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Title: Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I)

Abstract

Heat capacities of sulfate, perrhenate, chloride, and iodide sodalites with the ideal formula Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I) were measured from 2 K to 300 K using a Quantum Design Physical Property Measurement System (PPMS). From the heat capacity data, the standard thermodynamic functions were determined. All four sodalites undergo a phase transition below room temperature for which thermodynamic parameters were determined. Additionally, the heat capacity of one of the constituent compounds (NaReO4) was measured.

Authors:
 [1];  [2];  [3];  [2];  [4];  [1];  [2]
+ Show Author Affiliations
  1. Brigham Young Univ., Provo, UT (United States)
  2. Univ. of California, Davis, CA (United States). Peter A. Rock Thermochemistry Lab.
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Sponsoring Org.:
USDOE Office of Environmental Management (EM)
OSTI Identifier:
1361348
Alternate Identifier(s):
OSTI ID: 1550146
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Thermodynamics
Additional Journal Information:
Journal Volume: 114; Journal ID: ISSN 0021-9614
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Sodalite; Technetium; Rhenium

Citation Formats

Schliesser, Jacob, Lilova, Kristina, Pierce, Eric M., Wu, Lili, Missimer, David M., Woodfield, Brian F., and Navrotsky, Alexandra. Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I). United States: N. p., 2017. Web. doi:10.1016/j.jct.2017.05.035.
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Schliesser, Jacob, Lilova, Kristina, Pierce, Eric M., Wu, Lili, Missimer, David M., Woodfield, Brian F., & Navrotsky, Alexandra. Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I). United States. https://doi.org/10.1016/j.jct.2017.05.035
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Schliesser, Jacob, Lilova, Kristina, Pierce, Eric M., Wu, Lili, Missimer, David M., Woodfield, Brian F., and Navrotsky, Alexandra. Thu . "Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I)". United States. https://doi.org/10.1016/j.jct.2017.05.035. https://www.osti.gov/servlets/purl/1361348.
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@article{osti_1361348,
title = {Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I)},
author = {Schliesser, Jacob and Lilova, Kristina and Pierce, Eric M. and Wu, Lili and Missimer, David M. and Woodfield, Brian F. and Navrotsky, Alexandra},
abstractNote = {Heat capacities of sulfate, perrhenate, chloride, and iodide sodalites with the ideal formula Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I) were measured from 2 K to 300 K using a Quantum Design Physical Property Measurement System (PPMS). From the heat capacity data, the standard thermodynamic functions were determined. All four sodalites undergo a phase transition below room temperature for which thermodynamic parameters were determined. Additionally, the heat capacity of one of the constituent compounds (NaReO4) was measured.},
doi = {10.1016/j.jct.2017.05.035},
journal = {Journal of Chemical Thermodynamics},
number = ,
volume = 114,
place = {United States},
year = {Thu Jun 01 00:00:00 EDT 2017},
month = {Thu Jun 01 00:00:00 EDT 2017}
}
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https://doi.org/10.1016/j.jct.2017.05.035
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    Works referencing / citing this record:

    Perrhenate sodalite growth from alkali silicate melts by noble metal catalysis
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