soc. Rev., Vol. 38, Issue 2
Controlling molecular deposition and layer structure with supramolecular surface assemblies
journal, August 2003
- Theobald, James A.; Oxtoby, Neil S.; Phillips, Michael A.
- Nature, Vol. 424, Issue 6952
Scanning Tunneling Spectroscopy (STS)
book, January 2006
- Hipps, K. W.
- Handbook of Applied Solid State Spectroscopy
Properties of large organic molecules on metal surfaces
journal, June 2003
- Rosei, Federico; Schunack, Michael; Naitoh, Yoshitaka
- Progress in Surface Science, Vol. 71, Issue 5-8
Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques
journal, October 1997
- Forrest, Stephen R.
- Chemical Reviews, Vol. 97, Issue 6
Kinetics and thermodynamics in surface-confined molecular self-assembly
journal, January 2011
- Gutzler, Rico; Cardenas, Luis; Rosei, Federico
- Chemical Science, Vol. 2, Issue 12
Reversible Phase Transitions in Self-Assembled Monolayers at the Liquid−Solid Interface: Temperature-Controlled Opening and Closing of Nanopores
journal, April 2010
- Gutzler, Rico; Sirtl, Thomas; Dienstmaier, Jürgen F.
- Journal of the American Chemical Society, Vol. 132, Issue 14
Solvent Controlled Self-Assembly at the Liquid-Solid Interface Revealed by STM
journal, January 2006
- Mamdouh, Wael; Uji-i, Hiroshi; Ladislaw, Janine S.
- Journal of the American Chemical Society, Vol. 128, Issue 1
A Single Molecule Level Study of the Temperature-Dependent Kinetics for the Formation of Metal Porphyrin Monolayers on Au(111) from Solution
journal, January 2014
- Bhattarai, Ashish; Mazur, Ursula; Hipps, K. W.
- Journal of the American Chemical Society, Vol. 136, Issue 5
Single Molecule Imaging of Oxygenation of Cobalt Octaethylporphyrin at the Solution/Solid Interface: Thermodynamics from Microscopy
journal, June 2012
- Friesen, Benjamin A.; Bhattarai, Ashish; Mazur, Ursula
- Journal of the American Chemical Society, Vol. 134, Issue 36
Partial sequencing of a single DNA molecule with a scanning tunnelling microscope
journal, July 2009
- Tanaka, Hiroyuki; Kawai, Tomoji
- Nature Nanotechnology, Vol. 4, Issue 8, p. 518-522
STM and AFM of bio/organic molecules and structures
journal, January 1996
- Ikai, Atsushi
- Surface Science Reports, Vol. 26, Issue 8
Scanning probe microscopy (STM/AFM) and applications in biology
journal, February 1999
- Li, M. Q.
- Applied Physics A: Materials Science & Processing, Vol. 68, Issue 2
Review Article: Structures of phthalocyanine molecules on surfaces studied by STM
journal, December 2012
- Wang, Yongfeng; Wu, Kai; Kröger, Jörg
- AIP Advances, Vol. 2, Issue 4
Templates in Chemistry III
book, January 2009
- Broekmann, Peter; Dötz, Karl-Heinz; Schalley, Christoph A.
- Topics in Current Chemistry
Real-Time Single-Molecule Imaging of the Formation and Dynamics of Coordination Compounds
journal, December 2002
- Lin, Nian; Dmitriev, Alexandre; Weckesser, Jens
- Angewandte Chemie International Edition, Vol. 41, Issue 24
Surface-Assisted Formation, Assembly, and Dynamics of Planar Organometallic Macrocycles and Zigzag Shaped Polymer Chains with C–Cu–C Bonds
journal, December 2013
- Fan, Qitang; Wang, Cici; Han, Yong
- ACS Nano, Vol. 8, Issue 1
Controlling the Dimensionality of On-Surface Coordination Polymers via Endo- or Exoligation
journal, June 2014
- Shchyrba, Aneliia; Wäckerlin, Christian; Nowakowski, Jan
- Journal of the American Chemical Society, Vol. 136, Issue 26
Molecular Tectonics on Surfaces: Bottom-Up Fabrication of 1D Coordination Networks That Form 1D and 2D Arrays on Graphite
journal, January 2007
- Surin, Mathieu; Samorì, Paolo; Jouaiti, Abdelaziz
- Angewandte Chemie, Vol. 119, Issue 1-2
Molecular tectonics based nanopatterning of interfaces with 2D metal–organic frameworks (MOFs)
journal, January 2014
- Garah, Mohamed El; Ciesielski, Artur; Marets, Nicolas
- Chem. Commun., Vol. 50, Issue 82
Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays
journal, July 2004
- Ruben, Mario; Rojo, Javier; Romero-Salguero, Francisco J.
- Angewandte Chemie International Edition, Vol. 43, Issue 28
Ultrahigh-vacuum multitechnique study of AuCN monolayers on Au(111) formed by electrochemical deposition
journal, July 2000
- Yamada, Taro; Sekine, Rika; Sawaguchi, Takahiro
- The Journal of Chemical Physics, Vol. 113, Issue 3
Electrochemical Scanning Tunneling Microscopy and Ultrahigh-Vacuum Investigation of Gold Cyanide Adlayers on Au(111) Formed in Aqueous Solution
journal, September 1995
- Sawaguchi, Takahiro; Yamada, Taro; Okinaka, Yutaka
- The Journal of Physical Chemistry, Vol. 99, Issue 38, p. 14149-14155
Electron transfer processes on Au nanoclusters supported on graphite
journal, October 2013
- Shen, Jie; Jia, Juanjuan; Bobrov, Kirill
- Gold Bulletin, Vol. 46, Issue 4
Comparative STM studies of mixed ligand monolayers on gold nanoparticles in air and in 1-phenyloctane
journal, January 2014
- Ong, Quy Khac; Zhao, Shun; Reguera, Javier
- Chem. Commun., Vol. 50, Issue 72
High-Resolution Scanning Tunneling Microscopy Characterization of Mixed Monolayer Protected Gold Nanoparticles
journal, September 2013
- Ong, Quy Khac; Reguera, Javier; Silva, Paulo Jacob
- ACS Nano, Vol. 7, Issue 10
Spontaneous assembly of subnanometre-ordered domains in the ligand shell of monolayer-protected nanoparticles
journal, April 2004
- Jackson, Alicia M.; Myerson, Jacob W.; Stellacci, Francesco
- Nature Materials, Vol. 3, Issue 5
Spectroscopic STM Studies of Single Gold(III) Porphyrin Molecules
journal, December 2009
- Müllegger, Stefan; Schöfberger, Wolfgang; Rashidi, Mohammad
- Journal of the American Chemical Society, Vol. 131, Issue 49
A Nanoscale Model Catalyst Preparation: Solution Deposition of Phosphine-Stabilized Gold Clusters onto a Planar TiO 2 (110) Support
journal, June 2001
- Chusuei, C. C.; Lai, X.; Davis, K. A.
- Langmuir, Vol. 17, Issue 13
Electronic structure studies of six-atom gold clusters
journal, June 2001
- Omary, Mohammad A.; Rawashdeh-Omary, Manal A.; Chusuei, Charles C.
- The Journal of Chemical Physics, Vol. 114, Issue 24
STM Study of Gold(I) Pyrazolates: Distinct Morphologies, Layer Evolution, and Cooperative Dynamics
journal, April 2013
- den Boer, Duncan; Krikorian, Markrete; Esser, Birgit
- The Journal of Physical Chemistry C, Vol. 117, Issue 16
Metal Effect on the Supramolecular Structure, Photophysics, and Acid−Base Character of Trinuclear Pyrazolato Coinage Metal Complexes †
journal, November 2005
- Omary, Mohammad A.; Rawashdeh-Omary, Manal A.; Gonser, M. W. Alexander
- Inorganic Chemistry, Vol. 44, Issue 23
Intermolecular Interactions in Polymorphs of Trinuclear Gold(I) Complexes: Insight into the Solvoluminescence of Au I 3 (MeNCOMe) 3
journal, July 2005
- White-Morris, Rochelle L.; Olmstead, Marilyn M.; Attar, Saeed
- Inorganic Chemistry, Vol. 44, Issue 14
Molecular and Electronic Structure of Cyclic Trinuclear Gold(I) Carbeniate Complexes: Insights for Structure/Luminescence/Conductivity Relationships
journal, June 2014
- McDougald, Roy N.; Chilukuri, Bhaskar; Jia, Huiping
- Inorganic Chemistry, Vol. 53, Issue 14
Electronic and Charge-Transport Properties of the Au 3 (CH 3 N═COCH 3 ) 3 Crystal: A Density Functional Theory Study
journal, June 2013
- Zhu, Lingyun; Coropceanu, Veaceslav; Yi, Yuanping
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 13
Solventless Supramolecular Chemistry via Vapor Diffusion of Volatile Small Molecules upon a New Trinuclear Silver(I)-Nitrated Pyrazolate Macrometallocyclic Solid: An Experimental/Theoretical Investigation of the Dipole/Quadrupole Chemisorption Phenomena
journal, November 2013
- Galassi, Rossana; Ricci, Simone; Burini, Alfredo
- Inorganic Chemistry, Vol. 52, Issue 24
Epitaxial-Graphene RF Field-Effect Transistors on Si-Face 6H-SiC Substrates
journal, June 2009
- Moon, J. S.; Curtis, D.; Hu, M.
- IEEE Electron Device Letters, Vol. 30, Issue 6
Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene
journal, July 2008
- Wang, Xinran; Tabakman, Scott M.; Dai, Hongjie
- Journal of the American Chemical Society, Vol. 130, Issue 26
Structural and Electronic Properties of PTCDA Thin Films on Epitaxial Graphene
journal, October 2009
- Huang, Han; Chen, Shi; Gao, Xingyu
- ACS Nano, Vol. 3, Issue 11
Doping Single-Layer Graphene with Aromatic Molecules
journal, June 2009
- Dong, Xiaochen; Fu, Dongliang; Fang, Wenjing
- Small, Vol. 5, Issue 12
Symmetry Breaking of Graphene Monolayers by Molecular Decoration
journal, March 2009
- Dong, Xiaochen; Shi, Yumeng; Zhao, Yang
- Physical Review Letters, Vol. 102, Issue 13
Charge transfer induced chemical reaction of tetracyano-p-quinodimethane adsorbed on graphene
journal, January 2012
- Qi, Yun; Mazur, Ursula; Hipps, K. W.
- RSC Advances, Vol. 2, Issue 28
Rational Design of Macrometallocyclic Trinuclear Complexes with Superior π-Acidity and π-Basicity
journal, February 2008
- Tekarli, Sammer M.; Cundari, Thomas R.; Omary, Mohammad A.
- Journal of the American Chemical Society, Vol. 130, Issue 5
Phosphorescent Organogels via “Metallophilic” Interactions for Reversible RGB−Color Switching
journal, January 2005
- Kishimura, Akihiro; Yamashita, Takashi; Aida, Takuzo
- Journal of the American Chemical Society, Vol. 127, Issue 1
Notes
journal, January 1963
- Bowie, J. H.; Bullock, E.; Johnson, A. W.
- J. Chem. Soc., Vol. 0, Issue 0
Polyaryl Derivatives of Gold(I), Silver(I), and Gold(III)
book, January 1986
- Usón, Rafael; Laguna, Antonio
- Organometallic Syntheses
Syntheses and x-ray structures of group 11 pyrazole and pyrazolate complexes. X-ray crystal structures of bis(3,5-diphenylpyrazole)copper(II) dibromide, tris(.mu.-3,5-diphenylpyrazolato-N,N')trisilver(I)-2-tetrahydrofuran, tris(.mu.-3,5-diphenylpyrazolato-N,N')trigold(I), and hexakis(.mu.-3,5-diphenylpyrazolato-N,N')hexagold(I)
journal, January 1988
- Murray, H. H.; Raptis, Raphael G.; Fackler, John P.
- Inorganic Chemistry, Vol. 27, Issue 1
Gold carbene complexes: preparation, oxidation, and ligand displacement
journal, May 1974
- Parks, John E.; Balch, Alan L.
- Journal of Organometallic Chemistry, Vol. 71, Issue 3
Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg
journal, January 1985
- Hay, P. Jeffrey; Wadt, Willard R.
- The Journal of Chemical Physics, Vol. 82, Issue 1
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
journal, July 2007
- Zhao, Yan; Truhlar, Donald G.
- Theoretical Chemistry Accounts, Vol. 120, Issue 1-3
Theory of d 10 −d 10 Closed-Shell Attraction. III. Rings
journal, June 1998
- Pyykkö, Pekka; Mendizabal, Fernando
- Inorganic Chemistry, Vol. 37, Issue 12
Basis sets for transition metals: Optimized outer p functions
journal, August 1996
- Couty, Marc; Hall, Michael B.
- Journal of Computational Chemistry, Vol. 17, Issue 11
Modeling the Deposition of Metal Atoms on a p-Type Organometallic Conductor: Implications for Stability and Electron Transfer
journal, March 2011
- Chilukuri, Bhaskar; Cundari, Thomas R.
- The Journal of Physical Chemistry C, Vol. 115, Issue 13
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Van der Waals density functionals applied to solids
journal, May 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- Physical Review B, Vol. 83, Issue 19
Chemical accuracy for the van der Waals density functional
journal, December 2009
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- Journal of Physics: Condensed Matter, Vol. 22, Issue 2
Effect of dispersion on surface interactions of cobalt( ii ) octaethylporphyrin monolayer on Au(111) and HOPG(0001) substrates: a comparative first principles study
journal, January 2014
- Chilukuri, Bhaskar; Mazur, Ursula; Hipps, K. W.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 27
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Theory of the scanning tunneling microscope
journal, January 1985
- Tersoff, J.; Hamann, D. R.
- Physical Review B, Vol. 31, Issue 2
Theory and Application for the Scanning Tunneling Microscope
journal, June 1983
- Tersoff, J.; Hamann, D. R.
- Physical Review Letters, Vol. 50, Issue 25
Multiple scattering in a vacuum barrier obtained from real-space wavefunctions
journal, April 2005
- Palotás, Krisztián; Hofer, Werner A.
- Journal of Physics: Condensed Matter, Vol. 17, Issue 17
Solvent-Stimulated Luminescence from the Supramolecular Aggregation of a Trinuclear Gold(I) Complex that Displays Extensive Intermolecular AuċAu Interactions
journal, June 1997
- Vickery, Jess C.; Olmstead, Marilyn M.; Fung, Ella Y.
- Angewandte Chemie International Edition in English, Vol. 36, Issue 11
Predicted ligand dependence of the Au(I)…Au(I) attraction in (XAuPH3)2
journal, February 1994
- Pyykkö, Pekka; Li, Jian; Runeberg, Nino
- Chemical Physics Letters, Vol. 218, Issue 1-2
Surface interactions of Au(I) cyclo-trimer with Au(111) and Al(111) surfaces: A computational study
journal, July 2012
- Chilukuri, Bhaskar; Cundari, Thomas R.
- Surface Science, Vol. 606, Issue 13-14
A new approach to empirical intermolecular and conformational potential energy functions. II. Applications to crystal packing, rotational barriers, and conformational analysis.
journal, March 1975
- Burgess, A. W.; Shipman, L. L.; Scheraga, H. A.
- Proceedings of the National Academy of Sciences, Vol. 72, Issue 3
Temperature Stability of Three Commensurate Surface Structures of Coronene Adsorbed on Au(111) from Heptanoic Acid in the 0 to 60 °C Range
journal, January 2013
- Jahanbekam, Abdolreza; Vorpahl, Sarah; Mazur, Ursula
- The Journal of Physical Chemistry C, Vol. 117, Issue 6
Temperature-Induced Structural Phase Transitions in a Two-Dimensional Self-Assembled Network
journal, July 2013
- Blunt, Matthew O.; Adisoejoso, Jinne; Tahara, Kazukuni
- Journal of the American Chemical Society, Vol. 135, Issue 32
Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers
journal, March 2011
- Bellec, Amandine; Arrigoni, Claire; Schull, Guillaume
- The Journal of Chemical Physics, Vol. 134, Issue 12
Where does the dimethyl ether internal rotation barrier come from?
journal, September 1996
- Goodman, Lionel; Pophristic, Vojislava
- Chemical Physics Letters, Vol. 259, Issue 3-4
Formation of host–guest structure at an electrified electrode surface: An electrochemical STM investigation
journal, April 2012
- Yang, Liu; Wang, Dong; Wan, Li-Jun
- Electrochemistry Communications, Vol. 17
Hydrogen-Bonding Ability of a Methyl Group
journal, October 2003
- Knak Jensen, Svend J.; Tang, Ting-Hua; Csizmadia, Imre G.
- The Journal of Physical Chemistry A, Vol. 107, Issue 42
Formation of Hydrogen Bonds in Complexes between Dimethylcuprate(I) Anion and Methane, Propane, or Dimethyl Ether. A Theoretical Study
journal, November 2006
- Dem‘yanov, Piotr I.; Gschwind, Ruth M.
- Organometallics, Vol. 25, Issue 24
Triphenylene Substituted Pyrene Derivative: Synthesis and Single Molecule Investigation
journal, December 2012
- Zhang, Xue-mei; Wang, Hai-feng; Wang, Shuai
- The Journal of Physical Chemistry C, Vol. 117, Issue 1
Electronic properties of a π-stacked pyrene derivative at a liquid–solid interface studied with scanning tunneling spectroscopy
journal, June 2005
- Uji-i, Hiroshi; Nishio, Satoru; Fukumura, Hiroshi
- Chemical Physics Letters, Vol. 408, Issue 1-3
Ordered Architectures of a Soluble Hexa- p eri -hexabenzocoronene−Pyrene Dyad: Thermotropic Bulk Properties and Nanoscale Phase Segregation at Surfaces
journal, August 2003
- Tchebotareva, Natalia; Yin, Xiaomin; Watson, Mark D.
- Journal of the American Chemical Society, Vol. 125, Issue 32
Single-molecule observation of the K+-induced switching of valinomycin within a template network
journal, January 2013
- Li, Yibao; Liu, Chunhua; Xie, Yunzhi
- Chemical Communications, Vol. 49, Issue 79
Synthesis and Molecular Structures of BINOL Complexes: An STM Investigation of 2D Self-Assembly
journal, June 2015
- Zeng, Xianghua; Chang, Shaoqing; Deng, Ke
- Crystal Growth & Design, Vol. 15, Issue 7
Fresh perspectives for surface coordination chemistry
journal, June 2009
- Barth, Johannes V.
- Surface Science, Vol. 603, Issue 10-12
Self-assembly of hydrogen-bonded two-dimensional quasicrystals
journal, March 2014
- Wasio, Natalie A.; Quardokus, Rebecca C.; Forrest, Ryan P.
- Nature, Vol. 507, Issue 7490
Surface Confined Metallosupramolecular Architectures: Formation and Scanning Tunneling Microscopy Characterization
journal, February 2009
- Li, Shan-Shan; Northrop, Brian H.; Yuan, Qun-Hui
- Accounts of Chemical Research, Vol. 42, Issue 2
Two-dimensional (2D) Supramolecular Coordination at Liquid/Solid Interfaces Studied by Scanning Tunneling Microscopy
journal, November 2014
- Xu, Jing; Zeng, Qingdao
- Chinese Journal of Chemistry, Vol. 33, Issue 1
Hierarchically Self-Assembled Host–Guest Network at the Solid–Liquid Interface for Single-Molecule Manipulation
journal, May 2008
- Meier, Christoph; Landfester, Katharina; Künzel, Daniela
- Angewandte Chemie International Edition, Vol. 47, Issue 20
Locking the free-rotation of a prochiral star-shaped guest molecule inside a two-dimensional nanoporous network by introduction of chlorine atoms
journal, January 2011
- Bertrand, Hélène; Silly, Fabien; Teulade-Fichou, Marie-Paule
- Chemical Communications, Vol. 47, Issue 36
Solvent-Controlled 2D Host−Guest (2,7,12-Trihexyloxytruxene/Coronene) Molecular Nanostructures at Organic Liquid/Solid Interface Investigated by Scanning Tunneling Microscopy
journal, June 2010
- Liu, Jia; Zhang, Xu; Yan, Hui-Juan
- Langmuir, Vol. 26, Issue 11
Phosphorescence sensitization via heavy-atom effects in d10 complexes
journal, July 2011
- Elbjeirami, Oussama; Rawashdeh-Omary, Manal A.; Omary, Mohammad A.
- Research on Chemical Intermediates, Vol. 37, Issue 7
Remarkable Alteration of Photophysical Properties of Cyclic Trinuclear Complexes of Monovalent Coinage Metals upon Interactions with Small Organic Molecules
journal, May 2012
- Rawashdeh-Omary, Manal A.
- Comments on Inorganic Chemistry, Vol. 33, Issue 3-4
Two-Dimensional Crystal Engineering: A Four-Component Architecture at a Liquid-Solid Interface
journal, September 2009
- Adisoejoso, Jinne; Tahara, Kazukuni; Okuhata, Satoshi
- Angewandte Chemie, Vol. 121, Issue 40
Control and induction of surface-confined homochiral porous molecular networks
journal, August 2011
- Tahara, Kazukuni; Yamaga, Hiroyuki; Ghijsens, Elke
- Nature Chemistry, Vol. 3, Issue 9
Works referencing / citing this record:
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- Hahn, Raiko; Bohle, Fabian; Kotte, Stefan
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journal, January 2018
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