Neutron vibrational spectroscopic studies of novel tire-derived carbon materials
Abstract
Sulfonated tire-derived carbons have been demonstrated to be high value-added carbon products of tire recycling in several energy storage system applications including lithium, sodium, potassium ion batteries and supercapacitors. In this paper, we compared different temperature pyrolyzed sulfonated tire-derived carbons with commercial graphite and unmodified/non-functionalized tire-derived carbon by studying the surface chemistry and properties, vibrational spectroscopy of the molecular structure, chemical bonding such as C–H bonding, and intermolecular interactions of the carbon materials. The nitrogen adsorption–desorption studies revealed the tailored micro and meso pore size distribution of the carbon during the sulfonation process. XPS and neutron vibrational spectra showed that the sulfonation of the initial raw tire powders could remove the aliphatic hydrogen containing groups ([double bond splayed left]CH2 and –CH3 groups) and reduce the number of heteroatoms that connect to carbon. The absence of these functional groups could effectively improve the first cycle efficiency of the material in rechargeable batteries. Meanwhile, the introduced –SO3H functional group helped in producing terminal H at the edge of the sp2 bonded graphite-like layers. Finally, this study reveals the influence of the sulfonation process on the recovered hard carbon from used tires and provides a pathway to develop and improve advanced energy storagemore »
- Authors:
-
[6];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). The Bredesen Center for Interdisciplinary Research and Graduate Education
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- RJ Lee Group, Inc., Monroeville, PA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Univ. of Tennessee, Knoxville, TN (United States). The Bredesen Center for Interdisciplinary Research and Graduate Education; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Org.:
- Univ. of Tennessee, Knoxville, TN (United States); RJ Lee Group, Inc., Monroeville, PA (United States)
- OSTI Identifier:
- 1376440
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 19; Journal Issue: 33; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Li, Yunchao, Cheng, Yongqiang, Daemen, Luke L., Veith, Gabriel M., Levine, Alan M., Lee, Richard J., Mahurin, Shannon M., Dai, Sheng, Naskar, Amit K., and Paranthaman, Mariappan Parans. Neutron vibrational spectroscopic studies of novel tire-derived carbon materials. United States: N. p., 2017.
Web. doi:10.1039/C7CP03750C.
Li, Yunchao, Cheng, Yongqiang, Daemen, Luke L., Veith, Gabriel M., Levine, Alan M., Lee, Richard J., Mahurin, Shannon M., Dai, Sheng, Naskar, Amit K., & Paranthaman, Mariappan Parans. Neutron vibrational spectroscopic studies of novel tire-derived carbon materials. United States. https://doi.org/10.1039/C7CP03750C
Li, Yunchao, Cheng, Yongqiang, Daemen, Luke L., Veith, Gabriel M., Levine, Alan M., Lee, Richard J., Mahurin, Shannon M., Dai, Sheng, Naskar, Amit K., and Paranthaman, Mariappan Parans. Fri .
"Neutron vibrational spectroscopic studies of novel tire-derived carbon materials". United States. https://doi.org/10.1039/C7CP03750C. https://www.osti.gov/servlets/purl/1376440.
@article{osti_1376440,
title = {Neutron vibrational spectroscopic studies of novel tire-derived carbon materials},
author = {Li, Yunchao and Cheng, Yongqiang and Daemen, Luke L. and Veith, Gabriel M. and Levine, Alan M. and Lee, Richard J. and Mahurin, Shannon M. and Dai, Sheng and Naskar, Amit K. and Paranthaman, Mariappan Parans},
abstractNote = {Sulfonated tire-derived carbons have been demonstrated to be high value-added carbon products of tire recycling in several energy storage system applications including lithium, sodium, potassium ion batteries and supercapacitors. In this paper, we compared different temperature pyrolyzed sulfonated tire-derived carbons with commercial graphite and unmodified/non-functionalized tire-derived carbon by studying the surface chemistry and properties, vibrational spectroscopy of the molecular structure, chemical bonding such as C–H bonding, and intermolecular interactions of the carbon materials. The nitrogen adsorption–desorption studies revealed the tailored micro and meso pore size distribution of the carbon during the sulfonation process. XPS and neutron vibrational spectra showed that the sulfonation of the initial raw tire powders could remove the aliphatic hydrogen containing groups ([double bond splayed left]CH2 and –CH3 groups) and reduce the number of heteroatoms that connect to carbon. The absence of these functional groups could effectively improve the first cycle efficiency of the material in rechargeable batteries. Meanwhile, the introduced –SO3H functional group helped in producing terminal H at the edge of the sp2 bonded graphite-like layers. Finally, this study reveals the influence of the sulfonation process on the recovered hard carbon from used tires and provides a pathway to develop and improve advanced energy storage materials.},
doi = {10.1039/C7CP03750C},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 33,
volume = 19,
place = {United States},
year = {Fri Aug 11 00:00:00 EDT 2017},
month = {Fri Aug 11 00:00:00 EDT 2017}
}
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Works referenced in this record:
Mechanisms for Lithium Insertion in Carbonaceous Materials
journal, October 1995
- Dahn, J. R.; Zheng, T.; Liu, Y.
- Science, Vol. 270, Issue 5236
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Local Structure and Vibrational Spectroscopy of Disordered Carbons for Li Batteries: Neutron Scattering Studies
journal, January 1997
- Zhou, Ping
- Journal of The Electrochemical Society, Vol. 144, Issue 5
Study of Irreversible Capacities for Li Insertion in Hard and Graphitic Carbons
journal, January 1997
- Xing, Weibing
- Journal of The Electrochemical Society, Vol. 144, Issue 4
Characterization of Activated Carbon Using X-ray Photoelectron Spectroscopy and Inelastic Neutron Scattering Spectroscopy
journal, June 2002
- Lennon, D.; Lundie, D. T.; Jackson, S. D.
- Langmuir, Vol. 18, Issue 12
Tailored recovery of carbons from waste tires for enhanced performance as anodes in lithium-ion batteries
journal, January 2014
- Naskar, Amit K.; Bi, Zhonghe; Li, Yunchao
- RSC Advances, Vol. 4, Issue 72, p. 38213-38221
Anodic performance and mechanism of mesophase-pitch-derived carbons in lithium ion batteries
journal, October 1998
- Mochida, Isao; Ku, Cha-Hun; Yoon, Seong-Ho
- Journal of Power Sources, Vol. 75, Issue 2
Pyrolysis of automobile tyre waste. Influence of operating variables and kinetics study
journal, April 2001
- González, Juan F.; Encinar, José M.; Canito, José L.
- Journal of Analytical and Applied Pyrolysis, Vol. 58-59
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
Hard carbon: a promising lithium-ion battery anode for high temperature applications with ionic electrolyte
journal, January 2012
- Zheng, Honghe; Qu, Qunting; Zhang, Li
- RSC Advances, Vol. 2, Issue 11
Li-insertion in hard carbon anode materials for Li-ion batteries
journal, September 1999
- Buiel, Edward; Dahn, J. R.
- Electrochimica Acta, Vol. 45, Issue 1-2
Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000
- Ferrari, A. C.; Robertson, J.
- Physical Review B, Vol. 61, Issue 20, p. 14095-14107
Carbon surface functionalities and SEI formation during Li intercalation
journal, October 2015
- Collins, John; Gourdin, Gerald; Foster, Michelle
- Carbon, Vol. 92
Correlation Between Lithium Intercalation Capacity and Microstructure in Hard Carbons
journal, January 1996
- Xing, Weibing
- Journal of The Electrochemical Society, Vol. 143, Issue 11
Rubber Recycling: Chemistry, Processing, and Applications
journal, September 2012
- Myhre, Marvin; Saiwari, Sitisaiyidah; Dierkes, Wilma
- Rubber Chemistry and Technology, Vol. 85, Issue 3
Partial graphitization of activated carbon by surface acidification
journal, November 2014
- Collins, John; Zheng, Dong; Ngo, Tue
- Carbon, Vol. 79
Carbon materials for the electrochemical storage of energy in capacitors
journal, May 2001
- Frackowiak, Elzbieta; Béguin, François
- Carbon, Vol. 39, Issue 6, p. 937-950
Raman Spectrum of Graphite
journal, August 1970
- Tuinstra, F.; Koenig, J. L.
- The Journal of Chemical Physics, Vol. 53, Issue 3
Porosity and surface characteristics of activated carbons produced from waste tyre rubber
journal, January 2001
- Miguel, Guillermo San; Fowler, Geoffrey D.; Dall'Orso, Marco
- Journal of Chemical Technology & Biotechnology, Vol. 77, Issue 1
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Design of Nanostructured Heterogeneous Solid Ionic Coatings through a Multiscale Defect Model
journal, February 2016
- Pan, Jie; Zhang, Qinglin; Xiao, Xingcheng
- ACS Applied Materials & Interfaces, Vol. 8, Issue 8
Sustainable Potassium-Ion Battery Anodes Derived from Waste-Tire Rubber
journal, January 2017
- Li, Yunchao; Adams, Ryan A.; Arora, Anjela
- Journal of The Electrochemical Society, Vol. 164, Issue 6
Nanostructured Carbon and Carbon Nanocomposites for Electrochemical Energy Storage Applications
journal, February 2010
- Su , Dang Sheng; Schlögl, Robert
- ChemSusChem, Vol. 3, Issue 2
Lithium Insertion in High Capacity Carbonaceous Materials
journal, January 1995
- Zheng, Tao
- Journal of The Electrochemical Society, Vol. 142, Issue 8
Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
journal, September 2004
- Ferrari, Andrea Carlo; Robertson, John
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1824
Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries
journal, February 2016
- Zhang, Qinglin; Pan, Jie; Lu, Peng
- Nano Letters, Vol. 16, Issue 3
Pyrolysis Pathways of Sulfonated Polyethylene, an Alternative Carbon Fiber Precursor
journal, April 2013
- Younker, Jarod M.; Saito, Tomonori; Hunt, Marcus A.
- Journal of the American Chemical Society, Vol. 135, Issue 16
Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life
journal, September 2015
- Boota, M.; Paranthaman, M. Parans; Naskar, Amit K.
- ChemSusChem, Vol. 8, Issue 21, p. 3576-3581
The leaching of inorganic species from activated carbons produced from waste tyre rubber
journal, April 2002
- San Miguel, G.; Fowler, G. D.; Sollars, C. J.
- Water Research, Vol. 36, Issue 8
Tire-derived carbon composite anodes for sodium-ion batteries
journal, June 2016
- Li, Yunchao; Paranthaman, M. Parans; Akato, Kokouvi
- Journal of Power Sources, Vol. 316
Uncontrolled combustion of shredded tires in a landfill – Part 1: Characterization of gaseous and particulate emissions
journal, March 2015
- Downard, Jared; Singh, Ashish; Bullard, Robert
- Atmospheric Environment, Vol. 104
X-ray absorption spectroscopy and resonant inelastic scattering study of the first lithiation cycle of the Li-ion battery cathode Li2−xMnSiO4
journal, January 2014
- Kristiansen, P. T.; Dahbi, M.; Gustafsson, T.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 8
Liquefaction of waste tires by pyrolysis for oil and chemicals—A review
journal, May 2013
- Quek, Augustine; Balasubramanian, Rajasekhar
- Journal of Analytical and Applied Pyrolysis, Vol. 101, p. 1-16
Voltage hysteresis of lithium ion batteries caused by mechanical stress
journal, January 2016
- Lu, Bo; Song, Yicheng; Zhang, Qinglin
- Physical Chemistry Chemical Physics, Vol. 18, Issue 6
Intermolecular structure and hydrogen-bonding in liquid 1,2-propylene carbonate and 1,2-glycerol carbonate determined by neutron scattering
journal, January 2017
- Delavoux, Yoan M.; Gilmore, Mark; Atkins, Martin P.
- Physical Chemistry Chemical Physics, Vol. 19, Issue 4
The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013
- Goodenough, John B.; Park, Kyu-Sung
- Journal of the American Chemical Society, Vol. 135, Issue 4
New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon
journal, August 2015
- Bommier, Clement; Surta, Todd Wesley; Dolgos, Michelle
- Nano Letters, Vol. 15, Issue 9
Studies on Supercapacitor Electrode Material from Activated Lignin-Derived Mesoporous Carbon
journal, January 2014
- Saha, Dipendu; Li, Yunchao; Bi, Zhonghe
- Langmuir, Vol. 30, Issue 3
Works referencing / citing this record:
Magnetic adsorbents for selective removal of selenite from contaminated water
journal, February 2019
- Evans, Samuel F.; Ivancevic, Marko R.; Yan, Jiaqiang
- Separation Science and Technology, Vol. 54, Issue 13
Conversion of Waste Tire Rubber into High-Value-Added Carbon Supports for Electrocatalysis
journal, January 2018
- Hood, Zachary D.; Yang, Xuan; Li, Yunchao
- Journal of The Electrochemical Society, Vol. 165, Issue 14