Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework
Abstract
A Keggin-type polyoxometalate (H3PW12O40) was incorporated into a mesoporous Zr-based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the hybrid material, PW12@NU-1000. The POM@MOF composite was characterized by a suite of physical methods, indicating the retention of crystallinity and high porosity of the parent MOF. The hybrid material was also stable to leaching in aqueous media at varying pH. Lastly, the material was tested as a heterogeneous catalyst for the oxidation of 2-chloroethyl ethyl sulfide using hydrogen peroxide as the oxidant. PW12@NU-1000 was shown to have a higher catalytic activity than either of the individual constituents alone.
- Authors:
-
[1];
[1];
[3];
[1];
[5]
- Northwestern Univ., Evanston, IL (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Univ. of Washington, Seattle, WA (United States)
- Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)
- Sponsoring Org.:
- US Army Research Office (ARO); National Science Foundation (NSF); W.M. Keck Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division
- OSTI Identifier:
- 1372079
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 12; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; NU-1000; POM@MOF; catalysis; metal–organic frameworks; phosphotungstic acid; polyoxometalate; sulfide oxidation
Citation Formats
Buru, Cassandra T., Li, Peng, Mehdi, B. Layla, Dohnalkova, Alice, Platero-Prats, Ana E., Browning, Nigel D., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K. Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework. United States: N. p., 2017.
Web. doi:10.1021/acs.chemmater.7b00750.
Buru, Cassandra T., Li, Peng, Mehdi, B. Layla, Dohnalkova, Alice, Platero-Prats, Ana E., Browning, Nigel D., Chapman, Karena W., Hupp, Joseph T., & Farha, Omar K. Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework. United States. https://doi.org/10.1021/acs.chemmater.7b00750
Buru, Cassandra T., Li, Peng, Mehdi, B. Layla, Dohnalkova, Alice, Platero-Prats, Ana E., Browning, Nigel D., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K. Wed .
"Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework". United States. https://doi.org/10.1021/acs.chemmater.7b00750. https://www.osti.gov/servlets/purl/1372079.
@article{osti_1372079,
title = {Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework},
author = {Buru, Cassandra T. and Li, Peng and Mehdi, B. Layla and Dohnalkova, Alice and Platero-Prats, Ana E. and Browning, Nigel D. and Chapman, Karena W. and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {A Keggin-type polyoxometalate (H3PW12O40) was incorporated into a mesoporous Zr-based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the hybrid material, PW12@NU-1000. The POM@MOF composite was characterized by a suite of physical methods, indicating the retention of crystallinity and high porosity of the parent MOF. The hybrid material was also stable to leaching in aqueous media at varying pH. Lastly, the material was tested as a heterogeneous catalyst for the oxidation of 2-chloroethyl ethyl sulfide using hydrogen peroxide as the oxidant. PW12@NU-1000 was shown to have a higher catalytic activity than either of the individual constituents alone.},
doi = {10.1021/acs.chemmater.7b00750},
journal = {Chemistry of Materials},
number = 12,
volume = 29,
place = {United States},
year = {Wed May 24 00:00:00 EDT 2017},
month = {Wed May 24 00:00:00 EDT 2017}
}
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