Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic Electrolyte
Abstract
The selection of an appropriate substrate is an important initial step for many studies of electrochemically active materials. In order to help researchers with the substrate selection process, we employ a consistent experimental methodology to evaluate the electrochemical reactivity and stability of seven potential substrate materials for electrocatalyst and photoelectrode evaluation. Using cyclic voltammetry with a progressively increased scan range, we characterize three transparent conducting oxides (indium tin oxide, fluorine-doped tin oxide, and aluminum-doped zinc oxide) and four opaque conductors (gold, stainless steel 304, glassy carbon, and highly oriented pyrolytic graphite) in three different electrolytes (sulfuric acid, sodium acetate, and sodium hydroxide). Here, we determine the inert potential window for each substrate/electrolyte combination and make recommendations about which materials may be most suitable for application under different experimental conditions. Furthermore, the testing methodology provides a framework for other researchers to evaluate and report the baseline activity of other substrates of interest to the broader community.
- Authors:
-
- Stanford Univ., Stanford, CA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC), Washington, D.C. (United States). Center on Nanostructuring for Efficient Energy Conversion (CNEEC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1370703
- Grant/Contract Number:
- SC0001060
- Resource Type:
- Accepted Manuscript
- Journal Name:
- PLoS ONE
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 10; Related Information: CNEEC partners with Stanford University (lead); Carnegie Institution at Stanford; Technical University of Denmark; Journal ID: ISSN 1932-6203
- Publisher:
- Public Library of Science
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (heterogeneous); solar (fuels); photosynthesis (natural and artificial); bio-inspired; electrodes - solar; defects; charge transport; materials and chemistry by design; synthesis (novel materials)
Citation Formats
Benck, Jesse D., Pinaud, Blaise A., Gorlin, Yelena, and Jaramillo, Thomas F. Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic Electrolyte. United States: N. p., 2014.
Web. doi:10.1371/journal.pone.0107942.
Benck, Jesse D., Pinaud, Blaise A., Gorlin, Yelena, & Jaramillo, Thomas F. Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic Electrolyte. United States. https://doi.org/10.1371/journal.pone.0107942
Benck, Jesse D., Pinaud, Blaise A., Gorlin, Yelena, and Jaramillo, Thomas F. Thu .
"Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic Electrolyte". United States. https://doi.org/10.1371/journal.pone.0107942. https://www.osti.gov/servlets/purl/1370703.
@article{osti_1370703,
title = {Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic Electrolyte},
author = {Benck, Jesse D. and Pinaud, Blaise A. and Gorlin, Yelena and Jaramillo, Thomas F.},
abstractNote = {The selection of an appropriate substrate is an important initial step for many studies of electrochemically active materials. In order to help researchers with the substrate selection process, we employ a consistent experimental methodology to evaluate the electrochemical reactivity and stability of seven potential substrate materials for electrocatalyst and photoelectrode evaluation. Using cyclic voltammetry with a progressively increased scan range, we characterize three transparent conducting oxides (indium tin oxide, fluorine-doped tin oxide, and aluminum-doped zinc oxide) and four opaque conductors (gold, stainless steel 304, glassy carbon, and highly oriented pyrolytic graphite) in three different electrolytes (sulfuric acid, sodium acetate, and sodium hydroxide). Here, we determine the inert potential window for each substrate/electrolyte combination and make recommendations about which materials may be most suitable for application under different experimental conditions. Furthermore, the testing methodology provides a framework for other researchers to evaluate and report the baseline activity of other substrates of interest to the broader community.},
doi = {10.1371/journal.pone.0107942},
journal = {PLoS ONE},
number = 10,
volume = 9,
place = {United States},
year = {Thu Oct 30 00:00:00 EDT 2014},
month = {Thu Oct 30 00:00:00 EDT 2014}
}
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A wearable freestanding electrochemical sensing system
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Vibrational sum-frequency generation spectroscopy of electrode surfaces: studying the mechanisms of sustainable fuel generation and utilisation
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Theoretical exploration of 2,2′-bipyridines as electro-active compounds in flow batteries
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Biogenic Iron Sulfide Nanoparticles to Enable Extracellular Electron Uptake in Sulfate‐Reducing Bacteria
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Naphthalene flanked diketopyrrolopyrrole: a new conjugated building block with hexyl or octyl alkyl side chains for electropolymerization studies and its biosensor applications
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Electrocatalytic Volleyball: Rapid Nanoconfined Nicotinamide Cycling for Organic Synthesis in Electrode Pores
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