Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates
Abstract
The metal-insulator transitions and the intriguing physical properties of rare-earth perovskite nickelates have attracted considerable attention in recent years. However, a complete understanding of these materials remains elusive. Here, taking a NdNiO3 thin film as a representative example, we utilize a combination of x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) spectroscopies to resolve important aspects of the complex electronic structure of the rare-earth nickelates. The unusual coexistence of bound and continuum excitations observed in the RIXS spectra provides strong evidence for the abundance of oxygen 2p holes in the ground state of these materials. Using cluster calculations and Anderson impurity model interpretation, we show that these distinct spectral signatures arise from a Ni 3d8 configuration along with holes in the oxygen 2p valence band, confirming suggestions that these materials do not obey a “conventional” positive charge-transfer picture, but instead exhibit a negative charge-transfer energy, in line with recent models interpreting the metal to insulator transition in terms of bond disproportionation.
- Authors:
-
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Univ. of Geneva (Switzerland). Dept. of Quantum Matter Physics
- Univ. of British Columbia, Vancouver, BC (Canada). Dept. of Physics and Astronomy; Univ. of British Columbia, Vancouver, BC (Canada). Quantum Matter Inst.
- Univ. of Geneva (Switzerland). Dept. of Quantum Matter Physics
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics, and Inst. of Physics
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology
- Univ. of Geneva (Switzerland). Dept. of Quantum Matter Physics; University College London, London (United Kingdom). London Centre for Nanotechnology and Dept. of Physics and Astronomy
- Univ. of British Columbia, Vancouver, BC (Canada). Dept. of Physics and Astronomy
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1341699
- Report Number(s):
- BNL-113446-2017-JA
Journal ID: ISSN 2041-1723
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 7; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE
Citation Formats
Bisogni, Valentina, Catalano, Sara, Green, Robert J., Gibert, Marta, Scherwitzl, Raoul, Huang, Yaobo, Strocov, Vladimir N., Zubko, Pavlo, Balandeh, Shadi, Triscone, Jean-Marc, Sawatzky, George, and Schmitt, Thorsten. Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates. United States: N. p., 2016.
Web. doi:10.1038/ncomms13017.
Bisogni, Valentina, Catalano, Sara, Green, Robert J., Gibert, Marta, Scherwitzl, Raoul, Huang, Yaobo, Strocov, Vladimir N., Zubko, Pavlo, Balandeh, Shadi, Triscone, Jean-Marc, Sawatzky, George, & Schmitt, Thorsten. Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates. United States. https://doi.org/10.1038/ncomms13017
Bisogni, Valentina, Catalano, Sara, Green, Robert J., Gibert, Marta, Scherwitzl, Raoul, Huang, Yaobo, Strocov, Vladimir N., Zubko, Pavlo, Balandeh, Shadi, Triscone, Jean-Marc, Sawatzky, George, and Schmitt, Thorsten. Tue .
"Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates". United States. https://doi.org/10.1038/ncomms13017. https://www.osti.gov/servlets/purl/1341699.
@article{osti_1341699,
title = {Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates},
author = {Bisogni, Valentina and Catalano, Sara and Green, Robert J. and Gibert, Marta and Scherwitzl, Raoul and Huang, Yaobo and Strocov, Vladimir N. and Zubko, Pavlo and Balandeh, Shadi and Triscone, Jean-Marc and Sawatzky, George and Schmitt, Thorsten},
abstractNote = {The metal-insulator transitions and the intriguing physical properties of rare-earth perovskite nickelates have attracted considerable attention in recent years. However, a complete understanding of these materials remains elusive. Here, taking a NdNiO3 thin film as a representative example, we utilize a combination of x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) spectroscopies to resolve important aspects of the complex electronic structure of the rare-earth nickelates. The unusual coexistence of bound and continuum excitations observed in the RIXS spectra provides strong evidence for the abundance of oxygen 2p holes in the ground state of these materials. Using cluster calculations and Anderson impurity model interpretation, we show that these distinct spectral signatures arise from a Ni 3d8 configuration along with holes in the oxygen 2p valence band, confirming suggestions that these materials do not obey a “conventional” positive charge-transfer picture, but instead exhibit a negative charge-transfer energy, in line with recent models interpreting the metal to insulator transition in terms of bond disproportionation.},
doi = {10.1038/ncomms13017},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {Tue Oct 11 00:00:00 EDT 2016},
month = {Tue Oct 11 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 144 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Structural, magnetic and electronic properties of perovskites (R = rare earth)
journal, February 1997
- Medarde, María Luisa
- Journal of Physics: Condensed Matter, Vol. 9, Issue 8
Systematic study of insulator-metal transitions in perovskites RNiO3 (R=Pr,Nd,Sm,Eu) due to closing of charge-transfer gap
journal, April 1992
- Torrance, J.; Lacorre, P.; Nazzal, A.
- Physical Review B, Vol. 45, Issue 14
Progress in perovskite nickelate research
journal, July 2008
- Catalan, G.
- Phase Transitions, Vol. 81, Issue 7-8
Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates
journal, March 2014
- Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M.
- Nature Physics, Vol. 10, Issue 4
Sudden Appearance of an Unusual Spin Density Wave At the Metal-Insulator Transition in the Perovskites RNiO 3 (R = Pr, Nd)
journal, October 1992
- García-Muñoz, J. L.; Rodríguez-Carvajal, J.; Lacorre, P.
- Europhysics Letters (EPL), Vol. 20, Issue 3
Charge Disproportionation in Perovskites: Simultaneous Metal-Insulator and Structural Transition in
journal, May 1999
- Alonso, J. A.; García-Muñoz, J. L.; Fernández-Díaz, M. T.
- Physical Review Letters, Vol. 82, Issue 19
Heterointerface engineered electronic and magnetic phases of NdNiO3 thin films
journal, November 2013
- Liu, Jian; Kargarian, Mehdi; Kareev, Mikhail
- Nature Communications, Vol. 4, Issue 1
Electric-Field Control of the Metal-Insulator Transition in Ultrathin NdNiO3 Films
journal, October 2010
- Scherwitzl, Raoul; Zubko, Pavlo; Lezama, I. Gutierrez
- Advanced Materials, Vol. 22, Issue 48
Metal-Insulator Transition in Ultrathin Films
journal, June 2011
- Scherwitzl, R.; Gariglio, S.; Gabay, M.
- Physical Review Letters, Vol. 106, Issue 24
Low-dimensional Mott material: Transport in ultrathin epitaxial LaNiO3 films
journal, February 2010
- Son, Junwoo; Moetakef, Pouya; LeBeau, James M.
- Applied Physics Letters, Vol. 96, Issue 6
Orbital Order and Possible Superconductivity in Superlattices
journal, January 2008
- Chaloupka, Jiří; Khaliullin, Giniyat
- Physical Review Letters, Vol. 100, Issue 1
Exchange bias in LaNiO3–LaMnO3 superlattices
journal, January 2012
- Gibert, Marta; Zubko, Pavlo; Scherwitzl, Raoul
- Nature Materials, Vol. 11, Issue 3
Asymmetric Orbital-Lattice Interactions in Ultrathin Correlated Oxide Films
journal, September 2011
- Chakhalian, J.; Rondinelli, J. M.; Liu, Jian
- Physical Review Letters, Vol. 107, Issue 11
Strain and composition dependence of orbital polarization in nickel oxide superlattices
journal, September 2013
- Wu, M.; Benckiser, E.; Haverkort, M. W.
- Physical Review B, Vol. 88, Issue 12
Orbital reflectometry of oxide heterostructures
journal, February 2011
- Benckiser, Eva; Haverkort, Maurits W.; Brück, Sebastian
- Nature Materials, Vol. 10, Issue 3
Band gaps and electronic structure of transition-metal compounds
journal, July 1985
- Zaanen, J.; Sawatzky, G. A.; Allen, J. W.
- Physical Review Letters, Vol. 55, Issue 4
R perovskites ( R =Pr,Nd): Nickel valence and the metal-insulator transition investigated by x-ray-absorption spectroscopy
journal, December 1992
- Medarde, M.; Fontaine, A.; García-Muñoz, J. L.
- Physical Review B, Vol. 46, Issue 23
Electronic structure of studied by photoemission and x-ray-absorption spectroscopy: Band gap and orbital ordering
journal, November 1995
- Mizokawa, T.; Fujimori, A.; Arima, T.
- Physical Review B, Vol. 52, Issue 19
Electronic structure and metal-insulator transition in
journal, March 2002
- Abbate, M.; Zampieri, G.; Prado, F.
- Physical Review B, Vol. 65, Issue 15
Electronic structure of : An in situ soft x-ray photoemission and absorption study
journal, October 2007
- Horiba, K.; Eguchi, R.; Taguchi, M.
- Physical Review B, Vol. 76, Issue 15
Origin of the band gap in the negative charge-transfer-energy compound
journal, September 1991
- Mizokawa, T.; Namatame, H.; Fujimori, A.
- Physical Review Letters, Vol. 67, Issue 12
Low-energy description of the metal-insulator transition in the rare-earth nickelates
journal, February 2015
- Subedi, Alaska; Peil, Oleg E.; Georges, Antoine
- Physical Review B, Vol. 91, Issue 7
Role of magnetic and orbital ordering at the metal-insulator transition in
journal, March 2006
- Scagnoli, V.; Staub, U.; Mulders, A. M.
- Physical Review B, Vol. 73, Issue 10
Charge Ordering as Alternative to Jahn-Teller Distortion
journal, April 2007
- Mazin, I. I.; Khomskii, D. I.; Lengsdorf, R.
- Physical Review Letters, Vol. 98, Issue 17
Charge disproportionation in perovskites ( earth) from high-resolution x-ray absorption spectroscopy
journal, December 2009
- Medarde, M.; Dallera, C.; Grioni, M.
- Physical Review B, Vol. 80, Issue 24
Direct Observation of Charge Order in an Epitaxial Film
journal, March 2002
- Staub, U.; Meijer, G. I.; Fauth, F.
- Physical Review Letters, Vol. 88, Issue 12
Electric-field tuning of the metal-insulator transition in ultrathin films of LaNiO3
journal, November 2009
- Scherwitzl, R.; Zubko, P.; Lichtensteiger, C.
- Applied Physics Letters, Vol. 95, Issue 22
Magnetic and electronic properties of RNiO 3 (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction
journal, January 2011
- Bodenthin, Y.; Staub, U.; Piamonteze, C.
- Journal of Physics: Condensed Matter, Vol. 23, Issue 3
Evolution of electronic structure across the rare-earth RNiO3 series
journal, April 2016
- Freeland, John W.; van Veenendaal, Michel; Chakhalian, Jak
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 208
Resonant inelastic x-ray scattering spectra for electrons in solids
journal, February 2001
- Kotani, Akio; Shin, Shik
- Reviews of Modern Physics, Vol. 73, Issue 1
Resonant inelastic x-ray scattering studies of elementary excitations
journal, June 2011
- Ament, Luuk J. P.; van Veenendaal, Michel; Devereaux, Thomas P.
- Reviews of Modern Physics, Vol. 83, Issue 2
Electronic structure studies of by soft x-ray emission spectroscopy: Band-like and excitonic vanadium states
journal, March 2004
- Schmitt, T.; Duda, L. -C.; Matsubara, M.
- Physical Review B, Vol. 69, Issue 12
Localized and delocalized Ti 3 carriers in LaAlO /SrTiO superlattices revealed by resonant inelastic x-ray scattering
journal, May 2011
- Zhou, Ke-Jin; Radovic, Milan; Schlappa, Justine
- Physical Review B, Vol. 83, Issue 20
NiO as a test case for high resolution resonant inelastic soft x-ray scattering
journal, August 2005
- Ghiringhelli, G.; Matsubara, M.; Dallera, C.
- Journal of Physics: Condensed Matter, Vol. 17, Issue 35
Optical spectroscopy of the metal-insulator transition in
journal, February 1995
- Katsufuji, T.; Okimoto, Y.; Arima, T.
- Physical Review B, Vol. 51, Issue 8
Mott Physics near the Insulator-To-Metal Transition in
journal, October 2011
- Stewart, M. K.; Liu, Jian; Kareev, M.
- Physical Review Letters, Vol. 107, Issue 17
Tuning the metal-insulator transition in heterostructures via Fermi surface instability and spin fluctuations
journal, July 2015
- Dhaka, R. S.; Das, Tanmoy; Plumb, N. C.
- Physical Review B, Vol. 92, Issue 3
Orbital Engineering in Nickelate Heterostructures Driven by Anisotropic Oxygen Hybridization rather than Orbital Energy Levels
journal, September 2016
- Fabbris, G.; Meyers, D.; Okamoto, J.
- Physical Review Letters, Vol. 117, Issue 14
Intra- versus inter-site electronic excitations in NdNiO3 by resonant inelastic ultra-soft X-ray scattering at Ni 3p edge
journal, September 2005
- Butorin, S. M.; Såthe, C.; Agui, A.
- Solid State Communications, Vol. 135, Issue 11-12
Ordering and criticality in an underscreened Kondo chain
journal, May 2013
- Ko, Wing-Ho; Jiang, Hong-Chen; Rau, Jeffrey G.
- Physical Review B, Vol. 87, Issue 20
Key role of lattice symmetry in the metal-insulator transition of NdNiO3 films
journal, April 2016
- Zhang, Jack Y.; Kim, Honggyu; Mikheev, Evgeny
- Scientific Reports, Vol. 6, Issue 1
High-resolution soft X-ray beamline ADRESS at the Swiss Light Source for resonant inelastic X-ray scattering and angle-resolved photoelectron spectroscopies
journal, July 2010
- Strocov, V. N.; Schmitt, T.; Flechsig, U.
- Journal of Synchrotron Radiation, Vol. 17, Issue 5
SAXES, a high resolution spectrometer for resonant x-ray emission in the 400–1600eV energy range
journal, November 2006
- Ghiringhelli, G.; Piazzalunga, A.; Dallera, C.
- Review of Scientific Instruments, Vol. 77, Issue 11
Asymmetric orbital-lattice interactions in ultra-thin correlated oxide films
text, January 2010
- Chakhalian, J.; Rondinelli, J. M.; Liu, Jian
- arXiv
Origins of bad metal conductivity and the insulator-metal transition in the rare-earth nickelates
text, January 2013
- Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M.
- arXiv
Heterointerface engineered electronic and magnetic phases of NdNiO3 thin films
text, January 2013
- Liu, Jian; Kargarian, Mehdi; Kareev, Mikhail
- arXiv
Evolution of Electronic Structure Across the Rare-Earth RNiO$_3$ Series
preprint, January 2015
- Freeland, John W.; van Veenendaal, Michel; Chakhalian, Jak
- arXiv
Tuning the metal-insulator transition in NdNiO3 heterostructures via Fermi surface instability and spin-fluctuations
text, January 2015
- Dhaka, R. S.; Das, Tanmoy; Plumb, N. C.
- arXiv
Orbital engineering in nickelate heterostructures driven by anisotropic oxygen hybridization rather than orbital energy levels
text, January 2016
- Fabbris, G.; Meyers, D.; Okamoto, J.
- arXiv
Spin and charge ordering in self-doped Mott insulators
text, January 1999
- Mizokawa, T.; Khomskii, D. I.; Sawatzky, G. A.
- arXiv
Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates
journal, March 2014
- Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M.
- Nature Physics, Vol. 10, Issue 4
Key role of lattice symmetry in the metal-insulator transition of NdNiO3 films
journal, April 2016
- Zhang, Jack Y.; Kim, Honggyu; Mikheev, Evgeny
- Scientific Reports, Vol. 6, Issue 1
Electric-field tuning of the metal-insulator transition in ultrathin films of LaNiO3
journal, November 2009
- Scherwitzl, R.; Zubko, P.; Lichtensteiger, C.
- Applied Physics Letters, Vol. 95, Issue 22
Structural, magnetic and electronic properties of perovskites (R = rare earth)
journal, February 1997
- Medarde, María Luisa
- Journal of Physics: Condensed Matter, Vol. 9, Issue 8
Anomalous variation of phonon Raman intensities near the metal-to-Mott-insulator transition in titanium oxide systems
journal, July 1994
- Katsufuji, T.; Tokura, Y.
- Physical Review B, Vol. 50, Issue 4
Spin and charge ordering in self-doped Mott insulators
journal, May 2000
- Mizokawa, T.; Khomskii, D. I.; Sawatzky, G. A.
- Physical Review B, Vol. 61, Issue 17
Observation of Two Nondispersive Magnetic Excitations in NiO by Resonant Inelastic Soft-X-Ray Scattering
journal, January 2009
- Ghiringhelli, G.; Piazzalunga, A.; Dallera, C.
- Physical Review Letters, Vol. 102, Issue 2
Ultrafast Strain Engineering in Complex Oxide Heterostructures
journal, March 2012
- Caviglia, A. D.; Scherwitzl, R.; Popovich, P.
- Physical Review Letters, Vol. 108, Issue 13
Metal-Insulator Transition and Orbital Reconstruction in Mott-Type Quantum Wells Made of
journal, September 2012
- Liu, Jian; Kareev, M.; Meyers, D.
- Physical Review Letters, Vol. 109, Issue 10
Theory of the Magnetic and Metal-Insulator Transitions in Bulk and Layered Structures
journal, March 2013
- Lau, Bayo; Millis, Andrew J.
- Physical Review Letters, Vol. 110, Issue 12
Charge Disproportionation without Charge Transfer in the Rare-Earth-Element Nickelates as a Possible Mechanism for the Metal-Insulator Transition
journal, March 2014
- Johnston, Steve; Mukherjee, Anamitra; Elfimov, Ilya
- Physical Review Letters, Vol. 112, Issue 10
Orbital Engineering in Symmetry-Breaking Polar Heterostructures
journal, January 2015
- Disa, Ankit S.; Kumah, Divine P.; Malashevich, Andrei
- Physical Review Letters, Vol. 114, Issue 2
Heterointerface engineered electronic and magnetic phases of NdNiO3 thin films
text, January 2013
- Liu, Jian; Kargarian, Mehdi; Kareev, Mikhail
- arXiv
Works referencing / citing this record:
Heteroanionic Materials by Design: Progress Toward Targeted Properties
journal, March 2019
- Harada, Jaye K.; Charles, Nenian; Poeppelmeier, Kenneth R.
- Advanced Materials, Vol. 31, Issue 19
Electron‐Doping Mottronics in Strongly Correlated Perovskite
journal, December 2019
- Chen, Jikun; Mao, Wei; Gao, Lei
- Advanced Materials, Vol. 32, Issue 6
Structurally triggered metal-insulator transition in rare-earth nickelates
journal, November 2017
- Mercy, Alain; Bieder, Jordan; Íñiguez, Jorge
- Nature Communications, Vol. 8, Issue 1
Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates
journal, January 2018
- Shamblin, Jacob; Heres, Maximilian; Zhou, Haidong
- Nature Communications, Vol. 9, Issue 1
Electronic localization in CaVO3 films via bandwidth control
journal, February 2019
- McNally, Daniel E.; Lu, Xingye; Pelliciari, Jonathan
- npj Quantum Materials, Vol. 4, Issue 1
Electronic structure of the parent compound of superconducting infinite-layer nickelates
journal, January 2020
- Hepting, M.; Li, D.; Jia, C. J.
- Nature Materials, Vol. 19, Issue 4
Complex magnetic order in nickelate slabs
journal, July 2018
- Hepting, M.; Green, R. J.; Zhong, Z.
- Nature Physics, Vol. 14, Issue 11
Transmission zone plates as analyzers for efficient parallel 2D RIXS-mapping
journal, August 2017
- Marschall, Felix; Yin, Zhong; Rehanek, Jens
- Scientific Reports, Vol. 7, Issue 1
Mott Transition and Magnetism in Rare Earth Nickelates and its Fingerprint on the X-ray Scattering
journal, September 2017
- Haule, Kristjan; Pascut, Gheorghe L.
- Scientific Reports, Vol. 7, Issue 1
Unexpected 3+ valence of iron in FeO2, a geologically important material lying “in between” oxides and peroxides
journal, October 2017
- Streltsov, Sergey S.; Shorikov, Alexey O.; Skornyakov, Sergey L.
- Scientific Reports, Vol. 7, Issue 1
Fingerprints of an orbital-selective Mott phase in the block magnetic state of BaFe2Se3 ladders
journal, June 2019
- Patel, N. D.; Nocera, A.; Alvarez, G.
- Communications Physics, Vol. 2, Issue 1
Unifying double flame spray pyrolysis with lanthanum doping to restrict cobalt–aluminate formation in Co/Al 2 O 3 catalysts for the dry reforming of methane
journal, January 2019
- Horlyck, Jonathan; Pokhrel, Suman; Lovell, Emma
- Catalysis Science & Technology, Vol. 9, Issue 18
Metal–insulator-transition engineering by modulation tilt-control in perovskite nickelates for room temperature optical switching
journal, September 2018
- Liao, Zhaoliang; Gauquelin, Nicolas; Green, Robert J.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 38
Carrier localization in perovskite nickelates from oxygen vacancies
journal, October 2019
- Kotiuga, Michele; Zhang, Zhen; Li, Jiarui
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 44
Ultrafast electron and spin dynamics of strongly correlated NdNiO 3
journal, December 2018
- Liang, Weizheng; Hou, Huaming; Lin, Yuan
- Journal of Physics D: Applied Physics, Vol. 52, Issue 7
Electronic structure of Pr 2 MnNiO 6 from x-ray photoemission, absorption and density functional theory
journal, October 2018
- Balasubramanian, Padmanabhan; Joshi, Shalik Ram; Yadav, Ruchika
- Journal of Physics: Condensed Matter, Vol. 30, Issue 43
Fine structure of metal–insulator transition in EuO resolved by doping engineering
journal, March 2018
- Averyanov, Dmitry V.; Parfenov, Oleg E.; Tokmachev, Andrey M.
- Nanotechnology, Vol. 29, Issue 19
Rare-earth nickelates R NiO 3 : thin films and heterostructures
journal, February 2018
- Catalano, S.; Gibert, M.; Fowlie, J.
- Reports on Progress in Physics, Vol. 81, Issue 4
Conductivity noise across temperature-driven transitions of rare-earth nickelate heterostructures
journal, September 2019
- Daptary, Gopi Nath; Kumar, Siddharth; Kareev, M.
- Physical Review B, Vol. 100, Issue 12
Mass divergence type metal-insulator transition in charge transfer rare-earth nickelates
journal, September 2019
- Santhosh Kumar, K.; Phanindra, E. V.; Rana, D. S.
- Physical Review B, Vol. 100, Issue 12
Distortion mode anomalies in bulk : Illustrating the potential of symmetry-adapted distortion mode analysis for the study of phase transitions
journal, November 2019
- Gawryluk, D. J.; Klein, Y. M.; Shang, T.
- Physical Review B, Vol. 100, Issue 20
Possible absence of trimeron correlations above the Verwey temperature in
journal, February 2020
- Elnaggar, H.; Wang, R.; Lafuerza, S.
- Physical Review B, Vol. 101, Issue 8
Bond disproportionation and dynamical charge fluctuations in the perovskite rare-earth nickelates
journal, November 2016
- Green, R. J.; Haverkort, M. W.; Sawatzky, G. A.
- Physical Review B, Vol. 94, Issue 19
High-resolution resonant inelastic extreme ultraviolet scattering from orbital and spin excitations in a Heisenberg antiferromagnet
journal, November 2017
- Caretta, Antonio; Dell'Angela, Martina; Chuang, Yi-De
- Physical Review B, Vol. 96, Issue 18
Phenomenological three-orbital spin-fermion model for cuprates
journal, July 2018
- Hussein, Mostafa Sherif Derbala Aly; Daghofer, Maria; Dagotto, Elbio
- Physical Review B, Vol. 98, Issue 3
Epitaxial strain modulated electronic properties of interface controlled nickelate superlattices
journal, July 2018
- Middey, S.; Meyers, D.; Ojha, Shashank Kumar
- Physical Review B, Vol. 98, Issue 4
Emergent -axis magnetic helix in manganite-nickelate superlattices
journal, November 2018
- Fabbris, G.; Jaouen, N.; Meyers, D.
- Physical Review B, Vol. 98, Issue 18
Valence transition model of the pseudogap, charge order, and superconductivity in electron-doped and hole-doped copper oxides
journal, November 2018
- Mazumdar, Sumit
- Physical Review B, Vol. 98, Issue 20
Counter-thermal flow of holes in high-mobility thin films
journal, January 2019
- Liu, Changjiang; Wrobel, Friederike; Hoffman, Jason D.
- Physical Review B, Vol. 99, Issue 4
Anomalous electron transport in epitaxial films
journal, June 2019
- Ojha, Shashank Kumar; Ray, Sujay; Das, Tanmoy
- Physical Review B, Vol. 99, Issue 23
Doping Dependence of Collective Spin and Orbital Excitations in the Spin-1 Quantum Antiferromagnet Observed by X Rays
journal, April 2017
- Fabbris, G.; Meyers, D.; Xu, L.
- Physical Review Letters, Vol. 118, Issue 15
Charge-Spin Correlation in van der Waals Antiferromagnet
journal, March 2018
- Kim, So Yeun; Kim, Tae Yun; Sandilands, Luke J.
- Physical Review Letters, Vol. 120, Issue 13
Disentangled Cooperative Orderings in Artificial Rare-Earth Nickelates
journal, April 2018
- Middey, S.; Meyers, D.; Kareev, M.
- Physical Review Letters, Vol. 120, Issue 15
Continuum Charge Excitations in High-Valence Transition-Metal Oxides Revealed by Resonant Inelastic X-Ray Scattering
journal, September 2018
- Hariki, Atsushi; Winder, Mathias; Kuneš, Jan
- Physical Review Letters, Vol. 121, Issue 12
Hybridization-Switching Induced Mott Transition in Perovskites
journal, January 2019
- Paul, Atanu; Mukherjee, Anamitra; Dasgupta, Indra
- Physical Review Letters, Vol. 122, Issue 1
Antiferromagnetic defect structure in single crystals
journal, June 2018
- Wang, Bi-Xia; Rosenkranz, S.; Rui, X.
- Physical Review Materials, Vol. 2, Issue 6
High-density electron doping of from first principles
journal, November 2019
- Kotiuga, Michele; Rabe, Karin M.
- Physical Review Materials, Vol. 3, Issue 11
Site-Selective Probe of Magnetic Excitations in Rare-Earth Nickelates Using Resonant Inelastic X-ray Scattering
journal, July 2018
- Lu, Y.; Betto, D.; Fürsich, K.
- Physical Review X, Vol. 8, Issue 3
Factors Controlling the Redox Activity of Oxygen in Perovskites: From Theory to Application for Catalytic Reactions
journal, May 2017
- Yang, Chunzhen; Grimaud, Alexis
- Catalysts, Vol. 7, Issue 5
High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3
journal, June 2019
- Zheng, Hong; Zhang, Junjie; Wang, Bixia
- Crystals, Vol. 9, Issue 7
Complex magnetic order in nickelate slabs
text, January 2018
- Hepting, M.; Green, R. J.; Zhong, Z.
- Nature Publishing Group
High-resolution resonant inelastic extreme ultraviolet scattering from orbital and spin excitations in a Heisenberg antiferromagnet
text, January 2017
- Caretta, Antonio; Dell'Angela, Martina; Chuang, Yi-De
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Site-Selective Probe of Magnetic Excitations in Rare-Earth Nickelates Using Resonant Inelastic X-ray Scattering
text, January 2018
- Lu, Y.; Betto, D.; Fürsich, K.
- Karlsruhe
Transmission zone plates as analyzers for efficient parallel 2D RIXS-mapping
text, January 2017
- Marschall, Felix; Yin, Zhong; Rehanek, Jens
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Electronic localization in CaVO3 films via bandwidth control
text, January 2019
- McNally, Daniel E.; Lu, Xingye; Pelliciari, Jonathan
- ETH Zurich
Bond disproportionation and dynamical charge fluctuations in the perovskite rare earth nickelates
text, January 2016
- Green, Robert J.; Haverkort, Maurits W.; Sawatzky, George A.
- arXiv
Mott Transition and Magnetism in Rare Earth Nickelates and its Fingerprint on the X-ray Scattering
text, January 2017
- Haule, Kristjan; Pascut, Gheorghe L.
- arXiv
Electronic structure of Pr2MnNiO6 from x-ray photoemission, absorption and density functional theory
text, January 2017
- Balasubramanian, Padmanabhan; Joshi, Shalik Ram; Yadav, Ruchika
- arXiv
Continuum Charge Excitations in High-Valence Transition-Metal Oxides Revealed by Resonant Inelastic X-ray Scattering
text, January 2018
- Hariki, Atsushi; Winder, Mathias; Kuneš, Jan
- arXiv
Phenomenological Three-Orbital Spin-Fermion Model for Cuprates
text, January 2018
- Hussein, Mostafa Sherif Derbala Aly; Daghofer, Maria; Dagotto, Elbio
- arXiv
Emergent c-axis magnetic helix in manganite-nickelate superlattices
text, January 2018
- Fabbris, G.; Jaouen, N.; Meyers, D.
- arXiv
Epitaxial strain modulated electronic properties of interface controlled nickelate superlattice
text, January 2018
- Middey, S.; Meyers, D.; Ojha, Shashank Kumar
- arXiv
Fingerprints of an Exotic Orbital-Selective Mott Phase in the Block Magnetic State of BaFe$_2$Se$_3$ Ladders
text, January 2018
- Patel, Niravkumar D.; Nocera, Alberto; Alvarez, Gonzalo
- arXiv
Complex magnetic order in nickelate slabs
text, January 2019
- Hepting, Matthias; Green, Robert J.; Zhong, Zhicheng
- arXiv
High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3
text, January 2019
- Zheng, Hong; Zhang, Junjie; Wang, Bixia
- arXiv
Conductivity noise across temperature driven transitions of rare-earth nickelate heterostructures
text, January 2019
- Daptary, Gopi Nath; Kumar, Siddharth; Kareev, M.
- arXiv
Electronic Localization in CaVO3 Films via Bandwidth Control
text, January 2019
- McNally, Daniel E.; Lu, Xingye; Pelliciari, Jonathan
- arXiv
Electronic structure of the parent compound of superconducting infinite-layer nickelates
text, January 2019
- Hepting, M.; Li, D.; Jia, C. J.
- arXiv
Structurally triggered metal-insulator transition in rare-earth nickelates
journal, November 2017
- Mercy, Alain; Bieder, Jordan; Íñiguez, Jorge
- Nature Communications, Vol. 8, Issue 1
Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates
journal, January 2018
- Shamblin, Jacob; Heres, Maximilian; Zhou, Haidong
- Nature Communications, Vol. 9, Issue 1
Transmission zone plates as analyzers for efficient parallel 2D RIXS-mapping
journal, August 2017
- Marschall, Felix; Yin, Zhong; Rehanek, Jens
- Scientific Reports, Vol. 7, Issue 1
Mott Transition and Magnetism in Rare Earth Nickelates and its Fingerprint on the X-ray Scattering
journal, September 2017
- Haule, Kristjan; Pascut, Gheorghe L.
- Scientific Reports, Vol. 7, Issue 1
Finite-temperature phase diagram of (111) nickelate bilayers
journal, September 2018
- Janson, Oleg; Held, Karsten
- Physical Review B, Vol. 98, Issue 11
Observation of an antiferromagnetic quantum critical point in high-purity LaNiO$_3$
text, January 2020
- Liu, Changjiang; Humbert, Vincent F. C.; Bretz-Sullivan, Terence
- arXiv
Site-Selective Probe of Magnetic Excitations in Rare-Earth Nickelates Using Resonant Inelastic X-ray Scattering
text, January 2018
- Lu, Y.; Betto, D.; Fürsich, K.
- Karlsruhe