On the edge of periodicity: Unconventional magnetism of Gd117Co56.4Sn114.3

Liu, J.; Mudryk, Yaroslav; Ryan, D. H.; Pecharsky, Vitalij K.

doi:10.1016/j.jallcom.2017.08.009

Title: On the edge of periodicity: Unconventional magnetism of Gd₁₁₇Co_56.4Sn_114.3

Abstract

Magnetization measurements reveal the onset of magnetic ordering at T_C = 65 K followed by three additional magnetic anomalies at T₁ = 47 K, T₂ = 28 K, and T₃ = 11 K in Gd₁₁₇Co_56.4Sn_114.3 – a compound with a giant cubic unit cell that crystallizes in the Dy₁₁₇Co₅₆Sn₁₁₂ structure type with space group Fm3¯m and lattice parameter a = 30.186 Å. The magnetic ordering temperature increases with applied magnetic field; however, the analysis of magnetic data indicates that antiferromagnetic interactions also play a role in the ground state. AC magnetic susceptibility confirms multiple magnetic anomalies and shows minor frequency dependence. The local magnetic ordering below 60 K is supported by the Mössbauer spectroscopy. A single broad anomaly is detected at T₃ in the heat capacity; we suggest that magnetic domains form below this temperature. Furthermore, these data highlight unique features of magnetism in this and, potentially, other rare-earth intermetallics crystallizing with giant unit-cells where the exchange correlation lengths are much shorter when compared to the periodicity of the crystal lattice.

Authors:

Liu, J. ^[1];

^[2]; Ryan, D. H. ^[3]; Pecharsky, Vitalij K. ^[2]

Ames Lab. and Iowa State Univ., Ames, IA (United States); Seagate Technology, Bloomington, MN (United States)
Ames Lab. and Iowa State Univ., Ames, IA (United States)
McGill Univ., Montreal, QC (Canada)

Publication Date:: Fri Aug 04 00:00:00 EDT 2017

Research Org.:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1374753

Alternate Identifier(s):: OSTI ID: 1549728

Report Number(s):: IS-J-9410
Journal ID: ISSN 0925-8388; PII: S0925838817327378

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Alloys and Compounds

Additional Journal Information:: Journal Volume: 726; Journal Issue: C; Journal ID: ISSN 0925-8388

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; rare earth alloys and compounds; magnetization; magnetic frustration; heat capacity; Mössbauer

Citation Formats


                    Liu, J., Mudryk, Yaroslav, Ryan, D. H., and Pecharsky, Vitalij K. On the edge of periodicity: Unconventional magnetism of Gd117Co56.4Sn114.3.  United States: N. p., 2017. 
Web.  doi:10.1016/j.jallcom.2017.08.009.

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                    Liu, J., Mudryk, Yaroslav, Ryan, D. H., & Pecharsky, Vitalij K. On the edge of periodicity: Unconventional magnetism of Gd117Co56.4Sn114.3.  United States.  https://doi.org/10.1016/j.jallcom.2017.08.009

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                    Liu, J., Mudryk, Yaroslav, Ryan, D. H., and Pecharsky, Vitalij K. Fri .  
"On the edge of periodicity: Unconventional magnetism of Gd117Co56.4Sn114.3".  United States.  https://doi.org/10.1016/j.jallcom.2017.08.009.  https://www.osti.gov/servlets/purl/1374753.

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@article{osti_1374753,

  title        = {On the edge of periodicity: Unconventional magnetism of Gd117Co56.4Sn114.3},

  author       = {Liu, J. and Mudryk, Yaroslav and Ryan, D. H. and Pecharsky, Vitalij K.},

  abstractNote = {Magnetization measurements reveal the onset of magnetic ordering at TC = 65 K followed by three additional magnetic anomalies at T1 = 47 K, T2 = 28 K, and T3 = 11 K in Gd117Co56.4Sn114.3 – a compound with a giant cubic unit cell that crystallizes in the Dy117Co56Sn112 structure type with space group Fm3¯m and lattice parameter a = 30.186 Å. The magnetic ordering temperature increases with applied magnetic field; however, the analysis of magnetic data indicates that antiferromagnetic interactions also play a role in the ground state. AC magnetic susceptibility confirms multiple magnetic anomalies and shows minor frequency dependence. The local magnetic ordering below 60 K is supported by the Mössbauer spectroscopy. A single broad anomaly is detected at T3 in the heat capacity; we suggest that magnetic domains form below this temperature. Furthermore, these data highlight unique features of magnetism in this and, potentially, other rare-earth intermetallics crystallizing with giant unit-cells where the exchange correlation lengths are much shorter when compared to the periodicity of the crystal lattice.},

  doi          = {10.1016/j.jallcom.2017.08.009},

  journal      = {Journal of Alloys and Compounds},

  number       = C,

  volume       = 726,

  place        = {United States},

  year         = {Fri Aug 04 00:00:00 EDT 2017},

  month        = {Fri Aug 04 00:00:00 EDT 2017}

}

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Works referencing / citing this record:

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Title: On the edge of periodicity: Unconventional magnetism of Gd117Co56.4Sn114.3

Abstract

Citation Formats

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Title: On the edge of periodicity: Unconventional magnetism of Gd₁₁₇Co_56.4Sn_114.3

Synthesis, assembly and physical properties of magnetic nanoparticles
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Colloquium : Opportunities in nanomagnetism
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Crystal Structure of β-Aluminium-Magnesium Alloy
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The crsytal structure of the phase β Mg ₂ Al ₃
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Crystal Structure of NaCd2
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