Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming
Abstract
Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for studying fundamental phenomena linked to the operation of technical catalysts. In the last fifteen years, many combinations of well-defined systems involving different kinds of metals and ceria have been prepared and characterized using the modern techniques of surface science. So far most of the catalytic studies have been centered on a few reactions: CO oxidation, the hydrogenation of CO2, and the production of hydrogen through the water–gas shift reaction and the reforming of methane or alcohols. By using model catalysts it is been possible to examine in detail correlations between the structural, electronic and catalytic properties of ceria–metal interfaces. In situ techniques (X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, infrared spectroscopy, scanning tunneling microscopy) have been combined to study the morphological changes under reaction conditions and investigate the evolution of active phases involved in the cleavage of C–O, C–H and C–C bonds. Several studies with model ceria catalysts have shown the importance of strong metal–support interactions. Generally, a substantial body of knowledge has been acquired and concepts have been developed for a more rational approach to the design of novel technical catalysts containing ceria.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; State Univ. of New York (SUNY), Stony Brook, NY (United States). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- State Univ. of New York (SUNY), Stony Brook, NY (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1377054
- Report Number(s):
- BNL-114201-2017-JA
Journal ID: ISSN 0306-0012; CSRVBR; R&D Project: CO040; KC0302010
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Society Reviews
- Additional Journal Information:
- Journal Volume: 46; Journal Issue: 7; Journal ID: ISSN 0306-0012
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rodriguez, José A., Grinter, David C., Liu, Zongyuan, Palomino, Robert M., and Senanayake, Sanjaya D. Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming. United States: N. p., 2017.
Web. doi:10.1039/C6CS00863A.
Rodriguez, José A., Grinter, David C., Liu, Zongyuan, Palomino, Robert M., & Senanayake, Sanjaya D. Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming. United States. https://doi.org/10.1039/C6CS00863A
Rodriguez, José A., Grinter, David C., Liu, Zongyuan, Palomino, Robert M., and Senanayake, Sanjaya D. Fri .
"Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming". United States. https://doi.org/10.1039/C6CS00863A. https://www.osti.gov/servlets/purl/1377054.
@article{osti_1377054,
title = {Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming},
author = {Rodriguez, José A. and Grinter, David C. and Liu, Zongyuan and Palomino, Robert M. and Senanayake, Sanjaya D.},
abstractNote = {Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for studying fundamental phenomena linked to the operation of technical catalysts. In the last fifteen years, many combinations of well-defined systems involving different kinds of metals and ceria have been prepared and characterized using the modern techniques of surface science. So far most of the catalytic studies have been centered on a few reactions: CO oxidation, the hydrogenation of CO2, and the production of hydrogen through the water–gas shift reaction and the reforming of methane or alcohols. By using model catalysts it is been possible to examine in detail correlations between the structural, electronic and catalytic properties of ceria–metal interfaces. In situ techniques (X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, infrared spectroscopy, scanning tunneling microscopy) have been combined to study the morphological changes under reaction conditions and investigate the evolution of active phases involved in the cleavage of C–O, C–H and C–C bonds. Several studies with model ceria catalysts have shown the importance of strong metal–support interactions. Generally, a substantial body of knowledge has been acquired and concepts have been developed for a more rational approach to the design of novel technical catalysts containing ceria.},
doi = {10.1039/C6CS00863A},
journal = {Chemical Society Reviews},
number = 7,
volume = 46,
place = {United States},
year = {Fri Feb 17 00:00:00 EST 2017},
month = {Fri Feb 17 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Hydrogenation of CO 2 to Methanol on CeO x /Cu(111) and ZnO/Cu(111) Catalysts: Role of the Metal–Oxide Interface and Importance of Ce 3+ Sites
journal, January 2016
- Senanayake, Sanjaya D.; Ramírez, Pedro J.; Waluyo, Iradwikanari
- The Journal of Physical Chemistry C, Vol. 120, Issue 3
Inverse Oxide/Metal Catalysts in Fundamental Studies and Practical Applications: A Perspective of Recent Developments
journal, June 2016
- Rodriguez, José A.; Liu, Ping; Graciani, Jesús
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
High catalytic activity of Au/CeOx/TiO2(110) controlled by the nature of the mixed-metal oxide at the nanometer level
journal, March 2009
- Park, J. B.; Graciani, J.; Evans, J.
- Proceedings of the National Academy of Sciences, Vol. 106, Issue 13
Steam Reforming of Ethanol on Ni/CeO 2 : Reaction Pathway and Interaction between Ni and the CeO 2 Support
journal, April 2013
- Xu, Wenqian; Liu, Zongyuan; Johnston-Peck, Aaron C.
- ACS Catalysis, Vol. 3, Issue 5
WGS and CO-PrOx reactions using gold promoted copper-ceria catalysts: “Bulk CuO CeO2 vs. CuO CeO2/Al2O3 with low mixed oxide content”
journal, November 2016
- Reina, T. R.; Ivanova, S.; Laguna, O. H.
- Applied Catalysis B: Environmental, Vol. 197
Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction
journal, December 2007
- Rodriguez, J. A.; Ma, S.; Liu, P.
- Science, Vol. 318, Issue 5857
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006
- Huber, George W.; Iborra, Sara; Corma, Avelino
- Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098
Adsorption and Reaction of SO 2 on Model Ce 1 - x Zr x O 2 (111) Catalysts
journal, March 2004
- Liu, Gang; Rodriguez, José A.; Chang, Zhipeng
- The Journal of Physical Chemistry B, Vol. 108, Issue 9
Morphology and defect structure of the CeO2(111) films grown on Ru(0001) as studied by scanning tunneling microscopy
journal, November 2006
- Lu, J. -L.; Gao, H. -J.; Shaikhutdinov, S.
- Surface Science, Vol. 600, Issue 22
Gold, Copper, and Platinum Nanoparticles Dispersed on CeO x /TiO 2 (110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level
journal, January 2010
- Park, Joon B.; Graciani, Jesus; Evans, Jaime
- Journal of the American Chemical Society, Vol. 132, Issue 1
Defect Structure of Ultrathin Ceria Films on Pt(111): Atomic Views from Scanning Tunnelling Microscopy
journal, June 2010
- Grinter, David C.; Ithnin, Roslinda; Pang, Chi L.
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts
journal, October 2004
- Frusteri, F.; Freni, S.; Spadaro, L.
- Catalysis Communications, Vol. 5, Issue 10
Development of Ni-Pd bimetallic catalysts for the utilization of carbon dioxide and methane by dry reforming
journal, September 2009
- Steinhauer, Bernd; Kasireddy, Mohan Reddy; Radnik, Jörg
- Applied Catalysis A: General, Vol. 366, Issue 2
Structural and Redox Properties of Ceria in Alumina-Supported Ceria Catalyst Supports
journal, May 2000
- Martínez-Arias, A.; Fernández-García, M.; Salamanca, L. N.
- The Journal of Physical Chemistry B, Vol. 104, Issue 17
Catalytic Properties of Ceria and CeO 2 -Containing Materials
journal, November 1996
- Trovarelli, Alessandro
- Catalysis Reviews, Vol. 38, Issue 4
Photoemission Spectroscopy Study of Cu/CeO 2 Systems: Cu/CeO 2 Nanosized Catalyst and CeO 2 (111)/Cu(111) Inverse Model Catalyst
journal, March 2008
- Matolín, Vladimír; Sedláček, Libor; Matolínová, Iva
- The Journal of Physical Chemistry C, Vol. 112, Issue 10
Experimental and Theoretical Study on the Electronic Interaction between Rh Adatoms and CeO x Substrate in Dependence on a Degree of Cerium Oxide Reduction
journal, January 2016
- Ševčíková, Klára; Szabová, Lucie; Kettner, Miroslav
- The Journal of Physical Chemistry C, Vol. 120, Issue 10
Redox properties of water on the oxidized and reduced surfaces of CeO2
journal, February 2003
- Henderson, M. A.; Perkins, C. L.; Engelhard, M. H.
- Surface Science, Vol. 526, Issue 1-2
Characterising ultrathin ceria films at the nanoscale: Combining spectroscopy and microscopy
journal, August 2014
- Grinter, David C.; Pang, Chi L.; Muryn, Christopher A.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 195
Catalytic oxidation of CO by platinum group metals: from ultrahigh vacuum to elevated pressures
journal, August 2002
- Santra, A. K.; Goodman, D. W.
- Electrochimica Acta, Vol. 47, Issue 22-23
Water Dissociation on CeO 2 (100) and CeO 2 (111) Thin Films
journal, August 2012
- Mullins, David R.; Albrecht, Peter M.; Chen, Tsung-Liang
- The Journal of Physical Chemistry C, Vol. 116, Issue 36
The growth, structure and stability of ceria overlayers on Pd(111)
journal, December 1994
- Alexandrou, M.; Nix, R. M.
- Surface Science, Vol. 321, Issue 1-2
Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO 2 (111) catalysts: an in situ study of C–C and O–H bond scission
journal, January 2016
- Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru
- Physical Chemistry Chemical Physics, Vol. 18, Issue 25
Pathways for Ethanol Dehydrogenation and Dehydration Catalyzed by Ceria (111) and (100) Surfaces
journal, January 2015
- Beste, Ariana; Overbury, Steven H.
- The Journal of Physical Chemistry C, Vol. 119, Issue 5
Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies
journal, February 2010
- Rodríguez, José A.; Hrbek, Jan
- Surface Science, Vol. 604, Issue 3-4
Reduction Characteristics of Ceria under Ethanol Steam Reforming Conditions: Effect of the Particle Size
journal, December 2013
- Soykal, I. Ilgaz; Sohn, Hyuntae; Singh, Deepika
- ACS Catalysis, Vol. 4, Issue 2
Inverse CeO 2 /CuO Catalyst As an Alternative to Classical Direct Configurations for Preferential Oxidation of CO in Hydrogen-Rich Stream
journal, January 2010
- Hornés, A.; Hungría, A. B.; Bera, P.
- Journal of the American Chemical Society, Vol. 132, Issue 1
The Mechanism of Hydrocarbon Oxygenate Reforming: CC Bond Scission, Carbon Formation, and Noble-Metal-Free Oxide Catalysts
journal, November 2013
- Lykhach, Yaroslava; Neitzel, Armin; Ševčíková, Klára
- ChemSusChem, Vol. 7, Issue 1
Oxidation State Imaging of Ceria Island Growth on Re(0001)
journal, August 2013
- Grinter, David C.; Yim, Chi-Ming; Pang, Chi L.
- The Journal of Physical Chemistry C, Vol. 117, Issue 32
Adsorption and Reaction of C 1 −C 3 Alcohols over CeO X (111) Thin Films
journal, July 2010
- Mullins, D. R.; Senanayake, S. D.; Chen, T. -L.
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
Copper oxide catalysts supported on ceria for low-temperature CO oxidation
journal, December 2004
- Zheng, Xiucheng; Wang, Shuping; Wang, Shurong
- Catalysis Communications, Vol. 5, Issue 12
Water–Gas Shift and CO Methanation Reactions over Ni–CeO2(111) Catalysts
journal, January 2011
- Senanayake, Sanjaya D.; Evans, Jaime; Agnoli, Stefano
- Topics in Catalysis, Vol. 54, Issue 1-4
Reduction of thin-film ceria on Pt(111) by supported Pd nanoparticles probed with resonant photoemission
journal, June 2011
- Matharu, J.; Cabailh, G.; Lindsay, R.
- Surface Science, Vol. 605, Issue 11-12
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015
- Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
- Angewandte Chemie International Edition, Vol. 54, Issue 15
Controlling Heteroepitaxy by Oxygen Chemical Potential: Exclusive Growth of (100) Oriented Ceria Nanostructures on Cu(111)
journal, January 2016
- Höcker, Jan; Duchoň, Tomáš; Veltruská, Kateřina
- The Journal of Physical Chemistry C, Vol. 120, Issue 9
On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper
journal, January 2008
- Gokhale, Amit A.; Dumesic, James A.; Mavrikakis, Manos
- Journal of the American Chemical Society, Vol. 130, Issue 4
Water Chemistry on Model Ceria and Pt/Ceria Catalysts
journal, May 2012
- Lykhach, Yaroslava; Johánek, Viktor; Aleksandrov, Hristiyan A.
- The Journal of Physical Chemistry C, Vol. 116, Issue 22
Effects of Reaction Temperature and Support Composition on the Mechanism of Water–Gas Shift Reaction over Supported-Pt Catalysts
journal, May 2011
- Kalamaras, Christos M.; Gonzalez, Ines D.; Navarro, Rufino M.
- The Journal of Physical Chemistry C, Vol. 115, Issue 23
Ultrathin ordered CeO2 overlayers on Pt(111): interaction with NO2, NO, H2O and CO
journal, November 2000
- Berner, Ulrich; Schierbaum, Klaus; Jones, Graham
- Surface Science, Vol. 467, Issue 1-3
Active gold-ceria and gold-ceria/titania catalysts for CO oxidation: From single-crystal model catalysts to powder catalysts
journal, February 2015
- Rodriguez, José A.; Si, Rui; Evans, Jaime
- Catalysis Today, Vol. 240
Role of Ceria in Oxidative Dehydrogenation on Supported Vanadia Catalysts
journal, February 2010
- Ganduglia-Pirovano, Maria Veronica; Popa, Cristina; Sauer, Joachim
- Journal of the American Chemical Society, Vol. 132, Issue 7
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014
- Graciani, J.; Mudiyanselage, K.; Xu, F.
- Science, Vol. 345, Issue 6196
Cerium oxide stoichiometry alteration via Sn deposition: Influence of temperature
journal, January 2009
- Skála, Tomáš; Šutara, František; Prince, Kevin C.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 169, Issue 1
Cerium oxides and cerium-platinum surface alloys on Pt(111) single-crystal surfaces studied by scanning tunneling microscopy
journal, May 2002
- Berner, Ulrich; Schierbaum, Klaus-Dieter
- Physical Review B, Vol. 65, Issue 23
Boosting the activity of a Au/CeO2/Al2O3 catalyst for the WGS reaction
journal, September 2015
- Reina, T. R.; Ivanova, S.; Centeno, M. A.
- Catalysis Today, Vol. 253
Diffusion Barriers Block Defect Occupation on Reduced
journal, June 2016
- Lustemberg, P. G.; Pan, Y.; Shaw, B. -J.
- Physical Review Letters, Vol. 116, Issue 23
Unraveling the Active Site in Copper−Ceria Systems for the Water−Gas Shift Reaction: In Situ Characterization of an Inverse Powder CeO 2− x /CuO−Cu Catalyst
journal, February 2010
- Barrio, Laura; Estrella, Michael; Zhou, Gong
- The Journal of Physical Chemistry C, Vol. 114, Issue 8
A theoretical insight into the catalytic effect of a mixed-metal oxide at the nanometer level: The case of the highly active metal/CeOx/TiO2(110) catalysts
journal, March 2010
- Graciani, Jesús; Plata, José J.; Sanz, Javier Fdez.
- The Journal of Chemical Physics, Vol. 132, Issue 10
A photoemission study of the interaction of Ga with CeO2(111) thin films
journal, August 2008
- Skála, Tomáš; Šutara, František; Cabala, Miloš
- Applied Surface Science, Vol. 254, Issue 21
Catalysis and the nature of mixed-metal oxides at the nanometer level: special properties of MOx/TiO2(110) {M= V, W, Ce} surfaces
journal, January 2010
- Rodriguez, José A.; Stacchiola, Dario
- Physical Chemistry Chemical Physics, Vol. 12, Issue 33
Origin of chemical contrast in low-energy electron reflectivity of correlated multivalent oxides: The case of ceria
journal, December 2013
- Flege, Jan Ingo; Kaemena, Björn; Meyer, Axel
- Physical Review B, Vol. 88, Issue 23
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie International Edition, Vol. 52, Issue 19
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions
journal, February 2007
- Rodriguez, José A.; Liu, Ping; Hrbek, Jan
- Angewandte Chemie International Edition, Vol. 46, Issue 8
Simulations of ceria nanoparticles
journal, October 2015
- Cormack, A. N.; Lamphier, S.; Wang, Bu
- Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 471, Issue 2182
Gold catalysts for pure hydrogen production in the water–gas shift reaction: activity, structure and reaction mechanism
journal, January 2006
- Burch, Robbie
- Phys. Chem. Chem. Phys., Vol. 8, Issue 47
High Activity of Ce1−xNixO2−y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions
journal, November 2010
- Zhou, Gong; Barrio, Laura; Agnoli, Stefano
- Angewandte Chemie International Edition, Vol. 49, Issue 50
Resolving the Atomic Structure of Vanadia Monolayer Catalysts: Monomers, Trimers, and Oligomers on Ceria
journal, October 2009
- Baron, Martin; Abbott, Heather; Bondarchuk, Oleksandr
- Angewandte Chemie International Edition, Vol. 48, Issue 43
CO Oxidation on Inverse CeO x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O 2
journal, March 2011
- Yang, Fan; Graciani, Jesús; Evans, Jaime
- Journal of the American Chemical Society, Vol. 133, Issue 10
Low Pressure CO 2 Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeO x /TiO 2 Interface
journal, August 2015
- Yang, Xiaofang; Kattel, Shyam; Senanayake, Sanjaya D.
- Journal of the American Chemical Society, Vol. 137, Issue 32
A route to continuous ultra-thin cerium oxide films on Cu(111)
journal, December 2009
- Staudt, Thorsten; Lykhach, Yaroslava; Hammer, Lutz
- Surface Science, Vol. 603, Issue 23
Growth and Morphology of Ceria on Ruthenium (0001)
journal, December 2012
- Kaemena, B.; Senanayake, S. D.; Meyer, A.
- The Journal of Physical Chemistry C, Vol. 117, Issue 1
Growth of Pt Nanoparticles on Reducible CeO 2 (111) Thin Films: Effect of Nanostructures and Redox Properties of Ceria
journal, June 2010
- Zhou, Yinghui; Perket, Justin M.; Zhou, Jing
- The Journal of Physical Chemistry C, Vol. 114, Issue 27
Spillover Reoxidation of Ceria Nanoparticles
journal, May 2016
- Grinter, David C.; Muryn, Chris; Sala, Alessandro
- The Journal of Physical Chemistry C, Vol. 120, Issue 20
Atomic Scale Structure and Reduction of Cerium Oxide at the Interface with Platinum
journal, October 2015
- Luches, Paola; Giordano, Livia; Grillo, Vincenzo
- Advanced Materials Interfaces, Vol. 2, Issue 18
Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009
- Rodriguez, José A.; Graciani, Jesús; Evans, Jaime
- Angewandte Chemie International Edition, Vol. 48, Issue 43
Efficient Ceria–Platinum Inverse Catalyst for Partial Oxidation of Methanol
journal, June 2016
- Ostroverkh, Anna; Johánek, Viktor; Kúš, Peter
- Langmuir, Vol. 32, Issue 25
Recent conceptual advances in the catalysis science of mixed metal oxide catalytic materials
journal, February 2005
- Wachs, Israel E.
- Catalysis Today, Vol. 100, Issue 1-2
Gold supported on well-ordered ceria films: nucleation, growth and morphology in CO oxidation reaction
journal, February 2007
- Lu, J. -L.; Gao, H. -J.; Shaikhutdinov, S.
- Catalysis Letters, Vol. 114, Issue 1-2
Ordered ultra-thin cerium oxide overlayers on Pt(111) single crystal surfaces studied by LEED and XPS
journal, March 1998
- Schierbaum, Klaus-Dieter
- Surface Science, Vol. 399, Issue 1, p. 29-38
CO Oxidation on a CeO x /Pt(111) Inverse Model Catalyst Surface: Catalytic Promotion and Tuning of Kinetic Phase Diagrams
journal, November 2008
- Suchorski, Y.; Wrobel, R.; Becker, S.
- The Journal of Physical Chemistry C, Vol. 112, Issue 50
Nanopattering in CeO x /Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity
journal, March 2012
- Senanayake, Sanjaya D.; Sadowski, Jerzy T.; Evans, Jaime
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 7
Growth and Sintering of Au−Pt Nanoparticles on Oxidized and Reduced CeO x (111) Thin Films by Scanning Tunneling Microscopy
journal, January 2010
- Zhou, Yinghui; Zhou, Jing
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 3
Sensitivity of CO oxidation toward metal oxidation state in ceria-supported catalysts: an operando DRIFTS-MS study
journal, January 2016
- Kaftan, Andre; Kollhoff, Fabian; Nguyen, Thanh-Son
- Catalysis Science & Technology, Vol. 6, Issue 3
Oxidation-State Analysis of Ceria by X-ray Photoelectron Spectroscopy
journal, February 2015
- Allahgholi, Aschkan; Flege, J. Ingo; Thieß, Sebastian
- ChemPhysChem, Vol. 16, Issue 5
Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation
journal, July 2015
- Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru
- The Journal of Physical Chemistry C, Vol. 119, Issue 32
Spectromicroscopy of a Model Water–Gas Shift Catalyst: Gold Nanoparticles Supported on Ceria
journal, August 2014
- Grinter, David C.; Muryn, Chris; Santos, Benito
- The Journal of Physical Chemistry C, Vol. 118, Issue 33
Near ambient pressure XPS investigation of the interaction of ethanol with Co/CeO2(111)
journal, November 2013
- Óvári, L.; Krick Calderon, S.; Lykhach, Y.
- Journal of Catalysis, Vol. 307
Enhanced Carbon-Resistant Dry Reforming Fe-Ni Catalyst: Role of Fe
journal, March 2015
- Theofanidis, Stavros Alexandros; Galvita, Vladimir V.; Poelman, Hilde
- ACS Catalysis, Vol. 5, Issue 5
Room-Temperature Activation of Methane and Dry Re-forming with CO 2 on Ni-CeO 2 (111) Surfaces: Effect of Ce 3+ Sites and Metal–Support Interactions on C–H Bond Cleavage
journal, November 2016
- Lustemberg, Pablo G.; Ramírez, Pedro J.; Liu, Zongyuan
- ACS Catalysis, Vol. 6, Issue 12
Kinetics and mechanism of the water-gas shift reaction catalysed by the clean and Cs-promoted Cu(110) surface: a comparison with Cu(111)
journal, January 1990
- Nakamura, Junji; Campbell, Joseph M.; Campbell, Charles T.
- Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 15
Methane Activation by Heterogeneous Catalysis
journal, November 2014
- Horn, Raimund; Schlögl, Robert
- Catalysis Letters, Vol. 145, Issue 1
Use of biofuels to produce hydrogen (reformation processes)
journal, January 2008
- Piscina, Pilar Ramírez de la; Homs, Narcís
- Chemical Society Reviews, Vol. 37, Issue 11
Mechanism for the water–gas shift reaction on monofunctional platinum and cause of catalyst deactivation
journal, September 2011
- Flaherty, David W.; Yu, Wen-Yueh; Pozun, Zachary D.
- Journal of Catalysis, Vol. 282, Issue 2
Morphology Dependence of Catalytic Properties of Ni/CeO 2 Nanostructures for Carbon Dioxide Reforming of Methane
journal, April 2012
- Du, Xianjun; Zhang, Dengsong; Shi, Liyi
- The Journal of Physical Chemistry C, Vol. 116, Issue 18
Water–gas shift reaction over gold nanoparticles dispersed on nanostructured CeOx–TiO2(110) surfaces: Effects of high ceria coverage
journal, August 2016
- Grinter, D. C.; Park, J. B.; Agnoli, S.
- Surface Science, Vol. 650
Cu Deposited on CeOx-Modified TiO 2 (110): Synergistic Effects at the Metal–Oxide Interface and the Mechanism of the WGS Reaction
journal, June 2016
- Plata, Jose J.; Graciani, Jesús; Evans, Jaime
- ACS Catalysis, Vol. 6, Issue 7
Dry Reforming of Methane on a Highly-Active Ni-CeO 2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking
journal, May 2016
- Liu, Zongyuan; Grinter, David C.; Lustemberg, Pablo G.
- Angewandte Chemie International Edition, Vol. 55, Issue 26
Unraveling the Dynamic Nanoscale Reducibility (Ce 4+ → Ce 3+ ) of CeO x -Ru in Hydrogen Activation
journal, September 2015
- Höcker, Jan; Menteş, Tevfik Onur; Sala, Alessandro
- Advanced Materials Interfaces, Vol. 2, Issue 18
Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity
journal, July 1996
- Yoshihara, Jun; Campbell, Charles T.
- Journal of Catalysis, Vol. 161, Issue 2
The surface chemistry of cerium oxide
journal, March 2015
- Mullins, David R.
- Surface Science Reports, Vol. 70, Issue 1
Relating methanol oxidation to the structure of ceria-supported vanadia monolayer catalysts
journal, May 2010
- Abbott, H. L.; Uhl, A.; Baron, M.
- Journal of Catalysis, Vol. 272, Issue 1
Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming
journal, July 2002
- Llorca, Jordi; Homs, Narcı́s; Sales, Joaquim
- Journal of Catalysis, Vol. 209, Issue 2
Effect of Ceria on Gold–Titania Catalysts for the Water–Gas Shift Reaction: Fundamental Studies for Au/CeO x /TiO 2 (110) and Au/CeO x /TiO 2 Powders
journal, October 2012
- Si, Rui; Tao, Jing; Evans, Jaime
- The Journal of Physical Chemistry C, Vol. 116, Issue 44
Modeling Ceria-Based Nanomaterials for Catalysis and Related Applications
journal, July 2016
- Bruix, Albert; Neyman, Konstantin M.
- Catalysis Letters, Vol. 146, Issue 10
A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts
journal, May 2012
- Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J.
- Journal of the American Chemical Society, Vol. 134, Issue 21
Strain-induced formation of arrays of catalytically active sites at the metal–oxide interface
journal, April 2004
- Castellarin-Cudia, C.; Surnev, S.; Schneider, G.
- Surface Science, Vol. 554, Issue 2-3
In situ growth, structure, and real-time chemical reactivity of well-defined CeOx-Ru(0001) model surfaces
journal, November 2016
- Grinter, David C.; Senanayake, Sanjaya D.; Flege, Jan Ingo
- Applied Catalysis B: Environmental, Vol. 197
Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment
journal, December 2012
- Paier, Joachim; Penschke, Christopher; Sauer, Joachim
- Chemical Reviews, Vol. 113, Issue 6
Destruction of SO 2 on Au and Cu Nanoparticles Dispersed on MgO(100) and CeO 2 (111) †
journal, March 2010
- Rodriguez, José A.; Liu, Ping; Pérez, Manuel
- The Journal of Physical Chemistry A, Vol. 114, Issue 11
Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation
journal, April 2012
- Mattos, Lisiane V.; Jacobs, Gary; Davis, Burtron H.
- Chemical Reviews, Vol. 112, Issue 7
Preferential CO oxidation over a copper–cerium oxide catalyst in a microchannel reactor
journal, November 2008
- Snytnikov, P. V.; Popova, M. M.; Men, Y.
- Applied Catalysis A: General, Vol. 350, Issue 1
Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles
journal, March 2011
- Vayssilov, Georgi N.; Lykhach, Yaroslava; Migani, Annapaola
- Nature Materials, Vol. 10, Issue 4
Theoretical Studies of the Adsorption of CO and C on Ni(111) and Ni/CeO 2 (111): Evidence of a Strong Metal–Support Interaction
journal, April 2013
- Carrasco, Javier; Barrio, Laura; Liu, Ping
- The Journal of Physical Chemistry C, Vol. 117, Issue 16
Growth and Surface Structure of Ti-Doped CeO x (111) Thin Films
journal, May 2010
- Zhou, Yinghui; Zhou, Jing
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 11
Ti/CeOx(111) interfaces studied by XPS and STM
journal, April 2012
- Zhou, Yinghui; Zhou, Jing
- Surface Science, Vol. 606, Issue 7-8
Supported metal oxide and other catalysts for ethane conversion: a review
journal, June 1999
- Bañares, Miguel A.
- Catalysis Today, Vol. 51, Issue 2
A review of dry (CO 2 ) reforming of methane over noble metal catalysts
journal, January 2014
- Pakhare, Devendra; Spivey, James
- Chem. Soc. Rev., Vol. 43, Issue 22
In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO 2 Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds
journal, February 2015
- Carrasco, Javier; López-Durán, David; Liu, Zongyuan
- Angewandte Chemie International Edition, Vol. 54, Issue 13
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding
journal, August 2010
- Farmer, J. A.; Campbell, C. T.
- Science, Vol. 329, Issue 5994
Resolving the Atomic Structure of Vanadia Monolayer Catalysts: Monomers, Trimers, and Oligomers on Ceria
journal, October 2009
- Baron, Martin; Abbott, Heather; Bondarchuk, Oleksandr
- Angewandte Chemie, Vol. 121, Issue 43
In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO 2 Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds
journal, February 2015
- Carrasco, Javier; López-Durán, David; Liu, Zongyuan
- Angewandte Chemie, Vol. 127, Issue 13
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015
- Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
- Angewandte Chemie, Vol. 127, Issue 15
Dry Reforming of Methane on a Highly-Active Ni-CeO 2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking
journal, May 2016
- Liu, Zongyuan; Grinter, David C.; Lustemberg, Pablo G.
- Angewandte Chemie, Vol. 128, Issue 26
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, December 2006
- Huber, George W.; Iborra, Sara; Corma, Avelino
- ChemInform, Vol. 37, Issue 52
Gold Catalysts for Pure Hydrogen Production in the Water—Gas Shift Reaction: Activity, Structure and Reaction Mechanism
journal, April 2007
- Burch, Robbie
- ChemInform, Vol. 38, Issue 15
Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009
- Rodriguez, José A.; Graciani, Jesús; Evans, Jaime
- Angewandte Chemie, Vol. 121, Issue 43
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions
journal, February 2007
- Rodriguez, José A.; Liu, Ping; Hrbek, Jan
- Angewandte Chemie, Vol. 119, Issue 8
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie, Vol. 125, Issue 19
Works referencing / citing this record:
Layered Double Hydroxide-Based Catalysts: Recent Advances in Preparation, Structure, and Applications
journal, September 2018
- Xu, Ming; Wei, Min
- Advanced Functional Materials, Vol. 28, Issue 47
O 2 -Aktivierung an Cerdioxid-Katalysatoren - Zur Bedeutung der kristallographischen Orientierung des Substrats
journal, November 2017
- Yang, Chengwu; Yu, Xiaojuan; Heißler, Stefan
- Angewandte Chemie, Vol. 129, Issue 51
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction
journal, August 2017
- Li, Siwei; Xu, Yao; Chen, Yifu
- Angewandte Chemie International Edition, Vol. 56, Issue 36
Understanding CeO 2 -Based Nanostructures through Advanced Electron Microscopy in 2D and 3D
journal, October 2018
- Zhang, Yang; Bals, Sara; Van Tendeloo, Gustaaf
- Particle & Particle Systems Characterization, Vol. 36, Issue 1
Nucleation, morphology, and structure of sub-nm thin ceria islands on Rh(111)
journal, October 2018
- Flege, Jan Ingo; Höcker, Jan; Sadowski, Jerzy T.
- Surface and Interface Analysis, Vol. 51, Issue 1
Shape/Crystal Facet of Ceria Induced Well-Dispersed and Stable Au Nanoparticles for the Selective Hydrogenation of Phenylacetylene
journal, January 2019
- Liu, Yanan; Yang, Zhao; Zhang, Xinyi
- Catalysis Letters, Vol. 149, Issue 2
Oxy-steam reforming of methanol on copper catalysts
journal, June 2019
- Mierczynski, Pawel; Mosinska, Magdalena; Maniukiewicz, Waldemar
- Reaction Kinetics, Mechanisms and Catalysis, Vol. 127, Issue 2
Uniform small metal nanoparticles anchored on CeO2 nanorods driven by electroless chemical deposition
journal, May 2019
- Chen, Zheng; Cao, Fang-Xian; Gao, Wei
- Rare Metals, Vol. 39, Issue 7
Interfacing with silica boosts the catalysis of copper
journal, August 2018
- Xu, Chaofa; Chen, Guangxu; Zhao, Yun
- Nature Communications, Vol. 9, Issue 1
Remarkable active-site dependent H2O promoting effect in CO oxidation
journal, August 2019
- Zhao, Shu; Chen, Fang; Duan, Sibin
- Nature Communications, Vol. 10, Issue 1
Structure of the catalytically active copper–ceria interfacial perimeter
journal, February 2019
- Chen, Aling; Yu, Xiaojuan; Zhou, Yan
- Nature Catalysis, Vol. 2, Issue 4
Semi-solid and solid frustrated Lewis pair catalysts
journal, January 2018
- Ma, Yuanyuan; Zhang, Sai; Chang, Chun-Ran
- Chemical Society Reviews, Vol. 47, Issue 15
Inert V 2 O 3 oxide promotes the electrocatalytic activity of Ni metal for alkaline hydrogen evolution
journal, January 2019
- Ji, Dan; Peng, Lishan; Shen, Jingjun
- Chemical Communications, Vol. 55, Issue 22
Thermal reduction of ceria nanostructures on rhodium(111) and re-oxidation by CO 2
journal, January 2018
- Schaefer, Andreas; Hagman, Benjamin; Höcker, Jan
- Physical Chemistry Chemical Physics, Vol. 20, Issue 29
Metal substituted pyrochlore phase Li x La 2−x Ce 1.8 Ru 0.2 O 7−δ ( x = 0.0–0.6) as an effective catalyst for oxidative and auto-thermal steam reforming of ethanol
journal, January 2019
- Hsieh, Ho-Chen; Chang, Yuan-Chia; Tsai, Ping-Wen
- Catalysis Science & Technology, Vol. 9, Issue 6
Ultrathin CdS shell-sensitized hollow S-doped CeO 2 spheres for efficient visible-light photocatalysis
journal, January 2019
- Zheng, Ning-Chao; Ouyang, Ting; Chen, Yibo
- Catalysis Science & Technology, Vol. 9, Issue 6
Support morphology-dependent alloying behaviour and interfacial effects of bimetallic Ni–Cu/CeO 2 catalysts
journal, January 2019
- Liu, Yanan; McCue, Alan J.; Yang, Pengfei
- Chemical Science, Vol. 10, Issue 12
Interface engineering of palladium and zinc oxide nanorods with strong metal–support interactions for enhanced hydrogen production from base-free formaldehyde solution
journal, January 2019
- Du, Leilei; Qian, Kaicheng; Zhu, Xiaohui
- Journal of Materials Chemistry A, Vol. 7, Issue 15
MOF-derived noble-metal-free Cu/CeO 2 with high porosity for the efficient water–gas shift reaction at low temperatures
journal, January 2019
- Jampaiah, Deshetti; Damma, Devaiah; Chalkidis, Anastasios
- Catalysis Science & Technology, Vol. 9, Issue 16
Insights into interface engineering in steam reforming reactions for hydrogen production
journal, January 2019
- Chen, Sai; Pei, Chunlei; Gong, Jinlong
- Energy & Environmental Science, Vol. 12, Issue 12
A protective roasting strategy for preparation of stable mesoporous hollow CeO 2 microspheres with enhanced catalytic activity for one-pot synthesis of imines from benzyl alcohols and anilines
journal, January 2019
- Long, Yu; Zhang, Hongbo; Gao, Zekun
- Inorganic Chemistry Frontiers, Vol. 6, Issue 3
Exotic electronic structures of Sm x Ce 3−x O y (x = 0-3; y = 2-4) clusters and the effect of high neutral density of low-lying states on photodetachment transition intensities
journal, August 2018
- Topolski, Josey E.; Kafader, Jared O.; Marrero-Colon, Vicmarie
- The Journal of Chemical Physics, Vol. 149, Issue 5
Brief review of ceria and modified ceria: synthesis and application
journal, July 2018
- Mohd Fadzil, Nor Aqilah; AB Rahim, Mohd Hasbi; Pragas Maniam, Gaanty
- Materials Research Express, Vol. 5, Issue 8
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction
journal, August 2017
- Li, Siwei; Xu, Yao; Chen, Yifu
- Angewandte Chemie, Vol. 129, Issue 36
O 2 Activation on Ceria Catalysts-The Importance of Substrate Crystallographic Orientation
journal, November 2017
- Yang, Chengwu; Yu, Xiaojuan; Heißler, Stefan
- Angewandte Chemie International Edition, Vol. 56, Issue 51
Hydrogen Doping into MoO 3 Supports toward Modulated Metal-Support Interactions and Efficient Furfural Hydrogenation on Iridium Nanocatalysts
journal, February 2018
- Xie, Lifang; Chen, Ting; Chan, Hang Cheong
- Chemistry - An Asian Journal, Vol. 13, Issue 6
CO 2 Reduction by Hydrogen Pre‐Reduced Acceptor‐Doped Ceria
journal, June 2019
- Grünbacher, Matthias; Klötzer, Bernhard; Penner, Simon
- ChemPhysChem
CO Oxidation at SnO2/Pt3Sn(111) Interfaces
journal, September 2018
- Vandichel, Matthias; Grönbeck, Henrik
- Topics in Catalysis, Vol. 61, Issue 14
On the role of Ce in CO 2 adsorption and activation over lanthanum species
journal, January 2018
- Li, Xinyu; Zhao, Zhi-Jian; Zeng, Liang
- Chemical Science, Vol. 9, Issue 14
A redox interaction-engaged strategy for multicomponent nanomaterials
journal, January 2020
- Wang, Xiao; Song, Shuyan; Zhang, Hongjie
- Chemical Society Reviews, Vol. 49, Issue 3
A mini review of in situ near-ambient pressure XPS studies on non-noble, late transition metal catalysts
journal, January 2019
- Zhong, Liping; Chen, Dingkai; Zafeiratos, Spyridon
- Catalysis Science & Technology, Vol. 9, Issue 15
Recent Advances in the Gold-Catalysed Low-Temperature Water–Gas Shift Reaction
journal, December 2018
- Carter, James H.; Hutchings, Graham J.
- Catalysts, Vol. 8, Issue 12
Effects of preparation mode and doping on the genesis and properties of Ni/Ce1-xMxOy nanocrystallites (M = Gd, La, Mg) for catalytic applications
journal, January 2019
- Matus, Ekaterina V.; Okhlopkova, Lyudmila B.; Sukhova, Olga B.
- Journal of Nanoparticle Research, Vol. 21, Issue 1
Tuning the structure of bifunctional Pt/SmMn 2 O 5 interfaces for promoted low-temperature CO oxidation activity
journal, January 2019
- Liu, Xiao; Yang, Jiaqiang; Shen, Gurong
- Nanoscale, Vol. 11, Issue 17
Mesoporous Co‐Al oxide nanosheets as highly efficient catalysts for CO oxidation
journal, February 2020
- Zhang, Jian; Wang, Liang; Wu, Zhiyi
- AIChE Journal, Vol. 66, Issue 5
Selective Aerobic Oxidation of Vanillyl Alcohol to Vanillin Catalysed by Nanostructured Ce-Zr-O Solid Solutions
journal, January 2019
- Reddy, P. R. G. Nallappa; Rao, Bolla Govinda; Rao, Tumula Venkateshwar
- Catalysis Letters, Vol. 149, Issue 2