Photon Transport in One-Dimensional Incommensurately Epitaxial CsPbX 3 Arrays
Abstract
One-dimensional nanoscale epitaxial arrays serve as a great model in studying fundamental physics and for emerging applications. With an increasing focus laid on the Cs-based inorganic halide perovskite out of its outstanding material stability, we have applied vapor phase epitaxy to grow well aligned horizontal CsPbX3 (X: Cl, Br, or I or their mixed) nanowire arrays in large scale on mica substrate. The as-grown nanowire features a triangular prism morphology with typical length ranging from a few tens of micrometers to a few millimeters. Structural analysis reveals that the wire arrays follow the symmetry of mica substrate through incommensurate epitaxy, paving a way for a universally applicable method to grow a broad family of halide perovskite materials. We have studied the unique photon transport in the one-dimensional structure in the all-inorganic Cs-based perovskite wires via temperature dependent and spatially resolved photoluminescence. Furthermore, epitaxy of well oriented wire arrays in halide perovskite would be a promising direction for enabling the circuit-level applications of halide perovskite in high-performance electro-optics and optoelectronics.
- Authors:
-
- Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Materials Science and Engineering
- Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Physics, Applied Physics and Astronomy
- Univ. of Cambridge (United Kingdom). Cavendish Lab.
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1411015
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 16; Journal Issue: 12; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; incommensurate; halide; epitaxy; perovskite; photon; transport
Citation Formats
Wang, Yiping, Sun, Xin, Shivanna, Ravichandran, Yang, Yunbo, Chen, Zhizhong, Guo, Yuwei, Wang, Gwo-Ching, Wertz, Esther, Deschler, Felix, Cai, Zhonghou, Zhou, Hua, Lu, Toh-Ming, and Shi, Jian. Photon Transport in One-Dimensional Incommensurately Epitaxial CsPbX 3 Arrays. United States: N. p., 2016.
Web. doi:10.1021/acs.nanolett.6b04297.
Wang, Yiping, Sun, Xin, Shivanna, Ravichandran, Yang, Yunbo, Chen, Zhizhong, Guo, Yuwei, Wang, Gwo-Ching, Wertz, Esther, Deschler, Felix, Cai, Zhonghou, Zhou, Hua, Lu, Toh-Ming, & Shi, Jian. Photon Transport in One-Dimensional Incommensurately Epitaxial CsPbX 3 Arrays. United States. https://doi.org/10.1021/acs.nanolett.6b04297
Wang, Yiping, Sun, Xin, Shivanna, Ravichandran, Yang, Yunbo, Chen, Zhizhong, Guo, Yuwei, Wang, Gwo-Ching, Wertz, Esther, Deschler, Felix, Cai, Zhonghou, Zhou, Hua, Lu, Toh-Ming, and Shi, Jian. Wed .
"Photon Transport in One-Dimensional Incommensurately Epitaxial CsPbX 3 Arrays". United States. https://doi.org/10.1021/acs.nanolett.6b04297. https://www.osti.gov/servlets/purl/1411015.
@article{osti_1411015,
title = {Photon Transport in One-Dimensional Incommensurately Epitaxial CsPbX 3 Arrays},
author = {Wang, Yiping and Sun, Xin and Shivanna, Ravichandran and Yang, Yunbo and Chen, Zhizhong and Guo, Yuwei and Wang, Gwo-Ching and Wertz, Esther and Deschler, Felix and Cai, Zhonghou and Zhou, Hua and Lu, Toh-Ming and Shi, Jian},
abstractNote = {One-dimensional nanoscale epitaxial arrays serve as a great model in studying fundamental physics and for emerging applications. With an increasing focus laid on the Cs-based inorganic halide perovskite out of its outstanding material stability, we have applied vapor phase epitaxy to grow well aligned horizontal CsPbX3 (X: Cl, Br, or I or their mixed) nanowire arrays in large scale on mica substrate. The as-grown nanowire features a triangular prism morphology with typical length ranging from a few tens of micrometers to a few millimeters. Structural analysis reveals that the wire arrays follow the symmetry of mica substrate through incommensurate epitaxy, paving a way for a universally applicable method to grow a broad family of halide perovskite materials. We have studied the unique photon transport in the one-dimensional structure in the all-inorganic Cs-based perovskite wires via temperature dependent and spatially resolved photoluminescence. Furthermore, epitaxy of well oriented wire arrays in halide perovskite would be a promising direction for enabling the circuit-level applications of halide perovskite in high-performance electro-optics and optoelectronics.},
doi = {10.1021/acs.nanolett.6b04297},
journal = {Nano Letters},
number = 12,
volume = 16,
place = {United States},
year = {Wed Nov 16 00:00:00 EST 2016},
month = {Wed Nov 16 00:00:00 EST 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 113 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Towards stable and commercially available perovskite solar cells
journal, October 2016
- Park, Nam-Gyu; Grätzel, Michael; Miyasaka, Tsutomu
- Nature Energy, Vol. 1, Issue 11
The emergence of perovskite solar cells
journal, July 2014
- Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
- Nature Photonics, Vol. 8, Issue 7, p. 506-514
Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013
- Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
- Nature, Vol. 501, Issue 7467, p. 395-398
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014
- Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
- Nature Materials, Vol. 13, Issue 9, p. 897-903
Photon recycling in lead iodide perovskite solar cells
journal, March 2016
- Pazos-Outon, L. M.; Szumilo, M.; Lamboll, R.
- Science, Vol. 351, Issue 6280
Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015
- Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F.
- Nature Communications, Vol. 6, Issue 1
Self-Regulation Mechanism for Charged Point Defects in Hybrid Halide Perovskites
journal, December 2014
- Walsh, Aron; Scanlon, David O.; Chen, Shiyou
- Angewandte Chemie, Vol. 127, Issue 6
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
journal, December 2014
- Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng
- Nature Communications, Vol. 5, Issue 1
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013
- Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
- Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
Organometal halide perovskite solar cells: degradation and stability
journal, January 2016
- Berhe, Taame Abraha; Su, Wei-Nien; Chen, Ching-Hsiang
- Energy & Environmental Science, Vol. 9, Issue 2
Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells
journal, January 2014
- Unger, E. L.; Hoke, E. T.; Bailie, C. D.
- Energy Environ. Sci., Vol. 7, Issue 11
Inorganic caesium lead iodide perovskite solar cells
journal, January 2015
- Eperon, Giles E.; Paternò, Giuseppe M.; Sutton, Rebecca J.
- Journal of Materials Chemistry A, Vol. 3, Issue 39
Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells
journal, December 2015
- Kulbak, Michael; Gupta, Satyajit; Kedem, Nir
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 1
Growth of nanowire superlattice structures for nanoscale photonics and electronics
journal, February 2002
- Gudiksen, Mark S.; Lauhon, Lincoln J.; Wang, Jianfang
- Nature, Vol. 415, Issue 6872, p. 617-620
Nanowire Transistor Performance Limits and Applications
journal, November 2008
- Lu, Wei; Xie, Ping; Lieber, Charles M.
- IEEE Transactions on Electron Devices, Vol. 55, Issue 11, p. 2859-2876
Core/Multishell Nanowire Heterostructures as Multicolor, High-Efficiency Light-Emitting Diodes
journal, November 2005
- Qian, Fang; Gradečak, Silvija; Li, Yat
- Nano Letters, Vol. 5, Issue 11
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
journal, April 2015
- Zhu, Haiming; Fu, Yongping; Meng, Fei
- Nature Materials, Vol. 14, Issue 6
Vapor Phase Synthesis of Organometal Halide Perovskite Nanowires for Tunable Room-Temperature Nanolasers
journal, June 2015
- Xing, Jun; Liu, Xin Feng; Zhang, Qing
- Nano Letters, Vol. 15, Issue 7
Broad Wavelength Tunable Robust Lasing from Single-Crystal Nanowires of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, I)
journal, July 2016
- Fu, Yongping; Zhu, Haiming; Stoumpos, Constantinos C.
- ACS Nano, Vol. 10, Issue 8
Single-nanowire electrically driven lasers
journal, January 2003
- Duan, Xiangfeng; Huang, Yu; Agarwal, Ritesh
- Nature, Vol. 421, Issue 6920
Semiconductor nanowire lasers
journal, May 2016
- Eaton, Samuel W.; Fu, Anthony; Wong, Andrew B.
- Nature Reviews Materials, Vol. 1, Issue 6
Lasing in robust cesium lead halide perovskite nanowires
journal, February 2016
- Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 8
Nanowire sensors for medicine and the life sciences
journal, June 2006
- Patolsky, Fernando; Zheng, Gengfeng; Lieber, Charles M.
- Nanomedicine, Vol. 1, Issue 1
Single-nanowire photoelectrochemistry
journal, March 2016
- Su, Yude; Liu, Chong; Brittman, Sarah
- Nature Nanotechnology, Vol. 11, Issue 7
Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays
journal, April 2006
- Wang, Z. L.
- Science, Vol. 312, Issue 5771
Wafer-Scale Assembly of Highly Ordered Semiconductor Nanowire Arrays by Contact Printing
journal, January 2008
- Fan, Zhiyong; Ho, Johnny C.; Jacobson, Zachery A.
- Nano Letters, Vol. 8, Issue 1
Electric Field Guided Assembly of One-Dimensional Nanostructures for High Performance Sensors
journal, May 2012
- Brown, Devon A.; Kim, Jong-Hoon; Lee, Hyun-Boo
- Sensors, Vol. 12, Issue 5
Electric-field assisted assembly and alignment of metallic nanowires
journal, August 2000
- Smith, Peter A.; Nordquist, Christopher D.; Jackson, Thomas N.
- Applied Physics Letters, Vol. 77, Issue 9, p. 1399-1401
Magnetic Alignment of Fluorescent Nanowires
journal, March 2001
- Tanase, Monica; Bauer, Laura Ann; Hultgren, Anne
- Nano Letters, Vol. 1, Issue 3
Growth of Large-Area Aligned Molybdenum Nanowires by High Temperature Chemical Vapor Deposition: Synthesis, Growth Mechanism, and Device Application
journal, June 2006
- Zhou, Jun; Deng, Shaozhi; Gong, Li
- The Journal of Physical Chemistry B, Vol. 110, Issue 21
Directed assembly of nanowires
journal, May 2009
- Wang, Michael C. P.; Gates, Byron D.
- Materials Today, Vol. 12, Issue 5
Scalable synthesis and device integration of self-registered one-dimensional zinc oxide nanostructures and related materials
journal, January 2013
- Nikoobakht, Babak; Wang, Xudong; Herzing, Andrew
- Chem. Soc. Rev., Vol. 42, Issue 1
Electron–phonon coupling in hybrid lead halide perovskites
journal, May 2016
- Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.
- Nature Communications, Vol. 7, Issue 1
Guided Growth of Millimeter-Long Horizontal Nanowires with Controlled Orientations
journal, August 2011
- Tsivion, D.; Schvartzman, M.; Popovitz-Biro, R.
- Science, Vol. 333, Issue 6045
Guided Growth of Horizontal ZnO Nanowires with Controlled Orientations on Flat and Faceted Sapphire Surfaces
journal, June 2012
- Tsivion, David; Schvartzman, Mark; Popovitz-Biro, Ronit
- ACS Nano, Vol. 6, Issue 7
The structure of muscovite, KAl 2 (Si 3 Al)O 10 (OH) 2
journal, November 1960
- Radoslovich, E. W.
- Acta Crystallographica, Vol. 13, Issue 11
Two-Dimensional van der Waals Epitaxy Kinetics in a Three-Dimensional Perovskite Halide
journal, August 2015
- Wang, Yiping; Shi, Yunfeng; Xin, Guoqing
- Crystal Growth & Design, Vol. 15, Issue 10
Recent developments and future directions in the growth of nanostructures by van der Waals epitaxy
journal, January 2013
- Bakti Utama, Muhammad Iqbal; Zhang, Qing; Zhang, Jun
- Nanoscale, Vol. 5, Issue 9
Orientational Epitaxy—the Orientational Ordering of Incommensurate Structures
journal, May 1977
- Novaco, Anthony D.; McTague, John P.
- Physical Review Letters, Vol. 38, Issue 22
Lattice match: An application to heteroepitaxy
journal, January 1984
- Zur, A.; McGill, T. C.
- Journal of Applied Physics, Vol. 55, Issue 2
High-Quality Whispering-Gallery-Mode Lasing from Cesium Lead Halide Perovskite Nanoplatelets
journal, July 2016
- Zhang, Qing; Su, Rui; Liu, Xinfeng
- Advanced Functional Materials, Vol. 26, Issue 34
Crystal Growth of the Perovskite Semiconductor CsPbBr 3 : A New Material for High-Energy Radiation Detection
journal, June 2013
- Stoumpos, Constantinos C.; Malliakas, Christos D.; Peters, John A.
- Crystal Growth & Design, Vol. 13, Issue 7
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires
journal, July 2015
- Zhang, Dandan; Eaton, Samuel W.; Yu, Yi
- Journal of the American Chemical Society, Vol. 137, Issue 29
Ultraflat graphene
journal, November 2009
- Lui, Chun Hung; Liu, Li; Mak, Kin Fai
- Nature, Vol. 462, Issue 7271
Graphene adhesion on mica: Role of surface morphology
journal, January 2011
- Rudenko, A. N.; Keil, F. J.; Katsnelson, M. I.
- Physical Review B, Vol. 83, Issue 4
Commensurate–incommensurate transition in graphene on hexagonal boron nitride
journal, April 2014
- Woods, C. R.; Britnell, L.; Eckmann, A.
- Nature Physics, Vol. 10, Issue 6
Epitaxy and Molecular Organization on Solid Substrates
journal, February 2001
- Hooks, D. E.; Fritz, T.; Ward, M. D.
- Advanced Materials, Vol. 13, Issue 4
Thermodynamic Origin of Photoinstability in the CH 3 NH 3 Pb(I 1– x Br x ) 3 Hybrid Halide Perovskite Alloy
journal, March 2016
- Brivio, Federico; Caetano, Clovis; Walsh, Aron
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 6
Comparative investigation on temperature-dependent photoluminescence of CH 3 NH 3 PbBr 3 and CH(NH 2 ) 2 PbBr 3 microstructures
journal, January 2016
- Dai, Jun; Zheng, Hongge; Zhu, Can
- Journal of Materials Chemistry C, Vol. 4, Issue 20
Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells
journal, April 2014
- Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico
- Nano Letters, Vol. 14, Issue 5
Works referencing / citing this record:
An All‐Inorganic Perovskite‐Phase Rubidium Lead Bromide Nanolaser
journal, September 2019
- Tang, Bing; Hu, Yingjie; Dong, Hongxing
- Angewandte Chemie, Vol. 131, Issue 45
Large lattice distortions and size-dependent bandgap modulation in epitaxial halide perovskite nanowires
journal, January 2020
- Oksenberg, Eitan; Merdasa, Aboma; Houben, Lothar
- Nature Communications, Vol. 11, Issue 1
All-inorganic perovskite CsPbBr 3 microstructures growth via chemical vapor deposition for high-performance photodetectors
journal, January 2019
- Mo, Xindi; Li, Xing; Dai, Guozhang
- Nanoscale, Vol. 11, Issue 44
Kinetics and mechanism of planar nanowire growth
journal, December 2019
- Rothman, Amnon; Dubrovskii, Vladimir G.; Joselevich, Ernesto
- Proceedings of the National Academy of Sciences, Vol. 117, Issue 1
Groove-assisted solution growth of lead bromide perovskite aligned nanowires: a simple method towards photoluminescent materials with guiding light properties
journal, January 2019
- Rodriguez, Isabelle; Fenollosa, Roberto; Ramiro-Manzano, Fernando
- Materials Chemistry Frontiers, Vol. 3, Issue 9
Composition-Graded Cesium Lead Halide Perovskite Nanowires with Tunable Dual-Color Lasing Performance
journal, May 2018
- Huang, Ling; Gao, Qinggang; Sun, Ling-Dong
- Advanced Materials, Vol. 30, Issue 27
Advances in Small Perovskite-Based Lasers
journal, August 2017
- Zhang, Qing; Su, Rui; Du, Wenna
- Small Methods, Vol. 1, Issue 9
Liquid-phase growth and optoelectronic properties of two-dimensional hybrid perovskites CH 3 NH 3 PbX 3 (X = Cl, Br, I)
journal, January 2020
- Bai, Yu; Zhang, Haixin; Zhang, Mingjing
- Nanoscale, Vol. 12, Issue 2
Microwave-assisted synthesis of high-quality “all-inorganic” CsPbX 3 (X = Cl, Br, I) perovskite nanocrystals and their application in light emitting diodes
journal, January 2017
- Pan, Qi; Hu, Huicheng; Zou, Yatao
- Journal of Materials Chemistry C, Vol. 5, Issue 42
Horizontal GaN nanowires grown on Si (111) substrate: the effect of catalyst migration and coalescence
journal, November 2018
- Wu, Shaoteng; Wang, Liancheng; Liu, Zhiqiang
- Nanotechnology, Vol. 30, Issue 4
Defect-engineered epitaxial VO 2±δ in strain engineering of heterogeneous soft crystals
journal, May 2018
- Wang, Yiping; Sun, Xin; Chen, Zhizhong
- Science Advances, Vol. 4, Issue 5
Temperature Difference Triggering Controlled Growth of All-Inorganic Perovskite Nanowire Arrays in Air
journal, September 2018
- Wang, Yaguang; Yasar, Muhammad; Luo, Ziyi
- Small, Vol. 14, Issue 41
Bandgap engineering in semiconductor alloy nanomaterials with widely tunable compositions
journal, October 2017
- Ning, Cun-Zheng; Dou, Letian; Yang, Peidong
- Nature Reviews Materials, Vol. 2, Issue 12
Lasing from reduced dimensional perovskite microplatelets: Fabry-Pérot or whispering-gallery-mode?
journal, December 2019
- Li, Qi; Li, Chun; Shang, Qiuyu
- The Journal of Chemical Physics, Vol. 151, Issue 21
Fully-Inorganic Trihalide Perovskite Nanocrystals: A New Research Frontier of Optoelectronic Materials
journal, June 2017
- He, Xianghong; Qiu, Yongcai; Yang, Shihe
- Advanced Materials, Vol. 29, Issue 32
Nontrivial strength of van der Waals epitaxial interaction in soft perovskites
journal, July 2018
- Wang, Yiping; Gao, Lei; Yang, Yunbo
- Physical Review Materials, Vol. 2, Issue 7
Scalable room-temperature synthesis of plum-pudding-like Cs 4 PbBr 6 /CsPbBr 3 microcrystals exhibiting excellent photoluminescence
journal, January 2019
- Hu, Guomiao; Qin, Wenjing; Liu, Manman
- Journal of Materials Chemistry C, Vol. 7, Issue 16
Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties
journal, February 2019
- Fu, Yongping; Zhu, Haiming; Chen, Jie
- Nature Reviews Materials, Vol. 4, Issue 3
Merits and Challenges of Ruddlesden-Popper Soft Halide Perovskites in Electro-Optics and Optoelectronics
journal, October 2018
- Chen, Zhizhong; Guo, Yuwei; Wertz, Esther
- Advanced Materials, Vol. 31, Issue 1
Self-Powered, Flexible, and Solution-Processable Perovskite Photodetector Based on Low-Cost Carbon Cloth
journal, May 2017
- Sun, Haoxuan; Lei, Tianyu; Tian, Wei
- Small, Vol. 13, Issue 28
Solvothermal Synthesis of High-Quality All-Inorganic Cesium Lead Halide Perovskite Nanocrystals: From Nanocube to Ultrathin Nanowire
journal, April 2017
- Chen, Min; Zou, Yatao; Wu, Linzhong
- Advanced Functional Materials, Vol. 27, Issue 23
Recent advances in one-dimensional halide perovskites for optoelectronic applications
journal, January 2018
- Qiu, Ting; Hu, Yanqiang; Xu, Feng
- Nanoscale, Vol. 10, Issue 45
An All‐Inorganic Perovskite‐Phase Rubidium Lead Bromide Nanolaser
journal, November 2019
- Tang, Bing; Hu, Yingjie; Dong, Hongxing
- Angewandte Chemie International Edition, Vol. 58, Issue 45
Facile Two-Step Synthesis of All-Inorganic Perovskite CsPbX 3 (X = Cl, Br, and I) Zeolite-Y Composite Phosphors for Potential Backlight Display Application
journal, October 2017
- Sun, Jia-Yi; Rabouw, Freddy T.; Yang, Xian-Feng
- Advanced Functional Materials, Vol. 27, Issue 45
Synthesis and optical applications of low dimensional metal-halide perovskites
journal, January 2020
- Liu, Jingying; Chen, Keqiang; Khan, Sayed Ali
- Nanotechnology, Vol. 31, Issue 15