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Title: Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells

Abstract

In this paper, we present a brief summary on the most recent progress in the design of catalysts for electrochemical reduction of oxygen. The main challenge in the wide spread of fuel cell technology is to lower the content of, or even eliminate, Pt and other precious metals in catalysts without sacrificing their performance. Pt-based nanosized catalysts with novel and refined architectures continue to dominate in catalytic performance, and formation of Pt-skin-like surfaces is key to achieving the highest values in activity. Moreover, durability has also been improved in Pt-based systems with addition of Au, which plays an important role in stabilizing the Pt topmost layers against dissolution. However, various carbon-based materials without precious metal have shown improvement in activity and durability and have been explored to serve as catalyst supports. Finally, understanding how the doped elements interact with each other and/or carbon is challenging and necessary in the design of robust fuel cell catalysts.

Authors:
 [1];  [1];  [1];  [1];  [1]
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  1. Argonne National Laboratory, Lemont, IL (United States). Materials Science Division
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office
OSTI Identifier:
1352589
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Annual Review of Chemical and Biomolecular Engineering
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 1947-5438
Publisher:
Annual Reviews
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Carbon; Core-shell; Electrochemistry; Nanoparticle; Platinum; Thin films

Citation Formats

Li, Dongguo, Lv, Haifeng, Kang, Yijin, Markovic, Nenad M., and Stamenkovic, Vojislav R. Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells. United States: N. p., 2016. Web. doi:10.1146/annurev-chembioeng-080615-034526.
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Li, Dongguo, Lv, Haifeng, Kang, Yijin, Markovic, Nenad M., & Stamenkovic, Vojislav R. Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells. United States. https://doi.org/10.1146/annurev-chembioeng-080615-034526
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Li, Dongguo, Lv, Haifeng, Kang, Yijin, Markovic, Nenad M., and Stamenkovic, Vojislav R. Wed . "Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells". United States. https://doi.org/10.1146/annurev-chembioeng-080615-034526. https://www.osti.gov/servlets/purl/1352589.
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@article{osti_1352589,
title = {Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells},
author = {Li, Dongguo and Lv, Haifeng and Kang, Yijin and Markovic, Nenad M. and Stamenkovic, Vojislav R.},
abstractNote = {In this paper, we present a brief summary on the most recent progress in the design of catalysts for electrochemical reduction of oxygen. The main challenge in the wide spread of fuel cell technology is to lower the content of, or even eliminate, Pt and other precious metals in catalysts without sacrificing their performance. Pt-based nanosized catalysts with novel and refined architectures continue to dominate in catalytic performance, and formation of Pt-skin-like surfaces is key to achieving the highest values in activity. Moreover, durability has also been improved in Pt-based systems with addition of Au, which plays an important role in stabilizing the Pt topmost layers against dissolution. However, various carbon-based materials without precious metal have shown improvement in activity and durability and have been explored to serve as catalyst supports. Finally, understanding how the doped elements interact with each other and/or carbon is challenging and necessary in the design of robust fuel cell catalysts.},
doi = {10.1146/annurev-chembioeng-080615-034526},
journal = {Annual Review of Chemical and Biomolecular Engineering},
number = 1,
volume = 7,
place = {United States},
year = {Wed Apr 06 00:00:00 EDT 2016},
month = {Wed Apr 06 00:00:00 EDT 2016}
}
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https://doi.org/10.1146/annurev-chembioeng-080615-034526
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Functionalization of Graphene for Efficient Energy Conversion and Storage
journal, September 2012

Study of electrochemical capacitors utilizing carbon nanotube electrodes
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Hydrogen storage in carbon nanotubes modified by microwave plasma etching and Pd decoration
journal, April 2006

Nitrogen-Doped Carbon Nanotube Aerogels for High-Performance ORR Catalysts
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Advanced zinc-air batteries based on high-performance hybrid electrocatalysts
journal, May 2013

  • Li, Yanguang; Gong, Ming; Liang, Yongye
  • Nature Communications, Vol. 4, Issue 1
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Active and stable carbon nanotube/nanoparticle composite electrocatalyst for oxygen reduction
journal, May 2013

  • Chung, Hoon T.; Won, Jong H.; Zelenay, Piotr
  • Nature Communications, Vol. 4, Issue 1
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Bamboo-like Carbon Nanotube/Fe 3 C Nanoparticle Hybrids and Their Highly Efficient Catalysis for Oxygen Reduction
journal, January 2015

  • Yang, Wenxiu; Liu, Xiangjian; Yue, Xiaoyu
  • Journal of the American Chemical Society, Vol. 137, Issue 4
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Remarkable support effect of SWNTs in Pt catalyst for methanol electrooxidation
journal, December 2005

Enhanced stability of Pt electrocatalysts by nitrogen doping in CNTs for PEM fuel cells
journal, October 2009

Titanium nitride–carbon nanotube core–shell composites as effective electrocatalyst supports for low temperature fuel cells
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Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuelcells
journal, January 2011

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Recent progress in graphene-based nanomaterials as advanced electrocatalysts towards oxygen reduction reaction
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Graphene and its composites with nanoparticles for electrochemical energy applications
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Metal-Free Catalysts for Oxygen Reduction Reaction
journal, May 2015

  • Dai, Liming; Xue, Yuhua; Qu, Liangti
  • Chemical Reviews, Vol. 115, Issue 11
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Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015

  • Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
  • Nature Materials, Vol. 14, Issue 9
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Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

  • Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
  • Nature Communications, Vol. 2, Issue 1
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FePt Nanoparticles Assembled on Graphene as Enhanced Catalyst for Oxygen Reduction Reaction
journal, January 2012

  • Guo, Shaojun; Sun, Shouheng
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Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
journal, August 2011

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Boron-Doped Carbon Nanotubes as Metal-Free Electrocatalysts for the Oxygen Reduction Reaction
journal, June 2011

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Sulfur-Doped Graphene as an Efficient Metal-free Cathode Catalyst for Oxygen Reduction
journal, December 2011

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Phosphorus-Doped Ordered Mesoporous Carbons with Different Lengths as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction in Alkaline Media
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Phosphorus-Doped Graphite Layers with High Electrocatalytic Activity for the O2 Reduction in an Alkaline Medium
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BCN Graphene as Efficient Metal-Free Electrocatalyst for the Oxygen Reduction Reaction
journal, March 2012

  • Wang, Shuangyin; Zhang, Lipeng; Xia, Zhenhai
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A Highly Active and Support-Free Oxygen Reduction Catalyst Prepared from Ultrahigh-Surface-Area Porous Polyporphyrin
journal, June 2013

  • Yuan, Shengwen; Shui, Jiang-Lan; Grabstanowicz, Lauren
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Highly Efficient Non-Precious Metal Electrocatalysts Prepared from One-Pot Synthesized Zeolitic Imidazolate Frameworks
journal, December 2013

  • Zhao, Dan; Shui, Jiang-Lan; Grabstanowicz, Lauren R.
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Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network
journal, August 2015

  • Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 34
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    Works referencing / citing this record:

    3D Carbon Materials for Efficient Oxygen and Hydrogen Electrocatalysis
    journal, November 2019

    • Jorge, Ana Belen; Jervis, Rhodri; Periasamy, Arun Prakash
    • Advanced Energy Materials, Vol. 10, Issue 11
    • DOI: 10.1002/aenm.201902494

    Ferrocene-based porous organic polymer derived high-performance electrocatalysts for oxygen reduction
    journal, January 2017

    • Zhou, Baolong; Liu, Liangzhen; Cai, Pingwei
    • J. Mater. Chem. A, Vol. 5, Issue 42
    • DOI: 10.1039/c7ta06515a

    Iron-/Nitrogen-Doped Electrocatalytically Active Carbons for the Oxygen Reduction Reaction with Low Amounts of Cobalt
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    • Pimonova, Yulia A.; Budnyk, Andriy P.; Yohannes, Weldegebriel
    • ACS Omega, Vol. 4, Issue 22
    • DOI: 10.1021/acsomega.9b01534

    Palladium single atoms supported by interwoven carbon nanotube and manganese oxide nanowire networks for enhanced electrocatalysis
    journal, January 2018

    • Xiang, Weikai; Zhao, Yonghui; Jiang, Zheng
    • Journal of Materials Chemistry A, Vol. 6, Issue 46
    • DOI: 10.1039/c8ta09034c

    Carbon nanotube@ZIF–derived Fe-N-doped carbon electrocatalysts for oxygen reduction and evolution reactions
    journal, June 2019

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